The Chemistry of Nonaqueous Solvents III

List of Contributors

Preface

Contents of Previous Volumes


1. Brønsted Acid-Base Behavior in "Inert" Organic Solvents

I. Introduction

II. Acid-Base Concepts

III. Properties and Classification of Solvents

IV. Self-Association of Nitrogen-Containing Bases through Hydrogen Bonding

V. Self-Association of Acids through Hydrogen Bonding

VI. Evidence for Hydrogen Bonding in Ion Pairs

VII. Hydrogen Bonding of Neutral Proton Acceptors to Cations

VIII. Hydrogen Bonding of Neutral Proton Donors to Anions

IX. Acidity and Basicity Scales in "Inert" Solvents

X. Acid-Base Titrations in "Inert" Organic Solvents

References


2. Liquid Sulfur Dioxide

I. Physicochemical Properties of Sulfur Dioxide

II. Solvent Purification and Manipulation

III. Solvent Properties

IV. Solvent Character and Solution Species

V. Electrochemical Studies

VI. Reactions in Liquid Sulfur Dioxide

References


3. Acyl Halides as Nonaqueous Solvents

I. Introduction

II. Physical Constants

III. Molecular Structures

IV. Thermodynamic Properties

V. Purification of Solvents

VI. Solubility of Substances

VII. Solvate Formation

VIII. Isotopic Exchange Studies

IX. Solvolytic Reactions

X. Acid-Base Neutralization Reactions

XI. Conductometric Titrations

XII. Visual Titrations

XIII. Potentiometric Titrations

XIV. Thermochemical Studies

XV. Miscellaneous

References


4. Liquid Hydrogen Sulfide

I. Introduction

II. Preparation and Analysis of H2S

III. Physical and Chemical Properties

IV. Solvent Properties

V. Reactions

References


5. Anhydrous Acetic Acid as Nonaqueous Solvent

I. Introduction

II. Purification of Acetic Acid

III. Physical Properties and Structures of Acetic Acid

IV. Solubility of Salts and Ionic Equilibria in Acetic Acid

V. Cryoscopic and Ebullioscopic Studies

VI. Reactions in Acetic Acid

VII. Electrochemical Studies in Acetic Acid

VIII. Acid-Base Equilibria in Acetic Acid

IX. Analytical Chemistry in Acetic Acid

References


6. Other Carboxylic Acids

I. Formic Acid

II. Propionic Acid

III. Butyric Acid

IV. Trifluoroacetic Acid

References

Author Index

Subject Index