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Books in Chemistry

Chemistry topic areas include: physical and theoretical, computational, organic, organometallic and inorganic, pharmaceutical and medicinal, analytical and bioanalytical, nuclear, general, nanochemistry, geochemistry, materials and polymer, as well as environmental, green and sustainable chemistry.

  • Guide-Lines to Planning Atomic Spectrometric Analysis

    • 1st Edition
    • Volume 4
    • B. Magyar
    • English
    Studies in Analytical Chemistry, Volume 4: Guide-Lines to Planning Atomic Spectrometric Analysis covers the physico-chemical background of atomic absorption spectrometry (AAS) and atomic emission spectrometry (AES). This book is composed of six chapters and begins with an introduction to the criteria on choosing the best and most suitable method for solving a given analytical problem. The next chapters deal with the properties, generation, and absorption of electromagnetic radiation, as well as the theory of atomic spectra that require knowledge of X-ray. Other chapters discuss the broadening of atomic lines, which is important for understanding that calibration curves in AAS are always bent. A chapter examines the sensitivity of determination by AAS and AES. The last chapter describes the spectrometric measurement of atomic absorption and emission. This chapter also looks into the influence of the design of the monochromator upon the measured emission intensity and calibration curve by AAS. This book will prove useful to analytical chemists and researchers.
  • Base-Catalyzed Reactions of Hydrocarbons and Related Compounds

    • 1st Edition
    • Herman Pines
    • English
    Base-Catalyzed Reactions of Hydrocarbons and Related Compounds focuses on the use of bases as catalysts for the conversion of hydrocarbons and related compounds. In order to emphasize the broad scope of base-catalyzed reactions, examples dealing with the conversion of non-hydrocarbons are given. Comprised of 14 chapters, this book begins with a historical overview of base-catalyzed conversions of hydrocarbons, followed by a discussion on the isomerization of olefins, acetylenes, and allenes, as well as the dimerization and oligomerization of hydrocarbons. The reader is then introduced to a variety of reactions, including those between aromatic hydrocarbons and olefins and between alkylpyridines and alkenylpyridines; homogeneous carbon-carbon addition reactions; and reactions of aprotic solvents with olefins. Subsequent chapters explore carbon-carbon addition of olefins with miscellaneous compounds; addition of ammonia, amines, and anilines to olefinic hydrocarbons; hydrogenation and oxygenation; dehydrogenation, aromatization, and hydrogen transfer; and dehydration of alcohols. This monograph will be of interest to chemists.
  • Chemical Bonds - Better Ways to Make Them and Break Them

    • 1st Edition
    • Bozzano G Luisa
    • English
    Stereochemistry of Organometallic and Inorganic Compounds, Volume 3: Chemical Bonds—Better Ways to Make Them and Break Them focuses on the processes, methodologies, reactions, and approaches involved in the making and breaking of bonds. The selection first tackles heterometallic clusters in catalysis and steric and electronic effects on the photochemical reactions of metal-metal bonded carbonyls. Discussions focus on heterodinuclear metal carbonyls, hybrid catalysts prepared from molecular mixed-metal clusters, and heterometallic clusters in homogeneous catalysis. The book then examines the stereochemical aspects of organometallic clusters, including reactivity, dynamics, and the structures and rationalization of bonding in alkyne-substituted clusters. The publication takes a look at the stereochemistry of the Sakurai reaction, as well as intermolecular and intramolecular reactions, optically active allylsilanes, and other reactions. The selection is a highly recommended source of data for chemists and readers interested in the making and breaking of chemical bonds.
  • Molecular crystals and Molecules

    • 1st Edition
    • A Kitaigorodsky
    • English
    Molecular Crystals and Molecules deals with some of the problems of molecular crystallography and certain aspects of molecular structure. This book is composed of eight chapters that specifically cover the significant progress of conformational research. The opening chapter describes the structure of crystals considering the close-packing principle, disorder elements, and binary systems. The next two chapters examine the calculation of crystal lattice energy and dynamics. These topics are followed by discussions on the molecular movement, structural, and thermodynamic aspects of crystals. The final chapters look into the parameters for conformational calculations of molecules, macromolecules, and biopolymers. This book will be of great value to physical chemists and researchers who are interested in crystal and molecular structure.
  • Catalysis in Micellar and Macromoleular Systems

    • 1st Edition
    • Janos Fendler
    • English
    Catalysis in Micellar and Macromolecular Systems provides a comprehensive monograph on the catalyses elicited by aqueous and nonaqueous micelles, synthetic and naturally occurring polymers, and phase-transfer catalysts. It delineates the principles involved in designing appropriate catalytic systems throughout. Additionally, an attempt has been made to tabulate the available data exhaustively. The book discusses the preparation and purification of surfactants; the physical and chemical properties of surfactants and micelles; solubilization in aqueous micellar systems; and the principles of micellar catalysis. Separate chapters cover micellar catalysis of hydrolyses, solvolyses, aminolyses, and miscellaneous ionic reactions; micellar effects on organic equilibria and nucleophilic substitution reactions, and on hydrophobic interactions and protein structure; and radical and excited state reactions in micellar systems. The final chapters deal with interactions in and catalysis by micelles in nonaqueous solvents and in liquid crystalline phases; and catalysis in macromolecular and related systems. This book is aimed at the industrial and academic researcher regardless of his arbitrarily defined subfield, be it organic, inorganic, biological, colloid, etc. The treatment provides guidance and stimulus to bioorganic, inorganic, pharmaceutical, colloid, physical, and polymer chemists as well as to those who seek novel and unique catalysts in industrial processes. It can also serve as the basis of a graduate course.
  • Spectroscopy in Inorganic Chemistry V2

