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Elsevier

Books in Chemistry

Chemistry topic areas include: physical and theoretical, computational, organic, organometallic and inorganic, pharmaceutical and medicinal, analytical and bioanalytical, nuclear, general, nanochemistry, geochemistry, materials and polymer, as well as environmental, green and sustainable chemistry.

  • Ion Association in Proton Transfer Reactions

    Use of ESR for the Quantitative Determination of Gas Phase Atom and Radical Concentrations
    • 1st Edition
    • J R Jones + 1 more
    • K. R. Jennings + 1 more
    • English
    Ion Association in Proton Transfer Reactions: Use of ESR for the Quantitative Determination of Gas Phase Atom and Radical Concentrations summarizes the basic information essential for the measurement of both gas phase atoms and free radicals concentration by electron spin resonance (ESR) spectroscopy. Organized into two chapters, this book first explains the ion association in proton transfer reactions, and then characterizes the ion pairs. The second chapter focuses on the specific use of the ESR spectroscopy. This book also details the gas phase species detected by ESR spectroscopy, including each of the spectra, and the intensities of the spectral lines of the various atoms and radicals. The actual measurements made by this instrument are also shown.

  • Structure and Dynamics of Solutions

    • 1st Edition
    • Volume 79
    • Hideyuki Ohtaki + 1 more
    • English
    Recent advances in the study of structural and dynamic properties of solutions have provided a molecular picture of solute-solvent interactions. Although the study of thermodynamic as well as electronic properties of solutions have played a role in the development of research on the rate and mechanism of chemical reactions, such macroscopic and microscopic properties are insufficient for a deeper understanding of fast chemical and biological reactions. In order to fill the gap between the two extremes, it is necessary to know how molecules are arranged in solution and how they change their positions in both the short and long range. This book has been designed to meet these criteria.It is possible to develop a sound microscopic picture for reaction dynamics in solution without molecular-level knowledge of how reacting ionic or neutral species are solvated and how rapidly the molecular environment is changing with time. A variety of actual examples is given as to how and when modern molecular approaches can be used to solve specific solution problems. The following tools are discussed: x-ray and neutron diffraction, EXAFS, and XANES, molecular dynamics and Monte Carlo computer simulations, Raman, infrared, NMR, fluorescence, and photoelectron emission spectroscopic methods, conductance and viscosity measurements, high pressure techniques, and statistical mechanics methods. Static and dynamic properties of ionic solvation, molecular solvation, ion-pair formation, ligand exchange reactions, and typical organic solvents are useful for bridging the gap between classical thermodynamic studies and modern single-molecule studies in the gas phase.The book will be of interest to solution, physical, inorganic, analytical and structural chemists as well as to chemical kineticists.

  • Molten Alkali Metal Alkanoates

    • 1st Edition
    • Volume 33
    • P. Franzosini + 3 more
    • English
    Most alkali metal alkanoates exhibit polymorphism in the solid state. However, controversy exists about the number, nature and stability range of the polymorphs present in a given solvent. This volume discusses all available solubility data for the title compounds, and includes critical evaluations for all systems considered.

  • Survey of Progress in Chemistry

    Volume 2
    • 1st Edition
    • Arthur F. Scott
    • English
    Survey of Progress in Chemistry, Volume 2 covers the principles common to all chemistry that undergo major developments and modifications, including substitution reactions of metal complexes, salt chemistry, and photochemical reactions. This volume is composed of six chapters, and begins with an examination of the reaction mechanisms of substitution reactions of metal complexes. The succeeding chapters deal with the methods of measurement of fast reactions in solution and the general chemistry of fused salt, acids, and bases. These topics are followed by a presentation of several examples of displacement reactions at the sulfur-sulfur bond based on the basic mechanistic concepts. The concluding chapter considers the progress in the mechanistic aspects of photochemical reactions, with emphasis on the processes that occur in the interval between absorption of light and formation of products. This book will prove useful to general chemistry teachers and students.

  • Practical Heterocyclic Chemistry

    • 1st Edition
    • A. O. Fitton + 1 more
    • English
    Practical Heterocyclic Chemistry focuses on experiments, methodologies, processes, reactions, and transformations involved in practical heterocyclic chemistry. The manuscript first offers information on five-membered systems containing one heteroatom and benzoderivatives of five-membered systems containing one heteroatom, including 2,5 – dimethylpyrrole, 2,5 – dimethylthiophen, carbazole, indigotin, and 2-phenylindole. The text then elaborates on five-membered systems containing more than one heteroatom and benzoderivatives of five-membered systems containing more than one heteroatom, as well as benzimidazole, benzotriazole, and 2,4,5 – triphenyloxazole. The publication ponders on six-membered systems containing one heteroatom and benzoderivatives of six-membered systems containing one heteroatom. Discussions focus on 4-nitropyridine N-oxide, 6-chloroquinoline, 2-methyl-4-quinolone... and xanthone. The manuscript is highly recommended for chemists and readers interested in practical heterocyclic chemistry.

