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Elsevier

Books in Inorganic chemistry

Explore a broad spectrum of topics covering transition metals, coordination compounds, solid-state materials, and catalysis. Featuring pioneering research, synthesis strategies, and real-world applications, this collection supports inorganic chemists, materials scientists, and engineers in developing new materials, catalysts, and functional systems. Addressing sustainability and advanced characterization techniques, these resources facilitate discovery in areas such as energy storage, electronics, and environmental remediation.

  • Advances in Physical Organic Chemistry

    • 1st Edition
    • Volume 41
    • John P. Richard
    • English
    Advances in Physical Organic Chemistry provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry. The field is a rapidly developing one, with results and methodologies finding application from biology to solid state physics.

  • Advances in Organometallic Chemistry

    • 1st Edition
    • Volume 54
    • Robert C. West + 2 more
    • English
    Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. The widely acclaimed serial Advances in Organometallic Chemistry contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.

  • Advances in Inorganic Chemistry

    Homogeneous Biomimetic Oxidation Catalysis
    • 1st Edition
    • Volume 58
    • Rudi van Eldik + 1 more
    • English
    Advances in Inorganic Chemistry Volume 58 focuses on homogeneous biomimetic oxidation catalysis. Contributions by leading experts in the field cover important advances in inorganic and bioinorganic chemistry. Contributions include diversity-based approaches to selective biomimetic oxidation catalysis; the selective conversion of hydrocarbons with H2O2 using biomimetic non-heme iron and manganese oxidation catalysis; DNA oxidation by copper and manganese complexes; influences of the ligand in copper-dioxygen complex-formation and substrate oxidations; biomimetic oxidations by dinuclear and trinuclear copper complexes. In the final contribution the authors focus on green oxidation of alcohols using biomimetic copper complexes and enzymes as catalysts. Volume 58 provides another welcomed addition to the widely acclaimed series, Advances in Inorganic Chemistry.

  • Advances in Organometallic Chemistry

    • 1st Edition
    • Volume 53
    • Robert C. West + 1 more
    • English
    Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.

  • Contemporary Aspects of Boron: Chemistry and Biological Applications

    • 1st Edition
    • Volume 22
    • Hijazi Abu Ali + 2 more
    • English
    Contemporary Aspects of Boron: Chemistry and Biological Applications highlights the biological activity and applications of boron containing compounds. The authors’ specific approach surveys general features of the subject, while exploring new and novel strategies for preparing certain chemical and natural boron products that are of significant substance in medicinal chemistry. For example, cancer treatment is one of the most important issues related to such products. In addition to contributing to the development of new drugs by addressing biological applications in medicinal and industrial fields, the book provides a comprehensive review of the most relevant components that comprise the pharmaceutical, medicinal and environmental applications of boron containing compounds.

  • Mathematics for Physical Chemistry

    • 3rd Edition
    • Robert G. Mortimer
    • English
    Mathematics for Physical Chemistry, Third Edition, is the ideal text for students and physical chemists who want to sharpen their mathematics skills. It can help prepare the reader for an undergraduate course, serve as a supplementary text for use during a course, or serve as a reference for graduate students and practicing chemists. The text concentrates on applications instead of theory, and, although the emphasis is on physical chemistry, it can also be useful in general chemistry courses. The Third Edition includes new exercises in each chapter that provide practice in a technique immediately after discussion or example and encourage self-study. The first ten chapters are constructed around a sequence of mathematical topics, with a gradual progression into more advanced material. The final chapter discusses mathematical topics needed in the analysis of experimental data.

  • Advances in Inorganic Chemistry

    Relaxometry of Water-Metal Ion Interactions
    • 1st Edition
    • Volume 57
    • Rudi van Eldik + 1 more
    • English
    Water interacts with metal ions in a variety of contexts: from aqueous solutions of inorganic salts to enzymatic catalysis. The investigation of water-metal ion interactions is conveniently performed through water 1H NMR at different magnetic field-a technique known as relaxometry. Advances in Inorganic Chemistry, Volume 57 focuses on relaxometry of water-metal ion interactions.Contrib... by leading experts in the field cover important advances in inorganic and bioinorganic chemistry; another welcomed addition to the widely acclaimed series, Advances in Inorganic Chemistry.

  • Advances in Organometallic Chemistry

    • 1st Edition
    • Volume 52
    • Robert C. West + 1 more
    • English
    Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. The widely acclaimed serial Advances in Organometallic Chemistry contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.

