This fully updated and revised fifth edition of Nonequilibrium Thermodynamics: Transport and Rate Processes in Physical, Chemical, and Biological Systems emphasizes the unifying role of thermodynamics and their use in transport processes and chemical reactions in physical, chemical, and biological systems. This reorganized new edition provides thermodynamical approaches for foundational understanding of natural phenomena with multiscale chemical, physical, and biological systems, consisting of interactive processes leading to self-organized dissipative structures, fluctuations, and instabilities. This edition also emphasizes thermodynamic approaches, tools, and techniques, including energy analysis, process intensification, and artificial intelligence, for undertaking sustainable engineering.This book will be an excellent resource for graduate students and researchers in the fields of engineering, chemistry, physics, energy, biotechnology, and biology, as well as those whose work involves understanding the evolution of nonequilibrium systems, information theory, stochastic processes, and sustainable engineering. This may also be useful to professionals working in irreversibility, dissipative structures, process exergy analysis and thermoeconomics, digitalization in manufacturing, and data processing.
Industrial and Process Furnaces: Principles, Design and Operation, Third Edition continues to provide comprehensive coverage on all aspects of furnace operation and design, including topics essential for process engineers and operators to better understand furnaces. New to this edition are sections on production, handling and utilization of alternative fuels such as biomass, hydrogen and various wastes, modeling of the process, combustion and heat transfer, their benefits, advantages and limitations, mitigation and removal of CO2 , the role of solar and other renewable energy, recent research, and the practical approach of the Whyalla steelworks for harnessing solar energy for sustainable steelmaking, hydrogen and as a "clean fuel". The book also includes a discussion on the limitations of hydrogen supply owing to fresh water supply constraints, the difficulty of storing and transporting hydrogen, and the current sociopolitical impetus of CO2.
Thermodynamic Models for Chemical Engineering gives an overview of the main thermodynamic models used by engineers and in engineering researcher processes. These fall into two main families, equations of state and activity coefficient models. The book presents the state-of-the-art of purely predictive models.
Complexity and Complex Chemo-Electric Systems presents an analysis and synthesis of chemo-electric systems, providing insights on transports in electrolytes, electrode reactions, electrocatalysis, electrochemical membranes, and various aspects of heterogeneous systems and electrochemical engineering. The book describes the properties of complexity and complex chemo-electric systems as the consequence of formulations, definitions, tools, solutions and results that are often consistent with the best performance of the system. The book handles cybernetics, systems theory and advanced contemporary techniques such as optimal control, neural networks and stochastic optimizations (adaptive random search, genetic algorithms, and simulated annealing). A brief part of the book is devoted to issues such as various definitions of complexity, hierarchical structures, self-organization examples, special references, and historical issues. This resource complements Sieniutycz’ recently published book, Complexity and Complex Thermodynamic Systems, with its inclusion of complex chemo-electric systems in which complexities, emergent properties and self-organization play essential roles.
Thermodynamics: Principles Characterizing Physical and Chemical Processes, Fifth Edition is an authoritative guide on the physical and chemical processes based on classical thermodynamic principles. Emphasis is placed on fundamental principles, with a combination of theory and practice that demonstrates their applications in a variety of disciplines. Revised and updated to include new material and novel formulations, this edition features a new chapter on algebraic power laws and Fisher information theory, along with detailed updates on irreversible phenomena, Landau theory, self-assembly, Caratheodory’s theorem, and the effects of externally applied fields. Drawing on the experience of its expert author, this book is a useful tool for both graduate students, professional chemists, and physicists who wish to acquire a more sophisticated overview of thermodynamics and related subject matter.
Entropy of Complex Processes and Systems formalizes our understanding of many complex processes, including the development of the methodology of analytical computation of complex processes as applied in many industries, such as ore processing, or more generally, in areas of natural sciences. The adequacy of the results of these calculations is confirmed by numerous experimental data obtained both on pilots and industrial facilities. The book also provides a thorough analysis of the underlying physical foundations of entropy performed from new standpoints that are of interest to theoreticians studying contemporary expositions.
Complexity and Complex Thermoeconomic Systems describes the properties of complexity and complex thermo-economic systems as the consequence of formulations, definitions, tools, solutions and results consistent with the best performance of a system. Applying to complex systems contemporary advanced techniques, such as static optimization, optimal control, and neural networks, this book treats the systems theory as a science of general laws for functional integrities. It also provides a platform for the discussion of various definitions of complexity, complex hierarchical structures, self-organization examples, special references, and historical issues. This book is a valuable reference for scientists, engineers and graduated students in chemical, mechanical, and environmental engineering, as well as those in physics, ecology and biology, helping them better understand the complex thermodynamic systems and enhance their technical skills in research.
Nonequilibrium Thermodynamics: Transport and Rate Processes in Physical, Chemical and Biological Systems, Fourth Edition emphasizes the unifying role of thermodynamics in analyzing natural phenomena. This updated edition expands on the third edition by focusing on the general balance equations for coupled processes of physical, chemical and biological systems. Updates include stochastic approaches, self-organization criticality, ecosystems, mesoscopic thermodynamics, constructual law, quantum thermodynamics, fluctuation theory, information theory, and modeling the coupled biochemical systems. The book also emphasizes nonequilibrium thermodynamics tools, such as fluctuation theories, mesoscopic thermodynamic analysis, information theories, and quantum thermodynamics in describing and designing small scale systems.
Generalized van der Waals Theory of Molecular Fluids in Bulk and at Surfaces presents successful research on the development of a new density theory of fluids that makes it possible to understand and predict a wide range of properties and phenomena. The book brings together recent advances relating to the Generalized van der Waals Theory and its use in fluid property calculations. The mathematics presentation is oriented to an audience of varying backgrounds, and readers will find exercises that can be used as a textbook for a course at the upper undergraduate or graduate level in physics or chemistry. In addition, it is ideal for scientists from other areas, such as geophysics, oceanography and molecular biology who are interested in learning about, and understanding, molecular fluids.
Energy Optimization in Process Systems and Fuel Cells, Third Edition covers the optimization and integration of energy systems, with a particular focus on fuel cell technology. With rising energy prices, imminent energy shortages, and the increasing environmental impacts of energy production, energy optimization and systems integration is critically important. The book applies thermodynamics, kinetics and economics to study the effect of equipment size, environmental parameters, and economic factors on optimal power production and heat integration. Author Stanislaw Sieniutycz, highly recognized for his expertise and teaching, shows how costs can be substantially reduced, particularly in utilities common in the chemical industry. This third edition contains substantial revisions and modifications, with new material on catalytic reactors, sorption systems, sorbent or catalyst regenerators, dryers, and more.