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Elsevier

Books in Chemistry

Chemistry topic areas include: physical and theoretical, computational, organic, organometallic and inorganic, pharmaceutical and medicinal, analytical and bioanalytical, nuclear, general, nanochemistry, geochemistry, materials and polymer, as well as environmental, green and sustainable chemistry.

  • Solubility Data Series

    Carbon Monoxide
    • 1st Edition
    • Volume 43
    • R.W. Cargill
    • English
    This volume in the Solubility Data Series contains tabulated collections and critical evaluations of original data for the solubility of carbon monoxide in a variety of liquid solvents. The solvents include water, aqueous and non-aqueous salt solutions, a variety of hydrocarbons, a variety of oxygen-containing, halogen-containing, sulfur-containing, and nitrogen-containing organic compounds, and also some biological fluids with which carbon monoxide has an important interaction. The data were gathered from a search of the world's chemical literature through to the end of 1988, and make up a unique and valuable historical survey of the solubility of carbon monoxide. Their publication is timely in view of current concern about carbon monoxide as an atmospheric pollutant, and in view of the role which carbon monoxide is likely to play in the future, as chemical feedstocks may have to change in response to supply and demand patterns, and as alternative energy sources are developed, especially coal gasification technology. For all of these applications, and for numerous others, this volume of well documented and critically evaluated gas solubility data will be of tremendous benefit.

  • Organic Functional Group Analysis

    Theory and Development
    • 1st Edition
    • George H. Schenk
    • R. J. Magee
    • English
    Organic Functional Group Analysis: Theory and Development details the methods the best represent the progress in functional group analysis. In the second part, the title presents several papers that cover various areas in the field of functional group analysis. The text first covers the oximation of acetone and furfural, and then proceeds to tackling the utility of non-aqueous titrations. The selection also discusses how the determination of the per cent enol provides information which complements the per cent purity found by non-aqueous titration. Next, the title discusses the analytical advantages in using base catalysis and acid catalysis with the same reagent. The last chapters present useful functional group methods which have received impetus from contemporary research. The book will be of great use to students, researchers, and practitioners of chemistry related disciplines.

  • Application of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry

    International Series in Organic Chemistry
    • 2nd Edition
    • L. M. Jackman + 1 more
    • D. H. R. Barton + 1 more
    • English
    Applications of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry, Second Edition focuses on the applications of nuclear magnetic resonance spectroscopy to problems in organic chemistry and the theories involved in this kind of spectroscopy. The book first discusses the theory of nuclear magnetic resonance, including dynamic and magnetic properties of atomic nuclei, nuclear resonance, and relaxation process. The manuscript also examines the experimental method. Topics include experimental factors that influence resolution and the shapes of absorption lines; measurement of line positions and identification of the chemical shift; and measurement of intensities. The text reviews the theories of chemical effects in nuclear magnetic resonance spectroscopy and spin-spin multiplicity and the theory and applications of multiple irradiation. The book also tackles the theory of chemical shift, including the classification of shielding effects, local diamagnetic proton shielding, solvent effects, and contact shifts. The publication is a dependable source of data for readers interested in the applications of nuclear magnetic resonance spectroscopy.

  • Boron Fluoride and Its Compounds as Catalysts in Organic Chemistry

    International Series of Monographs on Organic Chemistry
    • 1st Edition
    • A. V. Topchiev + 2 more
    • W. Doering + 1 more
    • English
    Boron Fluoride and Its Compounds as Catalysts in Organic Chemistry deals with the concerns associated with the utilization of boron fluoride as a catalyst. The title provides a comprehensive account of boron fluoride, such as its properties, compounds, and related methodologies. The coverage of the text includes the preparation and recovery of boron fluoride, along with the physical and chemical properties. The selection also covers various boron fluoride compounds and their respective reaction to various processes, such as alkylation, polymerization, and nitration. The book will be of great interest to students, researchers, and practitioners of organic chemistry.

  • Krypton, Xenon & Radon

    • 1st Edition
    • Volume 2
    • H. L. Clever
    • English
    Solubility Data Series, Volume 2: Krypton, Xenon, and Radon – Gas Solubilities is a three-chapter text that presents the solubility data of various forms of the title compounds in different substrates. This series emerged from the fundamental trend of the Solubility Data Project, which is toward integration of secondary and tertiary services to produce in-depth critical analysis and evaluation. Each chapter deals with the experimental solubility data of the noble gases in several substrates, including water, salt solutions, organic compounds, and biological fluids. This book will prove useful to chemists, researchers, and students.

  • Gas Phase Ion Chemistry

    Volume 2
    • 1st Edition
    • Michael T. Bowers
    • English
    Gas Phase Ion Chemistry, Volume 2 covers the advances in gas phase ion chemistry. The book discusses the stabilities of positive ions from equilibrium gas-phase basicity measurements; the experimental methods used to determine molecular electron affinities, specifically photoelectron spectroscopy, photodetachment spectroscopy, charge transfer, and collisional ionization; and the gas-phase acidity scale. The text also describes the basis of the technique of chemical ionization mass spectrometry; the energetics and mechanisms of unimolecular reactions of positive ions; and the photodissociation of gas-phase ions. The applications of molecular beam techniques to the study of ion-molecule collisions; as well as the variational treatment of charge transfer reactions are also encompassed. Chemists and biochemists will find the book invaluable.

  • Mode of Action, Metabolism and Toxicology

    Pesticide Chemistry: Human Welfare and the Environment
    • 1st Edition
    • S. Matsunaka + 2 more
    • English
    Pesticide Chemistry: Human Welfare and the Environment, Volume 3: Mode of Action, Metabolism and Toxicology covers the proceeding of the Fifth International Congress of Pesticide Chemistry. This book is organized into three parts that tackle relevant issues regarding the use of pesticide. The opening part tackles topics relevant to the biochemistry of pests and mode of action of pesticides, such as influence of chlorinated and parathyroid insecticide on cellular calcium regulatory mechanisms; behavioral and lethal actions of amidines on invertebrates; and insect chitin synthetase as biochemical probe for insecticidal compounds. The second part encompasses metabolism and degradation of pesticides and xenobiotics and includes topics on propesticides; selective toxicity conferred by activation; and comparative biochemistry of animal, plant, and microorganism oxidases. The last part covers the toxicology of pesticides and xenobiotics, including the role of biochemical studies in modern toxicological assessment of pesticides; neurophysiological and behavioral assessment of pesticide toxicity; and genetic toxicology applied to the assessment of mutagenic, carcinogenic, and teratogenic action of pesticides and related compounds. This book will be of great interest to chemists, biologists, botanists, and entomologists or professionals whose line of work involves the use of pesticides and who are concerned with pesticide side-effects to the users and the environment.

