Ionic liquids and Their Application in Green Chemistry covers the synthesis and characterization of a broad range of ionic liquids (ILs) and their polymers, along with their application in multiple areas for nanomaterials and environmental sustainability. The book provides reference material for future research in IL-based technologies for environmental and energy applications. It covers not only the conventional IL applications. but also advanced IL polymer-based materials and their application in energy storage and energy generator applications. Finally, the book discusses the major fields of application of IL-based materials in synthesis of nanomaterials and the role in graphene synthesis and its composites. Written by eminent scholars and leading experts from around the world, this book brings the literature up to date on the most recent progress in the field of IL based materials and their applications for the environmental sustainability.
Solvents are used in nearly all industries, from cosmetics to semiconductors, and from biotechnology research to iron and steel production. This book is a comprehensive and extensive textual analysis of the principles of solvent selection and use. It is a balanced presentation of solvent performance, processing characteristics, and environment and health issues. The book is intended to help formulators select ideal solvents, safety coordinators to protect workers, legislators and inspectors to define and implement technically correct public safeguards on solvent use, handling, and disposal. The third edition contains the most recent findings and trends in the solvent application. This volume, together with Vol. 2: Use, Health & Environment, Databook of Green Solvents, and Databook of Solvents, contains the most comprehensive, and up to date information ever published on solvents. Each chapter in this volume is focused on a specific aspect of solvent properties which determine its selection, such as effect on properties of solutes and solutions, properties of different groups of solvents and the summary of their applications' effect on health and environment (given in tabulated form), swelling of solids in solvents, solvent diffusion and drying processes, nature of interaction of solvent and solute in solutions, acid-base interactions, effect of solvents on spectral and other electronic properties of solutions, effect of solvents on rheology of solution, aggregation of solutes, permeability, molecular structure, crystallinity, configuration, and conformation of dissolved high molecular weight compounds, methods of application of solvent mixtures to enhance the range of their applicability, and effect of solvents on chemical reactions and reactivity of dissolved substances.
Databook of Green Solvents, Second Edition, includes data and information that is divided into five separate sections: General, Physical, Health, Environmental and Use. Readers interested in this subject should note that two other volumes on all essential areas of solvent usage have also been published. They include Handbook of Solvents. Volume One, Properties and Handbook of Solvents, Volume Two: Use, Health, and Environment. Together, these books provide the most comprehensive information on the subject matter. The books are the authoritative sources of knowledge, with information updated from the most recent literature and developments occurring in the field of solvents.
Solvents are used in nearly all industries, from cosmetics to semiconductors, and from biotechnology research to iron and steel production. This book is a comprehensive and extensive textual analysis of the principles of solvent selection and use. It is a balanced presentation of solvent performance, processing characteristics, and environment and health issues. The book is intended to help formulators select ideal solvents, safety coordinators to protect workers, legislators and inspectors to define and implement technically correct public safeguards on solvent use, handling, and disposal. The volume begins with discussion of solvent use in over 30 industries, which are the main consumers of solvents. The analysis is conducted based on available data and contains information on the types (and frequently amounts) of solvents used and potential problems and solutions. This followed by discussion of residual solvents left in final products. The environmental impact of solvents, such as their fate and movement in water, soil and air, fate-based management of solvent containing wastes, and ecotoxicological effects are discussed. Practical guidance is also provided on immediate reaction to human solvent poisoning, persistence of symptoms of solvent exposure, and effects of solvents on various parts of the human body. These expert contributions should be frequently consulted by solvent users and agencies which are responsible for protection of people in industrial environments. Possibilities for solvent substitution are also discussed, with emphasis on supercritical solvents, ionic liquids, ionic melts, and agriculture-based products. Solvent recycling, removal from contaminated air, and degradation are covered.
