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Elsevier

Books in Chemistry

Chemistry topic areas include: physical and theoretical, computational, organic, organometallic and inorganic, pharmaceutical and medicinal, analytical and bioanalytical, nuclear, general, nanochemistry, geochemistry, materials and polymer, as well as environmental, green and sustainable chemistry.

  • Fundamental Chemical Kinetics

    An Explanatory Introduction to the Concepts
    • 1st Edition
    • M R Wright
    • English
    The unusual approach of this text gives final honours and post-graduate students a clear and explanatory account of one of the “harder” areas of physical chemistry. The author takes care to provide detailed verbal clarification of the concepts and their importance together with full explanations of the mathematical developments. Her explanations are an essential and vital feature of the text, which is scholarly, lucid and well-written with a combination of depth of coverage and clarity which helps students to work through on their own.

  • Biosensors: A Chinese Perspective

    • 1st Edition
    • Volume 4
    • Reinhard Renneberg + 1 more
    • English
    In this second volume of a sub-series dedicated to regional activities, eminent authorities form China in the field of biosensors provide an up-to-date overview of their laboratory's contribution, summarizing the primary research as it has appeared, possibly scattered, in the journal and conference literature and reflecting on their findings. This produces an innovative synthesis of such smaller research efforts into an overall perspective on the topic, which is difficult for the reader to glean from the multifarious original publications often available only in Chinese. There is latitude for the inclusion of detail that may have been excised from the original publication and for speculation on future possibilities. The net result is intense, yet highly readable accounts of the state of the art at this leading edge of analytical technology in this key region of the world.This is the first book in the English language summarizing biosensor and bioelectronics efforts in China.

  • Alkaloids: Chemical and Biological Perspectives

    • 1st Edition
    • Volume 13
    • S.W. Pelletier
    • English
    Volume 13 of this series presents five timely reviews of research on alkaloids such as new developments in the chemistry and biology of alkaloids from amphibian skins. It provides a synopsis and tabulation of the hundreds of alkaloids that have been detected, with an emphasis on occurrence, structure, dietary origins, and biological activity. Alkaloids containing the 1, 2, 3, 3a, 8, 8a - hexahydropyrrolo [2,3b] indole ring system and the cyclotryptamines are discussed. An exhaustive list of available structures is provided. The chemical and biological structures have been evaluated critically so as to identify existing errors and expose irregularities in appearance or biological function. In addition, attention is drawn to the possible implications of the accumulated knowledge related to the synthesis, occurrence, and biochemistry of this class of alkaloids.Recent work on alkaloids containing the comparatively non – basic pyrrole ring system is summarized. One of the chapters covers isolation, structure elucidation, biological activity, and selected chemical syntheses of certain pyrrole alkaloids.Recent developments in the chemistry of diterpenoid and norditerpenoid alkaloids occurring in Aconitum, Delphinium and Consolida genera of the Ranunculaceae family used in Chinese and Indian medicine are surveyed and the book ends with a focus on transition metal – catalyzed carbonylations as efficient and novel approaches to the construction of piperidine, izidine and quinazoline alkaloids, which occur in great numbers in nature.

  • Mathematics for Physical Chemistry

    • 2nd Edition
    • Robert G. Mortimer
    • English
    Mathematics for Physical Chemistry is the ideal textbook for upper-level undergraduates or graduate students who want to sharpen their mathematics skills while they are enrolled in a physical chemistry course. Solved examples and problems, interspersed throughout the presentation and intended to be worked when met in the text, encourage self-study by students new to the material. The author provides readers with a review of calculus and differential equations that will enable them to succeed in a physical chemistry course. An ideal reference text for practicing chemists as well.

  • Advances in Electron Transfer Chemistry

    • 1st Edition
    • Volume 6
    • P.S. Mariano
    • English
    It is clear that electron transfer chemisty is now one of the most active areas of chemical study. Advances in Electron Transfer Chemistry has been designed to allow scientists who are developing new knowledge in this rapidly expanding area to describe their most recent research findings. This volume will serve those interested in learning about current breakthroughs in this rapidly expanding area of chemical research.

  • Advances in Quantitative Structure-Property Relationships

    • 1st Edition
    • Volume 2
    • M. Charton + 1 more
    • English
    Quantitative structure property relationships (QSPR) have become a major method of chemical research. In the course of this development the field has suffered from fragmentation. Applications of QSPR are found in all major chemical disciplines including physical organic, physical, medicinal, agricultural, biological, enviromental, and polymer chemistry. Frequently workers in one area are unaware of parameterizations and models used in other ares which they might well find useful. The is a common thread which runs through these widely diverse areas. The basic principles, parameterizations and methodology are the same or similar throughout.The object of this series is to provide interesting and timely reviews covering all aspects of the field. It encourages the transfer of new methods, techniques, and parameterizations from the area in which they were developed to other areas that can make good use of them. In view of the widespread use of QSPR we believe that this is an important objective. This series will provide the cross-fertilization which is sorely needed.

