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Elsevier

Books in Chemical kinetics

  • Elementary Kinetic Modelling in Catalytic Reaction Engineering

    • 1st Edition
    • Joris W. Thybaut + 5 more
    • English
    Elementary Kinetic Modelling in Catalytic Reaction Engineering is a practical focused text that brings together the relevant basics for reaction engineering and shows their applications to a wide variety of examples, whilst looking at the intrinsic kinetics data acquisition, reaction mechanism elucidation, elementary step-based modelling and model-based design and optimization involved.The book aims at spanning the entire process from acquisition of the relevant data in dedicated experimental set-ups, over the proper treatment of the data and the corresponding interpretation up to the quantification of the gained understanding in a model. The latter aspect allows the reader to challenge the interpretation made of the data and design subsequent experiments or improve the interpretation/model formulation. The coverage is not just limited to the generic (theoretical) principles but will also carefully consider and explain their application to a variety of real-life applications including gas- and liquid-phase reactions, heterogeneously catalyzed reactions involving adsorption either in the Henry regime or at full saturation of the catalyst or combined homogeneous-heteroge... reactions.Elementary Kinetic Modelling in Catalytic Reaction Engineering is written primarily for graduate students and postdoc researchers in chemical engineering or applied industrial chemistry studying chemical reaction engineering and catalysis, as well as physical chemists studying kinetics.

  • Catalytic Kinetics

    Chemistry and Engineering
    • 2nd Edition
    • Dmitry Yu Murzin + 1 more
    • English
    Catalytic Kinetics: Chemistry and Engineering, Second Edition offers a unified view that homogeneous, heterogeneous, and enzymatic catalysis form the cornerstone of practical catalysis. The book has an integrated, cross-disciplinary approach to kinetics and transport phenomena in catalysis, but still recognizes the fundamental differences between different types of catalysis. In addition, the book focuses on a quantitative chemical understanding and links the mathematical approach to kinetics with chemistry. A diverse group of catalysts is covered, including catalysis by acids, organometallic complexes, solid inorganic materials, and enzymes, and this fully updated second edition contains a new chapter on the concepts of cascade catalysis. Finally, expanded content in this edition provides more in-depth discussion, including topics such as organocatalysis, enzymatic kinetics, nonlinear dynamics, solvent effects, nanokinetics, and kinetic isotope effects.

  • Advances in Mathematical Chemistry and Applications: Volume 1

    • 1st Edition
    • Subhash C. Basak + 2 more
    • English
    Advances in Mathematical Chemistry and Applications highlights the recent progress in the emerging discipline of discrete mathematical chemistry. Editors Subhash C. Basak, Guillermo Restrepo, and Jose Luis Villaveces have brought together 27 chapters written by 68 internationally renowned experts in these two volumes. Each volume comprises a wise integration of mathematical and chemical concepts and covers numerous applications in the field of drug discovery, bioinformatics, chemoinformatics, computational biology, mathematical proteomics, and ecotoxicology. Volume 1 includes chapters on mathematical structural descriptors of molecules and biomolecules, applications of partially ordered sets (posets) in chemistry, optimal characterization of molecular complexity using graph theory, different connectivity matrices and their polynomials, use of 2D fingerprints in similarity-based virtual screening, mathematical approaches to molecular structure generation, comparability graphs, applications of molecular topology in drug design, density functional theory of chemical reactivity, application of mathematical descriptors in the quantification of drug-likeness, utility of pharmacophores in drug design, and much more.

  • Theoretical Chemistry

    Theory of Scattering: Papers in Honor of Henry Eyring
    • 1st Edition
    • Douglas W. Henderson
    • English
    Theoretical Chemistry: Theory of Scattering: Papers in Honor of Henry Eyring, Volume 6, Part A covers the aspects of reactive and nonreactive scattering. The book discusses the applications of classical trajectory to reactive scattering and the accurate quantum calculations of reactive systems. The text also describes the fluctuations in chemically reacting systems, as well as the coupling of electronically adiabatic states in atomic and molecular collisions. Chemists, physicists, people involved in the study of the theory of scattering, and students taking related courses will find the book useful.

