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Books in Chemistry

Chemistry topic areas include: physical and theoretical, computational, organic, organometallic and inorganic, pharmaceutical and medicinal, analytical and bioanalytical, nuclear, general, nanochemistry, geochemistry, materials and polymer, as well as environmental, green and sustainable chemistry.

    • New Trends in CO Activation

      • 1st Edition
      • Volume 64
      • June 25, 1991
      • L. Guczi
      • English
      • eBook
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      The aim of this volume is to provide scientists with a comprehensive summary of new research areas in the activation of carbon monoxide, as one of the most reactive molecules, and in its applications. In order to understand the variety of the reactivity of CO, a quantum-chemical approach helps the reader to understand the binding state of CO to the solid surface (Chapter 1). The structure of the adsorbed CO can be better understood by examining its reactivity towards single crystals in the absence and in the presence of promoters (Chapter 2). The first approach in the reactivity study is that of studying catalytic activity of single crystals and structure sensitivity which are summarized in Chapter 3. One of the most prominent effects in the CO activation process is ascribed to the presence of additives, promoters which, in a real catalyst system, are far more complicated than on single crystal surfaces (Chapter 4). The original Fischer-Tropsch process applied fused iron or cobalt catalysts which were suitable for producing mainly straight chain hydrocarbons. The two most important processes involving CO activation, the new FT process and alcohol formation are discussed in Chapters 5 and 7. An important type of catalyst, the bimetallic catalysts, is discussed in Chapter 6. The role of hydrogen as one of the most frequently used partners in CO activation is discussed in Chapter 8. The field of production of specialty chemicals is an excellent example of the homogeneous catalytic activation of CO (Chapter 9). In Chapter 10 an overview is given of the industrial applications of CO chemistry and these are illustrated by working processes. The final chapter gives the reader some hints about future progress in the field.
    • Stationary Phases in Gas Chromatography

      • 1st Edition
      • Volume 48
      • August 21, 1991
      • H. Rotzsche
      • English
      • Hardback
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      • Paperback
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      • eBook
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      The primary aim of this volume is to make the chemist familiar with the numerous stationary phases and column types, with their advantages and disadvantages, to help in the selection of the most suitable phase for the type of analytes under study. The book also provides detailed information on the chemical structure, physico-chemical behaviour, experimental applicability, physical data of liquid and solid stationary phases and solid supports. Such data were previously scattered throughout the literature. To understand the processes occurring in the separation column and to offer a manual both to the beginner and to the experienced chromatographer, one chapter is devoted to the basic theoretical aspects. Further, as the effectiveness of the stationary phase can only be considered in relation to the column type, a chapter on different column types and the arrangement of the stationary phase within the column is included.The secondary aim of this book is to stimulate the development of new and improved standardized stationary phases and columns, in order to improve the reproducibility of separations, as well as the range of applications.
    • Gas Chromatography in Air Pollution Analysis

      • 1st Edition
      • Volume 49
      • April 25, 1991
      • V.G. Berezkin + 1 more
      • English
      • Paperback
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      • eBook
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      Air pollution determination is one of the most important fields of gas chromatography application in practice. This book provides a systematic description of the main stages of air pollution determination, ranging from sampling problems to the quantitative estimation of the acquired data. Special attention is paid to the problem of gas, vapor, spray and solid particles extraction from air. The main methods of sampling procedure, namely, container utilization, cryogenic concentration, absorption, adsorption, chemisorption and filter usage, and successive impurities extraction are also handled. Sorption theory and the problems of sorption and desorption efficiency for hazardous impurities being extracted from traps with sorbents are discussed in detail. The practical utilization of different sorbents (silica, activated carbon, polymers etc.) to carry out sampling procedures for 200 main pollutants with known TLV (USSR and USA) is also considered. This highly informative book, reflecting several insufficiently known techniques as well as the experience of both western and Soviet researchers, should be of interest to both beginners and skilled researchers.
    • Quantum Semiconductor Structures

