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Books in Chemistry

Chemistry topic areas include: physical and theoretical, computational, organic, organometallic and inorganic, pharmaceutical and medicinal, analytical and bioanalytical, nuclear, general, nanochemistry, geochemistry, materials and polymer, as well as environmental, green and sustainable chemistry.

    • High Pressure Phase Behaviour of Multicomponent Fluid Mixtures

      • 1st Edition
      • December 2, 2012
      • R.J. Sadus
      • English
      • Paperback
        9 7 8 0 4 4 4 5 6 4 2 8 3
      • eBook
        9 7 8 0 4 4 4 5 9 6 6 6 6
      The high pressure phase behaviour of binary fluid mixtures has been extensively studied during the last three decades. There is ample experimental data for a wide variety of binary mixtures and extensive methods for prediction have been developed. In contrast, the investigation of ternary and other multicomponent fluids is in its infancy. Experimental ternary mixture critical data are very rare and theoretical studies have been limited to data correlation rather than genuine prediction. The phase behaviour of ternary and other multicomponent fluid mixtures has many novel aspects which are not manifested in binary mixtures. The properties of ternary mixtures are also likely to be more difficult to characterize experimentally. It is in this context that calculated phase diagrams have an important role in leading the discovery of new phenomena and guiding experimental work.The criteria for phase equilibria of multicomponent fluids with particular emphasis on the critical state are examined in this book, and models for predicting fluid equilibria (e.g., different equations of state) are compared. Particular attention is paid to the critical state of ternary mixtures which has hitherto been largely neglected. The problems associated with predicting ternary equilibria are discussed, and some novel aspects of ternary critical phenomena are illustrated. The books also describes a novel type of critical transition which appears to be a common feature of the equilibria of ternary mixtures. Extensive phase diagrams of a wide range of ternary mixtures including systems containing carbon dioxide, water, nitrogen and tetrafluoromethane as one or more component are presented. The theoretical treatment is detailed in the appendix and a computation of known experimental critical points is also included.
    • Atmospheric Oxidation and Antioxidants

      • 1st Edition
      • Volume I
      • December 2, 2012
      • Bozzano G Luisa
      • English
      • Paperback
        9 7 8 0 4 4 4 5 6 4 4 0 5
      • eBook
        9 7 8 0 4 4 4 5 9 7 0 1 4
      Volume I reviews current understanding of autoxidation, largely on the basis of the reactions of oxygen with characterised chemicals. From this flows the modern mechanism of antioxidant actions and their application in stabilisation technology.
    • The Chemical Physics of Solid Surfaces

      • 1st Edition
      • December 2, 2012
      • D.A. King
      • English
      • Paperback
        9 7 8 0 4 4 4 5 6 9 5 2 3
      • eBook
        9 7 8 0 4 4 4 6 0 1 5 5 1
      The Chemical Physics of Solid Surfaces, Volume 6: Coadsorption, Promoters, and Poisons focuses on the processes, reactions, and approaches involved in coadsorption and the functions of promoters and poisons in synthesis and reactions. The selection first offers information on adsorbate-adsorbate interactions on metal surfaces and interaction between alkali metal adsorbates and adsorbed molecules. Discussions focus on coadsorption of alkali metals and other molecules; model experiments of catalyst promotion; effective medium theory; direct and indirect hybridization effects; and elastic interaction between adsorbates. The publication then ponders on coadsorption of carbon monoxide and hydrogen on metal surfaces and adsorption on bimetallic surfaces. The manuscript examines the chemical properties of alloy single crystal surfaces and promotion in ammonia synthesis. Topics include substrate dependence of nitrogen adsorption and ammonia synthesis; effects of promotion on nitrogen dissociation and ammonia synthesis; and theoretical modeling. The text then elaborates on promotion in the Fischer-Tropsch hydrocarbon synthesis, promoters and poisons in the water-gas shift reaction, and strong metal-support interactions. The selection is a recommended reference for physicists and readers interested in coadsorption, promoters, and poisons.
    • Introduction to Inductively Coupled Plasma Atomic Emission Spectrometry

