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Elsevier

Books in Chemistry

Chemistry topic areas include: physical and theoretical, computational, organic, organometallic and inorganic, pharmaceutical and medicinal, analytical and bioanalytical, nuclear, general, nanochemistry, geochemistry, materials and polymer, as well as environmental, green and sustainable chemistry.

  • Analytical Chemistry

    • 1st Edition
    • Clyde Frank
    • English
    Analytical Chemistry, Second Edition covers the fundamental principles of analytical chemistry. This edition is organized into 30 chapters that present various analytical chemistry methods. This book begins with a core of six chapters discussing the concepts basic to all of analytical chemistry. The fundamentals, concepts, applications, calculations, instrumentation, and chemical reactions of five major areas of analytical chemistry, namely, neutralization, potentiometry, spectroscopy, chromatography, and electrolysis methods, are emphasized in separate chapters. Other chapters are devoted to a discussion of precipitation and complexes in analytical chemistry. Principles and applications and the relationship of these reactions to the other areas are stressed. The remaining chapters of this edition are devoted to the laboratory. A chapter discusses the basic laboratory operations, with an emphasis on safety. This topic is followed by a series of experiments designed to reinforce the concepts developed in the chapters. This book is designed for introductory courses in analytical chemistry, especially those shorter courses servicing chemistry majors and life and health science majors.

  • Analysis of Seawater

    • 1st Edition
    • Crompton
    • English
    Analysis of Seawater deals with the investigation of the micro-constituents in seawater in terms of nutrient content and environmental concerns. The book describes sampling, determination of anions, analysis of dissolved gases, and metal preconcentration techniques. The book also deals with monitoring radioactive elements, the determination of seawater organics, organometallic compounds, and the oxygen-demand parameters in seawater. It describes in detail surface and deep water sampling, the types of devices used, storage, preservation, and prevention of contamination during sample analysis. In examining dissolved gases, the investigator can use the amperometric titrimetric method (with some reservations) on chlorine, the ultraviolet method on ozone, electron capture gas chromatography on nitric oxide, and also the flow injection analysis on hydrogen sulphide. The methods for determining metals in seawater concern either for single element or for groups of elements. The investigator should always initiate various pre-concentration techniques when determining metals due to their low concentration and occurrence in seawater. The investigator uses various methods to determine different radioactive compounds such as uranium, polonium, thorium, radium, barium, radon, plutonium, strontium-90, and cesium-137. The book can be beneficial for meteorologists, environmentalists, marine ecologists, biologists, oceanographers, fisheries experts, for students studying hydrology, meteorology, as well as for river and lake authorities.

  • Organometallic Vapor-Phase Epitaxy

    Theory and Practice
    • 1st Edition
    • Gerald B. Stringfellow
    • English
    Here is one of the first single-author treatments of organometallic vapor-phase epitaxy (OMVPE)--a leading technique for the fabrication of semiconductor materials and devices. Also included are metal-organic molecular-beam epitaxy (MOMBE) and chemical-beam epitaxy (CBE) ultra-high-vacuum deposition techniques using organometallic source molecules. Of interest to researchers, students, and people in the semiconductor industry, this book provides a basic foundation for understanding the technique and the application of OMVPE for the growth of both III-V and II-VI semiconductor materials and the special structures required for device applications. In addition, a comprehensive summary detailing the OMVPE results observed to date in a wide range of III-V and II-VI semiconductors is provided. This includes a comparison of results obtained through the use of other epitaxial techniques such as molecular beam epitaxy (MBE), liquid-phase epitaxy (LPE), and vapor phase epitaxy using halide transport.

  • Chemistry: Inorganic Qualitative Analysis in the Laboratory

    • 1st Edition
    • Clyde Metz
    • English
    Chemistry: Inorganic Qualitative Analysis in the Laboratory is a textbook dealing with qualitative analysis in the laboratory, as well as with the process of anion and cation analysis. The book presents an overview of the subject of inorganic qualitative analysis, including as the equipment, reagents, and procedures that are going to be used in the laboratory. Preliminary experiments include the classification of precipitates, handling precipitates, separation techniques, flame tests, Brown ring test, solvent extraction. The text also describes in detail how to prepare the experiment for anion and cation analysis such as testing for water solubility in a solid sample or the sodium carbonate treatment of a water-soluble sample. The book also explains the qualitative analysis for anions in preliminary and specific tests. In the qualitative analysis for cations, the student follows different procedures for Cation Groups I, II, III, IV or V. For example, the ions of Cation Group V cannot be precipitated by any Cation Groups I-IV reagents, nor by any single group reagent. The textbook is suitable for both chemistry teachers and freshmen students.

  • Analytical Chemistry of Polycyclic Aromatic Compounds

    • 1st Edition
    • Milton Lee
    • English
    Analytical Chemistry of Polycyclic Aromatic Compounds focuses on the chemical and physical properties of the polycyclic aromatic compounds, critically evaluating various chromatographic and spectroscopic methods. This book discusses how gas chromatography and high-performance liquid chromatography can be both competitive and complementary analytical methods. Ancillary techniques of both are emphasized for the structural elucidation of individual polycyclic aromatic compounds in complex mixtures. The merits of spectroscopic methods in both structural work and quantitation are also described. This text likewise provides background information concerning the chemistry, occurrence, and toxicology of polycyclic aromatic compounds, including the isolation of polycyclic aromatic compounds from a wide variety of materials and matrices. This publication is recommended to scientists involved with the study of polycyclic aromatic compounds, analysts who need to acquire routine data, and individuals charged with formulating environmental policies and drafting regulations.