  • Nitrosation Reactions and the Chemistry of Nitric Oxide

    • 1st Edition
    • D.L.H. Williams
    • English
    Since 1988, there has been much literature published on the chemistry of nitric oxide, particularly in the field of S-nitrosation and the chemistry of S-nitroso compounds. Written by a chemist for the chemistry community, this book provides an update of the chemistry of nitrosation reactions, dealing with both the synthetic and mechanistic aspects of these reactions. It also looks at the chemistry of nitric oxide in relation to the amazing biological properties of this simple diatomic molecule, which were unknown until around 1990.

  • Advances in Inorganic Chemistry

    Redox-active Metal Complexes
    • 1st Edition
    • Volume 56
    • Rudi van Eldik
    • English
    Advances in Inorganic Chemistry presents timely, informative and comprehensive reviews of the current progress in all areas within inorganic chemistry ranging from bio-inorganic to solid state studies. This acclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced.

  • Clay Surfaces

    Fundamentals and Applications
    • 1st Edition
    • Volume 1
    • Fernando Wypych
    • English
    Clay plays an important role in everyday life. This versatile mineral is used in housing, improving the environment as a waste treatment material and also in biological applications and medical health care. Clay Surfaces contains 17 chapters which deal with various aspects of natural and man made (synthetic) clay. Well written by experts in both experimental and theoretical areas, this book takes the reader into the fascinating world of the chemistry and physics of clay mineral surfaces and interfaces as well as the complex phenomena on the surfaces involved in clay related systems. This book will provide a better understanding of the intervention mechanisms of interactions of soils in contact with wastes, actions to be taken in the case of chemical spillage, methods to improve the production of food without affecting the ecological balance, increased fixation of carbon in the soil to increase grain production and reduction of carbon dioxide release into the atmosphere.

  • Advances in Inorganic Chemistry

    • 1st Edition
    • Volume 55
    • English
    Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry ranging from bio-inorganic to solid state studies. Thisacclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced.

  • Handbook of Lithium and Natural Calcium Chloride

    • 1st Edition
    • Donald E. Garrett
    • English
    Handbook of Lithium and Natural Calcium Chloride is concerned with two major industrial minerals: Lithium and Calcium Chloride. The geology of their deposits is first reviewed, along with discussions of most of the major deposits and theories of their origin. The commercial mining and processing plants are next described, followed by a review of the rather extensive literature on other proposed processing methods. The more important uses for lithium and calcium chloride are next covered, along with their environmental considerations. This is followed by a brief review of the production statistics for each industry, and some of their compounds' phase data and physical properties.

  • Advances in Organometallic Chemistry

    • 1st Edition
    • Volume 50
    • English
    Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. The widely acclaimed serial Advances in Organometallic Chemistry contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.

  • Advances in Macromolecular Carbohydrate Research

    • 1st Edition
    • Volume 2
    • Robert J. Sturgeon
    • English
    In recent years the most significant advances in carbohydrate research have been made in the knowledge of the structure and function of carbohydrates in the macromolecular state. This title addresses those areas in which the authors believe the most important work is being carried out.

  • Advances in Organometallic Chemistry

    • 1st Edition
    • Volume 49
    • English
    Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.

  • Advances in Inorganic Chemistry

    Inorganic Reaction Mechanisms
    • 1st Edition
    • Volume 54
    • English
    The Advances in Inorganic Chemistry series presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry ranging from bio-inorganic to solid state studies. This acclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced. This, the 54th volume in the series continues this tradition providing comprehensive reviews by leading experts in the field with the focus on inorganic and bioinorganic reaction mechanisms.

  • Advances in Inorganic Chemistry

    • 1st Edition
    • Volume 53
    • AG Sykes
    • English
    Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bioinorganic to solid state.Importance of TopicInorganic chemistry deals with the chemistry of the elements. As such it is of interest to chemists, materials scientists and molecular biologistsWhy This TitleThis acclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced. This series was cited 1,972 times in 2000 by the journals covered by ISI. ISI impact factor in 2000: 11.54Praise for the Series"These ... volumes continue the tradition of representing timely summaries of the current state of understanding on a wide variety of 'special topics'... These volumes provide much useful information and are quite well written." JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