  • Newer Redox Titrants

    International Series of Monographs in Analytical Chemistry
    • 1st Edition
    • A. Berka + 2 more
    • R. Belcher + 1 more
    • English
    International Series of Monographs in Analytical Chemistry, Volume 22: Newer Redox Titrants focuses on the processes, reactions, methodologies, and approaches involved in the study of redox titrants. The publication first offers information on potassium permanganate in alkaline solution and compounds of trivalent manganese, including standard solutions, indicator, and review of determinations. The text then ponders on compounds of trivalent copper and potassium hexacyanoferrate. The book ponders on hypohalites (hypochlorite and hypobromite), chloramine-T, and bromine, as well as standard solutions, indicator, and review of determinations. The publication also takes a look at iodine monochloride, periodic acid and its salts, lead (IV) acetate, compounds of pentavalent vanadium, and iron (III) salts. The compounds of trivalent cobalt, hydrogen peroxide, chromium (II) salts, tin (II) chloride, sodium arsenite, and compounds of monovalent copper are also elaborated. ? The publication is a reliable reference for readers interested in newer redox titrants.

  • Annual Reports in Inorganic and General Syntheses-1973

    • 1st Edition
    • Kurt Niedenzu + 1 more
    • English
    Annual Reports in Inorganic and General Syntheses-1973 presents an organized annual summary of synthetic developments in inorganic chemistry and its related areas. The book covers the synthetic aspects and structural or mechanistic features of elements, including the main group hydrides, alkali and alkaline earth elements, boron, aluminium, gallium, indium, thallium, silicon, germanium, tin, and lead, nitrogen, phosphorus, arsenic, antimony, bismuth, chalcogens, halogens and pseudohalogens, and noble gases. The text also discusses the synthetic aspects and structural or mechanistic features of elements of yttrium, scandium, lanthanides, and actinides, titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, technetium, rhenium, iron, cobalt, and nickel. The chemistry of ruthenium, osmium, rhodium, iridium, palladium, platinum, copper, silver, gold, zinc, cadmium, and mercury is also encompassed. The book concludes by describing the synthesis and structures of metalloporphyrins. Chemists, chemistry students, and people working in chemical laboratories will find the book invaluable.

  • An Introduction to the Chemistry of Complex Compounds

    • 1st Edition
    • Aleksander Abramovich Grinberg
    • D. H. Busch + 1 more
    • English
    An Introduction to the Chemistry of Complex Compounds discusses the fundamental concepts that are essential in understanding the underlying principles of complex compounds. The coverage of the book includes the compounds of the hexa, penta, and tetrammine type; compounds of the tri, dl, monoamine and hexacido types for the coordination number of 6; and complex compounds with a coordination number of 4. The text also covers the effects and chemical properties of complex compounds, such as the nature of the force of complex formation; the mutual effects of coordinated groups; and acid-base properties, oxidation-reduction properties, and solution equilibriums of complex compounds. The book will be of great use to chemists and chemical engineers.

  • Slurry Flow

    Principles and Practice
    • 1st Edition
    • C A Shook + 1 more
    • Howard Brenner
    • English
    Slurry Flow: Principles and Practice describes the basic concepts and methods for understanding and designing slurry flow systems, in-plan installations, and long-distance transportation systems. The goal of this book is to enable the design or plant engineer to derive the maximum benefit from a limited amount of test data and to generalize operating experience to new situations. Design procedures are described in detail and are accompanied by illustrative examples needed by engineers with little or no previous experience in slurry transport.The technical literature in this field is extensive: this book facilitates its use by surveying current research results and providing explanations of mechanistic flow models. This discussion of background scientific principles helps the practitioner to better interpret test data, select pumps, specify materials of construction, and choose measuring devises for slurry transport systems. The extensive range of topics covered in Slurry Flow: Principles and practice includes slurry rheology, homogeneous and heterogeneous slurry flow principles, wear mechanisms, pumping equipment, instrumentation, and operating aspects.

  • Gas Solubilities

    Widespread Applications
    • 1st Edition
    • William Gerrard
    • English
    Gas Solubilities: Widespread Applications discusses several topics concerning the various applications of gas solubilities. The first chapter of the book reviews Henr's law, while the second chapter covers the effect of temperature on gas solubility. The third chapter discusses the various gases used by Horiuti, and the following chapters evaluate the data on sulfur dioxide, chlorine data, and solubility data for hydrogen sulfide. Chapter 7 concerns itself with solubility of radon, thoron, and actinon. Chapter 8 tackles the solubilities of diborane and the gaseous hydrides of groups IV, V, and VI of the periodic table. Chapter 9 discusses the solubility of gases containing fluorine, while Chapter 10 talks about Hildebrand's theory in the light of all gas solubility data. Chapter 11 covers the hydrogen halide system, while Chapter 12 deals with the solubility of gases in water and aqueous solutions of slats, inorganic acids and bases, and organic compounds. Chapter 13 discusses gases in sea water, while Chapter 14 covers aerosol propellants and Chapter 15 tackles the solubility of nitric oxide. Chapter 16 discusses the biotechnological aspects, and Chapter 17 talks about more on making holes. Chapter 18 covers the evaluation of data on phosphine. The book would be of great interest to researchers and professionals concerned with applications of the soluble nature of gases.