  • The Organic Chemistry of Nickel

    Organonickel Complexes
    • 1st Edition
    • P.W. Jolly
    • English
    The Organic Chemistry of Nickel, Volume I: Organonickel Complexes is devoted to a description of the organonickel complexes. The major goal is to provide a reference work, and for this reason a conventional layout has been adopted with separate chapters devoted to each type of organic ligand. In the interest of readability, known compounds have been assembled in tables at the end of each chapter, thereby allowing the text to be used for discussions of the general chemistry involved and to highlight the special reactions associated with nickel. Conscious of the needs of organometallic chemists, the authors included systems in which no nickel-carbon bond is involved. Among these is a chapter on the tetrakisligand nickel complexes and sections on dioxygen and azobenzene complexes. The nitrosyl complexes and complexes containing a metal-metal bond—topics frequently considered to be part of the domain of the organometallic chemist—have not received individual attention. Tables of the observed bond distances in organonickel complexes are provided as an Appendix; a short list of the more important review articles relevant to each organic ligand can be found at the end of each chapter.

  • Analytical Gas Chromatography

    • 1st Edition
    • Walter Jennings
    • English
    Analytical Gas Chromatography is a free-standing introduction to and guide through the rapidly progressing field of analytical gas chromatography. The book is divided into 10 chapters that cover various aspects of analytical gas chromatography, from most advantageous column type to troubleshooting. The opening chapters of the book discuss the advantages of the open tubular column over the packed column. This topic is followed by significant chapters on various variables in the gas chromatographic process, including sample injection, stationary phase, carrier gas, and installation. The effect of changes in these variables on the solution elution order is also considered. A chapter also examines the influence of instrumental design features, such as excessive or unswept volumes in the flow path; suitability of the detection mode; and speed and fidelity of the data-handling equipment. The book also presents selected methods that have been employed to achieve better results for a given gas chromatographic problem. The application areas of gas chromatographic process, including food, flavor, fragrance, petroleum- and chemical-related, environment, biology, and medicine, are also presented. The concluding chapter addresses the basic troubleshooting knowledge and considers other chromatographic problems and methods for their rectification.

  • Organometallic Polymers

    • 1st Edition
    • Charles E. Jr. Carraher
    • English
    Organometallic Polymers focuses on the synthesis, characterization, and potential applications of organometallic polymers. The discussion is organized around seven themes: vinyl polymerization of organometallic monomers; condensation polymerization of organometallic monomers; polymer-bound catalysts; applications of organotin polymers; developments in organosilicon polymers; phosphonitrile and sulfur nitride polymers; and coordination polymers. This book is comprised of 33 chapters and begins with a general review of polymerized vinyl monomers containing transition metals, as well as the reactivity of such monomers in addition to homo- and copolymerizations. The following chapters explore the participation of the ferrocene nucleus in the polymerization of vinylferrocene and its effect on polymer properties; thermomechanical transitions of ferrocene-containing polymers; photocrosslinkable organometallic polyesters; and supported catalysts for ethylene polymerization. The remaining sections discuss antifouling applications of various tin-containing organometallic polymers; structure and applications of polyphosphazenes and polymeric sulfur nitride; and coordination of inorganic ions to polymers. This monograph will be a useful resource for organic chemists and research workers in the field.

  • Electrical, Optical and Magnetic Properties of Nucleic acid and Components

    • 1st Edition
    • J Duchesne
    • English
    Physico-chemical Properties of Nucleic Acids, Volume I deals with the intrinsic properties of nucleic acids (macromolecules) and their components. This volume includes the analysis of different types of bindings or interactions mechanisms such as photodynamic and radiation effects and fluorescence. Nine chapters comprise this volume. A number of chapters in the beginning of this book emphasize purines and pyrimidines. Dipole moments and charge transfer interactions are some of the specific topics covered regarding purines and pyrimidines. The topic of nucleic acids and components is discussed in detail in the middle up to the last part of the book, wherein electrical properties and energy transfer are explored. Other aspects covered include developments in fluorescence; free radicals in aqueous solutions; and irradiated single crystals. This volume will cater to undergraduates and graduate students as well as to researchers in the major fields of biology, chemistry, and physics.

  • Physical Principles and Techniques of Protein Chemistry Part C

    • 1st Edition
    • Sydney Leach
    • English
    Physical Principles and Techniques of Protein Chemistry, Part C focuses on the effects of intermolecular interactions that are transmitted between ligands and proteins and from protein to protein. This book discusses the density and volume change measurements; direct volume change; osmotic pressure; and small-angle X-ray scattering. The theory of particulate scattering; pulsed nuclear magnetic resonance; absorption of water by diamagnetic molecules; and use of least squares in data analysis are also elaborated. This text likewise covers the iteration process; optical rotatory dispersion and the main chain conformation of proteins; and basic relations for optically active molecules. Other topics include the circular dichroism, secondary structure of proteins, visible rotatory dispersion, and peptide cotton effects. This publication is intended for protein chemists, but is also useful to biologists, medical practitioners, and students researching on protein chemistry.

  • Object-Oriented Magnetic Resonance

    Classes and Objects, Calculations and Computations
    • 1st Edition
    • Michael Mehring + 1 more
    • English
    This book presents, for the first time, a unified treatment of the quantum mechanisms of magnetic resonance, including both nuclear magnetic resonance (NMR) and electron spin resonance (ESR). Magnetic resonance is perhaps the most advanced type of spectroscopy and it is applied in biology, chemistry, physics, material science, and medicine. If applied in conjunction with spectroscopy, the imaging version of magnetic resonance has no counterpart in any type of experimental technique. The authors present explanations and applications from fundamental to advanced levels.

  • The Proteins Pt 1

    • 3rd Edition
    • Hans Neurath
    • English
    The Proteins, Volume I, Third Edition presents the procedures for the isolation and characterization of proteins and methods for the establishment of homogeneity. This volume contains chapters that discuss molecular sieve techniques for protein analysis; the theory and practice of biospecific affinity chromatography; gel electrophoresis of proteins in sodium dodecyl sulfate; sedimentation analysis of proteins; the subunit structure of proteins; and the analysis of protein subunit structure by electron microscopy. Protein chemists, medical and biological researchers, and students who require more knowledge of protein chemistry will find the book of great value.

