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Elsevier Science

Separation, Preconcentration and Spectrophotometry in Inorganic Analysis
1st Edition
Z. Marczenko + 1 more
E. Kloczko
English
Spectrophotometry enables one to determine, with good precision and sensitivity, almost all the elements present in small and trace quantities of any material. The method is particularly useful in the determination of non-metals and allows the determination elements in a large range of concentrations (from single % to low ppm levels) in various materials.In Separation, Preconcentration and Spectrophotometry in Inorganic Analysis, much attention has been paid to separation and preconcentration methods, since they play an essential role in increasing the selectivity and sensitivity of spectrophotometric methods. Separation and preconcentration methods have also been utilised in other determination techniques.Spectroph... methods which are widely used for the determination of the elements in a large variety of inorganic materials are presented in the book whilst separation and preconcentration procedures combined with spectrophotometry are also described. This book contains recent advances in spectrophotometry, detailed discussion of the instrumentation, and the techniques and reagents used for spectrophotometric determination of elements in a wide range of materials as well as a detailed discussion of separation and preconcentration procedures that precede the spectrophotometric detection.
Amphiphilic Block Copolymers
Self-Assembly and Applications
1st Edition
P. Alexandridis + 1 more
English
It is the belief of the editors of this book that the recognition of block copolymers as being amphiphilic molecules and sharing common features with other well-studied amphiphiles will prove beneficial to both the surfactant and the polymer communities. An aim of this book is to bridge the two communities and cross-fertilise the different fields. To this end, leading researchers in the field of amphiphilic block copolymer self-assembly, some having a background in surfactant chemistry, and others with polymer physics roots, have agreed to join forces and contribute to this book.The book consists of four entities. The first part discusses theoretical considerations behind the block copolymer self-assembly in solution and in the melt. The second part provides case studies of self-assembly in different classes of block copolymers (e.g., polyethers, polyelectrolytes) and in different environments (e.g., in water, in non-aqueous solvents, or in the absence of solvents). The third part presents experimental tools, ranging from static (e.g., small angle neutron scattering) to dynamic (e.g., rheology), which can prove valuable in the characterization of block copolymer self-assemblies. The fourth part offers a sampling of current applications of block copolymers in, e.g., formulations, pharmaceutics, and separations, applications which are based on the unique self-assembly properties of block copolymers.
Hydrophile - Lipophile Balance of Surfactants and Solid Particles
Physicochemical Aspects and Applications
1st Edition
Volume 9
Pyotr M Kruglyakov
English
This book considers the different concepts of hydrophile-lipophile balance (HLB) of surfactants and solid particles and the main physicochemical properties of surfactant and solid interfaces which are used to definite the hydrophile-lipophile balance. The book comprehensively analyses all interfacial and bulk properties of surfactants used for the determination of HLB (such as interfacial tension, distribution coefficient, adsorption, surface pressure, surfactants solubility, structure characteristics, distribution between heteropolar phases, micellar formation, chromatographic characteristics, phase separation in emulsions, phase inversion temperature, formation of three phase systems).The central point of the book is the energetic interpretation of the balance, i.e. the hydrophile-lipophile ratio. At the same time the HLB-number systems of Griffin and Davies and other independant methods of the hydrophile-lipophile balance definitions are discussed: PIT, polarity indexes, surfactant affinity difference etc. The possibility of application of the different characteristics of the hydrophile-lipophile balance as a criterion of phase inversion in emulsions and microemulsion systems water-oil-surfactant are considered.For the first time the different methods of the hydrophile-lilophile balance definition for solid particles in compact and dispersed form are suggested by the author. The use of hydrophile-lipophile characteristics of solid particles as a criterion of phase inversion in emulsion stabilisation and for other applications is discussed.
Micro Mechanical Transducers
Pressure Sensors, Accelerometers and Gyroscopes
1st Edition
Volume 8
Min-hang Bao
S. Middelhoek
English
Some years ago, silicon-based mechanical sensors, like pressure sensors, accelerometers and gyroscopes, started their successful advance. Every year, hundreds of millions of these devices are sold, mainly for medical and automotive applications. The airbag sensor on which research already started several decades ago at Stanford University can be found in every new car and has saved already numerous lives. Pressure sensors are also used in modern electronic blood pressure equipment. Many other mechanical sensors, mostly invisible to the public, perform useful functions in countless industrial and consumer products. The underlying physics and technology of silicon-based mechanical sensors is rather complex and is treated in numerous publications scattered throughout the literature. Therefore, a clear need existed for a handbook that thoroughly and systematically reviews the present basic knowledge on these devices.After a short introduction, Professor Bao discusses the main issues relevant to silicon-based mechanical sensors. First a thorough treatment of stress and strain in diaphragms and beams is presented. Next, vibration of mechanical structures is illuminated, followed by a chapter on air damping. These basic chapters are then succeeded by chapters in which capacitive and piezoresistive sensing techniques are amply discussed. The book concludes with chapters on commercially available pressure sensors, accelerometers and resonant sensors in which the above principles are applied. Everybody, involved in designing silicon-based mechanical sensors, will find a wealth of useful information in the book, assisting the designer in obtaining highly optimized devices.
