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Books in Chemistry

Chemistry topic areas include: physical and theoretical, computational, organic, organometallic and inorganic, pharmaceutical and medicinal, analytical and bioanalytical, nuclear, general, nanochemistry, geochemistry, materials and polymer, as well as environmental, green and sustainable chemistry.

  • The Principles of Ion-Selective Electrodes and of Membrane Transport

    • 1st Edition
    • Volume 2
    • W.E. Morf
    • English
    The Principles of Ion Selective Electrodes and of Membrane Transport is a collection of research works on the theory, principles, and fundamentals of ion-selective electrodes and of membrane transport. This book is organized into two parts encompassing 15 chapters that highlight the application of the membrane model. Part A is a general discussion of membrane potentials and membrane transport. This part describes the formulations of the interfacial potential contribution due to phase boundaries. This part also explores the diffusion potential, the nonideality of diffusion layers or membrane phases, the liquid-junction potential arising in conventional potentiometric measuring cells. Other topics covered in this part include the practical solution for the membrane potential; the ion-transport and the electrical properties of bulk membranes; and the characteristics of lipid bilayer membranes. Part B considers the fundamentals of ion-selective electrodes. This part begins with discussions of the principles, response behavior, ion selectivity, and detection limits of solid-state membrane electrodes. This part also examines several important extensions and modifications of the Sandblom-Eisenman-Wa... theory; the characteristics of neutral carrier membrane electrodes; and the theory of glass electrodes.

  • Stereochemistry of Organometallic and Inorganic Compounds

    • 1st Edition
    • Bozzano G Luisa
    • English
    The authors of this fourth volume in the series have reviewed the making and breaking of chemical bonds in a sophisticated manner. In particular, new pressures brought about by environmental concerns, larger demands for the medical and pharmaceutical sectors and economics of the market place are forcing us into demanding greater stereochemical control and better product yields for chemical reactions capable of producing useful products. The chapters are written by leading experts in this area and give excellent overviews of the strengths and weaknesses of the various methodologies.In Chapter 1 newer discoveries in such tried and true methods of C-C bond formation as alkylations and aldol reactions of metal enolates are reviewed. The author of Chapter 2 discusses the ability of ab-initio methods to justify the results of empirical observations in the field of transition metal derivatives of small molecules such as N2, CO2 and similar small molecules. Having established the strengths and weaknesses of the various approaches to such theoretical calculations, a more interesting approach to these methods is pursued, namely, their ability to predict, in those areas in which they are particularly strong and reliable, chemical and stereochemical events and/or results in advance of experiments, later carried out in the laboratory. Finally, Chapter 3 reviews the stereochemical results of electron transfer reactions in mononuclear copper compounds.

  • Microchemistry

    Spectroscopy and Chemistry in Small Domains
    • 1st Edition
    • H. Masuhara + 3 more
    • English
    Microchemistry is an interdisciplinary area in which relevant results are presented and published in a range of fields including spectroscopy, optics, applied physics, electrochemistry and polymer science. This volume collects for the first time all the latest research and results and classifies them into five parts. Optical micromanipulation and creation, microfabrication and functionalization and dynamic microspectroscopy are novel methodologies for microchemistry where exploratory ideas and future perspectives are included. Microphotochemistry and microelectrochemistr... and microphotoconversion are concerned with the relaxation dynamics and chemical reactions in small domains. This comprehensive, up-to-date review of the field will be of great interest to scientists and students working in these areas.

  • Introduction to the Mathematics of Quasicrystals

    • 1st Edition
    • Marko V. Jaric
    • English
    Introduction to the Mathematics of Quasicrystals provides a pedagogical introduction to mathematical concepts and results necessary for a quantitative description or analysis of quasicrystals. This book is organized into five chapters that cover the three mathematical areas most relevant to quasicrystals, namely, the theory of almost periodic functions, the theory of aperiodic tilings, and group theory. Chapter 1 describes the aspects of the theory of tiling in two- and three-dimensional space that are important for understanding some of the ways in which “classical” mathematical crystallography is being generalized; this process is to include possible models for aperiodic crystals. Chapter 2 examines the non-local nature of assembly “mistakes” that might have significance to the quasicrystals growth. This chapter also describes how closely a physical quasicrystal might be able to approximate a three-dimensional version of tilings. Chapter 3 discusses the theoretical background and concepts of group theory of icosahedral quasicrystals. Chapter 4 presents the local properties of the three-dimensional Penrose tilings and their global construction is described through the projection method. This chapter emphasizes the relationship between quasiperiodic sets of points and quasiperiodic tiling. Chapter 5 explores the analysis of defects in quasicrystals and their kinetics, as well as some properties of the perfect system. This book is of great value to physicists, crystallographers, metallurgists, and beginners in the field of quasicrystals.

  • Synthetic Multidentate Macrocyclic Compounds

    • 1st Edition
    • Reed Izatt
    • English
    Synthetic Multidentate Macrocyclic Compounds attempts to bring together selected chapters in which the authors discuss in depth investigations in important areas of macrocycle research. The chapters deal mainly with macrocyclic compounds (saturated polyethers and their derivatives), and macrobicyclic compounds (cryptates). The book contains six chapters and opens with a first-hand account of the initial synthesis of the cyclic polyethers. This is followed by separate chapters on the synthesis of cyclic polyethers, polyether amines, and polyether sulfides; the synthesis of multidentate compounds; and the structure of synthetic macrocyclic compounds and their cation complexes. Subsequent chapters deal with the rates of reactions and the mechanism by which synthetic macrocyclic ligands complex substrates in solution; and commercial applications of the synthetic macrocyclic ligands. This book is primarily aimed at researchers and students in organic, physical, analytical, and inorganic chemistry, and in chemical engineering. However, it will also be of interest to many in the areas of biology, biochemistry, and physiology. Extensive literature references are found in each chapter.