  • Nonaqueous Electrolytes Handbook

    • 1st Edition
    • G.J. Janz
    • English
    Nonaqueous Electrolytes Handbook, Volume I, is an authoritative and updated information source for nonaqueous solvent systems. The information in this handbook covers the literature to 1972 and includes data for some 210 solvents. The book has been organized into eight well-defined areas: Physical Properties o f Solvents, Solvent Purification, Electrical Conductance, Diffusion, Density, Viscosity, Transference Numbers, and Additional References and Data Sources. The latter section covers additional data sources and reviews not adequately described in the preceding sections; recent data and references are also found in this section. The method of presentation of material is briefly described in the introduction to each section to facilitate the use of the tabulated information. Bibliographies are given at the end of each section. A Compound Index is included. Electrical conductance is the property most widely investigated. In view of the wealth of data, this section has been organized by solutes as follows: acids and alkali metal compounds, including ammonium compounds; quaternary ammonium salts and amines; solvent systems, electrolyte systems, and finally, all other solutes. For each, the data are reported not only for single component nonaqueous solvents but also for mixed solvents.

  • Organometallic Photochemistry

    • 1st Edition
    • Gregory Geoggroy
    • English
    Organometallic Photochemistry explores the photochemical properties of transition-metal organometallic complexes, such as metal carbonyls, olefin complexes, arene complexes, and cyclopentadienyl complexes. Isocyanide complexes, hydride complexes, and alkyl complexes are also covered. This book consists of eight chapters and begins with an overview of organometallic complexes and their electronic structure, along with the principles of photochemistry. The chapters that follow are detailed reviews of photochemical studies organized according to type of organometallic. Each chapter is organized according to the central metal atom and its group in the periodic table. The chapter on metal carbonyl complexes focuses on the excited-state chemistry of compounds, such as vanadium, niobium, chromium, molybdenum, manganese, iron, cobalt, and nickel. The next chapter deals with olefin complexes, such as niobium, chromium, rhenium, rhodium, platinum, and copper. The chapters on arene, cyclopentadienyl, isocyanide, hydride, and alkyl complexes explore topics ranging from bonding and electronic structure to photoreactions, photosubstitution, redox chemistry, homolysis, and decomposition. This text is a valuable resource for photochemists and those who are interested in organometallic photochemistry.

  • Modern Methods of Steroid Analysis

    • 1st Edition
    • Erich Heftmann
    • English
    Modern Methods of Steroid Analysis reviews modern methods of steroid analysis such as liquid column chromatography, mass spectrometry, and gas chromatography. Topics covered include qualitative and quantitative analysis of plant sterols by gas-liquid chromatography; Raman spectroscopy of steroids; nuclear magnetic resonance; and applications of lanthanide shift reagents. A computerized method for rapid comparison and retrieval of infrared spectral data is also described. This volume is comprised of 22 chapters and begins with an analysis of hormonal steroids using liquid column chromatography, followed by a discussion on the separation of insect molting hormones using high-pressure liquid chromatography. The reader is methodically introduced to the application of gradient elution and thin-layer chromatography to the analysis of corticosteroids and 17-ketosteroids, as well as some aspects of mass spectrometry in steroid analysis. Subsequent chapters explore other methods such as optical rotatory dispersion and circular dichroism, along with radioisotope techniques. In particular, the radioimmunoassay of plasma steroid hormones and plasma aldosterone is considered. This book should be of interest to biochemists.

  • Intra-and Intermolecular Interactions, Radiation Effects in DNA Cells, and Repair Mechanisms

    • 1st Edition
    • J Duchesne
    • English
    Physico-chemical Properties of Nucleic Acids, Volume III revolves around three major concepts, which are intra- and intermolecular interactions, radiation effects in DNA cells, and repair mechanisms. This volume also presents the stage of specific biological functions and how repair mechanisms relate to the problem of evolution. Comprised of six chapters, this volume begins with the concept of renaturation of polynucleotides. Interactions in nucleic acids and nucleotides are discussed in several chapters. Other topics covered in this volume include polymer and salt-induced condensation of DNA and strand-breaks in the DNA of mammalian cells. The last chapter explores the stability and evolution of DNA in terms of molecular radiobiology. This chapter also presents and reviews some evolutionary problems, specifically the prebiotic evolution. The elements of stabilization and variability of genetic information are also discussed in the last chapter. As with the other volumes, this volume is a valuable reference for students and researchers in the fields of chemistry, biology, molecular biology, microbiology, and biophysics.

  • Activation Of Small Inorganic Molecules

    • 1st Edition
    • M.M. Taqui Khan
    • English
    Homogeneous Catalysis by Metal Complexes, Volume I: Activation of Small Inorganic Molecules reviews and systematizes the chemistry of the metal ion activation of the small diatomic molecules. The book discusses the activation of molecular hydrogen, molecular oxygen, molecular nitrogen, carbon monoxide, and nitric oxide.

  • Transparency Masters for Basics for Chemistry

    • 1st Edition
    • David Ucko
    • English
    Transparency Masters for Basics for Chemistry consists of 47 figures, tables, and charts illustrating concepts in basic chemistry, including energy levels, molecular formation and characteristics, the periodic table of elements, and much more.

  • The Chemistry of Electrode Processes

    • 1st Edition
    • Ilana Fried
    • English
    The Chemistry of Electrode Processes discusses "electrodics" or the science dealing with the transfer of an electric charge between a solid and liquid phase. This book reviews the applications of electrodics, the history of electrochemistry, and the basic definitions and concepts of the galvanic cell. This text also deals with the rate expressions associated with the different types of electrode reaction mechanism including the passing of Faradaic current, the current-voltage curve, mass transport overpotential, and the influence of surface structure on electrode processes. This book describes the electrode-solution interphase at equilibrium, the properties of such interphase, and the ways it can influence electrode kinetics. Any electrode reaction involves several steps and can be influenced by diffusion, adsorption and other parameters. The techniques to study electrode reactions and the electrode-solution interphase consists of equilibrium measurements, steady state measurement, and transient measurement. This text also describes the significant and potential uses of electrodics in technology which need less expensive equipment compared to using spectrophotometric techniques. This book is suitable chemists, for advanced students in analytical chemistry, physics, thermodynamics, and related subjects.