  • Advances in Medicinal Chemistry

    • 1st Edition
    • Volume 4
    • B.E. Maryanoff + 1 more
    • English
    Volume 4 of Advances in Medicinal Chemistry is comprised of six chapters on a wide range of topics in medicinal chemistry, including molecular modeling, structure-based drug design, organic synthesis, peptide conformational analysis, biological assessment, structure-activity correlation, and lead optimization. Chapter 1 presents an account about amino acid-based peptide mimetics corresponding to b-turn, loop, helical motifs in proteins as a probe of ligand-receptor and ligand-enzyme molecular interactions. Chapter 2 addresses new facets of the medicinal chemistry of the important anticancer drug Taxol® (paclitaxel). Chapter 3 relates an account of the search for new drugs for the treatment of malaria based on the natural product artemisinin. Chapter 4 applies computational chemistry to the evaluation of compound libraries for biological testing. Chapter 5 describes the construction of a 3-dimensional molecular model of the human thrombin receptor, the first protease-activated G-protein coupled receptor (PAR-1), as a means to explore the intermolecular contacts involved in agonist peptide recognition. Finally, Chapter 6 describes the research conducted at Merck on inhibitors of farnesyl transferase as a potential treatment for human cancers.

  • Comprehensive Supramolecular Chemistry, Volume 3

    Cyclodextrins
    • 1st Edition
    • J. Szejtli + 1 more
    • English
    The total number of papers, conferences, abstracts and patents dedicated to cyclodextrins by the end of 1995 will be about 12,000 in number. This vast number of publications deals with the chemistry (structure, chemical reactivity), biology (enzymology, metabolism, toxicity, direct therapeutic effects), inclusion complex forming capacity and its consequences, and industrial utilization of cyclodextrins (in drugs, foods, cosmetics, chromatography, catalysis biotechnology, diagnostics etc) in unlimited numbers of products and technologies.This volume pulls all this information together, covering the chemistry, biology and industrial application of cyclodextrins as molecular encapsulating agents in research methods, analytical procedures, industrial technologies and products.

  • Comprehensive Supramolecular Chemistry, Volume 5

    Supramolecular Reactivity and Transport: Bioinorganic Systems
    • 1st Edition
    • K.S. Suslick
    • English
    In this volume, an overview of the expanse of bioinorganic systems that involve supramolecular chemistry has been assembled. It commences with introductions to the supramolecular aspects of bioinorganic synthetic analogues and of metalloprotein structure and function. From there, a range of topics involving diverse metallobiomolecules (proteins, nucleic acids, and their synthetic analogues) are developed.

  • Comprehensive Supramolecular Chemistry, Volume 6

    Solid-State Supramolecular Chemistry: Crystal Engineering
    • 1st Edition
    • D.D. MacNicol + 2 more
    • English
    This volume, containing 27 chapters, provides a state-of-the-art account of the chemistry of solid-state supramolecular systems. Following a valuable introductory chapter reviewing important general principles, the coherent coverage is structured in the form of a series ofcontributions all written by experts in the respective areas comprehensively described. Throughout the volume, emphasis is placed not only on the design and structure of new hostsystems but also on practical applications of these novel materials in real chemical situations. The crystal engineering methods described relate to the synthesis of both organic and inorganictailor-made hosts. Also the reader is presented with highly relevant descriptions ofthermodynamic and kinetic considerations germane to the formation crystalline inclusioncompounds. The final chapter gives a fascinating account of the self-organisation of moleculesin two and three dimensions, crucially important to any process of crystal nucleation.

  • Thermal Decomposition of Ionic Solids

    Chemical Properties and Reactivities of Ionic Crystalline Phases
    • 1st Edition
    • Volume 86
    • A.K. Galwey + 1 more
    • English
    The principal objective of this book is to stimulate interest in research that will extend available theory towards a greater understanding of the steps involved in solid-state decompositions and the properties of solids that control reactivities. Much of the activity in this field has been directed towards increasing the range of reactants for which decomposition kinetic data is available, rather than extending insights into the fundamental chemistry of the reactions being studied. The first part of the book (Chapters 1-6) is concerned with theoretical aspects of the subject. The second part (Chapters 7-17) surveys groups of reactions classified by similarities of chemical composition. The final Chapter (18) reviews the subject by unifying features identified as significant and proposes possible directions for future progress.Studies of thermal reactions of ionic compounds have contributed considerably to the theory of solid-state chemistry. Furthermore, many of these rate processes have substantial technological importance, for example, in the manufacture of cement, the exploitation of ores and in the stability testing of drugs, explosives and oxidizing agents. Despite the prolonged and continuing research effort concerned with these reactions, there is no recent overall review. This book is intended to contribute towards correcting this omission. The essential unity of the subject is recognized by the systematic treatment of reactions, carefully selected to be instructive and representative of the subject as a whole. The authors have contributed more than 200 original research articles to the literature, many during their 25 years of collaboration.Featur... of this book:• Gives a comprehensive in-depth survey of a rarely-reviewed subject.• Reviews methods used in studies of thermal decompositions of solids.• Discusses patterns of subject development perceived from an extensive literature survey.This book is expected to be of greatest value and interest to scientists concerned with the chemical properties and reactions of solids, including chemists, physicists, pharmacists, material scientists, crystallographers, metallurgists and others. This wide coverage of the literature dealing with thermal reactions of solids will be of value to both academic and industrial researchers by reviewing the current status of the theory of the subject. It could also provide a useful starting point for the exploitation of crystalline materials in practical and industrial applications. The contents will also be relevant to a wide variety of researchers, including, for example, those concerned with the stabilities of polymers and composite materials, the processing of minerals, the shelf-lives of pharmaceuticals, etc.