  • Advances in Liquid Crystal Research and Applications

    Proceedings of the Third Liquid Crystal Conference of the Socialist Countries, Budapest, 27–31 August 1979
    • 1st Edition
    • Lajos Bata
    • English
    Advances in Liquid Crystal Research and Applications, Volume 2 covers the proceedings of the Third Liquid Crystal Conference of the Socialist Countries. The book discusses several papers concerning the development and advancement of the research and application aspects of liquid crystals. The text is comprised of 52 chapters that are organized into four parts explaining an aspect of liquid crystal. Part I covers amphiphilic, while Part II discusses mesomorphic polymers. The third part tackles synthesis and the fourth part talks about the physical properties and applications. The book will be of great use to researchers and professionals whose line of work concerns liquid crystals.

  • Clinical Electroencephalography

    • 1st Edition
    • L. G. Kiloh + 1 more
    • English
    Clinical Electroencephalograp... provides an appraisal of the value of electroencephalograp... in clinical medicine and a brief exposition of its techniques. The book provides chapters that discuss the recording techniques of electroencephalograp... the normal adult EEG; applications of EEG to certain diseases such as epilepsy, cerebral tumors, head injuries and vascular lesions; and the value and limitations of electroencephalograp... Physicians, nurses, and medical technicians will find the book invaluable.

  • Zirconia

    MMR
    • 3rd Edition
    • Sam Stuart
    • English
    Zirconia, 3rd Edition, Volume 1 provides a comprehensive coverage of the various areas of concerns in the zirconia industry. The title first covers the various forms of zirconia, and then proceeds to tackling the sources of zirconia. Next, the selection deals with methods of production. The subsequent chapter covers the production, trade, and consumption of zirconia. The text also talks about end uses of zirconia along with its price. The book will be of great interest to professionals who are involved in the zirconia industry.

  • Basic Analytical Chemistry

    • 1st Edition
    • L. Pataki + 1 more
    • R. Belcher + 2 more
    • English
    Pergamon Series in Analytical Chemistry, Volume 2: Basic Analytical Chemistry brings together numerous studies of the vast expansion in the use of classical and instrumental methods of analysis. This book is composed of six chapters. After providing a theoretical background of analytical chemistry, this book goes on dealing with the fundamental principles of chemical equilibria in solution. The subsequent chapters consider the advances in qualitative and quantitative chemical analyses. These chapters present a unified view of these analyses based on the Bronsted-Lowry theory and the donor-acceptor principle. These topics are followed by discussions on instrumental analysis using various methods, including electrochemical, optical, spectroscopic, and thermal methods, as well as radioactive isotopes. The finals chapters examine the separation methods and the essential features of organic chemical analysis that are different from methods for inorganic compounds. This book is of value to analytical chemists and researchers.

  • Structure of Molecules and Internal Rotation

    Physical Chemistry: A Series of Monographs
    • 1st Edition
    • San-Ichiro Mizushima
    • Ernest M. Loebl
    • English
    Structure of Molecules and Internal Rotation reviews early studies on dihalogenoethanes. This book is organized into two parts encompassing 8 chapters that evaluate the Raman effect in ethane derivatives, the energy difference between rotational isomers, and the infrared absorption of ethane derivatives. Some of the topics covered in the book are the potential barrier to internal rotation; nature of the hindering potential; entropy difference between the rotational isomers; internal rotation in butane, pentane, and hexane; and internal rotation in long chain n-paraffins. Other chapters deal with the configuration of a polypeptide chain, as well as the sum rule and the product rule for rotational isomers. The normal vibrations of the 1,2-dihalogenoethane... are presented. The last chapters are devoted to the examination of the Raman effect, dielectric constant, and electron diffraction. The book can provide useful information to chemists, physicists, students, and researchers.

  • Indicators

    International Series of Monographs in Analytical Chemistry
    • 1st Edition
    • Edmund Bishop
    • English
    Indicators offers a comprehensive account of indicators and their applications in areas such as titrimetric analysis and the analysis of mineral waters. The theory and principles of visual indicators are discussed, along with acid-base indicators, indicators for non-aqueous acid-base titrations, and titrations with non-chelating ligands. Metallochromic indicators, adsorption indicators, oxidation-reduction indicators, and fluorescent and chemiluminescent indicators are also considered. This volume is comprised of 10 chapters and begins with a brief history of indicators, including the contribution of Robert Boyle in the field. The different kinds of indicators are also described, along with developments in indicators in the nineteenth century. The next chapter deals with the theory and principles of visual indicators, followed by a discussion on acid-base indicators such as organic dyes, inorganic substances, compounds capable of fluorescence, and chemiluminescent systems. Subsequent chapters explore other varieties of indicators, including indicators for non-aqueous acid-base titrations, metallochromic indicators, and adsorption indicators, as well as oxidation-reduction indicators and fluorescent and chemiluminescent indicators. This book will be of interest to chemists.

  • Advances in Liquid Crystal Research and Applications

    Proceedings of the Third Liquid Crystal Conference of the Socialist Countries, Budapest, 27–31 August 1979
    • 1st Edition
    • Lajos Bata
    • English
    Advances in Liquid Crystal Research and Applications, Volume 1 is a collection of papers presented at the Third Liquid Crystal Conference of the Socialist Countries, held in Budapest on August 27-31, 1979. This volume is comprised of three parts. The first part deals with the phases and structures of liquid crystals through methods employing synthesis, X-ray studies, electron diffraction, and calorimetric determination. The second part discusses molecular dynamics and dynamical methods where mostly dielectric investigations into liquid crystal properties are emphasized. This part includes the developments in the study of molecular dynamics in liquid crystals. Other topics presented in this part are the acousto-optical and ultrasonic relaxation methods. The third part covers the continual properties of liquid crystals: their properties and behavior when exposed to different testing methods and variables. For example, a correlation between viscosity coefficients of starting components and those of their mixtures is attempted, resulting when MBBA and EBBA in different percentages are mixed, that none of their coefficients is found to obey any pronounced law. However, the viscosity coefficients given in the table may serve as reference data for further studies. Physicists; process engineers; and graduate students in physics, chemistry, and materials science fields; and university professors and lecturers related to studies in the field of liquid crystals will find this collection of papers highly informative and rewarding.

