Chemical thermodynamics print books and ebooks | Elsevier

Modern Engineering Thermodynamics

1st Edition
January 25, 2011
Robert Balmer
English
eBook
9 7 8 0 0 8 0 9 6 1 7 3 6

Modern Engineering Thermodynamics is designed for use in a standard two-semester engineering thermodynamics course sequence. The first half of the text contains material suitable for a basic Thermodynamics course taken by engineers from all majors. The second half of the text is suitable for an Applied Thermodynamics course in mechanical engineering programs. The text has numerous features that are unique among engineering textbooks, including historical vignettes, critical thinking boxes, and case studies. All are designed to bring real engineering applications into a subject that can be somewhat abstract and mathematical. Over 200 worked examples and more than 1,300 end of chapter problems provide opportunities to practice solving problems related to concepts in the text.

The Yaws Handbook of Vapor Pressure: Antoine Coefficients

1st Edition
December 1, 2007
Carl L. Yaws
English
Hardback
9 7 8 1 9 3 3 7 6 2 1 0 4

Covering the properties of over 8,200 compounds, this volume, written by the world’s leading authority on chemical engineering, is more comprehensive and thorough than any other book of its kind. Antoine coefficients are one of the most important properties to industry processes, and Carl Yaws provides all the skills necessary for every chemical engineer, both academic and experienced. Understanding Antoine coefficients for vapor pressure extends to numerous other practical engineering processes, such as pure components in storage vessels, the concentration of species in vapor, relief valve design, as well as emissions into the environment from exposed liquids. The properties listed in The Yaws Handbook of Vapor Pressure: Antoine Coefficients are useful when calculating: Bubble point temperatures or pressures Dew point temperatures or pressures Vapor-liquid equilibrium And many other processes, for distillation columns, phase separators, and other mass transfer process equipment. Not available anywhere else, the information in this handbook is a valuable addition to any engineer’s library.

Solution Thermodynamics and its Application to Aqueous Solutions

1st Edition
October 3, 2007
Yoshikata Koga
English
eBook
9 7 8 0 0 8 0 5 5 1 8 7 6

As the title suggests, we introduce a novel differential approach to solution thermodynamics and use it for the study of aqueous solutions. We evaluate the quantities of higher order derivative than the normal thermodynamic functions. We allow these higher derivative data speak for themselves without resorting to any model system. We thus elucidate the molecular processes in solution, (referred to in this book “mixing scheme”), to the depth equal to, if not deeper, than that gained by spectroscopic and other methods. We show that there are three composition regions in aqueous solutions of non-electrolytes, each of which has a qualitatively distinct mixing scheme. The boundary between the adjacent regions is associated with an anomaly in the third derivatives of G. The loci of the anomalies in the temperature-composit... field form the line sometimes referred as “Koga line”. We then take advantage of the anomaly of a third derivative quantity of 1-propanol in the ternary aqueous solution, 1-propanol – sample species – H2O. We use its induced change as a probe of the effect of a sample species on H2O. In this way, we clarified what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H2O. We also apply the same methodology to ions that have been ranked by the Hofmeister series. We show that the kosmotropes (salting out, or stabilizing agents) are either hydrophobes or hydration centres, and that chaotropes (salting in, or destablizing agents) are hydrophiles.

Introduction to Non-equilibrium Physical Chemistry

1st Edition
September 12, 2007
R. P. Rastogi
English
Hardback
9 7 8 0 4 4 4 5 2 1 8 8 0
eBook
9 7 8 0 0 8 0 5 5 1 8 0 7

Introduction to Non-equilibrium Physical Chemistry presents a critical and comprehensive account of Non-equilibrium Physical Chemistry from theoretical and experimental angle. It covers a wide spectrum of non-equilibrium phenomena from steady state close to equilibrium to non-linear region involving transition to bistability, temporal oscillations, spatio-temporal oscillations and finally to far from equilibrium phenomena such as complex pattern formation, dynamic instability at interfaces, Chaos and complex growth phenomena (fractals) in Physico-chemical systems. Part I of the book deals with theory and experimental studies concerning transport phenomena in membranes (Thermo-osmosis,Elec... ) and in continuous systems (Thermal diffusion,Soret effect) close to equilibrium Experimental tests provide insight into the domain of validity of Non-equilibrium Thermodynamics ,which is the major theoretical tool for this region. Later developments in Extended Irreversible Thermodynamics and Non-equilibrium Molecular dynamics have been discussed in the Appendix. Part II deals with non-linear steady states and bifurcation to multistability, temporal and spatio- temporal oscillations (Chemical waves). Similarly Part II deals with more complex phenomena such as Chaos and fractal growth occurring in very far from equilibrium region. Newer mathematical techniques for investigating such phenomena along with available experimental studies. Part IV deals with analogous non-equilibrium phenomena occurring in the real systems (Socio-political, Finance and Living systems etc.) for which physico-chemical systems discussed in earlier chapters provide a useful model for development of theories based on non-linear science and science of complexity.