  • Clathrochelates

    Synthesis, Structure and Properties
    • 1st Edition
    • Y.Z. Voloshin + 2 more
    • English
    Clathrochelates are compounds which contain a metal ion encapsulated within a three dimensional cage of macrobicyclic ligand atoms. Within this cage the metal has unique properties and is to a great extent isolated from environmental factors. Such complexes are suitable as models of the most essential biological systems, membrane transport, electron carriers, highly selective and sensitive analytical reagents, catalysts for photochemical and redox processes, cation and anion receptors, etc. The aim of this monograph is to generalize and analyze experimental and theoretical data on clathrochelates in order to promote further research in this promising field of chemistry.Chapter 1 gives general concepts of complexes with encapsulated metal ions, discusses basic specific features of these compounds, considers and characterizes the main types of compounds with encapsulated metal ions and the main classes of clathrochelates, and includes the current nomenclature. Chapter 2 deals with the pathways of clathrochelate synthesis and the general procedures for the synthesis of macrobicyclic tris-dioximates, phosphorus-containin... tris-diiminates, sepulchrates, sarcophagi-nates, and polyene and other types of clathrochelate complexes. Chapter 3 concerns studies of the electronic and spatial structure of clathrochelate complexes. In Chapter 4, the kinetics and mechanism of synthesis and decomposition reactions of macrobicyclic tris-dioximates, sarcophaginates, and sepulchrates in solution and gas phases are discussed. Chapter 5 considers the electrochemical, photochemical, and some other characteristics of clathrochelates and their applications associated with these characteristics. Finally, the practical applications of the unique properties of clathrochelates and perspectives on the synthesis of new clathrochelates are described in Chapters 6 and 7, respectively.

  • Comprehensive Organometallic Chemistry II, Volume 5

    Vanadium and Chromium Groups
    • 1st Edition
    • J.A. Labinger + 1 more
    • English
    In addition to providing an updated survey of organometallic compounds of the group 5 elements, these chapters highlight developments in their utilization, most of which have taken place since COMC. Some of the important topics featured include the antitumor activity of vanadocene derivatives; uses in organic synthesis; and a wide variety of catalytic applications, such as the role of group 5 alkylidene complexes in alkene metathesis and ring-opening metathesis polymerization.

  • Comprehensive Organometallic Chemistry II, Volume 7

    Iron, Ruthenium and Osmium: A Review of the Literature 1982-1994
    • 1st Edition
    • D.F. Schriver + 1 more
    • English
    The section devoted to iron in this volume reflects the tremendous progress in the area. Specifically cluster chemistry, ligand transformations and detailed structural results are more prominent in COMC II. The organic chemistry of ruthenium and osmium is an area which has burgeoned during the period since the publication of COMC. This is especially true for the cluster chemistry of these elements, which have provided most of the advances in this important field. Consequently, this volume will include an update (1981-1993) of the chemistry of mono- and bi-nuclear complexes of ruthenium and osmium, with a rather more extensive treatment of tri- and tetra-nuclear complexes. This is because many of the early results in ruthenium and osmium cluster chemistry described in COMC are now much better understood and can thus be placed in a more general context. In the case of complexes containing clusters with five or more metal atoms, the coverage is essentially complete, again because this chemistry has developed during the 1980s.

  • Comprehensive Organometallic Chemistry II, Volume 9

    Nickel, Palladium and Platinum
    • 1st Edition
    • R.J. Puddephatt
    • English
    This volume covers the advances in the organometallic chemistry of nickel, palladium and platinum since publication of COMC in 1982. Major applications of the organometallic compounds of the nickel group are in catalytic and stoichiometric organic synthesis and in materials synthesis. This volume covers the fundamental organometallic chemistry which underpins these applications. The level of sophistication in many areas has increased substantially since COMC, for example in the development of chiral organometallics for use in synthesis, in the synthesis and characterization of larger cluster complexes, in testing the limits of binuclear organometallic chemistry and in the chemistry of metallacycles and organometallics derived from carbon dioxide. Since COMC there are also some quite new areas; for example, organopalladium (IV) chemistry with its possible relevance to several catalytic processes is reviewed in depth but was essentially unknown at the time COMC was published. The catalytic copolymerization of ethylene with carbon monoxide provides an example of an important new application in catalysis, while new developments in C–H bond activation are also described.

  • Comprehensive Organometallic Chemistry II, Volume 11

    Main-Group Metal Organometallics in Organic Synthesis
    • 1st Edition
    • A. McKillop
    • English
    The individual chapters in this volume cover the scope and impact of main group organometallic compounds and reagents on organic synthesis during the last ten to fifteen years. In a number of chapters, topics are dealt with in detail that either were not covered at all in COMC (eg selenium, tellurium) or were given scant attention (eg oxymercuration, organoantimony compounds). Certain topics, like directed metallation and LiKOR bases have only achieved prominence in synthesis in the last ten years, and are now reviewed by leading experts.

  • Comprehensive Organometallic Chemistry II, Volume 8

    Cobalt, Rhodium and Iridium
    • 1st Edition
    • J.D. Atwood
    • English
    This volume covers the advances of organometallic chemistry of cobalt, rhodium and iridium from 1982 to 1993 with over 3,000 references not previously included in COMC. It incorporates recent developments including carbon-hydrogen activation systems and C60 and C70 complexes that have been discovered since the original publication of COMC.

