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Elsevier

Books in Chemical engineering

The Chemical Engineering collection offers content that combines research with foundational knowledge, practical information, methods and case studies, in a variety of areas, including biochemical engineering, catalysis, filtration & separation, colloids & surface chemistry, electrochemical engineering, energy & transport processes, materials chemistry, metallurgy, process engineering, safety & reliability, sustainable & environmental, to help chemical engineers address the challenges we face today, including climate change, global warming, health and nutrition, and alternative energy.

  • Reactive Polymers Fundamentals and Applications

    A Concise Guide to Industrial Polymers
    • 2nd Edition
    • Johannes Karl Fink
    • English
    The use of reactive polymers enables manufacturers to make chemical changes at a late stage in the production process—these in turn cause changes in performance and properties. Material selection and control of the reaction are essential to acheive optimal performance. The second edition of Reactive Polymers Fundamentals and Applications introduces engineers and scientists to the range of reactive polymers available, explains the reactions that take place, and details applications and performance benefits. Basic principles and industrial processes are described for each class of reactive resin (thermoset), as well as additives, the curing process, and applications and uses. The initial chapters are devoted to individual resin types (e.g. epoxides, cyanacrylates, etc.); followed by more general chapters on topics such as reactive extrusion and dental applications. Material new to this edition includes the most recent developments, applications and commercial products for each chemical class of thermosets, as well as sections on fabrication methods, reactive biopolymers, recycling of reactive polymers, and case studies. Injection molding of reactive polymers, radiation curing, thermosetting elastomers, and reactive extrusion equipment are all covered as well.

  • Heterogeneous Catalysis of Mixed Oxides

    Perovskite and Heteropoly Catalysts
    • 1st Edition
    • Volume 176
    • M. Misono
    • English
    Mixed oxides are the most widely used catalyst materials for industrial catalytic processes. The principal objective of this book is to describe systematically the mixed oxide catalysts, from their fundamentals through their practical applications. After describing concisely general items concerning mixed oxide and mixed oxide catalysts, two important mixed oxide catalyst materials, namely, heteropolyacids and perovskites, are taken as typical examples and discussed in detail. These two materials have several advantages: 1. They are, respectively, typical examples of salts of oxoacids and double oxide, that is, the two main categories of mixed oxides in solid state chemistry. 2. Both exhibit excellent catalytic performance in nearly crystalline state and are used in several industrial applications. 3. They have studied for many years. In addition, metal oxides functioning as a catalyst support (carrier) are included. Although the supports are very important in practical applications, and tremendous progress has been made in the past decades, few systematic reviews exist. It is notable that heteropolyacids and perovskite exhibit unique performance when used as a support. Fundamental catalytic science and technology and solid state chemistry necessary is presented for the proper understanding of mixed oxide catalysts as well as for R&D. For the latter, the concept of design of practical catalysts is very important. This is considered throughout the book.

  • Filters and Filtration Handbook

    • 6th Edition
    • Trevor Sparks + 1 more
    • English
    Filters are used in most industries, especially the water, sewage, oil, gas, food and beverage, and pharmaceutical industries. The new edition of Filters and Filtration Handbook is an all-encompassing practical account of standard filtration equipment and its applications. Completely revised and rewritten, it is an essential book for the engineer working in a plant situation, who requires guidance and information on what’s available and whether it’s suitable for the job. Co-published with the Institution of Chemical Engineers.

  • Handbook of Membrane Reactors

    Fundamental Materials Science, Design and Optimisation
    • 1st Edition
    • Angelo Basile
    • English
    Membrane reactors are increasingly replacing conventional separation, process and conversion technologies across a wide range of applications. Exploiting advanced membrane materials, they offer enhanced efficiency, are very adaptable and have great economic potential. There has therefore been increasing interest in membrane reactors from both the scientific and industrial communities, stimulating research and development. The two volumes of the Handbook of membrane reactors draw on this research to provide an authoritative review of this important field.Volume 1 explores fundamental materials science, design and optimisation, beginning with a review of polymeric, dense metallic and composite membranes for membrane reactors in part one. Polymeric and nanocomposite membranes for membrane reactors, inorganic membrane reactors for hydrogen production, palladium-based composite membranes and alternatives to palladium-based membranes for hydrogen separation in membrane reactors are all discussed. Part two goes on to investigate zeolite, ceramic and carbon membranes and catalysts for membrane reactors in more depth. Finally, part three explores membrane reactor modelling, simulation and optimisation, including the use of mathematical modelling, computational fluid dynamics, artificial neural networks and non-equilibrium thermodynamics to analyse varied aspects of membrane reactor design and production enhancement.With its distinguished editor and international team of expert contributors, the two volumes of the Handbook of membrane reactors provide an authoritative guide for membrane reactor researchers and materials scientists, chemical and biochemical manufacturers, industrial separations and process engineers, and academics in this field.

  • Nanochemistry

    • 2nd Edition
    • Kenneth J. Klabunde + 1 more
    • English
    The second edition of Nanochemistry covers the main studies of nanoparticle production, reactions, and compounds, and reviews the work of leading scientists from around the world. This book is the first monograph on nanochemistry, giving perspectives on the present status and future possibilities in this rapidly advancing discipline. It provides the solid fundamentals and theory of nanoscience, and progress through topics including synthesis and stabilization of nanoparticles, cryochemistry of metal atoms and nanoparticles, chemical nanoreactors, and more. Nanoparticles are capable of transformations that have already led to revolutionary applications, including reagents for self-cleaning glass surfaces and fabrics, different antiseptic coverings, sensors for monitoring the environment and catalysts mitigating pollution.

  • Radiative Heat Transfer

    • 3rd Edition
    • Michael F. Modest
    • English
    The third edition of Radiative Heat Transfer describes the basic physics of radiation heat transfer. The book provides models, methodologies, and calculations essential in solving research problems in a variety of industries, including solar and nuclear energy, nanotechnology, biomedical, and environmental. Every chapter of Radiative Heat Transfer offers uncluttered nomenclature, numerous worked examples, and a large number of problems—many based on real world situations—making it ideal for classroom use as well as for self-study. The book's 24 chapters cover the four major areas in the field: surface properties; surface transport; properties of participating media; and transfer through participating media. Within each chapter, all analytical methods are developed in substantial detail, and a number of examples show how the developed relations may be applied to practical problems.