  • The South China Sea

    Hydrocarbon Potential and Possibilities of Joint Development
    • 1st Edition
    • Mark J. Valencia
    • English
    The South China Sea: Hydrocarbon Potential and Possibilities of Joint Development presents the proceedings of the EAPI/CCOP Workshop East-West Center held in Honolulu, Hawaii on August 5-12, 1980. The book contains papers on the geology and offshore hydrocarbon potential in the Philippines, Thailand, and Indonesia; and on the need for certain basic prerequisites for initiating and maintaining rational and orderly oil and gas exploration and development programs. The text also presents papers on the establishment of effective production-sharing type tax regimes for petroleum; on the implications of the Southeast Asian contractual framework; and on a general approach to the planning and management of environmental aspects related to offshore oil and gas prospecting, drilling, development and production. The precedents of the joint development of hydrocarbons in areas of overlapping boundary claims, with examples from the North Sea, the Persian Gulf, the Korea-Japan continental shelf and the Thai-Malaysian continental shelf, are also considered.

  • Ion Exchange Equilibrium Constants

    • 1st Edition
    • Y. Marcus + 1 more
    • English
    Ion Exchange Equilibrium Constants focuses on the test-compilation of equilibrium constants for ion exchange reactions. The book first underscores the scope of the compilation, equilibrium constants, symbols used, and arrangement of the table. The manuscript then presents the table of equilibrium constants, including polystyrene sulfonate cation exchanger, polyacrylate cation exchanger, polymethacrylate cation exchanger, polysterene phosphate cation exchanger, and zirconium phosphate cation exchanger. The text highlights zirconium oxide anion exchanger, zeolite type 13Y cation exchanger, and zeolite type 4A cation exchanger. The book also presents references for mineral exhangers and polymeric ion exchangers. The book is a valuable reference for readers interested in equilibrium constants.

  • Organic Syntheses Based on Name Reactions and Unnamed Reactions

    • 1st Edition
    • Volume 11
    • Alfred Hassner + 1 more
    • Patrick Perlmutter
    • English
    Synthetically useful organic reactions or reagents are often referred to by the name of the discoverer(s) or developer(s). Older name reactions are described in text books, but more recently developed synthetically useful reactions that may have been associated occasionally with a name are not always well known. For neither of the above are experimental procedures or references easy to find.In this monograph approximately 500 name reactions are included, of which over 200 represent newer name reactions and modern reagents. Each of these reactions are extremely useful for the contemporary organic chemistry researcher in industry or academic institutions. This book provides the information in an easily accessible form.In addition to seminal references and reviews, one or more examples for each name reaction are provided and a complete typical experimental procedure is included, to enable the student or researcher to immediately evaluate reaction conditions.Besides an alphabetical listing of reactions and reagents, cross references permit the organic practitioner to find those name reactions or reagents that enable specific transformations, such as, conversion of amines to nitriles, stereoselective reduction, fluoroalkylation, phenol alkynylation, asymmetric syntheses, allylic alkylation, nucleoside synthesis, cyclopentanation, hydrozirconation, to name a few. Emphasis has been placed on stereoselective and regioselective transformations as well as on enantioselective processes. The listing of reactions and reagents is supported by four indexes.

  • Studies in Natural Products Chemistry

    Stereoselective Synthesis
    • 1st Edition
    • Volume 14
    • Atta-ur-Rahman
    • English
    Studies in Natural Products Chemistry, Volume 14: Stereoselective Synthesis, Part I is a collection of discourses on the stereoselective synthesis of the anticancer anthrucycline antibiotics; tetramic acid antibiotics; 3-and 4-deoxyhexoses; polysaccharides; levoglucosenone as precursor to natural products; synthesis of oligoribonucleotides... and oxidation of guaiazulene. This volume deals with a broad range of natural products focusing on the synthesis of antibiotics and anticancer agents — anthracyclines, tetramic acid, taxodione, vinblastine, and vincristine. These aforementioned drugs are used for the treatment of cancer (anthracyclines) and Hodgkin's disease and childhood acute leukemia (vinblastine and vincristine). The importance of the latest developments in the stereocontrolled synthesis of polysaccharides is discussed as polysaccharides play a fundamental role in cell life and have many technical applications. The synthesis of bioactive carbohydrates 3- and 4-deoxy-hexoses is compared with the more occurring deoxyhexoses in nature such as the 2-deoxy, 6-deoxy, and 2,6-dideoxy-hexoses, because the former are rare compounds and useful tools in the study of biological and biochemical properties of mono- and oligosaccharides, glycoproteins, and antibiotics. Alkaloids derived from Apocynaceae are known for their medicinal properties; hence the synthetic approaches to vinblastine and vincristine are discussed. Because of the minute amounts available from herbal sources, efforts toward their chemical synthesis are given more reference. This book can be a useful reference for the organic chemists. Chemical researchers, pharmaceutical scientists, and professionals of bioorganic chemistry will likewise gain a lot from this collection.

  • Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis

    Pergamon Texts in Inorganic Chemistry
    • 1st Edition
    • B. L. Shaw + 1 more
    • English
    Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis deals with the chemistry of organo-transition metal complexes and their uses as homogeneous catalysts and as intermediates in organic synthesis. The compounds are classified mainly from the number of carbon atoms that are actually bonded to the metal and to each other. This volume is comprised of eight chapters and begins with a discussion on alkyls, aryls, acetylides, fluorocarbon complexes, and carbides, along with olefin, allene, and acetylene complexes. The reader is then introduced to π-allylic and related complexes such as fluoroallyl complexes; complexes with conjugated diolefins including fluorodiolefins but excluding cyclobutadienes; cyclopentadienyl-met... pentadienyl-metal, and related complexes; and arene complexes, related complexes with conjugated trienes, and thiophene complexes such as benzenoid-metal or arene-metal complexes, cyclopheptatriene complexes, and complexes with other six electron donors. Cycloheptatrienyl or tropylium complexes are also considered, along with cyclo-octatetraene, azulene complexes, and carborane complexes. This book will be a valuable source of information for inorganic chemists.

  • Recommendations for Nomenclature of Ion-Selective Electrodes

    International Union of Pure and Applied Chemistry: Analytical Chemistry Division
    • 1st Edition
    • Sam Stuart
    • English
    Recommendations for Nomenclature of Ion-Selective Electrodes presents the recommendations in the standardization of nomenclature in the field of ion-selective electrodes. The report contains most of the suggestions made on previous drafts by experts and other scientific bodies on analytical chemistry from different countries. The text is divided into three sections. The first section presents the general nomenclature recommendations. Part II focuses on the classification of ion-selective electrodes. The final section presents the constants and symbols used in the area of ion-selective electrodes. Chemists and physicists will find the book very useful.