  • Organic Solid-State Chemistry—2

    Plenary Lectures Presented at the 2n.d International Symposium on Organic Solid-State Chemistry
    • 1st Edition
    • M. D. Cohen
    • English
    Organic Solid-State Chemistry–2 presents the solid state reactions in molecular crystals. This book discusses the correlations of the chemical structures of products from organic solid state reactions with the molecular packing in the reactant crystal structures. Organized into 10 chapters, this book begins with an overview of the molecular behavior after the chemical transition state. This text then examines the electron paramagnetic resonance methods, which offer many features in connection with the study of chemical reactions in which a paramagnetic species is a product or a reactant. Other chapters consider the interpretation of radiationless transitions, thermal reactions, and photochemical decompositions and rearrangements. The final chapter deals with the experimental results concerning electron and hole production in anthracene crystals, with emphasis on the relevance of these studies to the fundamental question of the nature of the excess electron states in these low mobility crystals. This book is a valuable resource for solid state chemists, photochemists, spectroscopists, scientists, and research workers.

  • Fixed-Bed Reactor Design and Diagnostics

    Gas-Phase Reactions
    • 1st Edition
    • Howard F. Rase
    • English
    Fixed-Bed Reactor Design and Diagnostics: Gas-Phase Reactions presents the essential theoretical and conceptual background of gaseous reactions catalyzed by solid catalysts in fixed beds. This book intends to provide recommendations to professionals who seek for modeling, scale-up, and diagnostics of fixed-bed reactors. The text is divided into three parts. Part I provides the conceptual background and relevant theories. Part II presents recommended mathematical models, scale-up procedures, and diagnostic methods. Part III gives a number of practical examples. The topics that are specifically discussed include heterogeneous catalysis and kinetics; general tubular reactor model; and general diagnostics for fixed-bed reactors. Engineers and professionals working with fixed-bed reactors will find the book highly informative.

  • Chemical Evolution of the Early Precambrian

    • 1st Edition
    • Cyril Ponnamperuma
    • English
    Chemical Evolution of the Early Precambrian is a collection of papers presented at the Second College Park Colloquium on Chemical Evolution, held at the University of Maryland in October 1975. The book presents the discussions on the processes that led to the beginning of life on earth based on information gathered from the study of the Early Precambrian period. Topics on the origin of the atmosphere; early Precambrian weathering and sedimentation; carbon contents of early Precambrian rocks; and the establishment of the earliest date in the Precambrian period at which unambiguous living forms existed are expounded in the text. Geologists, biologists, chemists, paleobiologists, and students will find the book insightful and interesting.

  • Annual Reports in Organic Synthesis — 1976

    • 1st Edition
    • R. Bryan Miller + 1 more
    • English
    Annual Reports in Organic Synthesis—1976 presents an annual review of synthetically useful information that would prove beneficial to nearly all organic chemists, both specialist and nonspecialist in synthesis. It should help relieve some of the information storage burden of the specialist and should aid the nonspecialist who is seeking help with a specific problem to become rapidly aware of recent synthetic advances. In producing this volume the editors abstracted 47 primary chemistry journals, selecting useful synthetic advances. All reactions and methods which are new, synthetically useful, and reasonably general are included. Each entry is comprised primarily of structures accompanied by very few comments. The purpose of this is to aid the reader in rapidly scanning the book. Chapters I-III are organized by reaction type and constitute the major part of the book. Chapter IV deals with methods of synthesizing heterocyclic systems. Chapter V covers the use of new protecting groups. Chapter VI is divided into three main parts and covers those synthetically useful transformations that do not fit easily into the first three chapters. The first part deals only with functional group synthesis. The second part covers ring expansion and contraction, and the third part involves useful multistep sequences.

  • Comptes Rendus 28th Conference

    • 1st Edition
    • M. Williams
    • English
    Comptes Rendus 28th Conference, Part A contains names of IUPAC members, their category of Membership, and their division during the 1975 Madrid Conference. This book is divided into six chapters. Each chapter contains names of the members of the specific division. These divisions include the Physical Chemistry, Inorganic Chemistry, Organic Chemistry, Macromolecular, Analytical Chemistry, and Applied Chemistry.

  • The Kjeldahl Method for Organic Nitrogen

    • 1st Edition
    • R. B. Bradstreet
    • English
    The Kjeldahl Method for Organic Nitrogen volume presents a broad and comprehensive survey of the method as applied to natural products and organic nitrogen compounds. The quantitative determination of an element as widely distributed as nitrogen is of great importance, and the truth of this is borne out by the tremendous amount of literature published throughout the years. The analysis of nitrogen can be divided into two classes: inorganic and organic. This book is concerned only with organic nitrogen compounds, and specifically their determination by the Kjeldahl method. The book opens with a chapter on the historical background and the work leading to the evolution of the method. This is followed by separate chapters that discuss each of the several divisions of the method, e.g., salt addition, reduction, oxidation, catalysts, distillation.

  • Newer Redox Titrants

    International Series of Monographs in Analytical Chemistry
    • 1st Edition
    • A. Berka + 2 more
    • R. Belcher + 1 more
    • English
    International Series of Monographs in Analytical Chemistry, Volume 22: Newer Redox Titrants focuses on the processes, reactions, methodologies, and approaches involved in the study of redox titrants. The publication first offers information on potassium permanganate in alkaline solution and compounds of trivalent manganese, including standard solutions, indicator, and review of determinations. The text then ponders on compounds of trivalent copper and potassium hexacyanoferrate. The book ponders on hypohalites (hypochlorite and hypobromite), chloramine-T, and bromine, as well as standard solutions, indicator, and review of determinations. The publication also takes a look at iodine monochloride, periodic acid and its salts, lead (IV) acetate, compounds of pentavalent vanadium, and iron (III) salts. The compounds of trivalent cobalt, hydrogen peroxide, chromium (II) salts, tin (II) chloride, sodium arsenite, and compounds of monovalent copper are also elaborated. ? The publication is a reliable reference for readers interested in newer redox titrants.