  • Advances in Asymmetric Synthesis

    • 1st Edition
    • Volume 3
    • Alfred Hassner
    • English
    Enantioselective synthetic methods are not only in the forefront of chemical and pharmaceutical research but activity in this area is constantly increasing. It is stimulated by the urgency to obtain drugs or compounds of medicinal interest as single anantiomers, and the keeness to synthesize natural products in nonracemic form. This volume presents seven chapters from pioneers and authorities in this rapidly expanding field.

  • Thermodynamics of Atmospheres and Oceans

    • 1st Edition
    • Volume 65
    • Judith A. Curry + 1 more
    • English
    Atmospheric and climatological studies are becoming more and more important in day-to-day living. Winds and ocean current owe their existence to the thermodynamic imbalances that arise from the differential heating of the Earth and air by the sun. Accounting for heat exchanges with the atmosphere and ocean is essential in any predictive model of the ocean and/or atmosphere. Thermodynamic feedback processes in the atmosphere and ocean are critical to understanding the overall stability of the Earth's climate and climate change. Water and its phase changes make the thermodynamics of the atmosphere and ocean uniquely interesting and challenging.Written by leading scientists in the field, Thermodynamics of Atmospheres and Oceans incorporates all the relevant information from the varying fields of dynamics meteorology, atmospheric physics and cloud physics, into a comprehensive, self-contained guide ideal for students and researchers of atmospheric thermodynamics. At the moment, courses in atmospheric thermdynamics typically have to use one or two chapters in textbooks on dynamic meteorology, atmospheric physics or cloud physics. This book combines these topics in one text.

  • Handbook of Chemometrics and Qualimetrics

    • 1st Edition
    • Volume AB
    • English

  • Handbook of Chemometrics and Qualimetrics

    Part B
    • 1st Edition
    • Volume 20B
    • English

  • Analytical Pyrolysis of Natural Organic Polymers

    • 1st Edition
    • Volume 20
    • S.C. Moldoveanu
    • English
    Analytical pyrolysis is one of the many tools utilized for the study of natural organic polymers. This books describes in three parts the methodology of analytical pyrolysis, the results of pyrolysis for a variety of biopolymers, and several practical applications of analytical pyrolysis on natural organic polymers and their composite materials. Analytical pyrolysis methodology covers two distinct subjects, the instrumentation used for pyrolysis and the analytical methods that are applied for the analysis of the pyrolysis products. A variety of pyrolytic techniques and of analytical instruments commonly coupled with pyrolysis devices are given.The description of the results of pyrolysis for biopolymers and some chemically modified natural organic polymers is the core of the book. The main pyrolysis products of numerous compounds as well as the proposed mechanisms for their pyrolysis are described. In this part an attempt is made to present as much as possible the chemistry of the pyrolytic process of natural organic polymers.The applications of analytical pyrolysis include topics such as polymer detection used for example in forensic science, structure elucidation of specific polymers, and identification of small molecules present in polymers (anti-oxidants, plasticizers, etc.). Also, the degradation during heating is a subject of major interest in many practical applications regarding the physical properties of polymers. The applications to composite polymeric materials are in the fields of classification of microorganisms, study of a variety of biological samples, study of fossil materials, etc. Analytical pyrolysis can also be used for obtaining information on the burning area generate pyrolysates that have complex compositions. Their analysis is important in connection with health issues, environmental problems, and taste of food and cigarettes.Features of this book:• Presents analytical pyrolysis as a uniform subject and not as a conglomerate of scientific papers.• Puts together in an organized manner a large volume of available information in this specific field.• Provides original results which address subjects with relatively scarce information in literature.• Gives original views on subjects such as the parallel between the pyrolytic process and the ion fragmentation in mass spectrometry.• Includes the role of pyrolysis in the burning process.The three parts of the book are covered in 18 chapters, each divided into sections. Some sections are further divided by particular subjects. References are given for each chapter, and an effort has been made to include as much as possible from the available representative information. A few unpublished personal results are also included.

  • Designer Drugs Directory

    • 1st Edition
    • K. Valter + 1 more
    • J-C. Landry
    • English
    This book is intended to serve as quick reference handbook on so-called designer drugs. These new, mainly synthetic compounds are also often referred to as analogues of controlled substances. This new work provides a unique directory of 104 designer drugs. This class of drugs is rapidly growing in variety and number of compounds. Although identification, toxicology and other properties have been thoroughly investigated, their analogues and derivatives remain poorly documented. This book fills the gap.Data which is available is often contradictory and confused. This directory provides a critical treatment of the subject which is thoroughly indexed including both the subject index and an index listing more that 230 street names of the described designer drugs.Divided into two parts; the first section describes aspects of designer drug manufacture, new abuse trends, sources of information and terminology. The second, descriptive part, classifies the drugs into ten main categories according to their chemical structure and prevalent pharmacological action. A separate chapter is devoted to each category, followed by a set of corresponding data sheets, street names and eventual synonyms, Toxicological data, short notes on the history of drugs as well as the most pertinent bibliographic references are included.