  • Chemical Engineering for Renewables Conversion

    • 1st Edition
    • Volume 42
    • English
    Biomass has received considerable attention as a sustainable feedstock that can replace diminishing fossil fuels for the production of energy and chemicals. At the present moment in the oil refining, petrochemical and chemical industry, after fractionation of crude oil, various fractions are upgraded either to fuels or functionalized to produce intermediates and specialty chemicals. An analogous concept of biorefining is based on the utilization of biomass as a renewable source of carbon, which could be transformed to valuable chemicals. Although various aspects of biomass transformations are frequently discussed in the literature, chemical engineering aspects of such transformations are commonly not considered. The aim of the present book is to fill this void.

  • The Elements of Polymer Science and Engineering

    • 3rd Edition
    • Alfred Rudin + 1 more
    • English
    The Elements of Polymer Science and Engineering, Third Edition, is a textbook for one- or two-semester introductory courses in polymer science and engineering taught primarily to senior undergraduate and first-year graduate students in a variety of disciplines, but primarily chemical engineering and materials science. Since the publication of the second edition in 1999, the field of polymers has advanced considerably. A key feature of this new edition is the inclusion of new concepts such as polymer nanocomposites and metallocene catalysts in existing chapters as well as new chapters covering selected contemporary topics such as behavior of natural polymers, polymer dynamics, and diffusion in polymers. This book has been completely reorganized to become more aligned with how instructors currently teach the course. There are now several enhancements to the book’s pedagogy, including the addition of numerous worked examples and new figures to better illustrate key concepts and the addition of a large number of end-of-chapter exercises, many of which are based on recently published research and relevant industrial data. This third edition will appeal to advanced undergraduate and graduate students in the physics, chemistry, and chemical engineering departments who are taking courses related to polymer science and engineering, as well as engineers new to the field of polymers.

  • Advances in Catalysis

    • 1st Edition
    • Volume 55
    • English
    Advances in Catalysis fills the gap between the journal papers and the textbooks across the diverse areas of catalysis research. For more than 60 years Advances in Catalysis has been dedicated to recording progress in the field of catalysis and providing the scientific community with comprehensive and authoritative reviews. This series in invaluable to chemical engineers, physical chemists, biochemists, researchers and industrial chemists working in the fields of catalysis and materials chemistry.

  • Periodic Operation of Chemical Reactors

    • 1st Edition
    • P. L. Silveston + 1 more
    • English
    This comprehensive review, prepared by 24 experts, many of whom are pioneers of the subject, brings together in one place over 40 years of research in this unique publication. This book will assist R & D specialists, research chemists, chemical engineers or process managers harnessing periodic operations to improve their process plant performance. Periodic Operation of Reactors covers process fundamentals, research equipment and methods and provides "the state of the art" for the periodic operation of many industrially important catalytic reactions. Emphasis is on experimental results, modeling and simulation. Combined reaction and separation are dealt with, including simulated moving bed chromatographic, pressure and temperature swing and circulating bed reactors. Thus, Periodic Operation of Reactors offers readers a single comprehensive source for the broad and diverse new subject. This exciting new publication is a "must have" for any professional working in chemical process research and development.

  • Principles of Desalination

    • 1st Edition
    • K Spiegler
    • English
    Principles of Desalination focuses on the principles of the developing technology of large-scale desalting. This book presents the principal desalting methods and explores the process of hyperfiltration or reverse osmosis. Comprised of 11 chapters, this book starts with an overview of the water use and the problem of a potential water shortage. This text then discusses the fundamentals of the major desalting methods in use and explores the basic scientific and design principles that underlie the methods. Other chapters consider the method of vapor reheat distillation, which incorporates the liquid–liquid heat exchange principle. This book discusses as well the various aspects of ion exchange and explores the mechanisms in dual-purpose plants producing both distilled water and steam-turbine raised power. The final chapter considers the cost of conventional water supplies. This book is a valuable resource for technologists and scientists. Students in the graduate courses of engineering will also find this book useful.

  • Chemical Ecology

    • 1st Edition
    • Ernest Sondheimer
    • English
    Chemical Ecology contains a series of lectures presented in the fall of 1968 at State University of New York College of Forestry at Syracuse University. This book is composed of 11 chapters that deal with the salient facts and theories that are encompassed by chemical ecology and the possible application of fundamental research in this area to pressing problems of ecological importance. After briefly describing the distribution pattern of microorganisms in the soil, this book goes on exploring the coordination and regulation of sexual processes between cells and between individuals in lower and higher plants. These topics are followed by discussions on the aspects of the chemical environment; the diverse associations between insects and their host plants; the self-defense mechanisms of plants against insect predation; and the chemical communication systems within animal species. The subsequent chapters examine the chemical defense and ecology in arthropods and fish. The concluding chapters consider the biochemistry of terpenoid and steroid metabolism and the chemical aspects of juvenile and steroidal molting hormone interactions. This book will be of value to chemical ecologists and researchers and biochemists.

  • A Biochemical Phylogeny of the Protists

    • 1st Edition
    • Mark Ragan
    • English
    A Biochemical Phylogeny of the Protists covers a wide variety of biochemical characters and their usefulness in phylogenetics. This book is composed of 13 chapters that describe the methods of deducing phylogenies of protists from biochemical data. Protists are morphologically simple forms of life, including bacteria, fungi, many algae, protozoa, and sponges. The first chapters deal with the biochemistry, evolution, and phylogenetics of the protists. The subsequent chapters explore the DNA and RNA structure and the protein and enzyme content of some protists. Considerable chapters describe the various metabolic pathways in the protists. The remaining chapters other biochemical processes, including sulfate reduction, nitrogen utilization, and carbon monoxide production. These chapters also provide a summary of numerous research studies biochemical phylogeny. This book will prove useful to biochemists, microbiologists, researchers, and students.