  • Mode of Action, Metabolism and Toxicology

    Pesticide Chemistry: Human Welfare and the Environment
    • 1st Edition
    • S. Matsunaka + 2 more
    • English
    Pesticide Chemistry: Human Welfare and the Environment, Volume 3: Mode of Action, Metabolism and Toxicology covers the proceeding of the Fifth International Congress of Pesticide Chemistry. This book is organized into three parts that tackle relevant issues regarding the use of pesticide. The opening part tackles topics relevant to the biochemistry of pests and mode of action of pesticides, such as influence of chlorinated and parathyroid insecticide on cellular calcium regulatory mechanisms; behavioral and lethal actions of amidines on invertebrates; and insect chitin synthetase as biochemical probe for insecticidal compounds. The second part encompasses metabolism and degradation of pesticides and xenobiotics and includes topics on propesticides; selective toxicity conferred by activation; and comparative biochemistry of animal, plant, and microorganism oxidases. The last part covers the toxicology of pesticides and xenobiotics, including the role of biochemical studies in modern toxicological assessment of pesticides; neurophysiological and behavioral assessment of pesticide toxicity; and genetic toxicology applied to the assessment of mutagenic, carcinogenic, and teratogenic action of pesticides and related compounds. This book will be of great interest to chemists, biologists, botanists, and entomologists or professionals whose line of work involves the use of pesticides and who are concerned with pesticide side-effects to the users and the environment.

  • Ternary Systems

    Solubilities of Inorganic and Organic Compounds
    • 1st Edition
    • H. Stephen + 1 more
    • English
    Solubilities of Inorganic and Organic Compounds, Volume 2: Ternary Systems, Part I focuses on a selection from the International Chemical Literature on the Solubilities of Elements, Inorganic Compounds, Metallo-organic Compounds, and Organic Compounds in Ternary and Multicomponent Systems. The book underscores that Tables 1-4955 deal with Ternary Systems, while Tables 4956 et seq. are devoted to Multicomponent Systems. The first tables are systems in which an Element is a component, and these are supported by data for systems containing Inorganic Compounds and then Metallo-organic Compounds. The ion of ammonia is placed at the end of the first Group. The text also presents the arrangement of the compounds of elements. These include oxides and their hydrates and salts of halogen and other acids. The book is a dependable reference for readers interested in studying the solubilities of inorganic and organic compounds.

  • Advances in Liquid Crystals

    Volume 4
    • 1st Edition
    • Glenn H. Brown
    • English
    Advances in Liquid Crystals, Volume 4 is a collection of papers that deals with liquid crystal sciences, particularly the flow problems in liquid crystals, the effects of high pressure on liquid crystals, lyotropic and thermotropic polymeric liquid crystals, and the light-scattering properties of thermotropic liquid crystals. One paper reviews the continuum theory in flow problems in liquid crystals, presents theoretical predictions, and compares these with associated observations. High-pressure experiments in liquid crystals pave the way for discoveries involving pressure-induced mesomorphism in certain materials, suppression of mesophases, tricritical phase transitions, and re-entrant behavior. Another paper describes the types of macromolecular structures that have a propensity for mesomorphism — linear, conventional types of polymers, such as block copolymers and graft copolymers. Another paper examines the application of light scattering in fluctuations that happens during the liquid crystalline phases. The paper investigates the assumption that light is scattered by inhomogeneities in the dialectric constant of the medium it is passing through. This collection can prove useful for scientists in liquid crystals, and industrial researchers in the field of advanced chemistry and physics.

  • Piperidine

    Structure, Preparation, Reactivity, and Synthetic Applications of Piperidine and its Derivatives
    • 1st Edition
    • Volume 43
    • M. Rubiralta + 2 more
    • English
    Piperidine, one of the simplest heterocyclic systems, is found in nature as part of several alkaloid compounds. Both natural and especially unnatural piperidine derivatives present interesting pharmacological properties. From a structural viewpoint, the conformation of piperidine has been the subject of one of the fiercest controversies in structural organic chemistry in the last few years. As a result of the combined use of several spectroscopic techniques, the conformational behavior of most types of piperidine-related compounds has been clarified. Some piperidine derivatives, namely, N-acylpiperidine, &agr;-cyanopiper... and piperidones are extremely useful and versatile intermediates in organic synthesis. The present book offers an updated and integrated view of all these topics. The aim of the book is twofold. Firstly, to reveal to the reader the combined use of different spectroscopic data, to facilitate an insight into the structure and conformational properties of any new piperidine derivative. Secondly, to establish a consistent link between conformation and reactivity for a variety of piperidine derivatives. Such a bridge is a key step for stereocontrol when dealing with the application of piperidine derivatives as synthetic intermediates. The book is conceived so that most of the information comes from visual inspection of the very abundant graphic material. An exhaustive subject index of more than 450 entries is also included.

  • Advances in Liquid Crystals

    Volume 6
    • 1st Edition
    • Glenn H. Brown
    • English
    Advances in Liquid Crystals, Volume 6 is a collection of scientific essays that focuses on the developments and applications in the field of liquid crystal science. The text begins with an article about the smectic phases of substances with rodlike molecules in layered structures. This article focuses on the nematic phases of polymorphism that include cubic thermotropic phases and blue phases. A section of the book provides an extensive discussion of the means of experimental procedures used to evaluate the spectra and the implications of the spectral parameters. A critical analysis of the influence of molecular vibration including interdependence on the average order parameters is also included. The terms nuclear relaxation, quadrupole coupling constants, chemical shielding anisotropy, molecular order, and molecular structure and conformation are explained in detail. The last article briefly discusses the actions of liquid crystal systems in the muscle and connective tissue. The book will provide valuable insights for scientists, developers of crystal displays, students, and researchers in the field of chemistry.