Nonequilibrium Thermodynamics

2nd Edition
August 31, 2007
Yasar Demirel
English
eBook
9 7 8 0 0 8 0 5 5 1 3 6 4

Natural phenomena consist of simultaneously occurring transport processes and chemical reactions. These processes may interact with each other and lead to instabilities, fluctuations, and evolutionary systems. This book explores the unifying role of thermodynamics in natural phenomena. Nonequilibrium Thermodynamics, Second Edition analyzes the transport processes of energy, mass, and momentum transfer processes, as well as chemical reactions. It considers various processes occurring simultaneously, and provides students with more realistic analysis and modeling by accounting possible interactions between them. This second edition updates and expands on the first edition by focusing on the balance equations of mass, momentum, energy, and entropy together with the Gibbs equation for coupled processes of physical, chemical, and biological systems. Every chapter contains examples and practical problems to be solved. This book will be effective in senior and graduate education in chemical, mechanical, systems, biomedical, tissue, biological, and biological systems engineering, as well as physical, biophysical, biological, chemical, and biochemical sciences.

Yaws Handbook of Thermodynamic Properties

1st Edition
January 1, 2007
Carl L. Yaws
English
Hardback
9 7 8 1 9 3 3 7 6 2 0 7 4

Written by one of the most prolific and well-respected chemical engineers in the industry, this is the most comprehensive and thorough volume ever written on the thermodynamic properties of hydrocarbons and chemicals. This volume covers the spectrum, including chapters on the heat capacity and entropy of gas, solids and liquids, the entropy of formation, and many other topics. The design of heat exchangers and other equipment for heating or cooling substances to temperatures necessary in process applications requires knowledge of heat capacity, covered in the first portion of the book. The heat effects of chemical reactions are ascertained from enthalpy of formation. Other chapters cover the Helmholtz energy of formation and internal energy of formation, which is useful in modeling and ascertaining the energy of explosions. This coverage greatly exceeds the coverage of any other book and makes The Yaws Handbook of Thermodynamic Properties of Hydrocarbons and Chemicals a must-have for anyone working in the fields of chemical engineering, process engineering, refining and chemistry.

Critical Temperatures for the Thermal Explosion of Chemicals

1st Edition
Volume 7
November 18, 2005
Takashi Kotoyori
English
eBook
9 7 8 0 0 8 0 4 6 1 3 9 7

The value of the critical temperature (Tc), below which the thermal explosion of a chemical cannot occur, is indispensable to prevent such a chemical from exploding. In order to determine the Tc it has so far been necessary to measure the value in explosion experiments. Because of the inherent hazards, only few Tc values are available at present. Critical Temperatures for the Thermal Explosion of Chemicals introduces new and simple procedures to calculate the Tc. As a result Tc can be calculated for a range of chemicals, many of which are listed in this new volume. The calculated values of Tc are shown to be in agreement with experimentally determined values. The data and methods presented in Critical Temperatures for the Thermal Explosion of Chemicals will be of use to research laboratories as well as in the chemical industry.

The Corresponding-States Principle and its Practice

1st Edition
July 26, 2005
Hong Wei Xiang
English
eBook
9 7 8 0 0 8 0 4 5 9 0 4 2

The corresponding-states principle helps the understanding and calculating of thermodynamic, transport, and surface properties of substances in various states, required by our modern lifestyle. The Corresponding-States Principle and its Practice: Thermodynamic, Transport and Surface Properties of Fluids describes the origins and applications of the principle from a universal point of view with comparisons to experimental data where possible. It uses the universal theory to explain present theories. Emphasis is on the properties of pure systems, and the corresponding-states theory can also be extended to mixtures, which are treated as pure systems. Furthermore, the author discusses current progress, and shows technicians how to derive practical equations from molecular modeling. The Corresponding-States Principle and its Practice: Thermodynamic, Transport and Surface Properties of Fluids is the ideal handbook for those in chemical science and engineering related to energy, environment, natural gas, and petroleum.

Chemical Thermodynamics of Selenium

1st Edition
Volume 7
April 16, 2005
OECD
English
eBook
9 7 8 0 0 8 0 4 5 7 5 1 2

In order to quantitatively predict the chemical reactions that hazardous materials may undergo in the environment, it is necessary to know the relative stabilities of the compounds and complexes that may be found under certain conditions. This type of calculations may be done using consistent chemical thermodynamic data, such as those contained in this book for inorganic compounds and complexes of selenium.

Computer Aided Property Estimation for Process and Product Design

1st Edition
Volume 19
June 30, 2004
Georgios M. Kontogeorgis + 1 more
English
eBook
9 7 8 0 0 8 0 4 7 2 2 8 7

Properties of chemical compounds and their mixtures are needed in almost every aspect of process and product design. When the use of experimental data is not possible, one of the most widely used options in the use of property estimation models. Computer Aided Property Estimation for Process and Product Design provides a presentation of the most suitable property estimation models available today as well as guidelines on how to select an appropriate model. Problems that users are faced with, such as: which models to use and what their accuracy is, are addressed using a systematical approach to property estimation. The volume includes contributions from leading experts from academia and industry. A wide spectrum of properties and phase equilibria types is covered, making it indispensable for research, development and educational purposes.

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