      • 1st Edition
      • Volume 3
      • December 2, 2012
      • G.L. Moore
      • English
      • Paperback
        9 7 8 0 4 4 4 5 6 5 7 7 8
      • eBook
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      Today, atomic emission spectroscopy is a well-established analytical technique of widespread application - a technique that no-one involved or interested in chemical analysis can afford to ignore. The present book was written to meet the need for an extensive introduction to this technique. It is written in an easy-to-understand way, and is mainly aimed at tertiary-level students at universities and colleges, and at newcomers to the field.The book prepares the reader for the study of more advanced texts and the increasing number of research papers published in this area. It will not only be of great use to the analytical chemist, but will appeal to specialists in other fields of chemistry who need an understanding of analytical techniques. The book introduces the analytical techniques of atomic emission spectroscopy, outlining the principles, history and applications. It discusses spectrography, excitation sources, inductively coupled plasmas, instrumentation, nebulization, sample dissolution and introduction, accuracy and precision, internal standardization, plasma optimization, line selection and interferences, and inductively coupled plasma mass spectroscopy. Understanding of the material is aided by 128 illustrations, including 11 photographs. References follow each chapter, and an extensive index completes this useful work.
    • Conceptual Models In Exploration Geochemistry

      • 1st Edition
      • December 2, 2012
      • P Bradshaw
      • English
      • Paperback
        9 7 8 0 4 4 4 5 6 9 7 1 4
      • eBook
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      Conceptual Models in Exploration Geochemistry: The Canadian Cordillera and Canadian Shield is a compilation of 38 case histories from the shield and the cordillera. This volume aims to develop models ideally for the systematic description and exploration of geochemical data. These idealized models describe the principles and mechanisms of anomalies, which govern the use of exploration geochemistry. Furthermore, this volume focuses on the use of soils and sediments in exploration geochemistry. This volume is divided into four sections, the first of which is an introduction about landscape geochemistry, the idealized models, standardization of field data, and the general principles of geochemical migration. The second section consists of the idealized models and nineteen case studies obtained from the Canadian Cordillera. The third section also consists of idealized models and case studies but these were obtained from the Canadian Shield. Both the second and third sections discuss, in different views, the mineral zoning and distribution of mineralization, Pleistocene geology, physiography, climate and vegetation, and soils. This volume concludes with a discussion on orientation sampling and standardization of data collection and presentation.
    • Dielectrics in Time-Dependent Fields

      • 2nd Edition
      • December 2, 2012
      • Bozzano G Luisa
      • English
      • Paperback
        9 7 8 0 4 4 4 5 6 6 9 3 5
      • eBook
        9 7 8 0 4 4 4 6 0 0 6 9 1
      Theory of Electric Polarization, Volume II: Dielectrics in Time-Dependent Fields focuses on the processes, reactions, and principles involved in the application of dielectrics in time-dependent fields, as well as the Kerr effect, statistical mechanics, and polarization. The publication first examines the phenomenological theory of linear dielectrics in time-dependent fields; empirical description of dielectric relaxation; and the relationship between macroscopic and molecular dielectric relaxation behavior. Concerns cover the relationship between macroscopic and microscopic correlation functions; statistical mechanics of linear dissipative systems and the relationship between response functions and correlation functions; superpositions of distribution functions; and the use of complex dielectric constant in problems with time-dependent field sources. The book then ponders on the dipole correlation function, polarization in the infrared and optical frequency range, and the Kerr effect and related phenomena. Discussions focus on the Kerr effect in condensed systems, extensions of the Kerr effect, extrapolation of the refractive index to infinite wavelength, results obtained from computer simulations, rotational diffusion, and general aspects of molecular reorientation. The manuscript tackles the dielectric properties of molecular solids and liquid crystals and experimental determination of permanent dipole and quadrupole moments. The text is a valuable source of data for researchers interested in the application of dielectrics in time-dependent fields.
    • Computer-Based Medical Consultations: MYCIN