  • Comprehensive Organometallic Chemistry II, Volume 10

    Heteronuclear Metal and Metal Bonds
    • 1st Edition
    • R.D. Adams
    • English
    The number of organometallic compounds containing heteronuclear metal–metal bonds has grown tremendously in the last ten years. Also known as cluster compounds, these compounds have been found to exhibit a rich diversity of molecular structures and reactivities. Descriptions of the structures and transformations of the complexes are central features. Separate chapters have been prepared for compounds containing bonds between transition metals and the metals of the copper and zinc subgroups. Unlike COMC, this volume contains an entire chapter devoted to studies of heteronuclear metal compounds in catalysis.

  • Comprehensive Organometallic Chemistry II, Volume 3

    Copper and Zinc Groups
    • 1st Edition
    • J.L. Wardell
    • English

  • Comprehensive Organometallic Chemistry II, Volume 2

    Silicon Group, Arsenic, Antimony and Bismuth
    • 1st Edition
    • A.G. Davies
    • English
    A common theme within this section (Si, Ge and Sn), is the use of bulky groups to stabilize species which are otherwise unknown. This includes the divalent species R2M, the trivalent radicals R3M0, and the multiply-bonded compounds R2M=MR2, R2M=CR2, etc. A significant difference from COMC is the much greater availability of single crystal x-ray diffraction and this is covered. Other important developments covered include, silicone polymers derived from carbofunctional silanes and the developments in polysilane high polymers. The Sn chapter covers the biggest development, the use of organotin compounds in organic synthesis, and this chapter provides the background information.

  • Comprehensive Organometallic Chemistry II, Volume 6

    Manganese Group
    • 1st Edition
    • C.P. Casey
    • English
    This volume provides an update on the chemistry of manganese, technetium and rhenium covered in Volume 4 of COMC. The literature surveyed is from 1982 to 1993. The explosive growth in organorhenium chemistry, the use of manganese hydrocarbon complexes in organic synthesis, and the development of the chemistry of high oxidation manganese and rhenium compounds are highlighted. The growth of organotechnetium chemistry which was virtually unknown at the time of COMC is covered in depth.

  • Comprehensive Organometallic Chemistry II, Volume 4

    Scandium, Yttrium, Lanthanides and Actinides, and Titanium, Zirconium, and Hafnium
    • 1st Edition
    • M.F. Lappert
    • English

  • Comprehensive Organometallic Chemistry II, Volume 14

    Comprehensive Organometallic Chemistry II: A Review of the Literature 1982-1994: Cumulative Indexes
    • 1st Edition
    • Edward W. Abel
    • English
    Since the publication Comprehensive Organometallic Chemistry in 1982, studies on the chemistry of moleculeswith carbon-metal bonds have continued to expand rapidly. This is due to many factors, ranging from the sheer intellectual challenge and excitement provided by the continuing production of novel results, which demand new ideas, through to the successful application of organometallic species in organic syntheses, the generation of living catalysts for polymerization, and the synthesis of precursors for materials employed in the electronic and ceramic industries. These factors led to the publication of the updated Comprehensive Organometallic Chemistry II. The original work serves as a basis for new volumes, focusing on organometallic chemistry reported since 1982, with reference back to the original work when necessary. For ease of use the new volumes maintain the same general structure as employed previously but reflect the changes in substance and direction the field has undergone in the last ten years. This book will serve as a pivotal reference point for new work and will function to generate new ideas and perceptions for the continued advance of what will surely continue as a vibrant area of chemistry.

  • The Porphyrin Handbook

    Multporphyrins, Multiphthalocyanines and Arrays
    • 1st Edition
    • Karl Kadish + 2 more
    • English
    The Porphyrin Handbook, Volume 18: Multiporphyrins, Multiphthalocyanines and Arrays provides information pertinent to every aspect of the chemistry, synthesis, spectroscopy, and structure of phthalocyanines. This book examines the biology and medical implications of porphyrin systems. Organized into five chapters, this volume begins with an overview of the results obtained in the research concerning the properties and formation of a class of metal phthalocyanine derivatives containing of two macrocyclic units. This text then examines the luminescence and photophysical data of multiporphyrin systems in which the chromophore centers are held together by weak, medium, or strong bonding interactions. Other chapters consider the intensive electronic absorption and circular dichroism properties of chiral phthalocyanines. This book discusses as well the chemistry porphyrin and corrin systems. The final chapter deals with geoporphyrins or sedimentary porphyrins, which are the most abundant porphyrin derivatives on earth. This book is a valuable resource for research scientists, engineers, and clinicians.