  • Cogeneration in the Cane Sugar Industry

    • 1st Edition
    • Volume 12
    • J.H. Payne
    • English
    The cane plant is probably the most efficient utilizer of sun energy for food production, and at the same time provides an equivalent quantity of biomass. The purpose of this book is to set down the unique position of sugar cane in the cogeneration field. Simultaneous with the development of distance-transmissio... of electricity, sugar cane processors started cogeneration, making use of the cane plant to supply the power for its own processing, and in recent years excess power for export.A broad view of cogeneration in the cane industry, covering the energy available in a crop, the technology of processing for optimum recovery of energy as well as sugar is presented here. The book describes the most practicable processes for recovering energy in the form of process steam and electricity.Cogenera... in the Cane Sugar Industry should be of interest to a broad spectrum, including government agencies, biomass interests, power generators, public utilities as well as sugar producers and technologist.

  • Energy Changes in Biochemical Reactions

    • 1st Edition
    • Irving Klotz
    • English
    Energy Changes in Biochemical Reactions considers the basic principles and techniques of energetic in biochemical reactions. This book is composed of eight chapters that emphasize the statistical thermodynamics of these reactions. The first two chapters discuss the concept of energy and entropy using the First and Second Law of Thermodynamics, respectively. These topics are followed by a discussion on the fundamentals, calculation, and dependence on concentration of chemical potential. A chapter presents the experimental determination of group transfer potential. Another chapter focuses on the power of thermodynamic methods in the analysis of physicochemical behavior. The final chapter looks into the fundamentals of statistical thermodynamics, with a special emphasis on the significant of combined molecular models and statistical theorems to delineate energetics. This book will be of benefit to students interested in the fundamental concepts and simple calculations of biochemical energetics.

  • Glucuronic Acid Free and Combined

    Chemistry, Biochemistry, Pharmacology, and Medicine
    • 1st Edition
    • Geoffrey Dutton
    • English
    Glucuronic Acid Free and Combined: Chemistry, Biochemistry, Pharmacology, and Medicine focuses on the study of glucuronic acid, particularly its physiological role in different fields. Divided into three parts with nine chapters, the book contains the literature of authors who have incessantly conducted research on this kind of acid. The book starts with the discussion on the chemistry of free glucuronic acid and its derivatives, and then discusses the nature, characteristics, and properties of glucuronides and other known conjugates. The next part presents the occurrence and chemistry of glucuronic acid incorporated in animal, plant, and bacterial polysaccharides. This presentation is followed by the discussions on the biosynthesis of glucuronic acid as UDPglucuronic acid and its relationship with simple glucuronides. A summary of information of the enzymic hydrolysis of conjugates is then presented. The succeeding chapters deal with the entry of glucuronic acid into general carbohydrate metabolism; the incorporation of glucuronic acid with the polysaccharides of living tissues; the pharmacological implications of glucuronic acid in drug detoxification; and the isolation and identification of steroid glucuronides. The book is a primary source of data for readers interested in studying the nature, composition, functions, and uses of glucuronic acid.

  • Biochemical Applications of Raman and Resonance Raman Spectroscopes

    • 1st Edition
    • P Carey
    • English
    Biochemical Applications of Raman and Resonance Raman Spectroscopies focuses on the application of Raman and resonance Raman spectroscopies to biochemical problems. The book reviews biological systems and details the application of Raman spectroscopy to biological molecules such as proteins, nucleic acids, and lipids. It also looks at codevelopments of lasers, optics, and electronics that drive advances in experimental Raman spectroscopy, along with the important ramifications of these advances for biochemical applications. This volume is organized into eight chapters and begins with an overview of the theoretical and experimental aspects of Raman spectroscopy, including a very brief explanation of what Raman and resonance Raman spectroscopies are and a discussion of their advantages and disadvantages for biochemical studies. The explanation of the Raman and resonance Raman effects is taken up in more detail in the next chapter, which develops the concept of the vibrational motions of molecules by initially considering mechanical ""ball and spring"" models and goes on to use this concept to formulate a classical model for Raman scattering. The resonance Raman effect is then described by another model which emphasizes the discrete or quantized energy levels available to a molecule. The reader is also introduced to the experimental aspects of Raman spectroscopy and the application of Raman spectroscopy across the entire field of biochemistry. Each chapter contains an outline of the basic chemistry and biochemical nomenclature involved. This book will be of interest to chemists, biochemists, and spectroscopists, as well as graduate students and experienced research workers.

  • Kinetic and Thermodynamic Lumping of Multicomponent Mixtures

    • 1st Edition
    • G. Astarita + 1 more
    • English
    Information necessary to solve scientific or engineering problems is often so vast, that the need arises to lump information together into a more manageable subset in order to proceed. The idea of lumping is one which is used, more or less consciously, in a large variety of fields. The thermodynamics and kinetic behavior of multicomponent mixtures is an area where the requirements of lumping have been clearly identified and the techniques and results of lumping have been analyzed in considerable detail. This book comprises the proceedings of a Symposium on Kinetic and Thermodynamic Lumping of Multicomponent Mixtures which was held at the American Chemical Society Meeting in Atlanta, GA, in April 1991. Papers presented at the symposium consisted of both invited and contributed papers. Each invited paper was a review of a subfield within the landscape of the symposium while the contributed papers contain detailed analyses of specific problems. The symposium brought together active researchers in this field to report on and discuss the progress which has been made in the lumping of mixtures of very many components for a number of different applications, and to identify the important problem areas which still remain. This volume will serve both as an introduction to anyone entering the field, and as a reference work for more experienced researchers.