  • Alkali Halide Vapors

    Structure, Spectra, and Reaction Dynamic
    • 1st Edition
    • P. Davidovits
    • English
    Alkali Halide Vapors: Structure, Spectra, and Reaction Dynamics highlights the various studies done in the subject area of alkali halide chemistry. These studies have resulted to providing many relevant insights and paving the way for the study of more complex chemical systems. This book ultimately reviews and summarizes the said studies. This text is divided into two categories: structural and spectral properties of the alkali halide molecules and dynamics of various alkali atom-halogen reactions. The first category is discussed in Chapters 1, 3-5, and 15, while the second category is presented in Chapters 6-14. Chapter 2 however belongs to neither of the said categories as it describes the techniques and considerations related to alkali halogen experiments. Numerous quantitative data in table format are presented all of the discussions in this book. An index of these tables has been compiled and can be found in the last part of the book. This book will be a valuable material to students, scientists, and researchers in the scientific field of chemistry, physics, and applied science.

  • The Chemistry of Synthetic Dyes V5

    • 1st Edition
    • K Venkataraman
    • English
    The Chemistry of Synthetic Dyes, Volume V is a critical assessment of patent literature and scientific journals on the synthesis and applications of synthetic dyes. This volume contains eight chapters, and begins with a description of several interesting reactions involved in the synthesis of naphthoquinonoid dyes and pigments, followed by a discussion on the influence of coplanarity on the affinity of these dyes for cellulosic and synthetic fibers. The subsequent six chapters are devoted to the synthesis, reactions, properties, and applications of specific synthetic dyes, including acid anthraquinone, anthoquinonoid vat, phthalocyanine, phthalogen, organic, and hair dyes. The final chapter describes the fluorescent brightening agents and their close relationship to synthetic dyes. This book will prove useful to organic chemists and technologists who are concerned with the synthesis of dyes and their applications.

  • Anti-inflammatory Agents Part II

    Chemistry and Pharmacology
    • 1st Edition
    • Robert Scherrer
    • English
    Medicinal Chemistry: A Series of Monographs, Volume 13–II presents the context of inflammation and the therapeutic interventions in debilitating chronic inflammatory diseases. This book discusses the progress of therapeutics in the field of medicine with less cost but with the same degree of benefit. Comprised of 10 chapters, this volume begins with a discussion on the pathophysiological context of chronic inflammatory diseases. This book then explores the local hormones that act as alarm signals following a local injury, which includes serotonin, histamine, kinins, heparin, prostaglandin, adenylates, lysolecithins, and catecholamines. Other chapters feature contributors who have active research on the clinical evaluation and treatment of severely debilitating chronic inflammatory diseases, including gout, arthritis, rheumatoid arthritis, osteoarthritis, psoriasis, and systemic lupus erythematosus. The final chapter explores the metabolism of anti-inflammatory drugs that are organized around chemical classes of compounds. This book is a valuable source of information for physicians, chemists, and experimental biologists.

  • Aerosols and Atmospheric Chemistry

    The Kendall Award Symposium Honoring Professor Milton Kerker
    • 1st Edition
    • Milton Kerker
    • English
    Aerosols and Atmospheric Chemistry is a collection of papers presented at the American Chemical Society Kendall Award Symposium honoring Professor Milton Kerker, held in Los Angeles, California, on March 28-April 2, 1971. Contributors focus on the physical chemistry of aerosols and their relationship to atmospheric chemistry. Topics covered range from the optical and dynamical properties of aerosols to the kinetics of growth of an aerosol in a flow reactor. The formation and chemical reactions of atmospheric particles are also discussed. This book is comprised of 30 chapters and begins with an overview of some of the optical and dynamical properties of aerosols, along with the preparation of submicron aerosols by condensation. The discussion then turns to the formation and properties of neutral ultrafine particles and small ions conditioned by gaseous impurities of the air; preparation of ultrafine metal oxide particles in a hydrogen-oxygen flame; production of aerosols by X-rays; and condensational growth of atmospheric aerosols. A comparison of synthetic and smog aerosols is also presented. The final section is devoted to the Los Angeles (Pasadena) Smog Project—its genesis, objectives, and scope—and provides a detailed description of the Minnesota Aerosol Analyzing System used in the project. This monograph will be a useful resource for chemists as well as students and researchers interested in aerosol and atmospheric chemistry.

  • Study Guide to Accompany Basics for Chemistry

    • 1st Edition
    • Martha Mackin
    • English
    Study Guide to Accompany Basics for Chemistry is an 18-chapter text designed to be used with Basics for Chemistry textbook. Each chapter contains Overview, Topical Outline, Skills, and Common Mistakes, which are all keyed to the textbook for easy cross reference. The Overview section summarizes the content of the chapter and includes a comprehensive listing of terms, a summary of general concepts, and a list of numerical exercises, while the Topical Outline provides the subtopic heads that carry the corresponding chapter and section numbers as they appear in the textbook. The Fill-in, Multiple Choice are two sets of questions that include every concept and numerical exercise introduced in the chapter and the Skills section provides developed exercises to apply the new concepts in the chapter to particular examples. The Common Mistakes section is designed to help avoid some of the errors that students make in their effort to learn chemistry, while the Practical Test section includes matching and multiple choice questions that comprehensively cover almost every concept and numerical problem in the chapter. After briefly dealing with an overview of chemistry, this book goes on exploring the concept of matter, energy, measurement, problem solving, atom, periodic table, and chemical bonding. These topics are followed by discussions on writing names and formulas of compounds; chemical formulas and the mole; chemical reactions; calculations based on equations; gases; and the properties of a liquid. The remaining chapters examine the solutions; acids; bases; salts; oxidation-reduction reactions; electrochemistry; chemical kinetics and equilibrium; and nuclear, organic, and biological chemistry. This study guide will be of great value to chemistry teachers and students.