  • The Porphyrin Handbook

    Bioinorganic and Bioorganic Chemistry
    • 1st Edition
    • Roger Guilard + 2 more
    • English
    The Porphyrin Handbook, Volume 11: Bioinorganic and Bioorganic Chemistry presents the fundamental aspects of the synthesis, structure, chemistry, and spectroscopy of phthalocyanines. This book discusses the biology and medical implications of porphyrin systems. Organized into seven chapters, this volume begins with an overview of the design, synthesis, and study of the structural and functional models of heme/copper terminal oxidases. This text then examines the proteins containing iron-protoporphyrin IX (heme), which play key roles in photosynthesis and respiration. Other chapters consider the syntheses of chiral porphyrin derivatives and summarize the uses of such compounds in enantioselective control. This book discusses as well the reactivity and synthesis of synthetic carbine metalloporphyrins. The final chapter deals with the B12-coenzymes, which is the most complex and physiologically important organometallic enzymatic reactions that directly depend on the reactivity of metal coordinated organic ligands. This book is a valuable resource for research scientists, clinicians, and engineers.

  • The Porphyrin Handbook

    Phthalocyanines: Synthesis
    • 1st Edition
    • Karl Kadish + 2 more
    • English
    The Porphyrin Handbook, Volume 15: Phthalocyanines: Synthesis provides information pertinent to every aspect of the chemistry, synthesis, spectroscopy, and structure of phthalocyanines. This book examines the biology and medical implications of porphyrin systems. Organized into five chapters, this volume begins with an overview of the importance of compounds such as heme and chlorophyll that play vital roles in the biological systems responsible for the transportation of oxygen to cells in the body. This text then explores the different methods used for the preparation of phthalocyanine and its metallated derivatives. Other chapters consider the detailed survey of phthalocyanine formation, characterization, and purification. This book discusses as well the synthesis of low-symmetry phthalocyanines and related compounds. The final chapter deals with a survey of the structure, synthesis, and physiochemical properties of porphyrazines with annulated heterocycles. This book is a valuable resource for research scientists, engineers, and clinicians.

  • Recent Advances in Hydride Chemistry

    • 1st Edition
    • Maurizio Peruzzini + 1 more
    • English
    This book has been conceived to collect the most important recent advances in all areas of hydride chemistry research, including chemical reactivity, instrumental investigation, theory, and applications in the areas of catalysis, biochemistry and materials science.Many of the chapters have been written by the plenary lecturers of the EURO-Hydrides 2000 conference, but other leading scientists in this field have also been invited to contribute.The first part of the book focuses on the chemistry and catalysis of transition metal hydrides.Another block of chapters illustrates the most recent advances in the application of instrumental techniques to the study of the properties and reactivity of hydride compounds.The final part of the book illustrates the relevance of metal-hydrogen bonds in biochemistry and materials science.All of the chapters of this book have been evaluated by independent reviewers.

  • Advances in Organometallic Chemistry

    • 1st Edition
    • Volume 48
    • Robert C. West + 1 more
    • English
    Almost all branches of chemistry and material science now interface with organometallic chemistry-the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.

  • Oxide-based Systems at the Crossroads of Chemistry

    • 1st Edition
    • Volume 140
    • C. Colella + 2 more
    • English
    This volume includes papers presented at the second International Workshop on Oxide-based Systems at the Crossroads of Chemistry, held at Villa Olmo in Como, Italy, 8-11 October.The selected papers present the highlights of recent research in the field of oxide structure. A wide range of oxidic materials, including real oxides, zeolites and layer-structured systems, is considered and described in terms of preparation methods, structural characterization and the relation between active sites, structure and catalytic properties. The application of the most powerful simulation and physical-chemical techniques show their usefulness in discovering and explaining structural and dynamic properties of complex materials. Moreover the development of sophisticated spectroscopical and analytical techniques are shown to significantly improve the growth of surface oxide science, generating new tools for the knowledge of catalyst structure and reaction mechanisms. An interesting feature is the inclusion of papers which show the mutual roles of experiment and theoretical models.

  • Holleman-Wiberg's Inorganic Chemistry

    • 1st Edition
    • Nils Wiberg + 2 more
    • English
    Inorganic Chemistry easily surpasses its competitors in sheer volume and depth of information. Readers are presented with summaries that ease exam preparation, an extensive index, numerous references for further study, six invaluable appendixes, and over 150 tables that provide important data on elements at a quick glance.Now in its 101st printing, Inorganic Chemistry provides an authoritative and comprehensive reference for graduate students, as well as chemists and scientists in fields related to chemistry such as physics, biology, geology, pharmacy, and medicine.Translated for the first time into English, Holleman and Wiberg's book is a bestseller in Germany, where every chemist knows and values it. Prior to this translation, there was no equivalent to Holleman and Wiberg's book in English.

  • Advances in inorganic Chemistry

    • 1st Edition
    • Volume 52
    • English
    Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bioinorganic to solid state. This acclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced.