  • Immobilized Enzymes For Industrial Reactors

    • 1st Edition
    • Ralph Messing
    • English
    Immobilized Enzymes for Industrial Reactors aims to guide the engineer and scientist along the path toward the industrial application of immobilized enzymes. It is necessary to identify the hazards and pitfalls that will be encountered, not only in the initial research efforts, but also during the final engineering phases of a commercial program. Each contributing factor in an immobilized enzyme system will be scrutinized by the authors in an effort to accomplish the overall objectives. This book comprises 10 chapters, with the first being an introduction to and general history of immobilized enzymes. The next chapters go on to discuss basic enzymology; controlled-pore glasses for enzyme immobilization; carriers; immobilization by adsorption and inorganic bridge formation; immobilization by covalent attachment and by entrapment; characteristics of free vs. immobilized enzymes; immobilized coenzymes; design and operation of immobilized enzyme reactors; and applications of immobilized enzymes. This book will be of interest to practitioners in the fields of chemistry and engineering.

  • Stereo-Differentiating reactions

    The nature of asymmetric reactions
    • 1st Edition
    • Yoshiharu Izumi
    • English
    Stereo-Differentiati... Reactions: The Nature of Asymmetric Reactions provides an introduction to asymmetric reactions. It brings together synthetic organic chemistry, stereochemistry, group theory, the theory of optical rotation, experimental methods, etc., all of which are basic to the study of stereo-differentiati... reactions, to form a unified approach based on the new concept of "differentiation." The authors hope that the value of the new concept, which is rather more complex than conventional treatments of asymmetric reactions, will become clear in the present book. This new concept should be useful in many fields of study, not only the development of stereo-differentiati... reactions, but also in the study of general reaction mechanisms in organic chemistry. The book contains nine chapters and begins with a historical background of studies on asymmetric reactions. This is followed by separate chapters on molecular symmetry and chirality; nomenclature for chirality, prochirality, and stereo-differentiati... reactions; the mechanisms of stereo-differentiati... reactions; methods for studying stereo-differentiati... reactions; and the basic principle of optical activity.

  • Analytical Methods for Coal and Coal Products

    • 1st Edition
    • Clarence Jr. Karr
    • English
    Analytical Methods for Coal and Coal Products, Volume I presents the analytical problems and methods for coal and its numerous products. This book discusses the technological importance of the measurement of the physical properties of coal. Organized into four parts encompassing 19 chapters, this volume starts with an overview of the petrographic analysis of coal wherein it involves two distinctive methods, namely, the reflected light and the transmitted light techniques. This text then discusses the means and methods of reflectance determination and proceeds to outline some of the results obtained and conclusions derived from them about the nature of coal. Other chapters explain the mechanical properties of coal, which are measured in order to predict its behavior in coal mines, coal winning, coal storage, coal comminution, coal handling, briquetting and agglomeration, and several other situations. The final chapter deals with the characterization of the liquid products of coal conversion. This book is a valuable resource for engineers, scientists, chemists, and researchers.

  • Handbook of Organic Solvent Properties

    • 1st Edition
    • Ian Smallwood
    • English
    The properties of 72 of the most commonly used solvents are given, tabulated in the most convenient way, making this book a joy for industrial chemists to use as a desk reference. The properties covered are those which answer the basic questions of: Will it do the job? Will it harm the user? Will it pollute the air? Is it easy to handle? Will it pollute the water? Can it be recovered or incinerated? These are all factors that need to be considered at the early stages of choosing a solvent for a new product or process.

  • Analysis of Engineering Cycles

    Power, Refrigerating and Gas Liquefaction Plant
    • 4th Edition
    • R. W. Haywood
    • English
    Extensively revised, updated and expanded, the fourth edition of this popular text provides a rigorous analytical treatment of modern energy conversion plant. Notable for both its theoretical and practical treatment of conventional and nuclear power plant, and its studies of refrigerating and gas-liquefaction plant. This fourth edition now includes material on topics of increasing concern in the fields of energy 'saving' and reduction of environmental pollution. This increased coverage deals specifically with the following areas: CHP (cogeneration) plant, studies of both gas and coal burning plant designed to reduce toxic emissions, and the study of PWR plant in the nuclear industry, which has been extended to cover conceptual designs aimed at greater inherent safety. With over 20 new sections plus new appendices and more problems this text not only retains its value but also enhances its usefulness to the reader, covering areas of current interest and importance.

  • Turbulence and Molecular Processes in Combustion

    • 1st Edition
    • T. Takeno
    • English
    An understanding of the intricacies in the turbulent combustion process may be a key to solving many of the current energy and environmental problems. The essential nature of turbulent combustion can be derived from the interaction between stochastic flow fluctuations and deterministic molecular processes, such as chemical reaction and transport processes. Undoubtedly, this is one of the most challenging fields of engineering science today, requiring as it does the interaction of scientists and engineers in the respective fields of chemical kinetics and fluid mechanics. The 28 papers in this volume review recent advances in these two disciplines providing new insights into the fundamental processes, addressing a great deal of recent progress. This progress ranges from descriptions of elementary chemical kinetics, to working those descriptions into combustion calculations with large numbers of elementary steps, to improved understanding of turbulent reacting flows and advances in simulations of turbulent combustion. The contributions will inspire further research on many fronts, advancing the understanding of combustion processes, as well as fostering a growing interdisciplinary cooperation.

  • Biochemical Aspects of Plant-Parasite Relationships

    Proceedings of The Phytochemical Society Symposium University of Hull, England April, 1975
    • 1st Edition
    • J. Friend
    • English
    Biochemical Aspects of Plant-Parasite Relationships is a collection of papers from the Phytochemical Society Symposium of the same subject held at Hull in April 1975. This collection discusses biochemical research on the mechanisms involved in the invasion of plants by pathogens, the production of disease symptoms, and the mechanisms occurring in plant resistance against the invading microorganisms. Some papers discuss the genetics of fungal-plant interactions and the structural features of both infection and resistance processes, Such genetic interactions and structural features point to a biochemical reason for the plant-parasite interaction. Several attempts to correlate production of a cell wall degrading enzyme in vitro by a pathogen's virulence have shown great differences between in vitro and in vivo environments. One paper cites as an example the pathogens which produce both pectic hydrolases and lyases: the type of enzyme that is found to predominate often is actually associated with the pH of the environment. One paper also investigates nucleic acid transfer and the possible role of RNA in the host-parasite specificity. This collection can prove beneficial for microbiologists, biochemists, biotechnologists, plant biologists, and academicians connected with the biological sciences.