  • The Nature of Mathematics and the Mathematics of Nature

    • 1st Edition
    • S. Andersson + 1 more
    • English
    Chemistry, physics and biology are by their nature genuinely difficult. Mathematics, however, is man-made, and therefore not as complicated. Two ideas form the basis for this book: 1) to use ordinary mathematics to describe the simplicity in the structure of mathematics and 2) to develop new branches of mathematics to describe natural sciences.Mathematics can be described as the addition, subtraction or multiplication of planes. Using the exponential scale the authors show that the addition of planes gives the polyhedra, or any solid. The substraction of planes gives saddles. The multiplication of planes gives the general saddle equations and the multispirals. The equation of symmetry is derived, which contains the exponential scale with its functions for solids, the complex exponentials with the nodal surfaces, and the GD (Gauss Distribution) mathematics with finite periodicity.Piece by piece, the authors have found mathematical functions for the geometrical descriptions of chemical structures and the structure building operations. Using the mathematics for dilatation; twins, trillings, fourlings and sixlings are made, and using GD mathematics these are made periodic. This description of a structure is the nature of mathematics itself. Crystal structures and 3D mathematics are synonyms. Mathematics are used to describe rod packings, Olympic rings and defects in solids. Giant molecules such as cubosomes, the DNA double helix, and certain building blocks in protein structures are also described mathematically.

  • Electrochemistry at Metal and Semiconductor Electrodes

    • 1st Edition
    • Norio Sato
    • English
    Electrochemisty at Metal and Semiconductor Electrodes covers the structure of the electrical double layer and charge transfer reactions across the electrode/electrolyt... interface. The purpose of the book is to integrate modern electrochemistry and semiconductor physics, thereby, providing a quantitative basis for understanding electrochemistry at metal and semiconductor electrodes.Electrons and ions are the principal particles which play the main role in electrochemistry. This text, therefore, emphasizes the energy level concepts of electrons and ions rather than the phenomenological thermodynamic and kinetic concepts on which most of the classical electrochemistry texts are based. This rationalization of the phenomenological concepts in terms of the physics of semiconductors should enable readers to develop more atomistic and quantitative insights into processes that occur at electrodes.The book incorporates many traditional disciplines of science and engineering such as interfacial chemistry, biochemistry, enzyme chemistry, membrane chemistry, metallurgy, modification of solid interfaces, and materials' corrosion. The text is intended to serve as an introduction for the study of advanced electrochemistry at electrodes and is aimed towards graduates and senior undergraduates studying materials and interfacial chemistry or those beginning research work in the field of electrochemistry.

  • Solid-Supported Combinatorial and Parallel Synthesis of Small-Molecular-Weight Compound Libraries

    • 1st Edition
    • Volume 17
    • D. Obrecht + 1 more
    • English
    The words "Combinatorial Chemistry" have different meanings to different people, ranging from split and mix strategies to parallel synthesis using robots, and embracing the whole range of preparative chemistry from organic molecules, to catalyst ligands, and even inorganic solids. All of these activities have in common an attempt to expand the diversity of structure available to the chemist as well as the access to this diversity, permitting the discovery of new and valuable biological acid material properties. In this outstanding survey of combinatorial organic chemistry, the authors, Obrecht who has established a new combinatorial chemistry company called Polyphor, and Villalgardo have brought together the literature, including that from 1998, and have concisely analysed the applications and achievements of this new field. This work will be of value to all chemists engaged in preparative work, both in industry and academe.

  • Advances in Organometallic Chemistry

    • 1st Edition
    • Volume 43
    • English
    This book is an essential reference work for the academic and industrial chemists and will provide up-to-date material at the cutting edge of chemistry research.This widely-acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry.

  • Fluid Mechanics and Thermodynamics of Turbomachinery

    • 4th Edition
    • S. Larry Dixon
    • English
    Turbomachines are those in which energy is transferred to or from a continuously moving fluid by the motion of a rotating element. Some of the most common and important machines used in engineering and industry fall into this category, including those which absorb power (and thereby increase fluid pressure), such as fans, compressors and pumps. Also included are equally vital varieties of machines which generate power from the expansion of fluids to lower pressures such as hydraulic, steam and gas turbines. This general definition embraces a number of devices that are classified as 'open', such as propellers, windmills and unshrouded fans. The machines examined here are those defined as 'closed', where a finite quantity of fluid can be considered to pass through the machine in unit time, for it is these which are of the most interest to students and professionals in the fields of mechanical, chemical, and plant engineering. It is in these areas that the devices that form the subject matter of this book find their most important applications, making this treatment of vital importance to anyone working in or studying them.

  • Organic Synthesis: Theory and Applications

    • 1st Edition
    • Volume 4
    • T. Hudlicky
    • English
    This fourth volume in the series Organic Synthesis: Theory and Applications is composed of five chapters that span a wide range of disciplines. Alkaloid chemistry, total synthesis, synthetic methodology, carbohydrate technology, and spin-trapping agents are all covered by experts in these fields.The first chapter is one of the finest examples of deductive reasoning in the chemical literature, examining the rich history of the chemistry of morphine. Within the following chapters, synthetic challenges of the marine terpenoids are brought into focus, the chemistry and synthetic applications of cyclobutenediones are reviewed and the utility of glycosyl iodides in the preparation of glycosides are summarized. Finally a report on a new class of spin-traping agents, azulenyl nitrones is covered. In all, five diverse subdisciplines are brought together and reviewed in this volume.