  • Calorimetry of Non-Reacting Systems

    Prepared Under the Sponsorship of the International Union of Pure and Applied Chemistry Commission on Thermodynamics and the Thermochemistry
    • 1st Edition
    • John P. McCullough + 1 more
    • English
    Experimental Thermodynamics, Volume 1: Calorimetry of Non-Reacting Systems covers the heat capacity determinations for chemical substances in the solid, liquid, solution, and vapor states, at temperatures ranging from near the absolute zero to the highest at which calorimetry is feasible. This book is divided into 14 chapters. The first four chapters provide background information and general principles applicable to all types of calorimetry of non-reacting systems. The remaining 10 chapters deal with specific types of calorimetry. Most of the types of calorimetry treated are developed over a considerable period and brought to a relatively sophisticated state. For such calorimetry, the approach adopted is to give detailed accounts of a few examples of apparatus and techniques representative of the best current practice in the field. For the few types of calorimetry, a general review of the field was considered more appropriate. This book will prove useful to thermochemists, engineers, and experimentalists.

  • Kinetics of Inorganic Reactions

    The Commonwealth and International Library: Chemistry Division
    • 1st Edition
    • A. G. Sykes
    • Robert Robinson + 1 more
    • English
    Kinetics of Inorganic Reactions provides a comprehensive account of the mechanisms of inorganic reaction. The book is comprised of 15 chapters that deal with the two main fields of inorganic reaction, the homogeneous gas-phase reactions and solution reactions. The first chapter of the text provides an introduction to some of the basic concepts in inorganic reaction, which include the mechanisms of a reaction, reactions in different phases, and the feasibilities of a reaction. Next, the book details the experimental techniques and treatment of data. The next series of chapters talks about gas-phase reactions. The book also dedicates a chapter in covering various types of reactions, including isotopic reaction and redox reaction. Chapters 12 to 14 deal with substitution reactions, while Chapter 15 talks about acid-base reactions. The text will be most useful to chemists and chemical engineers, particularly those who deal with inorganic chemistry.

  • The Gaseous State

    The Commonwealth and International Library: Chemistry Division
    • 1st Edition
    • N. G. Parsonage
    • Robert Robinson + 2 more
    • English
    The Gaseous State provides a comprehensive discussion on the various areas of concerns in gases. The main concern of the title is the interpretation of the properties of bulk gases in terms of the characteristics of the constituent molecules. The text first details the perfect gas equation, and then proceeds to tackling various gaseous properties. The coverage of the selection includes gas imperfection, collisions, viscosity, thermal conductivity, and diffusion, and energy transfer. The title also covers the Brownian movement and the determination of Avogadro’s number. The book will be most useful to undergraduate students of chemistry.

  • Viscous Flows

    The Practical Use of Theory
    • 1st Edition
    • Howard Brenner
    • English
    Representing a unique approach to the study of fluid flows, Viscous Flows demonstrates the utility of theoretical concepts and solutions for interpreting and predicting fluid flow in practical applications. By critically comparing all relevant classes of theoretical solutions with experimental data and/or general numerical solutions, it focuses on the range of validity of theoretical expressions rather than on their intrinsic character.This book features extensive use of dimensional analysis on both models and variables, and extensive development of theoretically based correlating equations. The range of applicability of most theoretical solutions is shown to be quite limited; however, in combination they are demonstrated to be more reliable than purely empirical expressions, particularly in novel applications.

  • Reaction Kinetics

    Homogeneous Gas Reactions
    • 1st Edition
    • Keith J. Laidler
    • Robert Robinson + 2 more
    • English
    Reactions Kinetics: Volume I: Homogeneous Gas Reactions presents a general introduction to the subject of kinetics, including the basic laws of kinetics and the theoretical treatment of reaction rates. This four-chapter book deals mainly with homogeneous reactions in the gas phase. Chapter 1 presents the kinetic laws based on experimental results in terms of their simple concepts, with a special consideration of the way in which rates depend on concentration, while Chapter 2 deals with the interpretation of rates in terms of more fundamental theories. Chapter 3 covers the overall reactions that are believed to be elementary, such as the reaction between hydrogen and iodine, the reverse decomposition of hydrogen iodide, the corresponding reactions involving deuterium instead of hydrogen, and the dimerizations of butadiene and cyclopentadiene, as well as a few elementary termolecular reactions, all involving nitric oxide. This chapter also includes a general account of some of the elementary reactions that occur as steps in more complex mechanisms. Chapter 4 examines the reaction rates of numerous complex gas reactions. Undergraduate physical chemistry and chemical kinetics students, as well as advanced students in other fields, such as biology and physics, will find this book invaluable.

  • Applied Complexometry

    Pergamon Series in Analytical Chemistry
    • 1st Edition
    • Rudolf PÅ™ibil
    • Robert A. Chalmers
    • English
    Applied Complexometry tackles complexometry from a practical perspective. The book discusses more applications, and theories are reduced to the most important ones. Comprised of 22 chapters, this book deals first with volumetric reagents in complexometry, and then tackles detection of the titration end-point. Chapter 3 covers masking (screening) reagents. Chapter 4 discusses separation methods, and Chapter 5 covers apparatus and solutions. Chapter 6 talks about the classification of EDTA complexes, while Chapter 7 discusses the complexometry anions. Chapter 8 discusses the analytical applications; Chapters 9 to 21 explain the analysis of several materials and solutions, such as alloys, silicates and rocks, cement, ores and concentrates, semiconductors, pigments, and electroplating solutions. The last chapter discusses further applications of complexometry. This book will be of great interest to researchers, especially for chemists whose work involves various chemical techniques such as complexometry.