  • Clinical Electroencephalography

    • 3rd Edition
    • L. G. Kiloh + 2 more
    • English
    Clinical Electroencephalograp... is intended to serve as a guide to clinical practice, to provide critical evaluation of existing knowledge and the progress in clinical electroencephalograp... and to provide insights that may be helpful in the complex decision-making process that confronts the medical practitioner faced with an individual case with all its facets and ambiguities. This book is organized into 11 chapters. Most of the contents of previous volumes were retained in this third edition. A chapter on special techniques was added to describe some of the more common applications of EEG outside routine laboratory recording. It also includes a discussion on sensory evoked potentials and overnight sleep, though they are rapidly becoming specialties in their own right. This book will be of interest to students, practicing clinicians and other medical professionals.

  • Purines, Pyrimidines and Nucleotides

    And the Chemistry of Nucleic Acids
    • 1st Edition
    • T. L. V. Ulbricht
    • English
    Purines, Pyrimidines and Nucleotides and the Chemistry of Nucleic Acids serves as an introduction to the basic chemistry of purines and pyrimidines and their derivatives. The textbook focuses on topics that provide information on the nature and properties of purines and pyrimidines and nucleic acid. Chapters are devoted to topics on the general chemistry of purines and pyrimidines; synthesis of purines and pyrimidines; and the structure, synthesis, and mechanism of nucleosides, nucleotides, and nucleic acids. Biochemists, chemists, molecular biologists, and senior undergraduates taking courses in heterocyclic and natural products chemistry will find the book very useful.

  • Krypton, Xenon & Radon

    • 1st Edition
    • Volume 2
    • H. L. Clever
    • English
    Solubility Data Series, Volume 2: Krypton, Xenon, and Radon – Gas Solubilities is a three-chapter text that presents the solubility data of various forms of the title compounds in different substrates. This series emerged from the fundamental trend of the Solubility Data Project, which is toward integration of secondary and tertiary services to produce in-depth critical analysis and evaluation. Each chapter deals with the experimental solubility data of the noble gases in several substrates, including water, salt solutions, organic compounds, and biological fluids. This book will prove useful to chemists, researchers, and students.

  • Moon Rocks and Minerals

    Scientific Results of the Study of the Apollo 11 Lunar Samples with Preliminary Data on Apollo 12 Samples
    • 1st Edition
    • Alfred A. Levinson + 1 more
    • English
    Moon Rocks and Minerals compiles the important findings that have resulted from the first study of the Apollo 11 lunar rocks, including preliminary data on Apollo 12 lunar samples. The compiled study samples and proposals on the lunar rocks are categorized into four general categories— mineralogy and petrology, chemical and isotope analyses, physical properties, and bioscience and organic geochemistry. In these categories, this book specifically discusses the types and mineralogy of lunar rocks and soils; chemistry of samples brought by Apollo 11 and 12; and experimental studies and origin of the lavas. The age of the lunar rocks, isotope studies, cosmic ray, and solar wind effects and origin of the moon are also deliberated. This text also covers the examination of lunar samples for the presence of biochemical organic compounds in the general context of the possibility of extraterrestrial life. This publication is beneficial to scientists of disciplines such as geochemistry, cosmochemistry, mineralogy, and geophysics.

  • Sulphones in Organic Synthesis

    • 1st Edition
    • Volume 10
    • N S. Simpkins
    • Patrick Perlmutter
    • English
    Over the last twenty years the use of sulphones in organic synthesis has increased dramatically, the synthetic repertoire of sulphones having been developed to such an extent as to rival the carbonyl functionality for versatility. Not only have sulphones been employed in a great many synthetic methodologies, enabling the preparation of a vast array of functionalised products, but the sulphone group has also proved to be of enormous value in many of the most demanding and sophisticated total syntheses carried out in recent years. This book describes in detail all of the important sulphone chemistry employed in organic synthesis, ranging from the well-established sulphone-mediated methods to less familiar sulphone reactions and very recent discoveries of synthetic potential.

  • The Chemistry of the Lanthanides

    Pergamon Texts in Inorganic Chemistry
    • 1st Edition
    • Therald Moeller
    • English
    Inorganic Chemistry, Volume 26: The Chemistry of the Lanthanides provides information pertinent to the fundamental aspects of the chemistry of lanthanides. This book discusses the electronic configurations and the consequences thereof of lanthanides. Organized into four chapters, this volume begins with an overview of the characterized state of oxidation of all the lanthanides both in solid compounds and in solutions in water and other solvents. This text then presents the data indicating an overall decrease from lanthanum to lutetium even though there is the expected increase in the sizes of atoms and derived terpositive ions in Group IIIA elements. Other chapters consider the differences between the lanthanide elements and the d-transition. This book discusses as well the types of lanthanide complexes. The final chapter deals with the estimated absolute abundances of the lanthanides in the cosmos as well as in the crust. This book is a valuable resource for inorganic chemists.