  • Physical Chemistry An Advanced Treatise

    • 1st Edition
    • Wilhelm Jost
    • English
    Physical Chemistry: An Advanced Treatise, Volume I: Thermodynamics deals with the applications of thermodynamics to mixtures, fluids, and solid systems at high pressures and temperatures, critical phenomena, practical handling of coupled gas equilibriums, and matter in electric, magnetic, and gravitational fields. This book begins with a survey of basic laws, followed by discussions on questions of stability, irreversible processes, surfaces, the third law, and a short introduction to Caratheodory's axiomatic foundation. The zeroth law of thermodynamics, gaseous mixtures, internal equilibrium in solids, thermodynamic properties of the mixture, and theory of linear differential forms are also elaborated. This publication presents a comprehensive treatment of physical chemistry for advanced students and researchers.

  • The Chemistry of Nonaqueous Solvents III

    • 1st Edition
    • J.J. Lagowski
    • English
    The Chemistry of Nonaqueous Solvents, Volume III: Inert, Aprotic, and Acidic Solvents is a compilation of critical surveys of specific solvent systems. The compendium contains discussions on the solution chemistry of sulfur dioxide and acyl halides; the solvent properties of hydrogen sulfide and carboxylic acids; and the Bronsted acid-base behavior in inert organic solvents. Chemists, researchers, and students of chemistry and chemical engineering will find the book a good reference material.

  • The Chemistry of Synthetic Dyes V8

    • 1st Edition
    • K Venkataraman
    • English
    The Chemistry of Synthetic Dyes, Volume VII stresses the relation between the chemistry of synthetic dyes and their application properties. This book describes the dyes for leather, synthetic carotenoids as food colorants, and solvent dyes. The phenomenal progress made in transfer printing, which the first commercial process became available as recently as 1968, is also discussed. This text likewise considers the influence of structural factors on the lightfastness of dyed fibers and structures of dyes with their technical properties. This volume is a good reference for organic chemists and technologists working on the synthesis of dyes and their applications.

  • Determination of Organic Structures by Physical Methods V4

    • 1st Edition
    • F.C. Nachod
    • English
    Determination of Organic Structures by Physical Methods, Volume 4 is a seven-chapter text that discusses the refinements of some established physical methods for organic structure determination. Each chapter of this book examines specific physical method, including high-field and pulsed NMR, nuclear magnetic double resonance spectroscopy, and 15N, 13C, and 31P nuclear magnetic resonance. The historical developments, principles, instrumentation, and applications to organic chemistry of these methods are discussed. This work will be of value to organic and analytical chemists and researchers.

  • Contemporary Practice of Chromatography

    • 1st Edition
    • C.F. Poole + 1 more
    • English
    Written for all those who use chromatography as an analytical tool, this book covers all areas of gas, liquid, and thin-layer chromatography; no other book offers the same scope. The authors have had considerable experience in teaching graduate-level courses and the material presented here has been tried and tested, having formed the basis for short courses taught to groups of industrial chemists. Emphasis is on the practice of chromatographic methods, including ``how to'' sections and numerous examples of calculation methods. Extensively illustrated, the book contains numerous tables of all useful constants, materials and formulas frequently used by chromatographers. Valuable features are the chapters on sample preparation for chromatographic analysis, on instrumental methods for sample identification, and the comprehensive literature review.

  • Kinetics Of Gas Reaction VIA

    • 1st Edition
    • Willhelm Jost
    • English
    Physical Chemistry: An Advanced Treatise, Volume VIA: Kinetics of Gas Reactions discusses single reaction steps, such as transformations of atoms and molecules in specified velocities, impact parameters, and inner states into products of specified states. This book is divided into six chapters. Chapter 1 covers formal kinetics, while Chapter 2 reviews the survey of kinetic theory, as one of the bases of reaction kinetics. The Born-Oppenheimer adiabatic approximation, valence bond method, and orbital symmetry in reaction kinetics are elaborated in Chapter 3. Chapter 4 is devoted to the theory of energy transfer in molecular collisions, considering the several possible types of energy exchange. Chapter 5 focuses on the molecular beam scattering experiments on elastic, inelastic, and reactive collisions. The dynamics of bimolecular reactions are elaborated in the last chapter. This volume is intended for graduate and physical chemistry students interested in kinetics of gas reactions.

  • Polyatomic Molecules

    Results of ab Initio Calculations
    • 1st Edition
    • Robert S. Mulliken
    • English
    Polyatomic Molecules: Results of Ab Initio Calculations describes the symmetry of polyatomic molecules in ground states. This book contains 12 chapters that also cover the excited and ionized states of these molecules. The opening chapter describes the nature of the various ab initio computational methods. The subsequent four chapters deal with the three-atom systems, differing with respect to the number of hydrogen atoms in the molecules. These chapters also discuss the reaction surfaces of these systems. These topics are followed by discussions on the molecules whose ground states belong to relatively high, little or no symmetry groups. The concluding chapters explore the inorganic and relatively large organic molecules. These chapters also examine the ab initio calculations of molecular compounds and complexes, as well as hydrogen bonding and ion hydration. This text will be of great value to organic and inorganic chemists and physicists.

  • Molecular Graphics on The IBM ® PC Microcomputer

    • 1st Edition
    • James Henkel
    • English
    Molecular Graphics on the IBM® PC Microcomputer is a five-chapter manual that introduces the PC MODEL computer package and provides step-by-step instructions for using it. The PCMODEL is a program to draw and manipulate molecules in graphic form using the IBM® PC, PC/XT, PC/AT, PCjr, and true compatible personal computers. This package has a multitude of applications, including the study of conformations of organic molecules and the organization of organic and inorganic crystal lattices. This manual is organized into two sections, namely, the tutorial and reference parts. The first section is highly tutorial in nature because this is where one will need it most, whereas the later section is much less so because one will then be more in need of detailed reference material. This book will be of value to organic chemists and researchers.