  • Assembly Instructions for Nucleic Acid Models

    • 1st Edition
    • Edward Barrett
    • English
    Assembly Instructions for Nucleic Acid Models describes the step-by-step instructions in building a single nucleotide using the Academic Press/Molecular Design Inc. (AP/MDI) models. This booklet also provides instructions for constructing models of the DNA-B (Watson-Crick), DNA-A, and the DNA-Z forms. This text illustrates the chemical composition and atom numbering system of the nucleotide unit, the fundamental building block of all nucleic acids. The framework components include the atomic pieces for phosphorous, oxygen, carbon, nitrogen, and the fused pieces that represent two bases and two furanose rings. Building models of the different nucleic acid structure involves adjustments of seven torsion angles; in the AP/MDI Molecular Model System, only six angles are adjusted. In constructing larger DNA structures, the operator assembles a series of nucleotide units. He should also be familiar with the seven torsion angles of these structures which are composed of six adjustable angles and the correct ring conformation. This guide also contains a table listing the torsion angles for several forms of DNA. This booklet is suitable for students in chemistry, new chemist practioners, professors in chemistry, as well as other researchers whose works involve some chemical investigations and experiments.

  • Polypropylene and other Polyolefins

    Polymerization and Characterization
    • 1st Edition
    • Volume 7
    • S. van der Ven
    • English
    This book deals with polyolefins prepared via Ziegler-Natta catalysis, from a polymer chemist's viewpoint, i.e. with emphasis on their preparation and on their basic composition and properties. In addition to chapters on catalysts, polymerization behaviour and polymer properties such as tacticity, crystallinity, morphology etc., a chapter is also devoted to characterization methods. The main part of this work is reserved for polypropylene in all its forms, namely, homopolymer, random copolymer and toughened (`block') copolymers, for which extensive own-experience was present. The other polyolefins are also covered by means of a thorough literature review.This book is intended for scientists active in the field of polyolefins, including catalyst development, but should also prove an invaluable medium in academia to illustrate the growth of understanding in catalysis, kinetics and characterization of a commercially very important class of polymers.

  • Ring-Forming Polymerizations Pt A

    Carbocyclic and Metallorganic Rings
    • 1st Edition
    • Robert Cotter
    • English
    Ring-forming Polymerizations, Part A: Carbocyclic and Metallorganic Rings covers polymerization reactions that form carbocyclic rings and those that lead to metallorganic ring-containing structures. This book is organized into 11 chapters. The first four chapters describe ring-forming polymerizations that lead to the formation of homocyclic carbon-containing rings. These chapters specifically examine Diels-Alder polymerizations and certain diisopropenyl monomers polymerization yielding high molecular weight polyindanes. Chapter V is an introduction to polymers from metals and unsaturated carbon compounds, which has been called a ""natural coordination polymer"". Chapters VI to X deal with metallorganic ring polymers formed by chelation and are arranged according to the elements in the ligands that are affecting chelation. The final chapter explores ring forming polymerizations that yield polysiloxanes, polysilazanes, and certain polymetalloxanes. This book will be of value to organic chemists and researchers, as well as to organic chemistry teachers and students.

  • Current Biochemical Research in China

    • 1st Edition
    • C Tsou
    • English
    Current Biochemical Research in China presents the Chinese contributions to the biochemical sciences. This book aims to make the situation of biochemical research in China better known to the rest of the world. Organized into 21 chapters, this book begins with an overview of some of the fundamental research of Chinese biochemists, which may be found interesting by colleagues in the western world. This text then presents the investigations of the relationship between structure and function of proteins by synthetic methods. Other chapters provide the comprehensive and scientific compilation of the herb medicines used in China since ancient times. This book discusses as well the correlation of molecular structures of proteins with their biological functions. The final chapter deals with the importance of hemostasis and thrombosis wherein platelets adhere to injured vascular wall and aggregate to form the white hemostatic plug. This book is a valuable resource for biochemists, biophysicists, scientists, and research workers.

  • Redistribution Reactions

    • 1st Edition
    • J.C. Lockhart
    • English
    Redistribution Reactions is a comprehensive coverage of redistribution phenomena for the entire Periodic Table. This book is organized into two sections encompassing 10 chapters that tackle the concepts of structural reorganization. Part I provides first an overview of redistribution reactions, followed by a discussion on a series of techniques capable of detecting all compounds in a redistribution reaction, including electronic, vibrational, and nuclear magnetic spectroscopy, X-ray crystallography, mass spectroscopy, polarography, chromatography, and the use of phase diagram. Part II is devoted to the redistribution reactions of the elements under Periodic Group headings with available kinetics or thermodynamics information. This part also presents valuable structural information of the group elements, such as their vibrational frequencies and chemical shifts. This work will be of convenient reference for researchers already working on redistribution and for a more general range of research workers in inorganic chemistry who require information on scrambling for a specific element.

  • Chelating Agents and Metal Chelates

    • 1st Edition
    • F Dwyer
    • English
    Chelating Agents and Metal Chelates focuses on the structure and properties of metal chelates, as well as bond types, stereochemistry, and optical phenomena. The selection first offers information on historical background and fundamental concepts and the nature of metal-ligand bond. Discussions focus on the structure and stability of metal chelates, bond types and characteristic properties, classes of acceptor metal atoms, and metal-metal bonds in complex compounds. The text also touches on bidentate chelates, design and stereochemistry of multidentate chelating agents, and optical phenomena in metal chelates. The publication ponders on oxidation-reduction potentials as functions of donor atom and ligand and metal chelates of ethylenediaminetetra... acid and related substances. Topics include liquid junction potentials, reversibility, measurement of redox potentials, ethylenediaminetetra... chelate couples, and metal chelates of ethylenediaminetetra... acid. The text also takes a look at metal chelates in biological systems and physical and coordination chemistry of tetrapyrrole pigments. The manuscript is a vital reference for senior students, research workers, biologists, and medical scientists interested in the chemistry of metal chelates.