  • The Chemistry of Sulphur, Selenium, Tellurium and Polonium

    Pergamon Texts in Inorganic Chemistry
    • 1st Edition
    • M. Schmidt + 2 more
    • English
    The Chemistry of Sulfur, Selenium, Tellurium and Polonium deals with the chemistry of sulfur, selenium, tellurium, and polonium. The history, occurrence and distribution, and production of all four elements are discussed, along with their industrial uses, purification, and allotropy; nuclear, physical, and chemical properties; and biological activities. Comprised of two chapters, this volume begins with an overview of the history, occurrence and distribution, and production of sulfur, selenium, tellurium, and polonium, as well as their industrial uses, purification, and allotropy; nuclear, physical, and chemical properties; and biological activities. The compounds of all four elements are also considered, including sulfanes, sulfur halides, oxides and oxyacids, and compounds composed of sulfur, nitrogen, and halogen; peroxides, hydroxides and oxo-acids, sulfides, nitrides and azides, carbon selenides and tellurides; carbonates, salts of organic acids, alkoxides, nitrates, phosphates, chromates, halates and perhalates, and organo-compounds. This book will be of interest to inorganic chemists as well as students and researchers in the field of inorganic chemistry.

  • Advances in Metal-Organic Chemistry

    A Research Annual
    • 1st Edition
    • Volume 2
    • Lanny S. Liebeskind
    • English
    Advances in Metal-Organic Chemistry: A Research Annual, Volume 2 presents the virtues of metal-oriented organic chemistry utilizing stoichiometric and catalytic reagents. This book discusses of value for the synthesis of generally useful organic structures. Organized into seven chapters, this volume begins with an overview of the synthetic applications of chromium tricarbonyl stabilized benzylic carbanions. This text then examines the application of organometallic complexes to stereoselective organic synthesis. Other chapters consider the carbine addition reaction that has been shown to be useful in many cases, but complications arise because of the inherently high reactivity of these species. This book discusses as well the most common substituted-arene complexes, particularly those of benzaldehyde and benzoic acid that are stable when prepared by indirect routes via acetals or esters. The final chapter deals with the efficient ring homologation methodology for cyclic alkenes. This book is a valuable resource for synthetic organic chemists and organometallic chemists.

  • Small Peptides

    Chemistry, Biology and Clinical Studies
    • 1st Edition
    • A.S. Dutta
    • H. Timmerman
    • English
    Pharmacochemistry Library, Volume 19: Small Peptides: Chemistry, Biology, and Clinical Studies focuses on the processes, reactions, properties, and characteristics of peptides, including analogues and proteases. The publication first takes a look at angiotensin II and bombesin/gastrin-rel... peptide. Topics include conformationally restricted analogues of bombesin, non-peptide antagonists of angiotensin II, receptor subtypes of angiotensin II, and bombesin/GRP antagonists and cancer. The text then elaborates on bradykinin, cholecystokinin, and enkephalin analogues. The manuscript examines luteinizing hormone releasing hormone and somatostatin. Topics include enzymic degradation of somatostatin and analogues, clinical applications of somatostatin analogues, and pharmacological and clinical studies with LHRH agonists and antagonists. The formulation of peptides and inhibitors of aspartyl proteases are also mentioned. The book is a valuable source of information for chemists, biologists, and readers interested in small peptides.

  • Infections in Cancer Chemotherapy

    A Symposium Held at the Institute Jules Bordet, Brussels, Belgium
    • 1st Edition
    • J. Klastersky
    • English
    Infections in Cancer Chemotherapy is a collection of paper that details the advancement in the understanding of infections in chemotherapy. The coverage of the text includes aggressive cancer treatment and its role in predisposing to infection; diagnosis of infection in patients with cancer; and non-bacterial infections associated with neoplastic disease. The selection also tackles the protocol for an international prospective trial of initial therapy regimens in neutropenic patients with malignant disease; and the use of gnotobiotics in hematology in improving acute leukemia treatment. The book will be of great interest to oncologists and hematologists.

  • Carotenoids – 4

    Main Lectures Presented at the Fourth International Symposium on Carotenoids, Berne, Switzerland, 25-29 August 1975
    • 1st Edition
    • B. C. L. Weedon
    • English
    Carotenoids — 4 brings together the main lectures presented at the Fourth International Symposium on Carotenoids held in Berne, Switzerland, on August 25-29, 1975. The papers explore a wide range of topics relating to carotenoids, including their carbon-13 nuclear magnetic resonance (NMR) spectra, stereochemistry, and biosynthesis. Carotenoid-protein complexes, carotenoid glycosides, xanthoxin and abscisic acid, and photoregulation of carotenoid biosynthesis in plants are also discussed. This book is comprised of 13 chapters and begins with an analysis of the carbon-13 NMR spectra of derivatives of beta-carotene, such as zeaxanthin, isozeaxanthin, violaxanthin, and alloxanthin. The reader is then introduced to carotenoid-protein complexes, with emphasis on the distinction between carotenoid-lipoglyco... complexes and astaxanthin-proteins in which the absorption band of the carotenoid is unaltered in shape. Subsequent chapters deal with carotenoid glycosides; the structures, chemical reactions, and stereochemistry of naturally occurring carotenoids; synthesis of carotenoids and related polyenes; and the apocarotenoid system of sex hormones and prohormones in Mucoraceous fungi. The early steps in and later reactions of carotenoid biosynthesis are also examined. The last chapter is devoted to the photoregulation of carotenoid biosynthesis in plants. This monograph will be a valuable source of information for chemists.

  • Macromolecular Chemistry-11

    Plenary and Sectional Lectures Presented at the International Symposium on Macromolecules (the Third Aharon Katzir-Katchalsky Conference)
    • 1st Edition
    • H. Eisenberg
    • English
    Macromolecular Chemistry — 11 is a collection of lectures presented at the International Symposium on Macromolecules (The Third Aharon Katzir-Katchalsky Conference) held in Jerusalem, Israel, on July 13-18, 1975. The papers explore a wide range of topics related to macromolecular chemistry, including polyelectrolytes, biologically active synthetic polymers, and spans of polymer chains. The use of polymers as chemical reagents is also considered. This book is comprised of 19 chapters and begins with an introduction to the close relation between polyelectrolytes and hydrophilic colloids. A survey of polyelectrolyte knowledge that has accumulated since about 1940 is also presented. The discussion then turns to biologically active synthetic polymers; polymers and other composites; theories of the condensed polymer state; polymer adsorption inferred from electrical double layer measurements; and mobility and conductivity of ions in and into polymeric solids. The structure and viscoelastic properties of ion-containing polymers in the solid state are also examined, along with the use of graphite insertion compounds as chemical reagents in organic chemistry. The results of research on chemical modification of cellulose are also presented. This monograph will be of interest to chemists.

