Carbene Chemistry
- 1st Edition - December 2, 2012
- Latest edition
- Author: Wolfgang Kirmse
- Language: English
Organic Chemistry, Volume 1: Carbene Chemistry is a 12-chapter text that covers pertinent research studies on the carbene chemistry. The first ten chapters are devoted to… Read more
Organic Chemistry, Volume 1: Carbene Chemistry is a 12-chapter text that covers pertinent research studies on the carbene chemistry. The first ten chapters are devoted to comprehensive surveys of carbene chemistry. Each chapter tackles specific carbene compound, such as olefinic and acetylenic carbenes, aryl and diarylcarbenes, carboalkoxycarbenes, ketocarbenes, halocarbenes, heteroatom-containing carbenes, and dicarbenes. The formation, synthesis, and reactions of these compounds are discussed. The remaining two chapters the excess energy in reactions and spin states of carbenes. This book will be of value to organic chemists, organic chemistry researchers, teachers, and students.
Preface Chapter 1 Introduction I. Scope and Limitations II. Nomenclature III. History References Chapter 2 Methylene I. Formation of Methylene II. Reactions of Methylene References Chapter 3 Alkyl- and Dialkylcarbenes I. Formation of Alkyl- and Dialkylcarbenes II. Reactions of Alkyl- and Dialkylcarbenes References Chapter 4 Olefinic and Acetylenie Carbenes I. Alkenylcarbenes II. Alkynylcarbenes III. Alkylidenecarbenes IV. Alkenylidenecarbenes References Chapter 5 Aryl- and Diarylcarbenes I. Formation of Aryl- and Diarylcarbenes II. Reactions of Aryl- and Diarylcarbenes ReferencesChapter 6 Carboalkoxycarbenes I. Formation of Carboalkoxycarbenes II. Reactions of Carboalkoxycarbenes ReferencesChapter 7 Ketocarbenes I. Formation of Ketocarbenes II. Reactions of Ketocarbenes III. Thioketocarbenes ReferencesChapter 8 Halocarbenes I. Dlhalocarbenes II. Chlorocarbene III. Alkyl- and Arylhalocarbenes References Chapter 9 Carbenes Containing α-Hetero Atoms I. Aminocarbenes II. Alkoxy-, Aryloxy-, and Related Cabrenes III. Alkylthio- and Arylthiocarbenes IV. Phenylselenocarbene References Chapter 10 Dicarbenes Text References Chapter 11 Excess Energy in Carbene Reactions I. Rates of Reactions of Methylene II. Unimolecular Decomposition of Excited Molecules Formed By Methylene Reactions References Chapter 12 The Spin States of Carbenes I. Introduction II. Structural Theory III. Spectroscopic Evidence IV. Chemical Evidence References Author Index Subject Index
- Edition: 1
- Latest edition
- Published: December 2, 2012
- Language: English