  • Trace Elements in Coal

    • 1st Edition
    • Dalway J. Swaine
    • English
    Trace Elements in Coal focuses on the compositions, reactions, and properties of trace elements in coal. The book first discusses the origin of trace elements in coal. The formation of peat; geological and geochemical aspects of coal seams; geology of Australian coals; constitution of coal; history of trace elements in coal; and coal mining in Australia are discussed. The text also clarifies the mode of occurrence of trace elements in coal. The identification of minerals in coal; silicon-rich minerals; carbonate minerals; sulfide minerals; lignites and brown coals; and phosphates are discussed. The book then underscores the methods of analysis. Inductively coupled plasma atomic emission spectrometry; atomic absorption spectrometry; spark source mass spectrometry; and neuron activation analysis are described. The text also focuses on the contents of trace elements in coal; comparisons of coal with shale and soil; relationship of radioactivity and coal; and relevance of trace elements in coal. The book is a good source of data for readers wanting to study the trace elements in coal.

  • Introduction to Steroid Chemistry

    • 1st Edition
    • J. R. Hanson
    • Robert Robinson
    • English

  • Origin and Chemistry of Petroleum

    Proceedings of the Third Annual Karcher Symposium, Oklahoma, May 4, 1979
    • 1st Edition
    • Gordon Atkinson + 1 more
    • English
    Origin and Chemistry of Petroleum explains that petroleum is produced from exceptionally disseminated organic matter of biological origin encased in extremely buried sediments. Production of petroleum starts when such sediments are exposed to higher temperatures resulting from increased depths of entombment in the sedimentary column. The book discusses that once the petroleum is created from source rocks, the material transfers into porous reservoir rocks. Such rocks, when discovered, will give enough supply of petroleum for commercial production. An evaluation of the molecular analysis of the thermal history of sediments is also discussed in the book. Concepts such as the biological marker compounds, stereochemical conversion, and lower Toarcian sediments are covered in detail. Analysis of organic matters, such as acyclic isoprenoids, steranes, hopanes, and porphyrins, is highlighted. The molecular distributions and stereochemical ratios are also covered in the book. The text can serve as a valuable tool for geologists, chemists, miners, students, and researchers in the field of chemistry.

  • Physical Chemistry

    Session Lectures Presented at the Twentysixth International Congress of Pure and Applied Chemistry, Tokyo, Japan, 4-10 September 1977
    • 1st Edition
    • S. Nagakura
    • English
    Physical Chemistry covers the session lectures presented at the 26th International Congress of Pure and Applied Chemistry, held in Tokyo, Japan on 4-10 September 1977. The book focuses on the processes, reactions, properties, and transformations of molecules, including energy transfer and spectroscopy. The selection first discusses the applications of lasers in chemical spectroscopy and dynamics; microwave spectral studies of interstellar molecules; and molecular reaction dynamics by the crossed molecular beam technique. The text also reviews the chemical applications of ionizing excited atom-molecule collisions, including penning ionization by metastables and non-metastables, ionization in collisions with high-N-Rydberg atoms, and true associative ionization. The manuscript examines the picosecond time-resolved measurements of vibrational energy transfer and relaxation phenomena in large polyatomic molecules and microwave spectroscopy of short-lived molecules. The text also ponders on the electronic structures of aromatic hydrocarbons with high spin multiplicities in the electronic ground state and non-stoichiometry and structural disorder in inorganic compounds. The selection is a dependable reference for chemists and readers interested in pure and applied chemistry.

  • Indicators

    International Series of Monographs in Analytical Chemistry
    • 1st Edition
    • Edmund Bishop
    • English
    Indicators offers a comprehensive account of indicators and their applications in areas such as titrimetric analysis and the analysis of mineral waters. The theory and principles of visual indicators are discussed, along with acid-base indicators, indicators for non-aqueous acid-base titrations, and titrations with non-chelating ligands. Metallochromic indicators, adsorption indicators, oxidation-reduction indicators, and fluorescent and chemiluminescent indicators are also considered. This volume is comprised of 10 chapters and begins with a brief history of indicators, including the contribution of Robert Boyle in the field. The different kinds of indicators are also described, along with developments in indicators in the nineteenth century. The next chapter deals with the theory and principles of visual indicators, followed by a discussion on acid-base indicators such as organic dyes, inorganic substances, compounds capable of fluorescence, and chemiluminescent systems. Subsequent chapters explore other varieties of indicators, including indicators for non-aqueous acid-base titrations, metallochromic indicators, and adsorption indicators, as well as oxidation-reduction indicators and fluorescent and chemiluminescent indicators. This book will be of interest to chemists.

  • Methane

    Solubility Data Series
    • 1st Edition
    • Volume 27
    • H. Lawrence Clever
    • English
    This volume completes the compilation and critical evaluation of solubility data for the first five members of the alkane hydrocarbon series. Literature coverage is complete to mid-1985, and all relevant papers reporting the solubility of methane gas in liquids have been consulted. Where appropriate, the original data have been recalculated in different unit systems, to allow better comparison between data from different sources. This rigorous treatment results in 'recommended' solubility values which can be used with confidence.