  • Physicochemical Measurements

    Catalogue of Reference Materials from National Laboratories
    • 1st Edition
    • Sam Stuart
    • English
    Physicochemical Measurements: Catalogue of Reference Materials from National Laboratories offers information on chemicals, including their density, magnetic susceptibility, calorimetry, molecular conductance, and thermal conductivity. The catalog first offers information on acidimetry, calorimetry, and spectrophotometry and tristimulus colorimetry. The chemicals examined include potassium hydrogen, boric and benzoic acids, heptane, neopentane, and aluminum oxide. The text then presents data on density, dielectric constants, differential thermal analysis, magnetic susceptibility, and molar conductance. The chemicals evaluated include cyclohexane, kerosene, toluene, chlorobenzene, carbon tetrachloride, potassium nitrate, indium, tin, aluminum, platinum, and potassium chloride. The book discusses the molecular weight of polymers, refractive index, relative humidity, specular spectral reflectance, and surface tension. The text also takes a look at thermal conductivity and emissivity and vapor pressure. The catalog is a dependable reference for readers interested in the composition, characteristics, and reactions of chemicals.

  • Organicum

    Practical Handbook of Organic Chemistry
    • 1st Edition
    • Heinz Becker + 2 more
    • English
    Organicum: Practical Handbook of Organic Chemistry focuses on the theory, laboratory practice, and aspects of technical use related to organic chemistry. This book discusses the standard apparatus for organic reactions, heating of inflammable liquids, performance of a simple distillation, and partition chromatography in separating columns. The time factor in organic chemical reactions, distribution of the electron density in organic molecules, and synthesis of ethers from alkoxides or phenoxides are also elaborated. This text likewise covers the mechanism of electrophilic aromatic substitution, quinones from aromatic hydrocarbons, and reduction of carbonyl compounds by means of complex hydrides. Other topics include the reaction with ammoniacal solution of a silver salt, preparation of the dimedone derivatives, and saturated aliphatic hydrocarbons. This publication is suitable for chemists and researchers conducting work in organic chemistry.

  • Advances in Liquid Crystals

    Volume 2
    • 1st Edition
    • Glenn H. Brown
    • English
    Advances in Liquid Crystals, Volume 2 covers the study of lyotropic and thermotropic liquid crystals. The five articles in this volume discuss topics such as the effects of change in molecular geometry on the properties of liquid crystals formed by nonamphiphilic (thermotropic) compounds; aspects of the physics and chemistry of cholesteric liquid crystals with respect to temperature dependence and temperature sensitivity of the selective reflection of visible light; arrangements of emulsifier molecules and the interaction between the different components in emulsions; the type of information about liquid crystals obtained from vibrational spectroscopy; and the continuum theory of liquid crystals as it applies to static equilibrium. The book will be invaluable to materials engineers, inventors, physicists, and researchers in the field of electronics.

  • Advances in High Temperature Chemistry

    Volume 2
    • 1st Edition
    • Leroy Eyring
    • English
    Advances in High Temperature Chemistry, Volume 2 covers the advances in the knowledge of the high temperature behavior of materials and the complex and unfamiliar characteristics of matter at high temperature. The book discusses the dissociation energies and free energy functions of gaseous monoxides; the matrix-isolation technique applied to high temperature molecules; and the main features, the techniques for the production, detection, and diagnosis, and the applications of molecular beams in high temperatures. The text also describes the chemical research in streaming thermal plasmas, as well as the studies of the sublimation mechanism of sodium chloride, cadmium sulfide, and gallium arsenide. The temperature and emissivity measurements in the thermal imaging technique, freezing and melting point measurements of metal oxides, and phase studies on binary oxide systems at higher temperatures with a solar furnace are also encompassed. High temperature chemists and solar researchers will find the book invaluable.

  • High Resolution NMR

    Theory and Chemical Applications
    • 2nd Edition
    • Bozzano G Luisa
    • English
    High Resolution NMR: Theory and Chemical Applications, Second Edition covers the significant progress in understanding the NMR phenomena, instrumentation, and applications in chemical and biochemistry. This edition is divided into 14 chapters and begins with the historical developments and theoretical aspects of NMR. Considerable chapters are devoted to the basic principles, chemical shifts, coupling constants, and analysis of complex spectra. Other chapters contain expanded topics on carbon-13, nuclear Overhauser effect, relaxation mechanisms, and the use of superconducting magnets. The remaining chapters examine the concepts of solvent effects, hydrogen bonding, and the use of NMR in quantitative analysis. This book will prove useful to analytical chemists, biochemists, and researchers.

  • Plasma and Oscillations

    With Contributions in Memoriam Including a Complete Bibliography of His Works
    • 1st Edition
    • C. Guy Suits
    • English
    The Collected Works of Irving Langmuir, Volume 5: Plasma and Oscillations is an 11-chapter text covers the extensive research study of Langmuir in the field of gas discharges. This book specifically tackles oscillations in ionized gases. The opening chapters describe the plasma-boundary phenomena and the use of a probe to separate the primary electron beam from the scattered electrons. The succeeding chapters deal with the collisions between electrons and gas molecules, oscillations in ionized gases, and the interaction of electron and positive ion space charges in cathode sheaths. These topics are followed by discussions on the general theory of the plasma of an arc and the properties of metastable atoms and electrons produced by resonance radiation in neon. The concluding chapter provides experimental evidence that the secondary electrons originate from bombardment by metastable atoms. This book is of value to physical chemists and physical chemistry researchers.