Physical Chemistry of Polymer Solutions
Theoretical Background
1st Edition
K. Kamide + 1 more
English
This book is mainly concerned with building a narrow but secure ladder which polymer chemists or engineers can climb from the primary level to an advanced level without great difficulty (but by no means easily, either).This book describes some fundamentally important topics, carefully chosen, covering subjects from thermodynamics to molecular weight and its distribution effects. For help in self-education the book adopts a "Questions and Answers" format. The mathematical derivation of each equation is shown in detail. For further reading, some original references are also given. Numerous physical properties of polymer solutions are known to be significantly different from those of low molecular weight solutions. The most probable explanation of this obvious discrepancy is the large molar volume ratio of solute to solvent together with the large number of consecutive segments that constitute each single molecule of the polymer chains present as solute. Thorough understanding of the physical chemistry of polymer solutions requires some prior mathematical background in its students. In the original literature, detailed mathematical derivations of the equations are universally omitted for the sake of space-saving and simplicity. In textbooks of polymer science only extremely rough schemes of the theories and then the final equations are shown. As a consequence, the student cannot learn, unaided, the details of the theory in which he or she is interested from the existing textbooks; however, without a full understanding of the theory, one cannot analyze actual experimental data to obtain more basic and realistic physical quantities. In particular, if one intends to apply the theories in industry, accurate understanding and ability to modify the theory are essential.
Separation Methods in Drug Synthesis and Purification
1st Edition
Volume 1
Klara Valko
English
Fracture of Polymers, Composites and Adhesives
1st Edition
Volume 27
A Pavan + 1 more
English
This book contains a selection of fully peer-reviewed papers which were presented at the 2nd ESIS TC4 Conference, held in Les Diablerets, Switzerland 13 - 15 September 1999. The meeting was designed to reflect the activities of the Committee over the last 15 years, and to plan future activities. The papers have been divided into four chapters under the headings of Composites, Elastic-Plastic Fracture, Adhesion, and Impact and General Fracture. These are convenient groupings, but there are many interactions between the areas, with the common theme of Fracture Mechanics underlying it all.
CAFE: An Industrial-Strength Algebraic Formal Method
1st Edition
K. Futatsugi + 2 more
English
This book contains selected papers on the language, applications, and environments of CafeOBJ, which is a state-of -the-art algebraic specification language. The authors are speakers at a workshop held in 1998 to commemorate a large industrial/academic project dedicated to CafeOBJ. The project involved more than 40 people from more than 10 organisations, of which 6 are industrial. The workshop attracted about 30 talks and more than 70 attendees.The papers in the book however, are either heavily revised versions presented at the workshop, to reflect recent advancements or research; or completely new ones, written especially for this book. In this regard, the book is not a usual postpublication after a workshop. Also, although it is a compendium of papers that are related to CafeOBJ, the book is not a manual, reference, or tutorial of CafeOBJ. Probably the best description is that it is a collection of papers that investigate how to use, or to make it easy to use, CafeOBJ. Reflecting the diverse nature of the project and its participants (most of the authors are participants to the project), the papers, put together, offer a comprehensive picture from this methodological perspective.Some papers deal with various advanced aspects of the language, such as rewriting logic and behavioural logic. For rewriting logic, a couple of significant applications were reported. In particular, UML, now considered de facto standard language for modelling systems, is the subject of one paper. For behavioural logic, new methodological guidelines are presented. Some papers shed new light on a more traditional paradigm in the language; order-sorted equational specifications. One paper, in particular, deal with a way to associate CafeOBJ with object-oriented programming. The other papers deal with environments for writing and vertifying specifications written in CafeOBJ. Underlying those papers are two major considerations: user interfaces for manipulating specifications, and systematic supports for proofs. All the environments explained in the papers assume and support distributed computing, and de facto standard network technologies, such as WWW and http, are incorporated.
Novel Macromolecules in Food Systems
1st Edition
Volume 41
G. Doxastakis + 1 more
English
Applying recent advances in biological and physical sciences, food scientists have created "novel food ingredients" enzymatically, chemically or microbiologically. Chief among these are "novel proteins and polysaccharides" which, like the more established traditional macromolecules, can perform multifunctional roles such as thickening, stabilization, gelation or encapsulation and in this way determine to a large extent the shelf life, texture and nutritional value of natural and processed foods.Featuring the latest advances on chemistry, structure and functional properties of "novel proteins and polysaccharides", with an emphasis on fundamental structure-function relationships, this book will be valuable to all those working in product development and fundamental food research.
Recent Advances in Gas Separation by Microporous Ceramic Membranes
1st Edition
Volume 6
N.K. Kanellopoulos
English
This book is dedicated to the rapidly growing field of microporous ceramic membranes with separating layers of pore diameter less than 2nm.The chapters of this book bring forward a wide range of issues, namely fundamentals of complex sorption and transport processes in micropore structures, highly innovative methods of preparation of microporous membranes and examples of their possible commercial applications. This book presents insights by distinguished investigators, who have contributed significantly to the advance of research efforts in the diverse topics described herein.Recently, significant progress has been made with respect to the development of novel microporous asymmetric membranes, mainly involving modification by means of deposition of additional material within the pores of the substrates. Most state-of-the-art technologies aiming in the development of microporous ceramic membrane are presented in the third section of the book. These include several material deposition methods and techniques on macroporous or mesoporous supports and substrates from the liquid or vapour phase, namely those involving sol-gel, zeolite and chemical vapour deposition techniques. In addition to the above-mentioned methods, the classical technique of carbonizing polymeric deposits along with one of the novel techniques of plasma-treating, organically deposited Langmuir-Blodgett films, are also presented. Nanophase mixed ionic-electron membranes for enhanced oxygen transport are described, which pose a strong candidacy for a number of significant commercial applications.

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