  • Advances in Organometallic Chemistry

    • 1st Edition
    • Volume 47
    • English
    Almost all branches of chemistry and material science now interface with organometallic chemistry-the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.

  • Advances in Metal and Semiconductor Clusters

    Metal Ion Solvation and Metal-Ligand Interactions
    • 1st Edition
    • Volume 5
    • M.A. Duncan
    • English
    In previous volumes in this series, Advances in Metal and Semiconductor Clusters, the focus has been on atomic clusters of metals, semiconductors and carbon. Fundamental gas phase studies have been surveyed, and most recently scientists have explored new materials which can be produced from clusters or cluster precursors. In this latest volume, the focus shifts to clusters composed primarily of non-metal molecules or atoms which have one or more metal atoms seeded into the cluster as an impurity. These clusters provide model systems for metal ion solvation processes and metal-ligand interactions.Metal-l... bonding underlies the vast fields of organometallic chemistry, transition metal chemistry and homogeneous catalysis. Catalytic activity, ligand displacement reactions and photochemical activity depend on the specific details of metal-ligand bonding. Likewise, metal ions are ubiquitous in chemistry and biology and weaker electrostatic interactions play a leading role in their function. In solution, metals exist in different charge states depending on the conditions, and the solvation environment strongly influences their chemistry. Many enzymes have metal ions at their active sites, and electrostatic interactions influence the selectivity for metal ion transport through cell membranes. Metal ions (e.g., Mg+, Ca+) are deposited into the earth's atmosphere by meteor ablation, resulting in a rich variety of atmospheric chemistry. Similarly, metal ions ( Mg+) have been observed in planetary atmospheres and in the impact of the comet Shoemaker-Levy 9 on Jupiter. In various circumstances, the electrostatic interactions of metal ions determine the outcome of significant chemistry. Cluster chemistry has made significant contributions to the understanding of these stronger metal ligand interactions and weaker metal ion solvation interactions. In this volume, the authors explore a variety of work in these general areas, where new cluster science techniques in the gas phase have made it possible to synthesize new kinds of complexes with metals and to measure their properties in detail.

  • Solution NMR of Paramagnetic Molecules

    Applications to Metallobiomolecules and Models
    • 1st Edition
    • Volume 2
    • Ivano Bertini + 2 more
    • English
    NMR is a growing technique which represents a generalized, spread, common tool for spectroscopy and for structural and dynamic investigation. Part of the field of competence of NMR is represented by molecules with unpaired electrons, which are called paramagnetic. The presence of unpaired electrons is at the same time a drawback (negative effect) and a precious source of information about structure and dynamics. New phenomena and effects are described which are due to the high magnetic fields and advances in the methodology. Solution NMR of Paramagnetic Molecules is unique in dealing with these matters. The scope is that of presenting a complete description, which is both rigorous and pictorial, of theory and experiments of NMR of paramagnetic molecules in solution. Pertinent examples are described. From the time dependent behaviour of electrons in the various metal ions including polimetallic systems to the hyperfine-based information, and from NMR experiments to constraints for solution structure determination. The book's major theme is how to perform high resolution NMR experiments and how to obtain structural and dynamic information on paramagnetic metal ion containing systems.

  • Alkoxo and Aryloxo Derivatives of Metals

    • 1st Edition
    • Don Bradley + 3 more
    • English
    Alkoxo and Aryloxo Derivatives of Metals gives a comprehensive account of the chemistry of metal alkoxides and metal aryloxides, including their industrial applications such as microelectronics, ceramics, nonlinear optical materials, high-temperature superconductors, specialized glasses, and other advanced novel materials. It is an invaluable reference source book. The book is an updated edition of Metal Alkoxides, published by Academic Press in 1978, with additional coverage of metal aryloxides. It reflects the enormous growth in interest in this field in recent years. Alkoxo and aryloxo derivatives are organic compounds with metals for useful industrial purposes. Alkoxo and Aryloxo Derivatives of Metals will appeal to a wide-ranging audience, including university researchers and chemistry graduate students in industrial laboratories concerned with microelectronics, ceramics, glasses and other advanced novel materials; any laboratories doing research on nonlinear optical materials, high-temperature superconductors, ceramic materials, and specialized glasses. It can also serve as a supplementary text for final year courses in advanced inorganic chemistry, e.g., metallo-organic chemistry.