  • Stability and Stabilization of Enzymes

    Proceedings of an International Symposium Held in Maastricht, The Netherlands, 22-25 November 1992
    • 1st Edition
    • Volume 47
    • W.J.J. van den Tweel + 2 more
    • English
    These proceedings contain most of the oral presentations and posters of the international symposium on Stability and Stabilization of Enzymes held in Maastricht in November 1992. They provide a comprehensive overview of the state-of-the-art in this field.The possible applications of enzymes are enormous. Years of development have seen many enzymes brought onto the market, but they are still expensive to use. Therefore, their efficient application is a prerequisite for common usage. One of the main factors for this efficiency is the stability of the enzymes. The topics thus ranged from the extensive fundamental thermodynamic knowledge gathered in academic research to the practical applied knowledge built up in industry during the time that enzymes have been produced commercially.The subject Stability and Stabilization of Enzymes was discussed from various points of view, as was reflected in the themes of the symposium sessions. In the session on Fundamentals of Enzyme Stabilisation the thermodynamic background of the phenomenon was highlighted. In yet another session, the recently developed analytical tools to measure enzyme stability and stabilisation were discussed. Further sessions comprised the physical, chemical and biological ways to obtain enzyme stabilisation and finally, the industrial practice of enzyme stabilisation was treated by representatives of the world's most important enzyme producers. The book will be of interest to researchers in universities and industry in the fields of biochemistry, enzymology and biotechnology.

  • Atmospheric Oxidation and Antioxidants

    • 1st Edition
    • Volume II
    • Bozzano G Luisa
    • English
    This volume examines the oxidation chemistry of carbon-based materials in more detail with emphasis on the technological phenomena that result from the attack of oxygen and the practical procedures developed to prevent them.

  • The Theory of Kinetics

    • 1st Edition
    • Volume 2
    • R.G. Compton + 2 more
    • English
    The Theory of Kinetics covers the practice and theory of kinetics and the kinetics of inorganic and organic reactions in gaseous and condensed phases and at interfaces. This text is composed of five chapters and starts with a review of the kinetic characterization of complex reaction systems. The succeeding chapter describes the formal and radical kinetics, as well as the energy factor in chain reactions. These topics are followed by a survey of the theory of the kinetics of elementary gas phase reactions and the unimolecular reaction of activated chemical species. The discussion then shifts to the general properties, reactions, and the theory of elementary reactions in solution. The last chapter examines the theory of kinetics of solid-state reactions. This book is of great value to physical, inorganic, and organic chemists.

  • Research in Chemical Kinetics

    • 1st Edition
    • Bozzano G Luisa
    • English
    This is the second volume in a new series, which aims to publish authoritative review articles on a wide range of exciting and contemporary topics in gas and condensed phase kinetics. Research in Chemical Kinetics complements the acclaimed series Comprehensive Chemical Kinetics, and is edited by the same team of professionals.The reviews contained in this volume are concise, topical accounts of specific research written by acknowledged experts. The authors summarize their latest work and place it in a general context. Particular strengths of the volume are the quality of the contributions and their topicality, and the rapid publication realized.

  • Atmospheric Oxidation and Antioxidants

    • 1st Edition
    • Volume I
    • Bozzano G Luisa
    • English
    Volume I reviews current understanding of autoxidation, largely on the basis of the reactions of oxygen with characterised chemicals. From this flows the modern mechanism of antioxidant actions and their application in stabilisation technology.

  • Research in Chemical Kinetics

    • 1st Edition
    • Bozzano G Luisa
    • English
    This series of volumes aims to publish authoritative review articles on a wide range of exciting and contemporary topics in gas and condensed phase kinetics. Research in Chemical Kinetics complements the acclaimed series Comprehensive Chemical Kinetics, and is edited by the same team of professionals.The reviews contained in this volume are concise, topical accounts of specific research written by acknowledged experts. The authors summarize their latest work and place it in a general context. Particular strengths of the volume are the quality of the contributions and their topicality, and the rapid publication realized.

  • Research in Chemical Kinetics

    • 1st Edition
    • Bozzano G Luisa
    • English
    Research in Chemical Kinetics, Volume 1 focuses on authoritative review articles on a wide range of developing topics in the kinetics of gaseous and condensed phases. The selection first elaborates on gas-phase kinetics of free radicals studied by pulse radiolysis combined with time-resolved infrared diode laser spectroscopy and solid/liquid reactions of environmental significance. Discussions focus on coprecipitation of phosphate with calcite, reactions of silica and quartz, infrared spectroscopy of free radicals, and kinetics of methyl radicals. The book then examines the collision energy dependence of reaction cross sections and photoelectrochemical dynamics, including organometallic photoelectrochemistr... and photofragmentation voltammetry, contrasting reactivity of ion radical excited states, photoelectrochemical reaction mechanisms, and experimental methods. The publication tackles collisional electronic energy transfer in CN free radicals, photo-ion imaging techniques and future directions in reactive scattering, and photoelectrochemical dynamics. Topics include photoelectrochemical reaction mechanisms, photoelectrochemical measurement of quantum yields, photofragment translational spectroscopy, and velocity distributions. The selection is a valuable reference for researchers interested in the kinetics of gaseous and condensed phases.