  • Binary Systems

    Solubilities of Inorganic and Organic Compounds, Volume 1P1
    • 1st Edition
    • H. Stephen + 1 more
    • English
    Solubilities of Inorganic and Organic Compounds, Volume 1: Binary Systems, Part 1 is part of an approximately 5,500-page manual containing a selection from the International Chemical Literature on the Solubilities of Elements, Inorganic Compounds, Metallo-organic and Organic Compounds in Binary, Ternary and Multi-component Systems. A careful survey of the literature in all languages by a panel of scientists specially appointed for the task by the U.S.S.R. Academy of Sciences, Moscow, has made the compilation of this work possible. The complete English edition in five separately bound volumes will be published during 1963. Volume 1, parts 1 and 2, comprises the solubilities of elements, inorganic compounds, metallo-organic and organic compounds in binary systems. Volume II, parts 1, 2 and 3, comprises the solubilities in ternary and multi-component systems. The systematic arrangement of the compounds and the solvents together with the distinct and separate—binary, ternary, and multicomponent systems—ensures that the information required may be easily located. This manual will be of value to research workers, teaching establishments, and industry.

  • Analysis of Petroleum for Trace Elements

    International Series of Monographs on Analytical Chemistry
    • 1st Edition
    • O. I. Milner
    • R. Belcher + 1 more
    • English
    Analysis of Petroleum for Trace Elements details the methods for detecting the elements that are natural in various forms in petroleum. The book covers research and control applications, along with various types of petroleum stocks and products. The selection first covers the occurrence and importance of traces of non-hydrocarbon constituents, and then proceeds to tackling the principles and practices. The subsequent chapters cover the analytical and recommended method for analysis of a specific element, such as copper, iron, lead, and sulfur. The book will be of great use to scientists, engineers, and technicians involved in the oil industry.

  • Applications of Zeeman Graphite Furnace Atomic Absorption Spectrometry in the Chemical Laboratory and in Toxicology

    • 1st Edition
    • C. Minoia + 1 more
    • English
    The book aims at presenting an exhaustive survey of the applications of Electrothermal Atomization Atomic Absorption Spectrometry (ETA-AAS) with Zeeman background correction in a variety of fields. The unique role played by the technique in solving important analytical problems encountered today is highlighted throughout the 29 chapters which make up this multiauthored work. The overall picture that emerges from this collection of contributions testifies to the maturity reached by this instrumental methodology and lays emphasis on its capabilities, still unrivalled for many elements in terms ofoutstanding detection power afforded and minimal amounts of sample required.After an introductory chapter reviewing the major milestones of ETA-AAS over the decades, with special regard to the history and theory of the Zeeman effect and its use in background correction, the contributions which follow are distributed into four main categories, dealing with the analysis respectively of environmental samples, natural waters, foodstuffs and specimens relevant to clinical and toxicological chemistry. The substantial impact of the technique, as deduced from the literature published so far, as well as its future prospects are outlined in the final paper.

  • Compounds of the Transition Elements Involving Metal-Metal Bonds

    Pergamon Texts in Inorganic Chemistry, Volume 27
    • 1st Edition
    • D. L. Kepert + 1 more
    • English
    Compounds of the Transition Elements Involving Metal-Metal Bonds deals with compounds of the transition elements involving metal-metal bonds, with particular emphasis on metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. Factors that influence the formation, stability, and properties of such compounds, as well as their application in various fields of chemistry and physics, are discussed. This book is divided into four sections and begins with a classification of metal-metal bonds and some of the physical and chemical methods used to study them, including X-ray crystallography, magnetic susceptibility and electron spin resonance, nuclear spin resonance, Mössbauer measurements, infrared and Raman spectroscopy, visible and ultraviolet spectroscopy, mass spectrometry, electrical conductivity, electrochemical methods, and chemical reactivity. Factors influencing the strength of metal-metal bonds in metals and compounds are also examined. The remaining sections deal with metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. This monograph will be a useful resource for inorganic chemists.

  • Oxidation of Organic Compounds

    Medium Effects in Radical Reactions
    • 1st Edition
    • N. M. Emanuel + 2 more
    • M. M. Hirschler
    • English
    Oxidation of Organic Compounds: Medium Effects in Radical Reactions explores the role of solvents and of the composition of phase states in radical-chain processes involved in the oxidation of organic compounds. Organized into 10 chapters, this book begins with a discussion of the basic concepts relating to the mechanism involved in the oxidation of hydrocarbons and other organic compounds in liquid-phase reactions. Subsequent chapters detail some methods for studying the mechanism of oxidation reactions; role of solvation in chemical reaction kinetics; role of the medium in chain-initiation reactions; role of non-specific and specific solvation in chain-propagation and chain-termination reactions; and the role of solvation in chain-termination reactions in inhibitors. The influence of the solvent and the phase state of substances undergoing oxidation on the rates and mechanisms of individual elementary processes are also addressed. The last chapter examines the problem of the influence of the solid state of the polymer on the reactivity of radicals. This monograph will be valuable to scientific research workers, engineers, and engineering technologists specializing in the field of radical reactions and in particular in the oxidation of organic compounds.

  • Alkali Metal Halates, Ammonium Iodate and Iodic Acid

    Solubility Data Series
    • 1st Edition
    • Volume 30
    • H. Miyamoto + 1 more
    • English
    This volume presents compilations and critical evaluations of reported solubility data for the title compounds published up to mid-1984. These compounds have an important place in the history of analytical chemistry; practical applications include their use in pyrotechnics and the paper pulp industry. Also included are two BASIC computer programs which allow the calculation of solubilities at any temperature.

  • Computer Compilation of Molecular Weights and Percentage Compositions for Organic Compounds

    • 1st Edition
    • Michael J. S. Dewar + 1 more
    • English
    Computer Compilation of Molecular Weights and Percentage Compositions for Organic Compounds presents the outputs of computer programs that calculate the molecular weights and percentage compositions of organic compounds. The data presented in the text only covers compounds containing carbon, hydrogen, and heteroatoms, while the elements covered are bromine, chlorine, fluorine, iodine, nitrogen, oxygen, and phosphorus. The calculations of the result were conducted by Control Data Corporation 1604 computer. The book will be of great use to chemists and chemical engineers who need to have a quick access to the data on organic compounds.