  • Standard Methods of Clinical Chemistry

    • 1st Edition
    • Miriam Reiner
    • English
    Standard Methods of Clinical Chemistry, Volume I focuses on the methods used most frequently in the clinical laboratory. This book examines the scientific basis of each method, its scope, as well as its limitations. Organized into 19 chapters, this volume starts with an overview of the scope of the clinical chemist's responsibility, which includes the collection of the specimen for analysis, performance of the test, reporting the results to a responsible party, and interpretation of results to clinicians. This book then explores serum amylase activity, which may be demonstrated under several conditions of temperature, time, and substrate quality. Other chapters explore the significance of blood glucose determinations in the detection of diabetes mellitus and the control of this disease by evaluation of the various dosages of insulin. The final chapter deals with the methods for the estimation of uric acid. Clinical chemists, laboratory workers, and technicians will find this book extremely useful.

  • Carboranes

    • 1st Edition
    • Russell Grimes
    • English
    Carboranes offers a comprehensive treatment of carborane chemistry and covers topics ranging from structures and chemical bonding to the degradation of the icosahedral cage. Carborane polymers as well as small nido- and closo-carboranes, intermediate closo-carboranes, and o-, m-, and p-carboranes are also discussed. This book is comprised of nine chapters and begins with an overview of the chemistry and properties of carboranes. The discussion then turns to the molecular structures of polyhedral carboranes and open-cage carboranes, along with the isomerism and rearrangement of carboranes; nomenclature and numbering systems used for carboranes; and chemical bonding in boranes and carboranes. The following chapters explore the synthesis, reactions, structures, and properties of small nido- and closo-carboranes, intermediate closo-carboranes, and o-, m-, and p-carboranes. The reactions of boranes and alkylboranes with alkynes as well as the degradation of icosahedral carboranes are also described. This monograph will be a useful resource for organic and inorganic chemists.

  • Crystal Chemistry and Semiconduction in Transition Metal Binary Compounds

    • 1st Edition
    • J Suchet
    • English
    Crystal Chemistry and Semiconduction in Transition Metal Binary Compounds provides information pertinent to semiconductor materials. This book discusses the different semiconduction mechanisms in special compounds, including rare earth compounds or transition metals, vitreous or liquid substances, and organic semiconductors. Organized into three parts encompassing 11 chapters, this book starts with an overview of the basic principles of chemistry, such as the periodic table and the structure of the atom. This text then discusses the substances in which atomic magnetic moment exists, and whose transport properties are not typically metallic. Other chapters examine the experimental work on the electrical conductibility of compounds of transition metals, actinides, or rare earths. This book discusses as well the theoretical concepts necessary for the construction of approximate models to estimate the properties of compounds. The final chapter deals with the modulation of visible or infrared light, which is the only application of magneto- and electro-optical effects. This book is a valuable resource for research scientists, engineers, and teachers.

  • Colloid and Interface Science V5

    Biocolloids, Polymers, Monolayers, Membranes, And General Papers
    • 1st Edition
    • Milton Kerker
    • English
    Colloids and Interface Science, Volume V: Biocolloids, Polymers, Monolayers, Membranes, and General Papers is a collection of manuscripts presented at the International Conference on Colloids and Surfaces, held in San Juan, Puerto Rico on June 21-25, 1976. The conference is sponsored jointly by the Division of Colloid and Surface Chemistry of the American Chemical Society and the International Union of Pure and Applied Chemistry in celebration of the 50th Anniversary of the Division and the 50th Colloid and Surface Science Symposium. This volume is organized into 51 chapters that cover the subjects of biocolloids, polymers, monolayers, membranes, and general papers. Other topics discussed include the thermodynamic aspects of biocolloids; adsorption of polymers; ion-exchange behavior; optical properties of polymers; microvoid films; micellar systems; and liquid crystals. The remaining chapters explore the diffusion and sorption of simple ions, surface properties of copolymers, and adhesion of thermoplastic elastomers.

  • Organometallic Reaction Mechanisms Of The Nontransition Elements

    • 1st Edition
    • Donald Matteson
    • English
    Organometallic Reaction Mechanisms of the Nontransition Elements provides selected significant developments in organometallic reaction mechanisms and outlines a self-consistent set of interpretations of these mechanisms. This book is organized into eight chapters and begins with discussions on bonding in theoretically important types of organometallic compounds and the potential surfaces and their relation to mechanisms. This is followed by significant chapters on electrophilic displacement reactions. Polar 1,2-addition and elimination reactions are covered in a separate chapter. Radical and photochemical reactions are described in the concluding chapters of the book, including the reverse reaction involving incorporation of a free metal and an organic halide into an organometallic compound. Organic chemists and researchers will find this book invaluable.

  • High and Low Erucic Acid in Rapeseed Oils

    • 1st Edition
    • John K G Kramer
    • English
    High and Low Erucic Acid Rapeseed Oils: Production, Usage, Chemistry, and Toxicological Evaluation covers a wide range of subjects related to rapeseed, that is, from plant breeding, industrial processing, to nutrition and biochemistry. Composed of 22 chapters, this book first discusses the origin and properties of Brassica oilseed crops. Subsequent chapters describe the world production and trade of rapeseed and its products, as well as the history and marketing of rapeseed oil in Canada. Other chapters elucidate the chemical composition of rapeseed oil; the introduction and consumption of low erucic acid rapeseed varieties in Canada; and the development of improved rapeseed cultivars. Results obtained with consumption of high and low erucic acid rapeseed oils to experimental animals are also shown. This work will be helpful as an introductory material to those who are not familiar with the production, use, and properties of rapeseed oil.

  • Diatomic Molecules

    Results of ab Initio Calculations
    • 1st Edition
    • Robert Mulliken
    • English
    Diatomic Molecules: Results of Ab Initio Calculations provides the results obtained from quantum-mechanical calculations on the electronic structure of diatomic molecules. This six-chapter text also discusses the related concepts of ab initio calculation methods. This book considers first the primary methods used in the computation of molecular wave functions and of related properties. This topic is followed by discussions on the linear combination of atomic orbital and linear combination of mixed atomic orbital approximations and basis sets; electronic population analysis; spectroscopic transition probabilities; and the nature of chemical bonding. The remaining chapters examine the features of various theories that become prominent when two or more electrons are present, or are important in hydrides or homopolar and heteropolar molecules. This text will be of great value to organic and inorganic chemists and physicists.