  • Advances in Chemical Engineering

    Solution Thermodynamics
    • 1st Edition
    • Volume 39
    • English
    An important challenge brought to chemical engineering by new emerging technologies, in particular then by nano and bio technologies, is to deal with complex systems that cannot be dealt with and cannot be fully understood on a single scale. This volume of Advances in Chemical Engineering provides a framework for thermodynamic and kinetic modeling of complex chemical systems.

  • Thermodynamics of Non-Equilibrium Processes for Chemists with a Particular Application to Catalysis

    • 1st Edition
    • V. Parmon
    • English
    Thermodynamics of Non-Equilibrium Processes for Chemists with a Particular Application to Catalysis consists of materials adapted from lectures on the thermodynamics of nonequilibrium processes that have been taught at the Department of Natural Sciences of Novosibirsk State University since 1995. The thermodynamics of nonequilibrium processes traditionally required students to have a strong background in physics. However, the materials featured in this volume allow anyone with knowledge in classical thermodynamics of equilibrium processes and traditional chemical kinetics to understand the subject. Topics discussed include systems in the thermodynamics of irreversible processes; thermodynamics of systems that are close to and far from equilibrium; thermodynamics of catalysts; the application of nonequilibrium thermodynamics to material science; and the relationship between entropy and information. This book will be helpful for research into complex chemical transformations, particularly catalytic transformations.

  • Advances in Chemical Engineering

    Photocatalytic Technologies
    • 1st Edition
    • Volume 36
    • English
    The cross-fertilization of physico-chemical and mathematical ideas has a long historical tradition. This volume of Advances in Chemical Engineering is almost completely dedicated to a conference on “Mathematics in Chemical Kinetics and Engineering” (MaCKiE-2007), which was held in Houston in February 2007, bringing together about 40 mathematicians, chemists, and chemical engineers from 10 countries to discuss the application and development of mathematical tools in their respective fields.

  • Principles of Chemical Kinetics

    • 2nd Edition
    • James E. House
    • English
    James House's revised Principles of Chemical Kinetics provides a clear and logical description of chemical kinetics in a manner unlike any other book of its kind. Clearly written with detailed derivations, the text allows students to move rapidly from theoretical concepts of rates of reaction to concrete applications. Unlike other texts, House presents a balanced treatment of kinetic reactions in gas, solution, and solid states. The entire text has been revised and includes many new sections and an additional chapter on applications of kinetics. The topics covered include quantitative relationships between molecular structure and chemical activity, organic/inorganic chemistry, biochemical kinetics, surface kinetics and reaction mechanisms. Chapters also include new problems, with answers to selected questions, to test the reader's understanding of each area. A solutions manual with answers to all questions is available for instructors. A useful text for both students and interested readers alike, Dr. House has once again written a comprehensive text simply explaining an otherwise complicated subject.

  • An Introduction to Aspects of Thermodynamics and Kinetics Relevant to Materials Science

    • 3rd Edition
    • Eugene Machlin
    • English
    This book is based on a set of notes developed over many years for an introductory course taught to seniors and entering graduate students in materials science. An Introduction to Aspects of Thermodynamics and Kinetics Relevant to Materials Science is about the application of thermodynamics and kinetics to solve problems within Materials Science. Emphasis is to provide a physical understanding of the phenomenon under discussion, with the mathematics presented as a guide. The problems are used to provide practice in quantitative application of principles, and also to give examples of applications of the general subject matter to problems having current interest and to emphasize the important physical concepts. End of chapter problems are included, as are references, and bibliography to reinforce the text. This book provides students with the theory and mathematics to understand the important physical understanding of phenomena.

