Organometallic Chemistry is a comprehensive overview of this important branch of chemistry, including the important role of efficient catalytic systems which address industry, environmental and pharmaceutical problems. Fundamental concepts and industry-related examples are included to give a complete and practical view of the topic. The book begins with fundamentals and then covers various metal coordination, metal-organic frameworks, and bio-inspired multi-metallic catalysis. It concludes with a detailed look at pharmaceutical and environmental applications and future outlooks. Organometallic Chemistry is an ideal reference for organometallic chemists, synthetic organic chemists, and pharmaceutical chemists working in academia or industry.
Inorganic Chemistry Fourth Edition provides essential information for students of inorganic chemistry and is updated throughout. The presentation of topics is made with an effort to be clear and concise so that the book is portable and user friendly. The text emphasizes fundamental principles—including molecular structure, acid-base chemistry, coordination chemistry, ligand field theory, and solid state chemistry. It is organized into five major themes (structure, condensed phases, solution chemistry, main group and coordination compounds) with several chapters in each. There is a logical progression from atomic structure to molecular structure to properties of substances based on molecular structures, to behavior of solids, etc.The textbook contains a balance of topics in theoretical and descriptive chemistry. For example, the hard-soft interaction principle is used to explain hydrogen bond strengths, strengths of acids and bases, stability of coordination compounds, etc. Discussion of elements begins with survey chapters focused on the main groups, while later chapters cover the elements in greater detail. Each chapter opens with narrative introductions and includes figures, tables, and end-of-chapter problem sets.This new edition features updates throughout, with an emphasis on bioinorganic chemistry and a new chapter on nanostructures and graphene. More in-text worked-out examples encourage active learning and prepare students for their exams.This text is ideal for advanced undergraduate and graduate-level students enrolled in the Inorganic Chemistry course. This core course serves Chemistry and other science majors. The book may also be suitable for biochemistry, medicinal chemistry, and other professionals who wish to learn more about this subject area.
Electronic Energy Levels of Transition Metal Complexes guides the reader to understand how to comprehensively calculate (predict, reconstruct) electronic energy levels of separation between 0,1 to 30,000 cm-1 in d1 to d9 transition metal complexes. The applied apparatus helps to understand the individual effect of the interelectron repulsion, crystal field strength, spin-orbit coupling and the magnetic field for any symmetry. Symmetry labels can be attached to energy levels (eigenvalues) by analyzing the eigenvectors of the model Hamiltonian either at the level of crystal-field terms or crystal-field multiplets.This book includes basic formulae for matrix elements of the model Hamiltonian and a huge number of results presented as graphs identifying the order of the energy levels and their labelling using the group (double group) irreducible representations. Utilization of the generated energy levels in electron spectroscopy, electron spin resonance and magnetochemistry is presented. Massive modelling was done using the desktop computers.
Natural and Synthetic Hydrogels: Rational Design, Synthesis and Biomedical Applications provides acomprehensive text on hydrogels and their biomedical uses, covering both fundamental and applied aspects of hydrogels. Hydrogels are three-dimensional network of cross-linked polymers or particles that contain a large amount of water. They have received tremendous attention for applications in biomedicines, which has led to significant progress in the design and engineering of the hydrogels to meet the needs for such applications.The book covers the recent developments that have been made in this field, including new applications of hydrogels, providing a new and fresh overview of hydrogels and their applications.Natural and Synthetic Hydrogels: Rational Design, Synthesis and Biomedical Applications is valuableto upper level undergraduate and graduate students, researchers, and progressors teaching fundamental and applied aspects of hydrogels.
The editors of the volume Inorganic Chemistry in Spain have intended to achieve a collection of some chapters featuring the work of Spanish experts in Inorganic Chemistry, each one having specific expertise in some field. Areas that cover theory, classical coordination compounds, new materials, supramolecular assemblies, mechanisms of reactions, magnetism, organometallic complexes, and catalysis are included. In all cases, a special relevance is given to a deep understanding of the behavioural properties of the compounds featured, not only to their mere preparation methodologies, which had been historically related to classical Inorganic Chemistry.