  • Ziegler-Natta Catalysts Polymerizations

    • 1st Edition
    • John Jr. Boor
    • English
    Ziegler-Natta Catalysts and Polymerizations reviews the general aspects of Ziegler-Natta catalysts and polymerizations of olefins, dienes, and many other types of monomers. Topics covered include the physical state of the polymer during polymerization; modification of Ziegler-Natta catalysts by third components; and termination of polymer chain growth. The oxidation state of catalysts and active centers is also discussed, along with copolymerizations and block polymerizations. This book is comprised of 23 chapters and begins with an overview of Ziegler-Natta catalysts and polymerizations, their historical origins, scientific and commercial importance, and major advances in polymer science. The next chapter focuses on definitions and stereochemistry of Ziegler-Natta catalysts, together with analytical methods used to identify and quantitatively measure their structures. Some of the polymers produced commercially with Ziegler-Natta catalysts are considered. The discussion then turns to mechanisms for initiating and propagating olefins; mechanisms for stereochemical control of conjugated and nonconjugated dienes; and the basic kinetic parameters that characterize Ziegler-Natta polymerizations. This monograph is written especially for chemistry and engineering graduate students and for industrial chemists, engineers, and managers who may become involved in a Ziegler-Natta problem.

  • Biochemical Actions of Hormones V14

    • 1st Edition
    • Gerald Litwack
    • English
    Biochemical Actions of Hormones, Volume XIV is a compendium of papers dealing with DNA regulatory elements, leukotriene receptors, hormonal regulation of sodium-proton exchange activity, the structure of the mammalian progesterone receptor, stimulus-response, and signaling systems. One paper analyzes the hormonal factors that regulate the kinetic properties of the plasma membrane Na+ -H+ exchanger in epithelia and relates the control mechanisms to specific physiological function. Aqueous two-phase partitioning is a method that can be used in the study of steroid receptor activation and other conversions or interactions of steroid receptors. Using the two-phase partitioning, one can form a model of molecular changes during activation based on changes in the steroid receptor physico-chemical properties associated with the activation in vitro-phase. Another paper investigates the hypothesis that early androgenic modulation of nuclear effector-independent PKs is intimately related to the initial events in androgenic control of gene expression in the prostate. One paper describes the interaction between the estrogen receptor with DNA and the mechanism of transcription regulation by steroid receptors. Another paper reviews the role of GTP-binding proteins in receptor-mediated activation of phospholipase C, the formation and metabolism of novel inositol phosphates, as well as the possible role of protein kinase C in signal modulation. Micro-biologists, biochemists, molecular biologists, cellular biologists, and investigators in the field of cell research will find this collection useful.

  • Analytical Biotechnology

    • 1st Edition
    • C. van Dijk
    • English
    ANABIOTEC '92 focused on the further integration of biotechnology and analytical chemistry. The results of this symposium clearly demonstrated that a substantial progress could be reported in the application of both conventional and new analytical techniques, the latter essentially based on natural analytical tools such as biomolecules. The main themes covered during this meeting are fermentation monitoring, chromatography, instrumental analysis, biosensors and bioanalysis.

  • Activation, Deactivation, and Poisoning of Catalysts

    • 1st Edition
    • John Butt
    • English
    Activation, Deactivation, and Poisoning of Catalysts deals with the circumstances and mechanisms underlying catalyst activation, deactivation, and poisoning. The emphasis is on the techniques for handling deactivating systems, not on results per se. Deactivation by fouling and sintering is given consideration. This book is organized into three sections and consists of 12 chapters. The first part is devoted to a systematic development of the manner in which catalysts are activated, deactivated, poisoned, and in some cases reactivated on a microscopic basis. The first chapter explains the concept of the active center as utilized in catalysis, along with catalyst regeneration, rejuvenation, and detoxification. In the second part, the reader is introduced to the problem of heat transfer as well as the transport of reactants and products in the interior of the particle coupled with chemical reaction therein. The macroscopic deactivation behavior of the catalyst particle is described in terms of fundamental kinetic deactivation phenomena and of parameters governing heat and mass transfer. The last part is primarily concerned with a collection of catalyst particles within the reactor, with emphasis on the global activity of the reactor. In the last chapter, a pragmatic approach is presented to predict the design and performance of chemical reactors containing a deactivating catalyst. This book is written for catalytic chemists, researchers, reactor designers, and students interested in catalyst activation, deactivation, and poisoning.

  • Biochemical and Clinical Aspects of Hemoglobin Abnormalities

    • 1st Edition
    • Winslow Caughey
    • English
    Biochemical and Clinical Aspects of Hemoglobin Abnormalities contains the proceedings of a symposium held on the Pingree Park campus of Colorado State University on October 2-7, 1977. Contributors discuss the biochemical and clinical aspects of hemoglobin abnormalities and cover topics ranging from amino acid substitutions to sickle cell disease, glycosylated hemoglobins, cystamine inhibition of sickling, and gelation of sickle cell hemoglobin. This volume is organized into 52 chapters and begins with a discussion of the role of distal residues in structure, ligand binding, and oxidation of hemoglobins A, Zurich, and Sydney. It then turns to functional abnormalities of whole blood in sickle cell anemia, inhibition of sickle hemoglobin gelation by amino acids and peptides, and intermolecular interactions in crystals of human deoxy hemoglobins A, C, F, and S. The chapters that follow focus on glycosylation of human hemoglobin, the phase transitions of sickle-cell hemoglobin, conformational effects of the HbS mutation, and mechanisms for hemoglobin oxidation. The reader is also introduced to oxidation of oxyhemoglobin by reductants, the kinetics of oxygen binding to human red blood cells, and oxidation of human hemoglobin by copper. A chapter that assesses the effect of physiological parameters, such as pH, oxygen concentration, protein concentration, non-gelling hemoglobins, and the erythrocyte membrane, on the kinetics of polymerization of deoxyhemoglobin S concludes the book. This book is intended for biochemists and clinicians interested in knowing more about hemoglobin abnormalities.