  • Chemical Kinetics

    From Molecular Structure to Chemical Reactivity
    • 1st Edition
    • Luis Arnaut + 1 more
    • English
    Chemical Kinetics bridges the gap between beginner and specialist with a path that leads the reader from the phenomenological approach to the rates of chemical reactions to the state-of-the-art calculation of the rate constants of the most prevalent reactions: atom transfers, catalysis, proton transfers, substitution reactions, energy transfers and electron transfers. For the beginner provides the basics: the simplest concepts, the fundamental experiments, and the underlying theories. For the specialist shows where sophisticated experimental and theoretical methods combine to offer a panorama of time-dependent molecular phenomena connected by a new rational. Chemical Kinetics goes far beyond the qualitative description: with the guidance of theory, the path becomes a reaction path that can actually be inspected and calculated. But Chemical Kinetics is more about structure and reactivity than numbers and calculations. A great emphasis in the clarity of the concepts is achieved by illustrating all the theories and mechanisms with recent examples, some of them described with sufficient detail and simplicity to be used in general chemistry and lab courses.

  • Catalytic Kinetics

    • 1st Edition
    • Dmitry Yu Murzin + 1 more
    • English
    Chemistry and chemical technology have been at the heart of the revolutionary developments of the 20th century. The chemical industry has a long history of combining theory (science) and practice (engineering) to create new and useful products. Worldwide, the process industry (which includes chemicals, petrochemicals, petroleum refining, and pharmaceuticals) is a huge, complex, and interconnected global business with an annual production value exceeding 4 trillion dollars. Although in industry special focus is in heterogeneous catalysis, homogeneous, enzymatic, photochemical and electrochemical catalysis should not be overlooked; as the major aim is to produce certain chemicals in the best possible way, applying those types of catalysis, which suit a particular process in the most optimal way. Catalysis according to the very definition of it deals with enhancement of reaction rates, that is, with catalytic kinetics. This book unifies the main sub disciplines forming the cornerstone of catalytic kinetics.

  • Kinetics of Multistep Reactions

    • 2nd Edition
    • Volume 40
    • Friedrich G. Helfferich
    • English
    This book addresses primarily the engineer in industrial process development, the research chemist in academia and industry, and the graduate student intending to become a reaction engineer. In industry, competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such development should be based on "fundamental" kinetics that reflect the elementary steps of which the reaction consists. The book forges fundamental kinetics into a practical tool by presenting new, effective methods for elucidation of mechanisms and reduction of complexity without unacceptable sacrifice in accuracy: fewer equations (lesser computational load), fewer coefficients (fewer experiment to determine them). For network elucidation, new rules relating network configurations to observable kinetic behaviour allow incorrect networks to be ruled out by whole classes instead of one by one. For modelling, general equations and algorithms are given from which equations for specific networks can be recovered by simple substitutions. The procedures are illustrated with examples of industrial reactions including, among others, paraffin oxidation, ethoxylation, hydroformylation, hydrocyanation, shape-selective catalysis, ethane pyrolysis, styrene polymerization, and ethene oligomerization. Many of the rate equations have not been published before. The expanded edition of the 2001 title, Kinetics of Homogeneous Multistep Reactions includes new chapters on heterogeneous catalysis and periodic and chaotic re-actions; new sections on adsorption, statistical methods, and lumping; and other new detail.

  • Biosensors: Kinetics of Binding and Dissociation Using Fractals

    • 1st Edition
    • Ajit Sadana
    • English
    This title brings to the attention of researchers in the industry, and in academia, the application of fractals to help in modeling the analyte/receptor binding and dissociation kinetics on biosensor surfaces.The work builds on that done in Engineering Biosensors: Kinetics and Design Applications, published by Academic Press in 2002. In particular, more examples are provided of where biosensors may be effectively used. This sequel is extremely timely, given the anticipation that the applications and reliance on biosensors will increase due to the advances in miniaturization, (wireless) communications, and the development of new materials (especially biological and chemical). Other applications of biosensors on the increase can be found in: the protection of civilian structures and infrastructures; protection from possible biological and chemical threats; health care; energy; food safety; and the environment to name a few.

  • Energetic Materials

    Part 2. Detonation, Combustion
    • 1st Edition
    • Volume 13
    • English
    This volume provides an overview of current research and recent advances in the area of energetic materials, focusing on explosives and propellants. The contents and format reflect the fact that theory, experiment and computation are closely linked in this field. The challenge of developing energetic materials that are less sensitive to accidental stimuli continues to be of critical importance. This volume opens with discussions of some determinants of sensitivity and its correlations with various molecular and crystal properties. The next several chapters deal in considerable detail with different aspects and mechanisms of the initiation of detonation, and its quantitative description. The second half of this volume focuses upon combustion. Extensive studies model ignition and combustion, with applications to different propellants. The final chapter is an exhaustive computational treatment of the mechanism and kinetics of combustion initiation reactions of ammonium perchlorate.Overall, this volume illustrates the progress that has been made in the field of energetic materials and some of the areas of current activity. It also indicates the challenges involved in characterizing and understanding the properties and behaviour of these compounds. The work is a unique state-of-the-art treatment of the subject, written by pre-eminent researchers in the field.

