Homogeneous Carbonylation and Hydroformylation Reactions

1st Edition - August 20, 2024
Editors: Mohammad Reza Rahimpour, Mohammad Amin Makarem, Tayebeh Roostaie, Maryam Meshksar
Language: English
Paperback ISBN:
9 7 8 - 0 - 4 4 3 - 1 5 5 6 0 - 4
eBook ISBN:
9 7 8 - 0 - 4 4 3 - 1 5 5 6 1 - 1

Homogeneous Carbonylation and Hydroformylation Reactions, a volume is in the Advances in Homogeneous Catalysis series, is split into two sections. The first covers the homogeneo… Read more

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Homogeneous Carbonylation and Hydroformylation Reactions, a volume is in the Advances in Homogeneous Catalysis series, is split into two sections. The first covers the homogeneous carbonylation of various chemicals, such as methanol, methyl acetate, esters, and ethers. In addition, some common carbonylation homogeneous processes such as water-gas shift and Fischer–Tropsch reactions are included. The second part describes hydroformylation processes like cobalt and rhodium based reactions. Both parts cover the design of catalytic reactors, industrial applications, economic assessment and environmental impacts, providing detailed discussions of the subject from both a chemistry and engineering perspective.

Cover image
Title page
Table of Contents
Copyright
Contributors
About the editors
Preface
Reviewer acknowledgments
Section I. Carbonylation with homogeneous catalysts
Chapter 1. An overview of carbonylation systems and processes with homogeneous catalysts
1. Introduction
2. Carbonylation reactions in metal catalysts
3. Carbonylation reactions in organic synthesis
4. Conclusion and future outlooks
Abbreviations and symbols
Chapter 2. Homogeneous methanol carbonylation
1. Introduction
2. Processes
3. Current applications and cases
4. Conclusion and future outlooks
Abbreviations and symbols
Chapter 3. Higher alcohols carbonylation using homogeneous catalysts
1. Introduction
2. Homogeneous catalysts for ketones and esters carbonylation to higher alcohols
3. Application metal-catalyzed carbonation in higher alcohol
4. Conclusion and future outlooks
Abbreviations and symbols
Chapter 4. Carbonylation of aryl halides using homogeneous catalysts
1. Introduction
2. Principles and procedures
3. Processes
4. Current applications and cases
5. Conclusion and future outlooks
Abbreviations and symbols
Chapter 5. Oxidative carbonylation with homogeneous catalysts
1. Introduction
2. OC in organic synthesis with homogeneous catalysts
3. Application of ligands in OC of homogeneous catalyst
4. Conclusion and future outlooks
Abbreviations and symbols
Chapter 6. Water-gas shift reaction with homogeneous catalysts
1. Introduction
2. The water gas shift reaction
3. Thermodynamic interpretation of water gas shift reaction
4. Discussion of kinetics study of water gas shift reaction
5. Common catalysts which are used in water-gas- shift-reaction
6. Water-gas shift reaction using homogeneous catalyst
7. Homogeneous water gas shift reaction catalysis in simple environments
8. WGSR catalysis in acidic environments
9. Catalysis in totally aqueous solutions
10. Current applications and cases
11. Conclusion and future outlooks
Abbreviations and symbols
Chapter 7. Homogeneous versus heterogeneous catalysis of the Fischer-Tropsch reaction
1. Introduction
2. Iron catalyst for Fischer-Tropsch synthesis
3. Cobalt–iron catalyst for Fischer-Tropsch synthesis
4. Cobalt catalyst for Fischer-Tropsch synthesis
5. Ruthenium catalysts for Fischer-Tropsch synthesis
6. Platinum catalyst for Fischer-Tropsch synthesis
7. Conclusion and future outlooks
Abbreviations and symbols
Section II. Hydroformylation with homogeneous catalysts
Chapter 8. Overview of homogeneous hydroformylation catalysis
1. Introduction
2. Reactants involved in hydroformylation
3. Ligands that modify the catalysts
4. Various types of catalysts used for hydroformylation (excluded Co- and Rh-catalysts)
5. General reaction conditions
6. Processes
7. Preparation of homogeneous precatalysts
8. Diastereoselective hydroformylations
9. Asymmetric hydroformylation
10. Current applications and cases
11. Alternatives to syngas
12. Conclusions and future outlooks
Abbreviations and symbols
Chapter 9. Homogeneous Rhodium based hydroformylation processes
1. Introduction
2. Principles and procedures
3. Processes
4. Current applications and cases
5. Conclusion and future outlooks
Abbreviations and symbols
Chapter 10. Aqueous-phase hydroformylation processes with homogeneous catalysts
1. Introduction
2. Principles and procedures
3. Processes
4. Current applications and cases
5. Conclusions and future outlooks
Abbreviations and symbols
Index