Photochemistry and Photophysics of Earth-Abundant Transition Metal Complexes, Volume 83 in the Advances in Inorganic Chemistry series, highlights new advances in the field, with this new volume presenting interesting chapters on topics such as Radioluminescence of Copper(I) Clusters, Photophysics and Photochemistry of Chromium(III) Complexes (Molecular Rubies), Chromic behaviors of luminescent copper(I) complexes, Long-lived photoluminescence in group 4 metal complexes enabled by ligand-to-metal charge transfer, Photoactive MOFs for CO2 Activation utilizing Earth Abundant Metals, and more.Other sections cover Earth Abundant Metal Complexes for Optoelectronic Applications, Photoactive metal to ligand charge transfer excited states in 3d6 and 3d8 complexes, Ligand-to-metal charge-transfer excited states in d0 transition-metal complexes: Investigations into the photochemistry and photophysics of emissive titanocenes, Ultrafast dynamics in photoactive copper complexes from optical and Xray methods, and Photophysical properties of Ni(II) complexes and some copper(I) and zinc(II) complexes.
Metal Organic Frameworks: Fundamentals to Advanced offers a substantial and complete treatment of published results. The book includes a summary of current research, along with an in- depth explanation of Metal organic frameworks (MOFs) and applications in this versatile area. Metal organic frameworks (MOFs) are structured frameworks made up of metal ions and organic molecules. These materials are similar to sponges and can absorb, retain and remove molecules from their pores. As a result, metal-organic frameworks (MOFs) are the most rapidly evolving substances in chemistry with the highest surface areas due to their well-ordered pore structure.The exciting and vast surface area allows for more chemical reactions and molecule adsorption, hence this new resource provides the newest updates on the topics covered.
Inorganic Chemistry in Germany, Volume 82 in the Advances in Inorganic Chemistry series, highlights advances in the field, with this new volume presenting chapters written by an international board of authors. Specific chapters focus on Cooperative effects in bimetallic and multimetallic complexes, Harnessing transition metal nitrido complexes for challenging bond activation reactions and catalysis, Applications of N-heterocyclic carbene-pnictogen compounds in transition metal chemistry and homogeneous catalysis, Aminopyridinato ligands – from quintuple bonding via hydrogen storage to selective olefin syntheses, Multifunctional Perspectives of Metal-Organic Frameworks, Recent advances in low valent silicon chemistry, Recent developments in CO2 reduction by aluminum and silicon compounds, and much more.
Lanthanides: Fundamentals and Applications provides the fundamentals, new research, promising applications and future outlooks of lanthanide compounds and lanthanide-based materials. The book begins with an introduction, including key concepts, oxidation states and sources, extraction and separation of the lanthanides, followed by spectroscopic and magnetic properties, and metals, crystals and compounds. Organometallic compounds, coordination compounds, molecular magnetic materials and luminescent materials are covered before a discussion of specific lanthanide applications. Spintronics, bioimaging, photoelectric materials, catalysis and nuclear applications are discussed. This comprehensive resource is ideal for researchers and students studying inorganic and materials chemistry, in both academia and industry.
Advanced Fiber-Reinforced Alkali-Activated Composites: Design, Mechanical Properties, and Durability covers various fiber types and their usage as a sustainable material as well as their influence on mechanical properties and behavior, including compressive strength, tensile strength, flexural strength, and impact and bond resistance. Their durability in different environments (seawater, magnesium sulphate, sulphuric acid, elevated temperature, corrosive) is also discussed. The book also outlines a variety of mix design and curing regimes for alkali-activated composites. The additive manufacturing of these composites is also covered. Different types of fiber-reinforced alkali-activated composites discussed include steel fiber-reinforced, carbon fiber-reinforced, natural fiber-reinforced, synthetic fiber-reinforced, and others.