  • GC/LC, Instruments, Derivatives in Identifying Pollutants and Unknowns

    • 1st Edition
    • Raymond C. Crippen
    • English
    GC/LC Instruments, Derivatives in Identifying Pollutants and Unknowns outlines the methods of identifying various components in products, processes, or discharges to the environment. This book is composed of 14 chapters that demonstrate the utility of gas and liquid chromatographs in the analysis of unknown organic compounds. The opening chapters deal with the isolation and the preparation of derivatives of various pollutants. Considerable chapters are devoted to the analysis and detection of various organic group compounds, including derivatives of acetals, acetates, acids, acid halides, ethers, amines, amino acids, anilides, barbiturates, benzamides, esters, and hydrocarbons. Other chapters cover other group compounds, such as derivatives of oxalates, oximes, peroxides, phenyl, semicarbazones, silicones, sulfur, toluidides, tri-halo acids, and alcohols. The closing chapters describe the identification techniques and instrumentation of pollutant detection. These chapters highlight the utilization of GC/LC data in physic-chemical measurements of various organic pollutants. This book will prove useful to analytical and organic chemists, environmental scientists, and researchers.

  • Macromolecules

    Main Lectures Presented at the 27th International Symposium on Macromolecules, Strasbourg, France, 6-9 July 1981
    • 1st Edition
    • H. Benoit + 1 more
    • English
    Macromolecules covers the papers presented in the 27th International Symposium on Macromolecules that tackles themes that represent the trend of development in the field of macromolecular science. The book presents papers from qualified lecturers who discuss not only their work, but also the state of knowledge, developments, and applications in the field in which they are involved. The text covers topics ranging from polymer chemistry, polymer physics, to polymer technology that illustrate the diversity of the interest of researchers involved in polymer science and show the pluridisciplinarity nature of the field. The text will be of great interest to researchers and professionals who are concerned with the advances in macromolecular science.

  • Pericyclic Reactions

    Organic Chemistry: A Series of Monographs, Vol. 35.1
    • 1st Edition
    • Alan P. Marchand + 1 more
    • English
    Pericyclic Reactions, Volume 1 covers the theoretical approaches to pericyclic reactions and pericyclic reactions of reactive intermediates and of particular reaction types. The book discusses the operational criteria for evaluation of concertedness in potential pericyclic reactions; and the Mobius-Hückel treatment of organic systems and reactions and molecular orbital following as a technique in organic chemistry. The text also describes some pericyclic reactions of carbenes and carbanions. Physicists and people involved in the study of pericyclic reactions will find the book invaluable.

  • Progress in Heterocyclic Chemistry

    A Critical Review of the 1993 Literature Preceded by Two Chapters on Current Heterocyclic Topics
    • 1st Edition
    • Volume 6
    • H. Suschitzky + 1 more
    • English
    Progress in Heterocyclic Chemistry, Volume 6, reviews critically the heterocyclic literature essentially published in 1993. The first two chapters are given over to reviews. The first review deals with the subject of the "halogen dance." The second review describes the application of selected "heterocycles as vehicles for synthesis." This type of review dealing mainly with five-membered ring transformations will prove useful to many readers. The remaining chapters describe advances in the heterocyclic field arranged according to ring-size, i.e., three-, four-, five-, six-, seven-, eight-membered rings, and larger rings. Numerous diagrams and a brief index will assist in locating areas of interest.

  • The Chemistry of Phosphorus

    Pergamon Texts in Inorganic Chemistry, Volume 3
    • 1st Edition
    • Arthur D. F. Toy
    • English

  • Advances in High Temperature Chemistry

    Volume 2
    • 1st Edition
    • Leroy Eyring
    • English
    Advances in High Temperature Chemistry, Volume 2 covers the advances in the knowledge of the high temperature behavior of materials and the complex and unfamiliar characteristics of matter at high temperature. The book discusses the dissociation energies and free energy functions of gaseous monoxides; the matrix-isolation technique applied to high temperature molecules; and the main features, the techniques for the production, detection, and diagnosis, and the applications of molecular beams in high temperatures. The text also describes the chemical research in streaming thermal plasmas, as well as the studies of the sublimation mechanism of sodium chloride, cadmium sulfide, and gallium arsenide. The temperature and emissivity measurements in the thermal imaging technique, freezing and melting point measurements of metal oxides, and phase studies on binary oxide systems at higher temperatures with a solar furnace are also encompassed. High temperature chemists and solar researchers will find the book invaluable.

  • Viscous Flows

    The Practical Use of Theory
    • 1st Edition
    • Howard Brenner
    • English
    Representing a unique approach to the study of fluid flows, Viscous Flows demonstrates the utility of theoretical concepts and solutions for interpreting and predicting fluid flow in practical applications. By critically comparing all relevant classes of theoretical solutions with experimental data and/or general numerical solutions, it focuses on the range of validity of theoretical expressions rather than on their intrinsic character.This book features extensive use of dimensional analysis on both models and variables, and extensive development of theoretically based correlating equations. The range of applicability of most theoretical solutions is shown to be quite limited; however, in combination they are demonstrated to be more reliable than purely empirical expressions, particularly in novel applications.