  • Art in Biosynthesis

    The Synthetic Chemist's Challenge
    • 1st Edition
    • Darshan Ranganathan + 1 more
    • English
    Art in Biosynthesis: The Synthetic Chemists Challenge, Volume 1 presents representative examples whose biosynthetic pathways are known on the basis of experimentation. This book is divided into 44 chapters that demonstrate the creativity associated with the construction of molecular frameworks. It is a work of appreciation and criticism of the complexity of biosynthetic processes and of the interaction between man, the organic chemist, and Nature. This text describes an established biosynthetic sequence which is a challenge to the synthetic organic chemist to imitate and to equal Nature. The aim of each chapter is to enable a quick comparison of the specific synthetic strategies. This work covers the biosynthesis of natural antibiotics, amino acids, enzymes, fatty acids, and vitamins. This book will prove useful to organic chemists and researchers.

  • The Biochemistry of Foreign Compounds

    International Series of Monographs in Pure and Applied Biology: Biochemistry
    • 1st Edition
    • Dennis V. Parke
    • H. H. V. Arnstein + 2 more
    • English
    The Biochemistry of Foreign Compounds presents the various aspects of biochemistry of foreign compounds in relation to toxicology, pathology, and pharmacology. This book discusses the classification of foreign compounds according to usage, namely, food additives, drugs, pesticides, industrial chemicals, and natural foreign compounds. Organized into two sections encompassing 12 chapters, this book starts with the absorption and secretion of foreign compounds. This text then discusses the two phases of reaction in the metabolism of foreign compounds. Other chapters consider the rate at which each reaction proceeds wherein its relative significance may be affected by many factors that may result in changes in the pattern of metabolism and differences in toxicity. This book discusses as well the physiological factors that affect metabolism, including age, sex, pregnancy, disease, and the nutritional state of the animal. The final chapter deals with the metabolism of some of the commonly used industrial chemicals. This book is a valuable resource for biochemists, chemists, toxicologists, pharmacologists, and pathologists.

  • Alkaline Earth Hydroxides in Water and Aqueous Solutions

    • 1st Edition
    • Volume 52
    • I. Lambert + 1 more
    • English
    This volume contains evaluated data on the solubility of beryllium hydroxide, magnesium hydroxide, calcium hydroxide, strontium hydroxide and barium hydroxide in water and in a number of electrolyte and nonelectrolyte solutions in water. The alkaline earth hydroxides can be divided into two groups depending on the hydration of the solid. First, the sparingly soluble anhydrous beryllium, magnesium and calcium hydroxides, whose freshly precipitated solids are poorly crystalline and show decreasing solubility with aging, and whose solubility in water decreases with increasing temperature. Second, the soluble strontium and barium hydroxide octahydrates that form crystalline precipitates which do not show changes in solubility on aging, and whose solubility in water increases with increasing temperature.

  • The Chemistry of Vanadium, Niobium and Tantalum

    Pergamon Texts in Inorganic Chemistry
    • 1st Edition
    • R. J. H. Clark + 1 more
    • J. C. Bailar + 2 more
    • English

  • Ternary Systems

    Solubilities of Inorganic and Organic Compounds
    • 1st Edition
    • H. Stephen + 1 more
    • English
    Solubilities of Inorganic and Organic Compounds, Volume 2: Ternary Systems, Part I focuses on a selection from the International Chemical Literature on the Solubilities of Elements, Inorganic Compounds, Metallo-organic Compounds, and Organic Compounds in Ternary and Multicomponent Systems. The book underscores that Tables 1-4955 deal with Ternary Systems, while Tables 4956 et seq. are devoted to Multicomponent Systems. The first tables are systems in which an Element is a component, and these are supported by data for systems containing Inorganic Compounds and then Metallo-organic Compounds. The ion of ammonia is placed at the end of the first Group. The text also presents the arrangement of the compounds of elements. These include oxides and their hydrates and salts of halogen and other acids. The book is a dependable reference for readers interested in studying the solubilities of inorganic and organic compounds.

  • Underground Cable Thermal Backfill

    Proceedings of the Symposium on Underground Cable Thermal Backfill, Held in Toronto, Canada, September 17 and 18, 1981
    • 1st Edition
    • S.A. Boggs + 2 more
    • English
    Underground Cable Thermal Backfill documents the proceedings of the ""Symposium on Underground Cable Thermal Backfill,"" held in Toronto, Canada, 17-18 September 1981. The symposium brought together research, design, and installation engineers from utilities, cable manufacturers, and universities to present and discuss developments in the field. The contributions of researchers at the symposium are organized into five chapters. Chapter 1 presents an overview of the state-of-the-art of cable backfill materials and soil thermal property measurements. The papers in Chapter 2 deal with developments in cable backfill materials. These include materials stabilized with moisture substitutes, pumpable materials, and materials stabilized with bound water. Chapter 3 covers thermal property measurements of soils and backfills. Through the automation of measurements and analysis using microprocessor based instruments and better control of experimental conditions, substantial improvements have been made in the area of measurement technology. Chapter 4 reports developments in the study of soil thermal stability and the implication thereof for thermal cable design. Chapter 5 discusses various aspects of thermal cable design, including methods for incorporating historical weather records to predict worst case soil and backfill thermal conductivities. This volume should serve as a useful introduction to the subject of cable thermal design for engineers involved in underground transmission and distribution systems.

  • Extrusion Reactions

    • 1st Edition
    • B. P. Stark + 1 more
    • English
    Extrusion Reactions presents a critical review of the reactions which presents a rupture of both of the bonds connecting an atom or a small group of atoms into a ring system. It discusses the loss of small fragments from cyclic structures under non-catalyzed conditions. It addresses those reactions wherein the major output and starting materials are cyclic. It demonstrates the general characteristics of the main classes of residua. Some of the topics covered in the book are the conditions for extrusion; types of concurrent reactions; choice of experimental conditions in extrusion; structural requirements for extrusion, and special cases of the reaction; extrusion from analogous systems; extrusions of carbon monoxide and carbon dioxide; and extrusion of sulfur dioxide and oxidized sulfur fragments. The extrusions of the elementary chalcogens: sulfur, selenium, and oxygen are fully covered. Extrusion of nitrogen from pyrazolines and 3H-pyrazoles are extensively discussed. An in-depth evaluation of the course of extrusion from pyrazolines is provided. The extrusion of nitrogen from triazolines and formation of aziridines from triazolines are also presented. A chapter is devoted to possible intervention of oxadiazolines and thiadiazolines in syntheses of oxirans. The book can provide useful information to chemists, students, and researchers.

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