Spectroscopy in Inorganic Chemistry V2

1st Edition - December 2, 2012
Editor: C.N.R. Rao
Language: English
Paperback ISBN:
9 7 8 - 0 - 1 2 - 4 3 3 2 7 1 - 3
eBook ISBN:
9 7 8 - 0 - 3 2 3 - 1 5 5 7 9 - 3

Spectroscopy in Inorganic Chemistry, Volume II is a collection of research studies on some of the spectroscopic methods and areas of inorganic chemistry in which spectroscopy has… Read more

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Spectroscopy in Inorganic Chemistry, Volume II is a collection of research studies on some of the spectroscopic methods and areas of inorganic chemistry in which spectroscopy has been used effectively. This book is divided into seven chapters that present the status reports and potentialities in the fields of study. Each chapter outlines the theoretical and experimental aspects, as well as the application to a specific field of the analytical method. The first three chapters deal with the molecular structure determination by neutron and X-ray diffraction, high-pressure vibrational spectroscopy, and electronic Raman transitions of rare earth ions. Other chapters explore the potential of electron spin resonance spectroscopy for inorganic radical and radical ion determination, as well as the application of electron spin resonance for coordination compound analysis. The remaining chapters examine the use of electronic spectroscopy for organometalloid study and the fluorescence and laser action in rare earth chelates. This book is intended primarily for analytical and inorganic chemists and spectroscopists who are interested in inorganic systems.

List of Contributors

Preface

Contents of Volume I

Molecular Structure Determination by Neutron and X-Ray Diffraction

I. Some General Aspects of Diffraction

II. Structure Determination

III. Structure Refinement

IV. Neutron Diffraction

V. Applications

References

High-Pressure Vibrational Spectroscopy

I. Introduction

II. Available Instrumentation for Far Infrared-High-Pressure Studies

III. Applications

IV. Limitations of Technique

References

Electronic Raman Transitions of Rare Earth Ions and Crystal Field Effects

I. Introduction

II. The Vibrational and Electronic Raman Process

III. The Raman Scattering Tensor

IV. Raman Intensities and the Crystal Field

V. Experimental Methods

VI. Some Experimental Results

VII. Summary

References

Electron Spin Resonance Spectra of Inorganic Radicals and Radical Ions

I. Introduction

II. Energy Levels and Experimental Parameters

III. Theoretical Interpretation of Experimental Parameters

IV. Instrumentation

V. Preparation of Samples

VI. ESR Studies of Atoms and of Trapped Electrons

VII. Inorganic Radicals and Radical Ions

VIII. Organometallic Radicals and Radical Ions

IX. Other Applications and Future Developments

References

Electron Spin Resonance of Coordination Compounds

I. Introduction

II. Review of Coordination Bonding and Molecular Orbital Theory

III. Theoretical Interpretation of ESR Parameters in Terms of Molecular Orbital Coefficients

IV. Conclusion

References

Electronic Spectra of Organometalloids

I. Introduction

II. Simple Metalloids

III. Catenated Metalloids

IV. Heterocyclic Molecules

V. Metalloid Substitution on Common Chromophores

References

Fluorescence and Laser Action in Rare Earth Chelates

I. Introduction

II. Compounds

III. Mechanism of Energy Transfer

IV. Emission Spectrum

V. Intensity of Ion Fluorescence

VI. Fluorescence Decay and Lifetime

VII. Sensitization

VIII. Laser Action

References

Author Index

Subject Index

Life Sciences

Physical Sciences & Engineering

Social Sciences & Humanities

Health

Spectroscopy in Inorganic Chemistry V2

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