      • 1st Edition
      • April 28, 1991
      • Claude Weisbuch + 1 more
      • English
      • Paperback
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      • eBook
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      In its original form, this widely acclaimed primer on the fundamentals of quantized semiconductor structures was published as an introductory chapter in Raymond Dingle's edited volume (24) of Semiconductors and Semimetals. Having already been praised by reviewers for its excellent coverage, this material is now available in an updated and expanded "student edition." This work promises to become a standard reference in the field. It covers the basics of electronic states as well as the fundamentals of optical interactions and quantum transport in two-dimensional quantized systems. This revised student edition also includes entirely new sections discussing applications and one-dimensional and zero-dimensional systems.
    • Free Radical Chain Reactions in Organic Synthesis

      • 1st Edition
      • November 8, 1991
      • William B. Motherwell + 1 more
      • English
      • Hardback
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      • eBook
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      Written for both the experienced practitioner and the newcomer, this book provides essential guidance to the practical aspects of free radical chain reactions. The book presents tried and tested synthetic schemes as well as a selection of recently developed methods describing rationally designed, highly efficient syntheses giving high yield interconversions of functional groups and carbon*b1carbon bond formation under mild, neutral conditions. Written by two experienced practitioners in the field, this volume explodes the myth that free radicals are highly reactive, non-selective intermediates.
    • An Introduction to Ultrathin Organic Films

      • 1st Edition
      • April 28, 1991
      • Abraham Ulman
      • English
      • Paperback
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      • Hardback
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      • eBook
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      The development of oriented organic monomolecular layers by the Langmuir-Blodgett (LB) and self-assembly (SA) techniques has led researchers toward their goal of assembling individual molecules into highly ordered architectures. Thus the continually growing contribution of LB and SA systems to the chemistry and physics of thin organic films is widely recognized. Equally well-known is the difficulty in keeping up to date with the burgeoning multidisciplinary research in this area. Dr. Ulman provides a massive survey of the available literature. The book begins with a section on analytical tools to broaden the understanding of the structure and properties of monolayers and films. Following sections discuss LB films, the preparation and properties of SA monolayers and films, the modeling of LB and SA monolayers, and the application of LB and SA films.
    • Catalysis and Adsorption by Zeolites

      • 1st Edition
      • Volume 65
      • June 19, 1991
      • G. Öhlmann + 2 more
      • English
      • eBook
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      The proceedings of ZEOCAT 90 reflect the wide-ranging aspects of the rapidly expanding field of zeolite science and technology. The invited plenary lectures given by eminent zeolite scientists summarize current knowledge and address topical areas of zeolite research, including a contribution on the use of zeolites as membranes. The field of investigations described in the submitted articles in this volume covers a wide area of problems ranging from the influence of the synthesis process on the properties to questions of acidity, adsorption, diffusion, and catalysis. Of special interest are the newly developed applications of zeolites in the synthesis of fine chemicals, the use of zeolites for sensors and solid electrolytes, and the sophisticated zeolite-based separation processes.
    • Kinetic Models of Catalytic Reactions

      • 1st Edition
      • Volume 32
      • April 17, 1991
      • G.S. Yablonskii + 3 more
      • English
      • eBook
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      This book has been written by a group of mathematicians and chemists whose common interest is in the complex dynamics of catalytic reactions. Based on developments in mathematical chemistry, a general theory is described that allows the investigation of the relationships between the kinetic characteristics of complex reactions and their detailed reaction mechanism. Furthermore, a comprehensive analysis is made of some typical mechanism of catalytic reactions, in particular for the oxidation of carbon monoxide on platinum metals. In fact, the book presents three kinetics: (a) detailed, oriented to the elucidation of a detailed reaction mechanism according to its kinetic laws; (b) applied, with the aim of obtaining kinetic relationships for the further design of chemical reactors; and (c) mathematical kinetics whose purpose is the analysis of mathematical models for heterogeneous catalytic reactions taking place under steady- or unsteady-state conditions.