    • 1st Edition
    • C.N.R. Rao
    • English
    Spectroscopy in Inorganic Chemistry, Volume II is a collection of research studies on some of the spectroscopic methods and areas of inorganic chemistry in which spectroscopy has been used effectively. This book is divided into seven chapters that present the status reports and potentialities in the fields of study. Each chapter outlines the theoretical and experimental aspects, as well as the application to a specific field of the analytical method. The first three chapters deal with the molecular structure determination by neutron and X-ray diffraction, high-pressure vibrational spectroscopy, and electronic Raman transitions of rare earth ions. Other chapters explore the potential of electron spin resonance spectroscopy for inorganic radical and radical ion determination, as well as the application of electron spin resonance for coordination compound analysis. The remaining chapters examine the use of electronic spectroscopy for organometalloid study and the fluorescence and laser action in rare earth chelates. This book is intended primarily for analytical and inorganic chemists and spectroscopists who are interested in inorganic systems.
  • Modern Experimental Chemistry

    • 1st Edition
    • George W. Jr. Latimer
    • English
    Modern Experimental Chemistry provides techniques of qualitative analysis that reinforce experiments on ionic equilibriums. This book includes the determination of water in hydrated salts; identification of an organic compound after determining its molecular weight; and nonaqueous titration of a salt of a weak acid. The calculation of chemical stoichiometry; calculation of thermodynamic properties by determining the change in equilibrium with temperature; and chromium chemistry are also covered. This compilation contains enough experiments for classes which have six hours of laboratory (two 3-hour meetings) per week to last two semesters. This publication is intended for chemistry students as an introductory manual to chemistry laboratory.
  • Theoretical Chemistry Advances and Perspectives

    • 1st Edition
    • Henry Eyring
    • English
    Theoretical Chemistry: Advances and Perspectives, Volume 1 analyzes all aspects of theoretical chemistry. This volume describes the statistical techniques for studying the nonequilibrium behavior of physical systems, followed by a discussion on the theory of optical activity. The interactions of inert gas molecules at large separations and conformal theory of solutions are also reviewed. This book likewise covers the application of the Hartree-Fock approximation to solids. Other topics include the line of sight interaction model, calculation of long-range interaction coefficients, perturbation expansion, common M-fluid theories, and classical Madelung sums. This publication is intended for researchers and practitioners of disciplines related to theoretical chemistry.
  • Organotransition Metal Chemistry A Mechanistic Approach

    • 1st Edition
    • Richard Heck
    • English
    Organotransition Metal Chemistry: A Mechanistic Approach describes a mechanistic approach to the study of the chemistry of organotransition metals. Organotransition metals are discussed in relation to their reactions with specific functional groups or types of compounds rather than by metals. Topics covered include the formation of hydrogen and carbon bonds to transition metals; reactions of transition metal δ- and π-bonded derivatives; and addition and elimination reactions of olefinic compounds. This book is comprised of 10 chapters and begins with a historical overview of organotransition metal chemistry, together with the unique chemistry of transition metals and mechanisms of ligand replacements. The following chapters discuss the methods of preparation of hydrido complexes and carbon-transition metal bonds; homogeneous hydrogenation reactions; isomerization, dimerization, oligomerization, and polymerization of olefins; and reactions of dienes, trienes, and tetraenes with transition metal compounds. Transition metal reactions with acetylenes and carbon monoxide as well as organic carbonyl compounds are also examined. This monograph should be of value to organic chemists as well as students and researchers of organic chemistry.
  • Active Nitrogen

    • 1st Edition
    • A. Nelson Wright
    • English
    Active Nitrogen focuses on the experimental and theoretical investigations on active nitrogen. Divided into five chapters, the book starts by giving an introduction to the discovery of active nitrogen, the energy content, and the methods by which this may be produced. The succeeding part deals with light emissions from active nitrogen system. This discussion includes molecular spectrum of nitrogen, emission from atomic energy and condensed active nitrogen, emission from molecular species with electronic energy levels below and above 9.76 eV, and light-emitting systems of active nitrogen. The next part focuses on theories on active nitrogen. The theories discussed are long-lived Lewis-Rayleigh afterglow and short-lived, energetic afterglows. Numerical representations are provided to test the validity of the theories. Lastly, the discussions end with chemical reactions of active nitrogen. Topics contained in this part are text on recombination of N(4S) atoms; rate constants for reactions presumably induced by direct N(4S) attack; reactions caused by excited nitrogen molecular attack; and mechanism for reactions of active nitrogen that seem to influence direct N(4S) attack. The book is a valuable source of information for readers interested in the research on active nitrogen.