  • Advances in Metal and Semiconductor Clusters

    Cluster Materials
    • 1st Edition
    • Volume 4
    • M.A. Duncan
    • English
    Cluster Materials is the fourth volume of the highly successful series Advances in Metal and Semiconductor Clusters. In this volume the focus is on the properties of clusters which determine their potential applications as new materials. Metal and semiconductor clusters have been proposed as precursors for materials or as actual materials since the earliest days of cluster research. In the last few years, a variety of techniques have made it possible to produce clusters in sizes varying from a few atoms up to several thousand atoms. While some measurements are performed in the gas phase on non-isolated clusters, many cluster materials can now be isolated in macroscopic quantities and more convenient studies of their properties become possible. In this volume the authors focus on measurement of optical, electronic, magnetic, chemical and mechanical properties of clusters or of cluster assemblies. All of these properties must fall into acceptable ranges of behaviour before useful materials composed of clusters can be put into practical applications. As evidenced by the various work described here, the realisation of practical products based on cluster materials seems to be approaching rapidly.

  • Advances in Carbene Chemistry, Volume 2

    • 1st Edition
    • U.H. Brinker
    • English
    Beginning as chemical curiosities, carbenes are now solidly established as reactive intermediates with fascinating and productive research areas of their own. Five decades of divalent carbon chemistry have provided us with a vast repertoire of new, unusual and surprising reactions. Some of those reactions, once classified as exotic, have become standard methods in organic synthesis. These highly reactive carbene species have been harnessed and put to work to achieve difficult synthetic tasks that other reactive intermediates cannot easily perform. The fruitful relationship between experiment and theory has pushed carbene chemistry further toward the direction of reaction control; that is, regio- and stereoselectivity in intra- and intermolecular addition and insertion reactions. The interplay between experiment and modern spectroscopy has led to the characterisation of many carbenes that are crucial to both an understanding and a further development of this field. Understanding of carbene chemistry has advanced dramatically, especially in the last decade, and new developments continue to emerge. Some of the recent exciting findings have been collected in the first volume of Advances in Carbene Chemistry. With this second volume, the series will continue to provide a periodic coverage of carbene chemistry in its broadest sense - leading into the next century.

  • Advances in Gas Phase Ion Chemistry

    • 1st Edition
    • Volume 3
    • N.G. Adams + 1 more
    • English
    Gas-phase ion chemistry is a broad field which has many applications and which encompasses various branches of chemistry and physics. An application that draws together many of these branches is the synthesis of molecules in interstellar clouds. This was part of the motivation for studies on the neutralization of ions by electrons and on isomerization in ion-neutral associations. The results of investigations of particular aspects of ion dynamics are presented in this volume. Solvation in ion-molecule reactions is discussed and extended to include multiply charged ions by the application of electrospray techniques. This volume also provides a wealth of information on reaction thermodynamics which is critical in determining reaction spontaneity and availability of reaction channels. More focused studies are also presented towards the end of this volume, relating to the ionization process and its nature.

  • Alternative Careers in Science

    Leaving the Ivory Tower
    • 1st Edition
    • Cynthia Robbins-Roth
    • English
    Alternative Careers in Science describes the various career tracks available to scientists and gives the inside scoop on the skills and personality types suited to each profession. It also contains important information regarding career expectations and salary potential.This book will allow scientists to compare career opportunities. Each chapter covers a different career track and includes the basic job description, qualifications, responsibilities, and what career opportunities stem from each position.

  • Theoretical and Mathematical Models in Polymer Research

    Modern Methods in Polymer Research and Technology
    • 1st Edition
    • Volume 5
    • Alexander Grosberg
    • English
    In this book, Professor Alexander Grosberg, one of the pioneers and leaders in the field of theoretical polymer science has selected the most important topics within polymer science and matched them with experts whocan clearly present the state of the art of each.Using this book readers will learn the fundamental concepts, as well as the techniques that are currently employed on the frontier of science.

  • Theoretical Organic Chemistry

    • 1st Edition
    • Volume 5
    • C. Párkányi
    • English
    This volume is devoted to the various aspects of theoretical organic chemistry. In the nineteenth century, organic chemistry was primarily an experimental, empirical science. Throughout the twentieth century, the emphasis has been continually shifting to a more theoretical approach. Today, theoretical organic chemistry is a distinct area of research, with strong links to theoretical physical chemistry, quantum chemistry, computational chemistry, and physical organic chemistry.The objective in this volume has been to provide a cross-section of a number of interesting topics in theoretical organic chemistry, starting with a detailed account of the historical development of this discipline and including topics devoted to quantum chemistry, physical properties of organic compounds, their reactivity, their biological activity, and their excited-state properties.