  • Colloid and Interface Science V3

    Adsorption, Catalysis, Solid Surfaces, Wetting, Surface Tension, And Water
    • 1st Edition
    • Milton Kerker
    • English
    Colloid and Interface Science, Volume III: Adsorption, Catalysis, Solid Surfaces, Wetting, Surface Tension, and Water covers the proceedings of the International Conference on Colloids and Surfaces, held in San Juan, Puerto Rico on June 21-25, 1976. The conference is sponsored jointly by the Division of Colloid and Surface Chemistry of the American Chemical Society and the International Union of Pure and Applied Chemistry in celebration of the 50th Anniversary of the Division and the 50th Colloid and Surface Science Symposium. This volume contains 56 chapters that cover the subjects of adsorption, catalysis, solid surfaces, wetting, surface tension, and water. Other topics discussed include chemisorption; analytical methods for surface analysis; reaction kinetics; polymeric colloid systems; hydrogel-water interface; and the effect of various parameters, such as temperature and pressure. The concluding chapters explore surface and interfacial tension measurement, capillarity, thermal expansion of water, and heat capacity of vicinal water.

  • Polymers as Aids in Organic Chemistry

    • 1st Edition
    • N.K Mather
    • English
    Polymers as Aids in Organic Chemistry covers the broad classifications and application of polymers in organic chemistry. This book is organized into 15 chapters that focus on the transformation of polymers and their role in other reagents that must be easily separated from their final product. After a brief introduction to polymer chemistry, the book presents a tabulation of the various types of polymers that have been used and the methods for their characterization. It then discusses the use of polymers as supports in peptide, oligonucleotide, and oligosaccharide chemistry; in peptide sequencing; in monofunctionalized difunctional compounds preparation, as aids in asymmetric syntheses; and as trapping agents in the determination of reaction intermediates. The subsequent chapters describe the use of polymers as catalysts, with particular emphasis on transition metals immobilized in the polymer matrix and used as catalysts. The concluding chapters examine polymer-immobilized compounds, enzymes, and whole cells that have been used to carry out a large number of reaction, most of which impinge on the area of organic chemistry. Polymer scientists and researchers and organic chemists will find this book invaluable.

  • Higher Excited States of Polyatomic Molecules V2

    • 1st Edition
    • Melvin Robin
    • English
    Higher Excited States of Polyatomic Molecules, Volume II focuses on a higher level of activity in vacuum ultraviolet spectroscopy. This book explores the Rydberg states in atoms and molecules. Comprised of five chapters, this volume starts with an overview of the two-center unsaturated molecules that usually display sharp Rydberg transitions originating with the pi electrons. This book then discusses the unsaturated double bond that adds another dimension to the spectrum. Other chapters explore the optical spectrum of the amide group, which is the basic chromophoric unit in polypeptides. This text further discusses the all-electron calculations of the electronic structure of the amide group that is performed in Gaussian orbital basis sets. This book considers as well the prominent characteristic of Rydberg excitations in benzene. The final chapter deals with the biological molecules that are polyfunctional in general. Analytical chemists, photochemists, molecular spectroscopists, and researchers will find this book extremely useful.

  • The Chemistry of Synthetic Dyes V4

    • 1st Edition
    • K Venkataraman
    • English
    The Chemistry of Synthetic Dyes, Volume IV is a critical assessment of patent literature and scientific journals on the synthesis and applications of synthetic dyes. This volume is composed of seven chapters, and begins with a discussion on the application of dyes in textile fibers and printing, as well as in dyeing industry. A chapter provides a general description of dyeing, other properties, and applications of basic dyes. These topics are followed by a survey of the classification and potential application of cationic dyes. Another chapter focuses on the synthesis and reaction mechanisms of cyanine dyes. The final chapters look into the principles and chemistry of the formation of images by oxidative coupling. These chapters also examine the general laws governing the photochemical processes of dyes and of other organic compounds; the photochemical reactions of dyes in solution; the light-fading of dyed textiles and other dyes substrates; and the effect of spectral sensitization and special photo-reactions of dyes. This book will prove useful to organic chemists and technologists who are concerned with the synthesis of dyes and their applications.

  • Chemisorption and Magnetization

    • 1st Edition
    • P. W. Selwood
    • English
    Chemisorption and Magnetization focuses on particle size determination and on the number of adsorbent atoms affected when any molecule is adsorbed on a surface. This book examines the adsorption of a molecule on the surface of a ferromagnetic solid that produces a change in the magnetization of the solid. Organized into 12 chapters, this book starts with an overview of the experimental methods used for studying chemisorption and magnetization, which are applicable in granulometry. This text then discusses the measurement of saturation magnetization in a ferromagnetic substance in the form of small particles. Other chapters consider the conditions in a typical nickel silica hydrogenation catalyst. This text examines as well the magnetization at moderate fields and near room temperature. The final chapter deals with the properties and complexities of palladium, platinum, and nickel. Students and researchers interested in heterogeneous catalysis and related areas will find this book extremely useful.

  • Organometallic Chemistry of Titanium, Zirconium, and Hafnium

    • 1st Edition
    • P.C. Wailes
    • English
    Organometallic Chemistry of Titanium, Zirconium, and Hafnium covers the chemistry of organic complexes of titanium, zirconium, and hafnium having metal-to-carbon linkage. This book is organized into eight chapters that consider the significant developments in delineating the chemistry of these metal derivatives. This book starts with a description of the stability and bonding in cyclopentadienyl derivatives of the metals, based on the thermodynamic and spectroscopic evidence. The remaining chapters discuss the preparation and reactions of titanium-, zirconium-, and hafnium-bonded organic compounds. These chapters also look into the synthetic difficulties encountered from the reactions and preparation of these compounds. The stabilization and adduct formation of these metal complexes are also explored. Organic chemists and organic chemistry researchers and students will find this book invaluable.

