Spectroscopy in Inorganic Chemistry V2
- 1st Edition - January 28, 1971
- Imprint: Academic Press
- Editor: C.N.R. Rao
- Language: English
- Paperback ISBN:9 7 8 - 0 - 1 2 - 4 3 3 2 7 1 - 3
- eBook ISBN:9 7 8 - 0 - 3 2 3 - 1 5 5 7 9 - 3
Spectroscopy in Inorganic Chemistry, Volume II is a collection of research studies on some of the spectroscopic methods and areas of inorganic chemistry in which spectroscopy has… Read more
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Request a sales quoteSpectroscopy in Inorganic Chemistry, Volume II is a collection of research studies on some of the spectroscopic methods and areas of inorganic chemistry in which spectroscopy has been used effectively. This book is divided into seven chapters that present the status reports and potentialities in the fields of study. Each chapter outlines the theoretical and experimental aspects, as well as the application to a specific field of the analytical method. The first three chapters deal with the molecular structure determination by neutron and X-ray diffraction, high-pressure vibrational spectroscopy, and electronic Raman transitions of rare earth ions. Other chapters explore the potential of electron spin resonance spectroscopy for inorganic radical and radical ion determination, as well as the application of electron spin resonance for coordination compound analysis. The remaining chapters examine the use of electronic spectroscopy for organometalloid study and the fluorescence and laser action in rare earth chelates. This book is intended primarily for analytical and inorganic chemists and spectroscopists who are interested in inorganic systems.
List of Contributors
Preface
Contents of Volume I
Molecular Structure Determination by Neutron and X-Ray Diffraction
I. Some General Aspects of Diffraction
II. Structure Determination
III. Structure Refinement
IV. Neutron Diffraction
V. Applications
References
High-Pressure Vibrational Spectroscopy
I. Introduction
II. Available Instrumentation for Far Infrared-High-Pressure Studies
III. Applications
IV. Limitations of Technique
References
Electronic Raman Transitions of Rare Earth Ions and Crystal Field Effects
I. Introduction
II. The Vibrational and Electronic Raman Process
III. The Raman Scattering Tensor
IV. Raman Intensities and the Crystal Field
V. Experimental Methods
VI. Some Experimental Results
VII. Summary
References
Electron Spin Resonance Spectra of Inorganic Radicals and Radical Ions
I. Introduction
II. Energy Levels and Experimental Parameters
III. Theoretical Interpretation of Experimental Parameters
IV. Instrumentation
V. Preparation of Samples
VI. ESR Studies of Atoms and of Trapped Electrons
VII. Inorganic Radicals and Radical Ions
VIII. Organometallic Radicals and Radical Ions
IX. Other Applications and Future Developments
References
Electron Spin Resonance of Coordination Compounds
I. Introduction
II. Review of Coordination Bonding and Molecular Orbital Theory
III. Theoretical Interpretation of ESR Parameters in Terms of Molecular Orbital Coefficients
IV. Conclusion
References
Electronic Spectra of Organometalloids
I. Introduction
II. Simple Metalloids
III. Catenated Metalloids
IV. Heterocyclic Molecules
V. Metalloid Substitution on Common Chromophores
References
Fluorescence and Laser Action in Rare Earth Chelates
I. Introduction
II. Compounds
III. Mechanism of Energy Transfer
IV. Emission Spectrum
V. Intensity of Ion Fluorescence
VI. Fluorescence Decay and Lifetime
VII. Sensitization
VIII. Laser Action
References
Author Index
Subject Index
- Edition: 1
- Published: January 28, 1971
- No. of pages (eBook): 326
- Imprint: Academic Press
- Language: English
- Paperback ISBN: 9780124332713
- eBook ISBN: 9780323155793
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