  • Advanced Problems in Organic Reaction Mechanisms

    • 1st Edition
    • Volume 16
    • English
    The Elsevier Tetrahedron Organic Chemistry Series is a topical series of monographs by world-renowned scientists in several fields of organic chemistry. The Tetrahedron Organic Chemistry Series has been very successful in providing some of the very best scholarly works in these topical areas that have proven to be of lasting quality as indispensable reference sources. These books have provided the practicing researcher, student and scholar with an invaluable source of comprehensive reviews in organic chemistry, predominantly in the areas of synthesis and structure determination, including:* Reagents* Reaction mechanisms* Molecular Diversity* Asymmetric Synthesis* Multi-dimensional nmr* Enzymatic Synthesis* Organometallic Chemistry* Biologically Important Molecules

  • Advances in Amino Acid Mimetics and Peptidomimetics

    • 1st Edition
    • Volume 1
    • A. Abell
    • English
    Peptidomimetics are compounds which mimic the biological activity of peptides while offering the advantages of increased bioavailability, biostability, bioefficiency, and bioselectivity against the natural biological target of the parent peptide. Examples of peptidomimetics have been isolated as natural products, synthesized as libraries from novel subunits, and designed on the basis of X-ray crystallographic studies and through an intricate knowledge of the biological mode of action of natural peptides. They offer challenging synthetic targets and are increasingly important medicinal agents and biological probes. As a consequence, peptidomimetics embrace much of what is modern medicinal and organic chemistry. This volume highlights some recent and exciting developments in the area.

  • Advances in Heterocyclic Chemistry

    • 1st Edition
    • Volume 69
    • English
    This volume includes the third, and final, part of a trilogy on acyclonucleosides by E.S.H. El Ashry and Y. El Kilany which began in Volume 67. This chapter covers tri-, tetra-, and penta- seco-nucleosides. These compounds are of considerable interest due to their relationship to newer anti AIDS drugs. Other chapters deal with the use of organohypervalent iodine reagents in the synthesis of organic compounds, a review of the conformational analysis of saturated 6-membered oxygen containing rings, comprising the oxanes, the various dioxanes, trioxanes, and tetroxanes, and heteropentalenes with fused imidazoles of 1,2,4-triazole rings.

  • Structure and Chemistry (Part E)

    • 1st Edition
    • Volume 19
    • Atta-ur Rahman
    • English

  • Advances in Supramolecular Chemistry

    • 1st Edition
    • Volume 4
    • G.W. Gokel
    • English
    Part of a series which presents reports of efforts in all areas of supramolecular science, this volume discusses a variety of topics in the field.

  • Annual Reports in Organic Synthesis 1997

    • 1st Edition
    • English
    This handy inexpensive reference tool is an organized annual review of synthetically useful information. It abstracts synthetic reactions from the major chemistry journals of the past year and includes reactions and methods that are new and reasonably general. The reactions are presented in a convenient pictorial format designed for rapid visual retrieval of information. A comprehensive table of contents and a senior author index are included.The Journal of the American Chemical Society has aptly described this publication as an "aid to the harassed organic chemist who cannot keep up with the never-diminishing stream of new primary literature" and hails it "an outstandingly good buy."

  • Progress in Heterocyclic Chemistry

    A Critical Review of the 1996 Literature Preceded by Two Chapters on Current Heterocyclic Topics
    • 1st Edition
    • Volume 9
    • Thomas L. Gilchrist + 1 more
    • English
    Progress in Heterocyclic Chemistry (PHC) is an annual review series commissioned by the International Society of Heterocyclic Chemistry (ISHC). The volumes in the series contain both highlights of the previous year's literature on heterocyclic chemistry and articles on new developing topics of interest to heterocyclic chemists.The highlight chapters in Volume 9 are all written by leading researchers in their field and these chapters constitute a systematic survey of the important original material reported in the literature on heterocyclic chemistry in 1996. Additional articles in this volume also review "The Synthesis of Oxazoles from Diazocarbonyl Compounds" and "The Heterocyclic Chemistry Associated with the Herbicide Glyphosate".As with previous volumes in the series, Volume 9 will enable academic and industrial chemists, and advanced students to keep abreast of developments in heterocyclic chemistry in an effortless way.

  • Advances in Asymmetric Synthesis

    • 1st Edition
    • Volume 2
    • Bozzano G Luisa
    • English

  • Biotechnological Innovations in Chemical Synthesis

    • 1st Edition
    • BIOTOL + 2 more
    • English
    Demonstrates how biological catalysis can be applied to the production of value added chemicals. Use is made of a diverse range of case studies to give a breadth of experience. It also reveals how bio-systems are being employed to produce a wide range of valuable commodities including antibiotics and other therapeutics, intermediary metabolites such as citrate, malate, gels and other valuable polymers.

  • Advances in Heterocyclic Chemistry

    • 1st Edition
    • Volume 68
    • English
    The first chapter in this volume, by E.S.H. El-Ashry, represents the second part of a trilogy on nucleosides he began in Volume 67. This chapter deals with diseco-nucleosides, or analogs of nucleosides in which thereare two bond disconnections. Other chapters deal with the importance of cyclic sulfates as intermediates in organic synthesis, methlypyridines and other methylazines as precursors to biand polyheterocycles, and the variety of heterocycles in nucleoside analogs in heteromonocyclic bases.

  • Advances in Cycloaddition

    • 1st Edition
    • Volume 4
    • Michael Harmata
    • English
    This is the fourth volume in the series, aimed at those wishing to stay abreast of developments in the mechanisms and synthetic applications of 1,3-dipolar cycloaddition reactions.