  • Aliphatic and Polyhalogenated Carcinogens

    Structural Bases and Biological Mechanisms
    • 1st Edition
    • Yin-Tak Woo + 2 more
    • English
    Chemical Induction of Cancer: Structural Bases and Biological Mechanisms, Volume IIIB: Aliphatic and Polyhalogenated Carcinogens covers environmentally and occupationally significant carcinogens of industrial origins. The book discusses the structure-activity relationships, metabolism, and environmental significance of the halogenated linear alkanes and alkenes and the halogenated cycloalkanes; and cycloalkene pesticides, biphenyls, and related aromatics. The text also describes the structure-activity relationships, metabolism, and environmental significance of the halogenated phenoxy acids, aromatic ethers, dibenzofurans, and dibenzo-p-dioxins; and ethylene glycol, diethylene glycol, dioxane, and related compounds. The structure-activity relationships, metabolism, and environmental significance of phenols and phenolic compounds; nitroalkanes and nitroalkenes; and acetamide, dimethylcarbamyl chloride, and related compounds thiocarbonyl compounds are also encompassed. The book further tackles the structure-activity relationships, metabolism, and environmental significance if fatty acids, detergents, and other surfactants with oncogenic potential. The text then looks into the effect of chemical reactivity, molecular geometry, and metabolism on carcinogenic activity. Chemists, geneticists, and those involved in cancer research will find the book invaluable.

  • Gas Phase Ion Chemistry

    Volume 2
    • 1st Edition
    • Michael T. Bowers
    • English
    Gas Phase Ion Chemistry, Volume 2 covers the advances in gas phase ion chemistry. The book discusses the stabilities of positive ions from equilibrium gas-phase basicity measurements; the experimental methods used to determine molecular electron affinities, specifically photoelectron spectroscopy, photodetachment spectroscopy, charge transfer, and collisional ionization; and the gas-phase acidity scale. The text also describes the basis of the technique of chemical ionization mass spectrometry; the energetics and mechanisms of unimolecular reactions of positive ions; and the photodissociation of gas-phase ions. The applications of molecular beam techniques to the study of ion-molecule collisions; as well as the variational treatment of charge transfer reactions are also encompassed. Chemists and biochemists will find the book invaluable.

  • Esters with Water

    Esters 2-C to 6-C
    • 1st Edition
    • Volume 48
    • F.W. Getzen + 2 more
    • English
    This volume is the first of two devoted to esters and water. It includes solubility data for binary systems containing an ester and water up to the end of 1988. The critical evaluations were all prepared by one author and an introductory section has been included to elaborate the philosophy and methodology followed in the evaluations.

  • Ion Exchange in Analytical Chemistry

    International Series of Monographs in Analytical Chemistry
    • 1st Edition
    • William Rieman + 1 more
    • R. Belcher + 1 more
    • English
    Analytical Chemistry, Volume 38: Ion Exchange in Analytical Chemistry provides a broad survey of the important role that ion exchange can and should play in chemical analysis. This book focuses on the plate-equilibrium theory of chromatography, which is less difficult theoretically than the mass-transfer theory. Organized into 11 chapters, this volume begins with an overview of the earliest recorded application of ion exchange. This text then examines how high temperature affects ion-exchange resins. Other chapters consider the exchange of ions between a solid ion-exchanging material and a solution, which is a typically reversible reaction. This book describes as well the relatively simple separations and other applications of ion exchange to analytical chemistry. The final chapter deals with the interesting nature of the metal complexes formed within the exchanger and describe the use of ion-exchange distribution studies to determine the stability and nature of complexes existing in the solution. This book is a valuable resource for analytical chemists.

  • Advances in Organic Geochemistry

    Proceedings of the International Meeting in Milan, 1962
    • 1st Edition
    • Umberto Colombo + 1 more
    • English
    Advances in Organic Geochemistry documents the proceedings of the First International Meeting of the European Branch of the Organic Geochemistry Group held in Milan on September 10-12, 1962. This compilation discusses research and review problems relating to the geochemistry of organic materials in the earth's crust, such as petroleum and coal, as well as less highly concentrated, but more widespread, organic matter present in various rocks, soils, and waters. Other topics covered include duplex origins of petroleum; chemical study of coal macerals; mineralized micro-structures in carbonaceous meteorites; primary investigation of the oleiferous dolerite of Dyvika; and organic residues in Jurassic oolitic limestones. Geochemical aspects of the microbial modification of carbon compounds; trace metal analysis of oils and asphalts by neutron activation techniques; and application of ultraviolet spectroscopy to the examination of dissolved organic substances in water are also deliberated in this text. This publication is beneficial to students and individuals conducting work on organic geochemistry.

  • Diffraction and Related Studies

    Proceedings of the International Symposium on Biomolecular Structure, Conformation, Function and Evolution, Madras, January 1978
    • 1st Edition
    • R. Srinivasan
    • English

  • Annual Reports in Organic Synthesis — 1975

    • 6th Edition
    • R. Bryan Miller + 1 more
    • English
    Annual Reports in Organic Synthesis – 1975 is a collection of useful information about the advancements in the field of organic chemistry. Said information is presented in the form of pictures and/or organic chemistry equations. The book covers topics such as carbon-carbon bond forming reactions; oxidations; reductions; synthesis of heterocycles; synthetic preparations; and other miscellaneous reactions. The monograph is recommended for organic chemists who would like to know more about the advancements in the field without the need to read extensive texts.

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