  • Monodispersed Particles

    • 1st Edition
    • Tadao Sugimoto
    • English
    This is the first comprehensive book for all aspects of monodispersed particles, consisting of four parts: Part 1 for the fundamentals of the elementary processes; Part 2 for the preparation of monodispersed particles, including the general principles, explanations of almost all known monodispersed systems on the basis of their classification, and techniques for controlling their mean size, shape, internal structure, composition, heterojunction, surface modification, etc.; Part 3 for the analytical methods for the formation processes and the characterization of monodispersed products; Part 4 for applications of monodispersed particles to fundamental studies and practicle uses, such as photographic materials, ceramics, catalysts, magnetic recording materials, pigments, cosmetics, biological and medical devices, etc.This book not only covers the most of known uniform particles, including inorganic and polymer particles and their composites, from nanometers to a few hundreds of micrometers, but also compiles numerous references about 2000.While this book is organized from the fundamentals to the ultimate levels, the text is replete with new theories, developed for this book, and novel ideas of the author's own interpretation on the formation mechanisms throughout the whole volume. In this sense, this is a unique book, as entirely different from ordinary textbooks.Since the functions and dynamic behaviours of particles strongly depend on their size, well-defined monodispersed particles are ideal particulate materials for advanced devices as well as models for fundamental studies of colloid science. This may be the sheer reason for the persistent demands for the advent of a comprehensive book focussed on this subject.

  • Advances in Organometallic Chemistry

    • 1st Edition
    • Volume 46
    • English
    Almost all branches of chemistry and material science now interface with organometallic chemistry-the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.Organometallics are used extensively in the synthesis of compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry.

  • Handbook on the Physics and Chemistry of Rare Earths

    The Role of Rare Earths in Catalysis
    • 1st Edition
    • Volume 29
    • K.A. Gschneidner + 2 more
    • English
    Among the numerous applications of the rare-earth elements, the field of catalysis accounts for a large number. Catalysis represents approximately 20% of the total market sales of rare earths worldwide. As a matter of fact two main applications have been prominent in the last decades: zeolite stabilization for fluid cracking catalysts, and automotive post-combustion catalytic treatment.The oldest use of rare earths in catalysis deals with the structural and chemical stabilization of the zeolites for petroleum cracking applications. For a long time this has been an area of application for non-separated rare earths. The addition of several percent of rare earths in the pores of the zeolite results in a strong surface acidity, which is essential for an efficient conversion of high-weight molecules into lighter species, like low-octane fuel, even in the very aggressive conditions of the petroleum industry.The popular demand for high-quality air in spite of the traffic congestion in large cities resulted in larger and larger constraints in the emission exhaust from cars. Thus highly efficient catalysts have had to be designed, and due to the combination of its redox properties and very good thermal stability, cerium oxide has been since the beginning, early in the 1980s, a major component of the three-way catalysts (TWC) now used in all modern gasoline cars.The future of rare earths in catalysis is probably bright. The fact that approximately 400 patents are applied for yearly in the area since 1992 is an illustration of a very active area. Usage of rare earths in catalysis is expected to grow due to their highly specific properties. Instead of the physical properties used in electronic applications, one deals now with redox properties, water and thermal stability, coordination numbers and so forth. The rare earths are so specific in these properties that their use can hardly be avoided, not only for the beauty of academic studies but also for the development of industrial applications with immediate influence on everyday life. Careful control of the synthesis conditions and the definition of optimum composition in each case are the keys to the preparation of highly performing compounds for catalytic applications. They must actually be considered as high performance products with functional properties, and not just chemical species.Chapters devoted primarily to catalysis have been published in earlier volumes of the Handbook. In this volume several more are added. The first is an extension of the earlier chapter 43, on interactions at surfaces of metals and alloys, to reactions such as hydrogenation, methanation, ammonia synthesis, saturated hydrocarbon reactions, dehydrogenation of hydrogenated materials, hydrodesulfurization... and carbon monoxide oxidation. The second chapter reports on the wide variety of catalyzed reactions involving metals and alloys in the innovated form of metal overlayers or bimetallic compounds with some transition metals produced from ammonia solutions. This is followed by a chapter on catalysis with mixed oxides usually having perovskite or perovskite-related structures. Then follows a comprehensive discussion on the background and current role of cerium oxide and associated materials for post-treatment of exhaust gases for pollution control. These three-way catalysts (TWC) are designed to render harmless the CO, NOx, and unburned hydrocarbons from internal combustion engines. The next chapter considers the wide field of zeolite catalysts containing rare earths from their historic use in petroleum refining in the 1960s to other petrochemical and fine chemical applications today. The final chapter documents the use of the triflates (the trifluoro-methane-su... group which is a hard Lewis acid in both aqueous and organic solutions) as versatile catalysts in carbon-carbon bond-forming reactions. Their stability in the presence of water, in spite of their being hard Lewis acids, enhances their growing usefulness.