Mechanics of Liquids and Gases, Second Edition is a 10-chapter text that covers significant revisions concerning the dynamics of an ideal gas, a viscous liquid and a viscous gas. After an expanded introduction to the fundamental properties and methods of the mechanics of fluids, this edition goes on dealing with the kinetics and general questions of dynamics. The next chapters describe the one-dimensional pipe flow of a gas with friction, the elementary theory of the shock tube; Riemann's theory of the wave propagation of finite intensity, and the theory of plane subsonic and supersonic flows. Other chapters consider the elements of the theory of three-dimensional subsonic and supersonic flows past bodies; the fluctuating laminar flow in a uniform pipe of circular cross-section; the hydrodynamic theory of lubrication; the variational principle of Helmholtz; and the theory of plane and axisymmetric laminar jets. The remaining chapters look into the semi-empirical theories of turbulence and their application in the analysis of axisymmetric jets, with and without swirl, and in the calculation of the resistance of rough plates. These chapters also discuss the dynamics of a viscous gas and the elements of the theory of laminar and turbulent boundary layers at high speeds. This book will be of value to mechanical engineers, physicists, and researchers.
Black Liquor Gasification (BLG) is a first of its kind to guide chemical engineers, students, operators of paper plants, technocrats, and entrepreneurs on practical guidelines and a holistic techno-enviro-economic perspective applicable to their future or existing projects based on the treatment of black liquor for energy production. BLG describes the gasification process as a more efficient alternative to current processes for the conversion of black liquor biomass into energy. BLG operates largely in sync with other methods to improve pulp-making efficiency. This book explains how BLG offers a way to generate electricity and to reclaim pulping chemicals from black liquor, and why BLG would replace the Tomlinson recovery boiler for the recovery of spent chemicals and energy.
Pressure, like temperature, is one of the most important parameters governing the state of matter. Today, high-pressure science and technology is applied to diverse research fields: physics, chemistry, biology, earth and marine sciences, material science and technology, chemical engineering, biotechnology and medicine. Research on liquids and solutions at high pressure is not only important for elucidating the structure of liquids, intermolecular interactions between solutes and solvents and chemical reactions in solutions, but also for providing fundamental numerical data for the design of chemical plants and the development of chemical processes. In particular, high-pressure studies of water and aqueous solutions are closely correlated with research into bioscience and biotechnology.In this volume some of the most important and most recent advances in liquids and solutions at high pressure in Japan are presented.
This compilation - the first of its kind - fills a real gap in the field of electrolyte data. Virtually all self-diffusion data in electrolyte solutions as reported in the literature have been examined and the book contains over 400 tables covering diffusion in binary and ternary aqueous solutions, in mixed solvents, and of non-electrolytes in various solvents.An important feature of the compilation is that all data have been critically examined and their accuracy assessed. Other features are an introductory chapter in which the methods of measurement are reviewed; appendices containing tables of the limiting self-diffusion coefficients of ions; and a list of references to data which have been omitted but where information about the diffusing system is given.This is the only complete compilation of self-diffusion data in electrolyte solutions. It will appeal to electrochemists in general, particularly now that recent developments in the theory of transport processes require these data. It will also have a special appeal to electroanalytical chemists in that the ionic self-diffusion coefficient is an important quantity for the interpretation of electrode reactions. In addition, the book will interest geochemists and environmental chemists because the migration of radioactive ions from nuclear waste in certain aqueous media will be governed by the tracer-diffusion coefficient.
Comprehensive coverage of topics in the theory of classical liquids Widely regarded as the standard text in its field, Theory of Simple Liquids gives an advanced but self-contained account of liquid state theory within the unifying framework provided by classical statistical mechanics. The structure of this revised and updated Fourth Edition is similar to that of the previous one but there are significant shifts in emphasis and much new material has been added. Major changes and Key Features in content include: Expansion of existing sections on simulation methods, liquid-vapour coexistence, the hierarchical reference theory of criticality, and the dynamics of super-cooled liquids. New sections on binary fluid mixtures, surface tension, wetting, the asymptotic decay of pair correlations, fluids in porous media, the thermodynamics of glasses, and fluid flow at solid surfaces. An entirely new chapter on applications to 'soft matter' of a combination of liquid state theory and coarse graining strategies, with sections on polymer solutions and polymer melts, colloidal dispersions, colloid-polymer mixtures, lyotropic liquid crystals, colloidal dynamics, and on clustering and gelation.
Inductively coupled plasma atomic or mass spectrometry is one of the most common techniques for elemental analysis. Samples to be analyzed are usually in the form of solutions and need to be introduced into the plasma by means of a sample introduction system, so as to obtain a mist of very fine droplets. Because the sample introduction system can be a limiting factor in the analytical performance, it is crucial to optimize its design and its use. It is the purpose of this book to provide fundamental knowledge along with practical instructions to obtain the best out of the technique.