      • 1st Edition
      • December 2, 2012
      • Edward Shortliffe
      • English
      • Paperback
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      • eBook
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      Computer-Based Medical Consultations: MYCIN focuses on MYCIN, a novel computer-based expert system designed to assist physicians with clinical decisions concerning the selection of appropriate therapy for patients with infections. It discusses medical computing, artificial intelligence, and the clinical problem areas for which the MYCIN program is designed, and it describes in detail how the MYCIN program helps physicians in making decisions. Comprised of seven chapters, this volume begins with an overview of MYCIN and the criteria used in its design. It then discusses data structures and control structures in the context of prior work regarding rule-based problem-solving, inferential model building and inexact reasoning in medicine. The book also explores MYCIN'S ability to answer questions with respect to its knowledge base and the details of a specific consultation, evaluation and future extensions of the MYCIN system, the limitations and accomplishments of MYCIN, and its contributions in artificial intelligence and computer-based medical decision making. This book is a valuable source of information for computer scientists and members of the medical community.
    • Theory of Electric Polarization

      • 2nd Edition
      • December 2, 2012
      • Bozzano G Luisa
      • English
      • Paperback
        9 7 8 0 4 4 4 5 6 6 6 0 7
      • eBook
        9 7 8 0 4 4 4 6 0 0 0 6 6
      Theory of Electric Polarization: Dielectrics in Static Fields: Second Edition concerns the theory of the static behavior of dielectrics. The book reviews electric moment, electric dipoles, some concepts of, and problems of electrostatics. One problem concerns the phenomena of a conducting sphere in a homogeneous external field which was resolved using Laplace's equation. The text also discusses the work required to assemble a charge distribution, the energy of a dialectric or an induced dipole in an external field, and the electrostatic interaction of two particles. The book explores the reaction field of a polarizable or non-polarizable point dipole, the reaction field in an ellipsoidal cavity, the reaction field of an eccentric dipole in a spherical cavity, and the contribution of the permanent dipoles to the cohesion energy of a liquid. The text tackles the Onsager equation, the Debye equation, a correction to the Clausius-Mossotti equation, and the Kirkwood correlation factor. The book explains normal and anomalous saturation, electrostriction, as well as the non-linear effect due to the anisotropy of polarizability and hyperpolarizabilitie... The text can prove beneficial for researchers, investigators or scientists whose work involve organic chemistry, analytical chemistry, physical chemistry, and inorganic chemistry.
    • Research in Chemical Kinetics

      • 1st Edition
      • December 2, 2012
      • Bozzano G Luisa
      • English
      • Paperback
        9 7 8 0 4 4 4 5 6 6 0 7 2
      • eBook
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      Research in Chemical Kinetics, Volume 1 focuses on authoritative review articles on a wide range of developing topics in the kinetics of gaseous and condensed phases. The selection first elaborates on gas-phase kinetics of free radicals studied by pulse radiolysis combined with time-resolved infrared diode laser spectroscopy and solid/liquid reactions of environmental significance. Discussions focus on coprecipitation of phosphate with calcite, reactions of silica and quartz, infrared spectroscopy of free radicals, and kinetics of methyl radicals. The book then examines the collision energy dependence of reaction cross sections and photoelectrochemical dynamics, including organometallic photoelectrochemistr... and photofragmentation voltammetry, contrasting reactivity of ion radical excited states, photoelectrochemical reaction mechanisms, and experimental methods. The publication tackles collisional electronic energy transfer in CN free radicals, photo-ion imaging techniques and future directions in reactive scattering, and photoelectrochemical dynamics. Topics include photoelectrochemical reaction mechanisms, photoelectrochemical measurement of quantum yields, photofragment translational spectroscopy, and velocity distributions. The selection is a valuable reference for researchers interested in the kinetics of gaseous and condensed phases.
    • Atmospheric Oxidation and Antioxidants

      • 1st Edition
      • Volume III
      • December 2, 2012
      • Bozzano G Luisa
      • English
      • Paperback
        9 7 8 0 4 4 4 5 6 4 4 2 9
      • eBook
        9 7 8 0 4 4 4 5 9 7 0 3 8
      Volume III addresses our present understanding of how oxidation is involved both positively and negatively in life processes. This is a more recent and rapidly developing aspect of oxidation chemistry and many of the concepts still have to be proved by rigorous scientific investigation. Nevertheless, the mechanistic principles developed as a result of studies in vitro over the years now provide the basis for understanding the complex oxidation chemistry of life processes and its control by biological antioxidants.