  • Maize

    Recent Progress in Chemistry and Technology
    • 1st Edition
    • George Inglett
    • English
    Maize: Recent Progress in Chemistry and Technology covers the proceedings of a symposium on the progress in chemistry and technology of maize. The symposium is held at the Seventh World Cereal and Bread Congress in Prague, Czechoslovakia on June 28–July 2, 1982. This book is composed of 16 chapters that focus on considerable progress in the composition and processing of maize. This text initially covers the composition of lipids in maize starches and the hemicelluloses content of corn seed. It goes on discussing corn bran as a source of dietary fiber; extrusion cooking of corn flours and starches; and use of debranching enzymes in dextrose production. Other chapters examine the effect of composition and structure of maize on double enzyme processing; the utilization of maize flour in breadmaking; the energy preservation in maize drying; and the drying conditions related to wet-milling of maize. A chapter also examines the biochemical and microbiological changes in stored maize. Moreover, this book also describes the effect of mycotoxin contamination in the maize field. Finally, moisture determinations in maize and maize germ flour prepared by supercritical carbon dioxide extraction are considered. This book will be a useful reference for students, scientists, technologists, and manufacturers who are involved in any facet of maize production and utilization.

  • Food Irradiation

    • 1st Edition
    • Walter Urbain
    • English
    Food Irradiation focuses on the fundamental aspects and applications of food irradiation. It summarizes efforts to establish the wholesomeness of irradiated foods, and it discusses the nature of ionizing radiation, as well as its interaction with matter, the biological effects it induces in living organisms associated with food such as raw fruits and vegetables, and the application of these effects in treating foods. The book also highlights some aspects of food irradiation that have potential significance in commercial usage, including consumer attitudes, costs, facilities, and safety. Organized into 15 chapters, this volume begins with an overview of ionizing radiation and its biological effects, the basics of radiation chemistry, and radiation chemistry of foods and food components. It then discusses the general effects of ionizing radiation on foods; irradiation of foods, such as meats and poultry, marine and freshwater animal foods, beverages, and dairy products; government regulation of irradiated foods; and consumer acceptance of irradiated foods. This book is a valuable source of information for food technologists, nutritionists, and suppliers of irradiation facilities and equipment.

  • Adsorptive Bubble Separation Techniques

    • 1st Edition
    • Robert Lemlich
    • English
    Adsorptive Bubble Separation Techniques focuses on the mechanisms of the various adsorptive bubble separation methods. This book examines the various adsorptive bubble separation techniques, including ion flotation, foam fractionation, precipitate flotation, mineral flotation, bubble fractionation, and solvent sublation. Organized into 20 chapters, this book starts with an overview of the certain important properties of foam. This text then examines the results of several separations, as well as the results of additional studies into the mechanisms of the different techniques. Other chapters explain the studies of foam separation in the case of synthetic solutions, which provide a good knowledge of the extraction mechanisms of the radioactive cations, cesium, cerium, and strontium. This book discusses as well the experimental and theoretical work on foam separation done in Israel. The final chapter deals with the separation of surfactants and metallic ions at various places around the world. This book is a valuable resource for materials scientists, engineers, and chemists.

  • Non-Stoichiometry in Semiconductors

    • 1st Edition
    • K.J. Bachmann + 2 more
    • English
    Significant advances have occurred in the theory of non-stoichiometry problems and fundamentally new and wide-ranging applications have been developed, helping to better identify relevant issues. The contributions in this volume bring together the experience of specialists from different disciplines (materials scientists, physicists, chemists and device people) confronted with non-stoichiometry problems. The 40 papers, including 9 invited papers, give an advanced scenario of this wide interdisciplinary area, which is highly important in its diverse aspects of theory, implementation and applications. This work will be of interest not only to universities and laboratories engaged in studies and research in this field, but also to organizations and industrial centres concerned with implementations and applications. The diversity of the topics, as well as the extraordinary tempo in which Non-stoichiometry in Semiconductors has progressed in recent years attest to the permanent vitality of this field of research and development.

  • Gas Chromatography with Glass Capillary Columns

    • 2nd Edition
    • Walter Jennings
    • English
    The need for this second edition is dictated by developments that have occurred in this rapidly changing field and by sins of omission and sins of commission in the first edition. Projections available at the time of this writing indicate that gas chromoatography will remain the world's most widely used analytical technique for some time.

  • Anthocyanins as Food Colors

    • 1st Edition
    • Pericles Markakis
    • English
    Anthocyanins as Food Colors aims to assemble scattered information on anthocyanins pertinent to food coloration. Both basic and applied aspects of these pigments are discussed. Organized into nine chapters, this book begins with a discussion of the chemical structure of anthocyanins, followed by its copigmentation and biosynthesis. It then discusses the distribution of anthocyanin in food plants, as well as the compounds' stability in food. This work also looks into the analysis of anthocyanins and their presence in grapes and wine. Utilization of anthocyanins as food additives is addressed in the last chapter. This book will provide additional information in order to maximize the visual appeal of these pigments both in products in which they are naturally present and in products to which they may be added as colorants.

  • Handbook of Naturally Occurring Compounds V1

    • 1st Edition
    • T.K. Devon
    • English
    Handbook of Naturally Occurring Compounds, Volume I: Acetogenins, Shikimates, and Carbohydrates contains most of the known naturally occurring compounds and their corresponding structures, classified into acetogenins, shikimates, and carbohydrates. Each structure includes the molecular formula, molecular weight, optical rotation, melting point, literature reference, and classification number. This handbook is comprised of nine chapters and begins with an introduction to the primary classes of naturally occurring compounds to be discussed in the following chapters, namely shikimate aromatics, acetate/shikimate aromatics, acetate/malonate aromatics, acyclic and heterocyclic acetogenins, carbohydrates, and complex classes. The shikimic acid pathway is described, along with the oxygenation patterns of shikimate-derived aromatics. Compounds such as lignans, terphenyls, macrolides, and miscellaneous phenols are considered. Oxyheterocyclics related to the linear acetogenins/phenylpo... are also analyzed. The final chapter provides three indices in addition to the structural guides, namely, Molecular Weight Index, Molecular Formula Index, and Alphabetical Index. This volume will be a useful resource for chemists and chemistry students.