  • Handbook of Palladium-Catalysed Organic Reactions

    • 1st Edition
    • J. C. Fiaud + 2 more
    • English
    This comprehensive handbook will be an indispensable research tool for chemists. Handbook of Palladium Catalysed Organic Reactions provides a synoptic description of the main types of reactions which are catalyzed by Palladium and the mechanism which causes these reactions. Each reaction is presented in graphical form and classified according to the type of transformation involved.Other books covering the use of Palladium complexes as catalysts have been written, but the Handbook is the only to offer a synoptic view, showing the catalytic cycle of each reaction. This complete coverage provides the reader with a good understanding of the parameters involved. The tables included can be viewed from the point of view of the reagents, the product of the reaction, or the mechanism involved. The Handbook is a companion to the Database of Palladium Chemistry: Reactions andCatalytic Cycles, published on CD-ROM.

  • Organic Chemistry

    A Comprehensive Degree Text and Source Book
    • 1st Edition
    • H Beyer + 2 more
    • English
    This book deals with purification methods, chemical bonding theory and spectroscopic methods and is a reference book for chemists at any stage of their career. Rich in practical applications and historic vignettes, its lavish provision of knowledge reflects the authors' deliberate strategy to place chemistry in the widest perspective, providing a sound understanding of this complex and important branch of science.

  • Advances in Molecular Similarity

    • 1st Edition
    • Volume 1
    • R. Carbo-Dorca + 1 more
    • English
    The aim of this text is to provide reviews and monographs on topics involving molecular similarity, ranging from the fundamental physical properties underlying molecular behaviour to applications in industrially important fields such as pharmaceutical drug design and molecular engineering. The editors hope that this series will encourage new ideas and approaches, help to systematize the rapidly accumulating new chemical information, and make chemistry better understood and better applied.

  • Advances in Dendritic Macromolecules

    • 1st Edition
    • Volume 3
    • G.R. Newkome
    • English
    The series Advances in Dendritic Macromolecules aims to cover the synthesis and supramolecular chemistry of dendritic or cascade super-molecules as well as their less perfect hyperbranched cousins.In Volume 3, Chapter 1 describes the synthesis and characterization of dendrimers and hyperbranched polyesters, both based on 2,2-bis(hydroxymethy... acid, as the AB2-monomer. Chapter 2, discusses the advantages and drawbacks of dendritic molecular architectures necessary to create polymeric organic magnetic materials. In Chapter 3, Balzani and colleagues delineate their contributions to the field of polynuclear transition metal complexes in the design and construction of dendritic nanostructures; these luminesence and redox-active complexes suggest their role as photochemical molecular devices operating by photoinduced energy and electron transfer processes. Chapter 4, reviews the overall progress on redox-active dendrimers, especially as redox catalysts, organic conductors, modified electrodes, and models for electron transfer proteins. Chapter 5, summarizes the pioneering research in organometallic dendritic macromolecules and then delineates the redox properties of a series of silicon-based ferrocenyl-containin... dendrimers.

  • Alkaloids: Chemical and Biological Perspectives

    • 1st Edition
    • Volume 11
    • S.W. Pelletier
    • English
    Volume 11 of this series presents five timely reviews on current research on alkaloids. Chapter 1 by Paul L. Schiff, Jr. is a monumental survey of research that has been carried out over the past decade on the Thalictrum alkaloids. Forty-six new alkaloids are described from fifteen species of the genus Thalictrum, as well as 116 alkaloids of known structure from thirty-six species and subspecies of the genus. The chapter includes discussions of isolation and structure elucidation, analysis, biosynthesis, cell culture, and pharmacology. Also featured are inclusive compilations of botanical sources, alkaloids by alkaloid types, and calculated molecular weights of the Thalictrum alkaloids.Chapter 2 by Giovanni Appendino provides a fascinating treatment of Taxine, a collective name referring to a mixture of diterpenoid alkaloids from the yew tree (genus: Taxus). Taxine is responsible for the toxic properties of the yew tree that has been documented in historical and fictional literature, from Julius Caesar to Shakespeare, and from Agatha Christie to T.S. Eliot. The chapter treats the history, isolation techniques, structure elucidation, chemistry, and pharmacology of Taxine.Chapter 3 by Mary D. Menachery surveys the alkaloids of South American Menispermaceae (moonseed family). Many different structural types are included in this family. The alkaloid-bearing plants are woody-vines, shrubs, or small trees. Several of these species possess potent curare activity. The chemistry as well as pharmacology of these alkaloids is summarized.Chapter 4 by Russell J. Molyneux, Robert J. Nash, and Naoki Asano treats the chemistry and biological activity of the calystegines and related nortropane alkaloids. These polyhydroxylated bicyclic alkaloids represent another class of compounds that inhibit glycosidases, producing profound effects in biological systems by disrupting the essential cellular function of glycoprotein processing.Chapter 5, a related chapter by Robert J. Nash, Naoki Asano, and Alison A. Watson, reviews polyhydroxylated alkaloids that inhibit glycosidases. Topics covered include distribution, ecological significance and toxicity, isolation, synthesis, and biosynthesis.

  • NMR Spectroscopy and its Application to Biomedical Research

    • 1st Edition
    • S.K. Sarkar
    • English
    NMR has become the most diverse spectroscopic tool available to date in biomedical research. It is now routinely used to study biomolecular structure and dynamics particularly as a result of recent developments of a cascade of highly sophisticated multidimensional NMR pulse sequences, and of advances in genetic engineering to produce biomolecules, uniformly or selectively enriched with 13C, 15N and 2H.Features of this book:• Provides an up-to-date treatment of NMR techniques and their application to problems of biomedical interest• Most refined multidimensional pulse sequences including the basic aspects are covered by leading NMR spectroscopists.The book will be useful to NMR spectroscopists, biochemists, and to molecular biologists interested in the use of NMR techniques for solving biological problems.