Mohammad Reza Rahimpour

Prof. Mohammad Reza Rahimpour is a professor in Chemical Engineering at Shiraz University, Iran. He received his Ph.D. in Chemical Engineering from Shiraz University joint with University of Sydney, Australia 1988. He started his independent career as Assistant Professor in September 1998 at Shiraz University. Prof. M.R. Rahimpour, was a Research Associate at University of California, Davis from 2012 till 2017. During his stay in University of California, he developed different reaction networks and catalytic processes such as thermal and plasma reactors for upgrading of lignin bio-oil to biofuel with collaboration of UCDAVIS. He has been a Chair of Department of Chemical Engineering at Shiraz University from 2005 till 2009 and from 2015 till 2020. Prof. M.R. Rahimpour leads a research group in fuel processing technology focused on the catalytic conversion of fossil fuels such as natural gas, and renewable fuels such as bio-oils derived from lignin to valuable energy sources. He provides young distinguished scholars with perfect educational opportunities in both experimental methods and theoretical tools in developing countries to investigate in-depth research in the various field of chemical engineering including carbon capture, chemical looping, membrane separation, storage and utilization technologies, novel technologies for natural gas conversion and improving the energy efficiency in the production and use of natural gas industries.

Affiliations and expertise

Professor, Department of Chemical Engineering, Shiraz University, Shiraz, Iran

Mohammad Amin Makarem

Dr. Mohammad Amin Makarem is a research associate at Taylor's University, Malaysia. He former worked at Shiraz University. His research interests are gas separation and purification, nanofluids, microfluidics, catalyst synthesis, reactor design and green energy. In gas separation, his focus is on experimental and theoretical investigation and optimization of pressure swing adsorption process, and in the gas purification field, he is working on novel technologies such as microchannels. Recently, he has investigated methods of synthesizing bio-template nanomaterials and catalysts. Besides, he has collaborated in writing and editing various books and book-chapters for famous publishers such as Elsevier, Springer and Wiley, as well as guest editing journals special issues.

Affiliations and expertise

Taylor's University, Malaysia

Tayebeh Roostaie

Tayebeh Roostaie is a research associate at Shiraz University. Her research has focused on catalyst, clean energy, biofuel, demulsification and membrane. In the clean energy field, she has worked on hydrogen production. She has also synthesized novel catalysts for this process which are tested in a laboratory reactor. Recently, she has written various book chapters for famous publishers such as Elsevier.

Affiliations and expertise

Department of Chemical Engineering Shiraz University, Shiraz, Iran

Maryam Meshksar

Maryam Meshksar is a research associate at Shiraz University. Her research has focused on gas separation, clean energy, and catalyst synthesis. In gas separation, she is working on membrane separation process, and in the clean energy field, she has worked on reforming-based processes for hydrogen production from methane experimentally. She has also synthesized novel catalysts for this process which are tested in for the first time. Recently, she has written various book chapters for famous publishers such as Elsevier, Springer and Wiley

Affiliations and expertise

Department of Chemical Engineering Shiraz University, Shiraz, Iran

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Homogeneous Carbonylation and Hydroformylation Reactions

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Mohammad Reza Rahimpour

Mohammad Amin Makarem

Tayebeh Roostaie

Maryam Meshksar