  • A Textbook of Physical Chemistry

    • 2nd Edition
    • Arthur Adamson
    • English
    A Textbook of Physical Chemistry, Second Edition serves as an introductory text to physical chemistry. Topics covered range from wave mechanics and chemical bonding to molecular spectroscopy and photochemistry; ideal and nonideal gases; the three laws of thermodynamics; thermochemistry; and solutions of nonelectrolytes. The kinetics of gas-phase reactions; colloids and macromolecules; and nuclear chemistry and radiochemistry are also discussed. This edition is comprised of 22 chapters; the first of which introduces the reader to the behavior of ideal and nonideal gases, with particular emphasis on the van der Waals equation. The discussion then turns to the kinetic molecular theory of gases and the application of the Boltzmann principle to the treatment of molar polarization; dipole and magnetic moments; the phenomenology of light absorption; and classical and statistical thermodynamics. The chapters that follow focus on the traditional sequence of chemical and phase equilibria, electrochemistry, and chemical kinetics in gas phase and solution phase. This book also considers wave mechanics and its applications; molecular spectroscopy and photochemistry; and the excited state, and then concludes with an analysis of crystal structure, colloid and polymer chemistry, and radio and nuclear chemistry. This reference material is intended primarily as an introductory text for students of physical chemistry.

  • Physical Principles and Techniques of Protein Chemistry Part B

    • 1st Edition
    • Sydney Leach
    • English
    Physical Principles and Techniques of Protein Chemistry, Part B deals with the theories and application of selected physical methods in protein chemistry evaluation. This book is divided into seven chapters that cover the ultracentrifugal analysis, light scattering, infrared (IR) methods, nuclear magnetic resonance (NMR) spectroscopy, and differential thermal analysis of protein properties. This text first describes the fundamental ideas and methodology of sedimentation analysis of ideal noninteracting solutes and the problems of nonideality and solute-solute interaction. This book then deals with the problems involved in the interpretation of viscometric data for evaluation of intrinsic viscosity of proteins. The following chapters examine the principles, measurement and analysis of spectra, and experimental techniques of light scattering, IR, and NMR spectroscopic methods. Discussions on coordination phenomena, identification of binding sites, and ion binding in the crystalline state and in protein solutions are included. The concluding chapter presents some examples of protein analysis using differential thermal analysis technique. This book is of great value to chemists, biologists, and researchers who have great appreciation of protein chemistry.

  • New Frontiers in Rare Earth Science and Applications

    • 1st Edition
    • Xu Guangxian
    • English
    New Frontiers in Rare Earth Science and Applications, Volume I consists of extended abstracts of the lectures, papers, and posters presented at the International Conference on Rare Earth Development and Applications held in Beijing on September 10-14, 1985. This compilation discusses rare earth chemical and physical metallurgy, geology of rare earth mineralization in China, and study of hydroxamic acids for the floatation of rare earth minerals. The reactions of organolanthanoid complexes, use of lanthanide ions in the study of calmodulin structure, and influence of the weak magnetic field on red blood cell electrophorisis in mice bodies are also deliberated. This publication is a good source for researchers and scientists of disciplines related to earth science.

  • Methods for Oxidation of Organic Compounds V1

    Alcohols, Alcohol Derivatives, Alky Halides, Nitroalkanes, Alkyl Azides, Carbonyl Compounds Hydroxyarenes and Aminoarenes
    • 1st Edition
    • Alan Haines
    • English
    Methods for the Oxidation of Organic Compounds: Alkanes, Alkenes, Alkynes, and Arenes is an account of the different methods used for the controlled oxidation of alkanes, alkenes, alkynes, and arenes. Most of the oxidative techniques considered are illustrated with detailed experimental procedures taken from the literature. This book is comprised of five chapters and begins with a discussion on alkanes, alkyl groups, and hydrocarbon residues. The formation of alkenes, alcohols, hydroperoxides, dialkyl peroxides, cyclic peroxides, ethers, and esters as well as aldehydes, ketones, and carboxylic acids is described, together with the aromatization of cyclic systems. The following chapters are devoted to alkenes, alkynes, and arenes and focus on the formation of compounds ranging from 1,2-diols and oxiranes (1,2-epoxides) to 1,2-dicarbonyl compounds, phenols and their derivatives, and quinones. The formation of dialkynes by oxidative coupling of 1-alkynes is described, along with the oxidative cleavage of arenes and oxidative coupling of phenols. This monograph should be of interest to organic chemists and research students.

  • Multidimensional Pharmacochemistry

    Design of Safer Drugs
    • 1st Edition
    • Peter Mager
    • English
    Multidimensional Pharmacochemistry: Design of Safer Drugs deals with techniques based on the theory of simultaneous statistical inference and the qualitative rules that can be applied in solving problems of high toxicity. This book points out that the multidimensional view of data analysis can be applied to solve problems in medicinal chemistry. Investigators use different approaches; a certain procedure can prove to be the most beneficial for a specific drug design. This text presents the theoretical assumptions that mathematicians make to derive the basis for their multivariate techniques. This book also describes, in nonmathematical terms, a set of methods that are valuable, as well as explain the different designs by using numerical examples. According to E.J. Ariens, drug action involves the pharmaceutical, pharmacokinetic-toxo... and pharmacodynamics-tox... phases. The multivariate structure-activity analysis (MASCA) Model of Pharmacochemistry is a highly unified multivariate approach to drug design. To develop a multidimensionally oriented pharmacology, the book notes that the investigator can use the "dynamic structure-activity analysis." This entails the experimentalist and chemist using quantitative approaches and intuitive elements from a small number of compounds toward larger groups, with successive changes being inputted in the desired biological activity. This book is strongly recommended for toxicologists, pharmacologists, applied mathematicians, medicinal and agricultural chemists.

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