  • Polymer Solutions, Blends, and Interfaces

    • 1st Edition
    • Volume 11
    • I. Noda + 1 more
    • English
    The behaviour of polymers in multi-component and multiphase systems such as solutions, blends and interfaces derived from both natural and synthetic sources and the subsequent influence of this on their physical properties is the theme of this book. Important new material on multiphase polymer systems such as block copolymers and liquid crystalline polymers is provided, and the solution and surface properties of enzymes and surface active polymers is described both theoretically and experimentally. The application of theory to the development of new cellulosic materials is particularly noteworthy. The relationship between end-use properties, such as adhesion, wetting, and colloidal stability, and molecular structure at the interface is addressed. Examples include the capillary pressure of nylon microporous membranes, a new technique for characterizing the adhesion between incompatible polymers, and the influence of the glass transition temperature at the fiber/matrix interface on interfacial shear strength.Characteriz... of polymer films, both electrochemically and via optical techniques is covered and the interactions of amphiphilic ions with polyacrylate polymer are described. The final two chapters introduce the topic of enzyme mobility at an interface and show how this may affect their role as biological catalysts.

  • Chemical and Biochemical Applications of Lasers V5

    • 1st Edition
    • C. Bradley Moore
    • English
    Chemical and Biological Applications of Lasers, Volume V focuses on the laser applications in photochemistry and spectroscopy. This book examines the spectroscopic detection of single atoms and explores the purification of industrial chemicals. Organized into seven chapters, this volume starts with an overview of the methods developed for laser detection of single atoms, including fluorescence, photoionization, photodeflection, and their combinations. This text then discusses the methods of high resolution spectroscopy, which provide detailed information on molecular structure and reaction kinetics studies. Other chapters review several laser photodissociation studies, which explain dissociation dynamics. This book discusses as well the possibilities for selective photochemical reactions and examines the potential of lasers for practical application in chemical processing. The final chapter considers the various metals that can undergo a photochemical change in oxidation state in ordinary solvents. This book is a valuable resource for physicists, chemists, electrochemists, photochemists, electrical engineers, and chemical engineers.

  • Biotechnology

    A Laboratory Course
    • 1st Edition
    • Jeffery M. Becker
    • English
    Biotechnology: A Laboratory Course is a series of laboratory exercises demonstrating the in-depth experience and understanding of selected methods, techniques, and instrumentation used in biotechnology. This manual is an outgrowth of an introductory laboratory course for senior undergraduate and first year graduate students in the biological sciences at The University of Tennessee. This book is composed of 19 chapters and begins with some introductory notes on record keeping and safety rules. The first exercises include pH measurement, the use of micropipettors and spectrophotometers, the concept of aseptic technique, and preparation of culture media. The subsequent exercises involve the application of the growth curve, the isolation, purification, and concentration of plasmid DNA from Escherichia coli, and the process of agarose gel electrophoresis. Other exercises include the preparation, purification, and hybridization of probe, the transformation of Saccharomyces cerevisiae, the transformation of E. coli by plasmid DNA, and the principles and applications of protein assays. The final exercises explore the ?-galactosidase assay and the purification and determination of ?-galactosidase in permeabilized yeast cells. This book is of great value to undergraduate biotechnology and molecular biology students.

  • Biological Electrochemistry

    • 1st Edition
    • Glenn Dryhurst
    • English
    Biological Electrochemistry, Volume I is a result of a series of lectures given regarding the electrochemistry of small and large organic and inorganic molecules and how electrochemical information helps in understanding some of the biological redox reactions of these systems. This volume ultimately focuses on the electrochemistry of small and macromolecular organic compounds. This book is divided into seven chapters where each focuses on a particular organic compound. These compounds are quinones, catecholamines, phenothiazines, ascorbic acid, purines, vitamin B12 and related compounds, and proteins. Each chapter starts with a brief introduction to the compounds and then its structure and electrochemistry aspect. The last chapter gives a detailed discussion on different kinds of proteins and their electrochemistry aspects. This volume will be of help to students as well as electrochemists, biochemists, biologists, and other scientists in the field of biotechnology.

  • Industrial Chemicals

    Their Characteristics and Development
    • 1st Edition
    • Volume 6
    • G. Agam
    • English
    The special world of industrial chemistry is illuminated in this text. Issues such as naming and classification of chemicals, safety, formulations and specifications, information and patents are treated. Process-related topics are discussed, such as scaling-up, equipment selection, construction materials, environmental impact and waste minimization. Aspects which fall in between the traditional disciplines of chemistry and chemical engineering are covered, which are so critical for the development of a successful industrial process, and the awareness of which avoids pitfalls in industrial research and development. Case studies are given, and special appendices provide useful information for the industrial chemist or student.The book is aimed at industrial chemists and engineers, and at students in those faculties, intending to pursue this field in industry. Marketing and purchasing staff will also find this text valuable.

  • Artificial Intelligence in Chemical Engineering

    • 1st Edition
    • Thomas E. Quantrille + 1 more
    • English
    Artificial intelligence (AI) is the part of computer science concerned with designing intelligent computer systems (systems that exhibit characteristics we associate with intelligence in human behavior). This book is the first published textbook of AI in chemical engineering, and provides broad and in-depth coverage of AI programming, AI principles, expert systems, and neural networks in chemical engineering. This book introduces the computational means and methodologies that are used to enable computers to perform intelligent engineering tasks. A key goal is to move beyond the principles of AI into its applications in chemical engineering. After reading this book, a chemical engineer will have a firm grounding in AI, know what chemical engineering applications of AI exist today, and understand the current challenges facing AI in engineering.

  • Plastics

    Their Behaviour in Fires
    • 1st Edition
    • Volume 6
    • H. Macskásy + 1 more
    • English
    Presented here in detail is a number of generally accepted, standardised inflammability tests. A comprehensive survey of ISO, IEC, ASTN, VL, BS and DIN is given and other standards are also mentioned. The testing of materials, products and full-scale model-testing are described. Furthermore, the book describes methods for reducing the inflammability of plastics, various techniques for fires involving plastics and fire regulations.

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