  • Handbook on the Physics and Chemistry of Rare Earths

    • 1st Edition
    • Volume 28
    • English
    Even at the beginning of the new millenium the rare earths still remain, to a certain extent, a mystery. The chapters in this volume will help to unravel some of these. In the filling of the 4f electronic orbitals the lanthanides defy the elementary aufbau principle that underlies the periodic sequence of the elements, and the authors of the first chapter introduce the readers to the basic physics of the orbital collapse leading to that failure. Furthermore an explanation is offered in terms of double-well potentials. The phenomenon is illustrated using the valence transitions observed in some of the rare earth atoms, including Sm group metals and the higher oxides of cerium, praseodymium and terbium. In the second chapter the synthesis and structure of the many types of rare earth halides are described. They have been described as simple, complex, binary, ternary and multinuclear complex, and other categories needed to deal with the most studied of the rare earth compounds. The structure types are skillfully illustrated to show the elementary architecture of each type.In chapter three the authors discuss the science and applications of rare earth super ionic conductors as solid electrolytes. Conduction by oxygen and fluorine anions as well as hydrogen and other cations associated with these electrolytes is emphasized. They deal with extrinsic and intrinsic types together with their associated structures and structural types including structural defects. The chapter concludes with an outline of the many applications of solid electrolytes.Chapter four introduces the reader to the principles that underlie thermoluminescence and its application to dosimetry and provides detailed information on the R-activated phosphors that support dosimetry. This is a selective review of detailed literature based on the areas making most progress.The final chapter elaborates on the data gained by the studies and interpretation around the analytical separation of the individual rare earth elements utilizing chromatographic techniques. The authors describe the fundamental chemistry that underpins contemporary analytical separation techniques for lanthanide separation and analysis. This is done after a description of the rich assortment of separation methods in use has been introduced.

  • Advanced Inorganic Fluorides: Synthesis, Characterization and Applications

    • 1st Edition
    • T. Nakajima + 2 more
    • English
    This book summarizes recent progresses in inorganic fluorine chemistry. Highlights include new aspects of inorganic fluorine chemistry, such as new synthetic methods, structures of new fluorides and oxide fluorides, their physical and chemical properties, fluoride catalysts, surface modifications of inorganic materials by fluorination process, new energy conversion materials and industrial applications. Fluorine has quite unique properties (highest electronegativity; very small polarizability). In fact, fluorine is so reactive that it forms fluorides with all elements except with the lightest noble gases helium, neon and argon. Originally, due to its high reactivity, fluoride chemistry faced many technical difficulties and remained undeveloped for many years. Now, however, a large number of fluorine-containing materials are currently produced for practical uses on an industrial scale and their applications are rapidly extending to many fields. Syntheses and structure analyses of thermodynamically unstable high-oxidation-state fluorides have greatly contributed to inorganic chemistry in this decade. Fluoride catalysts and surface modifications using fluorine are developing a new field of fluorine chemistry and will enable new syntheses of various compounds. The research on inorganic fluorides is now contributing to many chemical energy conversion processes such as lithium batteries. Furthermore, new theoretical approaches to determining the electronic structures of fluorine compounds are also progressing. On the industrial front, the use of inorganic fluorine compounds is constantly increasing, for example, in semi-conductor industry. "Advanced Inorganic Fluorides: Synthesis, Characterization and Applications" focuses on these new features in inorganic fluorine chemistry and its industrial applications. The authors are outstanding experts in their fields, and the contents of the book should prove to be of valuable assistance to all chemists, graduates, students and researchers in the field of fluorine chemistry.

  • Main Chemistry Group

    • 1st Edition
    • Volume 50
    • English
    Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bioinorganic to solid state. This acclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced.

  • Job$ in the Drug Indu$try

    A Career Guide for Chemists
    • 1st Edition
    • Richard J. Friary
    • English
    This book is intended to help newly graduated chemists, particularly organic chemists, at all levels from bachelors to post-doctorates, find careers in the North American pharmaceutical industry. It will serve as a practical, detailed guiedbook for job seekers as well a reference work for faculty advisers, research supervisors, development officers, employment agents, and personnel managers in the industry. The book gathers in a single volume the fundamentals of getting an industrial job as a medicinal or process chemist, and covers all aspects of a chemist's job--scientific, financial, and managerial--within a pharmaceutical/biote... company. Other scientists looking for jobs as analytical or physical chemists and even biochemists and biologists will find the book useful. The valuable appendix is a unique compendium of 365 commercial, governmental, or non-profit institutions that comprise the North American pharmaceutical industry.

  • Advances in Inorganic Chemistry

    Cumulative Subject and Author Indexes, and Tables of Contents for Volumes1-47
    • 1st Edition
    • Volume 48
    • English
    Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bioinorganic to solid state. This acclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced.

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