  • Azides and Nitrenes

    Reactivity and Utility
    • 1st Edition
    • Eric Scriven
    • English
    Azides and Nitrenes: Reactivity and Utility provides information pertinent to the fundamentals aspects of the chemistry of azides and nitrenes. This book discusses the mechanism and synthetic applications of alkyl azides. Organized into 10 chapters, this book begins with an overview of the properties and chemistry of alkyl azides and alkylnitrenes. This text then examines the various pathways to the preparation of vinyl azides. Other chapters consider the magnetic resonance spectrum of phenyl azide, which may be taken as a representative to which more complex examples can be related. This book discusses as well the acyl azides and acylnitrenes that have their nitrogen function attached to electron-withdrawing groups not possessing a heteroatom bearing an unshared electron pair next to the nitrogen function. The final chapter deals with the main uses for organic azides involved in photochemical cross-linking of polymeric systems. This book is a valuable resource for chemists, spectroscopists, and theoreticians.

  • Phase Transitions and Adsorbate Restructuring at Metal Surface

    • 1st Edition
    • Volume 7
    • D.A. King + 1 more
    • English
    The objective in initiating this series in 1980 was to provide an in-depth review of advances made in the understanding key aspects of surface chemistry and physics through the application of new techniques to the study of well-defined surfaces. Since then the field of surface science has greatly matured, and further important techniques, particularly scanning probe microscopies, have been successfully assimilated into the applications armoury of the surface scientist.The present volume is a series of timely reviews by many of the current experts in the field of phase transitions and adsorbate-induced surface restructuring. No aspect of the science of solid surfaces can be fully understood without accounting for the structural diversity of surfaces, now revealed in atomic detail by techniques based on diffraction and scanning probe microscopies. For example, it is now clear to those working in heterogeneous catalysis that adsorbate-induced restructuring of surfaces can play a critical role in phenomena such as bistability, kinetic oscillations, and promotion and poisoning. Structural transitions at surfaces can also play a key role in determining the electronic properties of surfaces, reviewed in volume 5.

  • Nuclear Spectroscopy and Reactions 40-D

    • 1st Edition
    • Joseph Cerny
    • English
    Nuclear Spectroscopy and Reactions, Part D covers information regarding the development of nuclear spectroscopy and its reactions, while emphasizing in-beam spectroscopy. This part covers the general theoretical concepts of nuclear investigations. This book provides in-depth analysis of several concepts of nuclear spectroscopy, such as models of heavy and light nuclei, approaches in resonance reactions, inelastic scattering, charge exchange, and one- and two-nucleon transfer reactions. This series is written to primarily benefit graduate students who are engaged in research that concerns nuclear spectroscopy.

  • Multiphoton Spectroscopy of Molecules

    • 1st Edition
    • S.H. Lin
    • English
    Multiphoton Spectroscopy of Molecules deals with the fundamental theory, methods, and basic results in multiphoton spectroscopy research made possible by using powerful lasers. This book reviews the progress made in visible and UV multiphoton spectroscopy, including the characteristic properties of multiphoton transitions. Certain theoretical methods such as the time-dependent perturbation, density matrix, Green's function, and susceptibility methods, can point to multiphoton transitions in a molecular system, beginning from first principles. This text also describes the technique in detecting two- or three-photon absorption by multiphoton ionization of molecules. A type of optical mass spectroscopy combining spectroscopic information derived from multiphoton absorption with mass spectrometric information has provided interesting results. This book also discusses the polarization behavior of two-photon absorption processes of molecules. Monson, McClain, and Nascimento have investigated the polarization dependence of the two-photon absorption cross section of randomly oriented, nonrotating molecules. his text also presents the spectroscopic results of excited states confirmed when the multiphoton techniques is applied, as well as some experimental and theoretical approaches related to multiphoton spectroscopy of molecules. Nuclear scientists and physicists, atomic researchers, molecular physicists, and academicians in the field of quantum mechanics or physical chemistry will greatly appreciate the book.

  • Phytochemicals in Plant Cell Cultures

    • 1st Edition
    • Indra K. Vasil
    • English
    Cell Culture and Somatic Cell Genetics of Plants, Volume 5: Phytochemicals in Plant Cell Cultures provides comprehensive coverage of the wide variety of laboratory procedures used in plant cell culture, fundamental aspects of cell growth and nutrition, and plant regeneration and variability. This book consists of five main topics—phenylpropano... naphthoquinones, and anthraquinones; mevalonates; alkaloids; glucosinolates, polyacetylenes, and lipids; and biologically active compounds. This publication specifically discusses the coumarins in crown gall tumors, natural occurrence of bufadienolides, and accumulation of protoberberine alkaloids. The flavor production in tissue cultures of allium species and callus cultures derived from carrot root explants is also reviewed. This volume is valuable to experienced researchers and those newly entering the field of plant cell and tissue culture.

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