  • Molecular Electrostatic Potentials

    Concepts and Applications
    • 1st Edition
    • Volume 3
    • J.S. Murray + 1 more
    • English
    Over the past 25 years, the molecular electrostatic potential has become firmly established as an effective guide to molecular interactions. With the recent advances in computational technology, it is currently being applied to a variety of important chemical and biological systems. Its range of applicability has expanded from primarily a focus on sites for electrophilic and nucleophilic attack to now include solvent effects, studies of zeolite, molecular cluster and crystal behavior, and the correlation and prediction of a wide range of macroscopic properties. Moreover, the increasing prominence of density functional theory has raised the molecular electrostatic potential to a new stature on a more fundamental conceptual level. It is rigorously defined in terms of the electron density, and has very interesting topological characteristics since it explicitly reflects opposing contributions from the nuclei and the electrons.This volume opens with a survey chapter by one of the original pioneers of the use of the electrostatic potential in studies of chemical reactivity, Jacopo Tomasi. Though the flow of the succeeding chapters is not stringently defined, the overall trend is that the emphasis changes gradually from methodology to applications. Chapters discussing more theoretical topics are placed near the end. Readers will find the wide variety of topics provided by an international group of authors both convincing and useful.

  • Principles of Asymmetric Synthesis

    • 1st Edition
    • Volume 14
    • R.E. Gawley + 1 more
    • English
    The world is chiral. Most of the molecules in it are chiral, and asymmetric synthesis is an important means by which enantiopure chiral molecules may be obtained for study and sale. Using examples from the literature of asymmetric synthesis (more than 1300 references), the aim of this book is to present a detailed analysis of the factors that govern stereoselectivity in organic reactions. It is important to note that the references were each individually checked by the authors to verify relevance to the topics under discussion. The study of stereoselectivity has evolved from issues of diastereoselectivity... through auxiliary-based methods for the synthesis of enantiomerically pure compounds (diastereoselectivit... followed by separation and auxiliary cleavage), to asymmetric catalysis. In the latter instance, enantiomers (not diastereomers) are the products, and highly selective reactions and modern purification techniques allow preparation - in a single step - of chiral substances in 99% ee for many reaction types. After an explanation of the basic physical-organic principles of stereoselectivity, the authors provide a detailed, annotated glossary of stereochemical terms. A chapter on "Analytical Methods" provides a critical overview of the most common methods for analysis of stereoisomers. The authors then follow the 'tried-and-true' format of grouping the material by reaction type. Thus, there are four chapters on carbon-carbon bond forming reactions (enolate alkylations, organometal additions to carbonyls, aldol and Michael reactions, and cycloadditions and rearrangements), one chapter on reductions and hydroborations (carbon-hydrogen bond forming reactions), and one on oxidations (carbon-oxygen and carbon-nitrogen bond forming reactions). Leading references are provided to natural product synthesis that have been accomplished using a given reaction as a key step. In addition to tables of examples that show high selectivity, a transition state analysis is presented to explain - to the current level of understanding - the stereoselectivity of each reaction. In one case (Cram's rule) the evolution of the current theory is detailed from its first tentative (1952) postulate to the current Felkin-Anh-Heathcock formalism. For other reactions, only the currently accepted rationale is presented. Examination of these rationales also exposes the weaknesses of current theories, in that they cannot always explain the experimental observations. These shortcomings provide a challenge for future mechanistic investigations.

  • Hypervalent Iodine in Organic Synthesis

    • 1st Edition
    • A. Varvoglis
    • English
    This book describes the fascinating chemistry of the many kinds of organic compounds of hypervalent iodine. Each chapter deals with a particular iodine compound or families of compounds which have been used as reagents in a plethora of useful transformations. These include assorted oxidation, such as with the precious Dess-Martin reagent as well as with a wide range of further reactions. Prominent features of hypervalent iodine reagents derived from iodobenzene are: ready availability, operational simplicity, mild reaction conditions, and high efficiency. They are environmentally safe and can be recycled. New species may be easily prepared by introducing substituents in the benzene ring or changing the ligand attached to iodine. Their combination with other reagents broadens considerably their synthetic potential. Today, no synthetic chemist can afford to ignore the valuable hypervalentiodine reagents.

  • Polymer Synthesis

    Volume 3
    • 2nd Edition
    • Stanley R. Sandler + 1 more
    • English
    This volume, which completes the Second Edition of this widely respected three-volume set, continues the tradition of providing detailed and concise laboratory instructions for the preparation of organic and inorganic polymers. Updates are provided on the preparation of various types of polymers including olefin-sulfur dioxide copolymers, polythioesters, sulfide polymers, polyisocyanates, polyoxyalkylhydroxy compounds, polyvinyl carbazole, polyvinyl acetate, polyallyl esters, and polyvinyl flouride. The procedures were chosen on the basis of safety and to be representative of preparation methods for a general class of polymers. Fundamental and practical information on polymer synthesis is combined with extensive references and reviews of the patent literature.

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