  • Comprehensive Chemical Kinetics

    Unimolecular Kinetics, Part 1. The Reaction Step
    • 1st Edition
    • Volume 39
    • Nicholas Green
    • English
    Unimolecular reactions are in principle the simplest chemical reactions, because they only involve one molecule. The basic mechanism, in which the competition between the chemical reaction step and a collisional deactivation leads to a pressure-dependent coefficient, has been understood for a long time. However, this is a rapidly developing field, and many new and important discoveries have been made in the past decade.This First Part Part of Two CCK Volumes dealing with Unimolecular Rections, deals with the Reaction Step. The first chapter is an introduction to the whole project, aiming to cover the material necessary to understand the content of the detailed chapters, as well as the history of the development of the area. Chapter 2 is a review of the modern view of the statistical theories, as embodied in the various forms of RRKM theory. Chapter 3 deals with the fully quantum mechanical view of reactive states as resonances.

  • Chemical Kinetics: Fundamentals and Recent Developments

    • 1st Edition
    • Evgeny Denisov + 2 more
    • English
    Comprehensive manual embracing essentially all the classical and modern areas of chemical kinetics. Provides details of modern applications in chemistry, technology and biochemistry.Special sections of the book treat subjects not covered sufficiently in other manuals, including: modern methods of experimental determination of rate constants of reactions including laser pico- and femtochemistry, magnetochemistry, and ESR; and descriptions of advanced theories of elementary chemical processes.

  • Experimental Methods in Kinetic Studies

    • 1st Edition
    • Bohdan Wojciechowski + 1 more
    • English
    This book is a guide to kinetic studies of reaction mechanisms. It reviews conventional reactor types and data collection methods, and introduces a new methodology for data collection using Temperature Scanning Reactors (TSR). It provides a theoretical and practical approach to temperature scanning (TS) methodology and supports a revival of kinetic studies as a useful approach to the fundamental understanding of chemical reaction mechanisms and the consequential reaction kinetics.

  • Non-Linear Mass Transfer and Hydrodynamic Stability

    • 1st Edition
    • C.B. Boyadjiev + 1 more
    • English
    Surveyed in this book are the kinetics of non-linear mass transfer and its effects on hydrodynamic stability in systems with intensive interphase mass transfer, in electrochemical systems with high current density and in chemically reacting systems.In Part 1 the non-linear mass transfer as a result of an intensive interphase mass transfer in the gas (liquid)-solid surface, gas-liquid and liquid-liquid systems is considered in the duffusion boundary layer approximation as well as in flat channel taking the longitudinal diffusion into account. The influence of the direction of the intensive interphase mass transfer on heat transfer and multi-component mass transfer is illustrated.Part 2 discusses non-linear mass transfer in electrochemical systems with high current density using the examples of the anode dissolving of metals in the electrolyte flow and the electro-separation of metals out of concentrated solutions. The theory of the measured electrochemical treatment of metals and alloys, which is a method of wide practical use, has been elaborated on this basis.In Part 3 the non-linear mass transfer in chemically reacting systems is considered in the cases of: non-linearity of the equations of the chemical reaction's kinetics and intensive interphase mass transfer or thermo-capillary effect due to chemical reactions. On this basis, the mechanisms and the macro-kinetics of the chemical transformations in the gas-liquid systems are discussed.Part 4 is dedicated to the chemical reaction kinetics in stationary two phase systems at an arbitrary contact time between phases.In Part 5 the effects of concentration gradients are considered in the approximations of the linear theory of the hydrodynamic stability of almost parallel flows.In systems with intensive interphase mass transfer, the Marangoni effect could also be observed, beside the effect of non-linear mass transfer. A comparative analysis of both effects is made in this book.

  • Fundamental Chemical Kinetics

    An Explanatory Introduction to the Concepts
    • 1st Edition
    • M R Wright
    • English
    The unusual approach of this text gives final honours and post-graduate students a clear and explanatory account of one of the “harder” areas of physical chemistry. The author takes care to provide detailed verbal clarification of the concepts and their importance together with full explanations of the mathematical developments. Her explanations are an essential and vital feature of the text, which is scholarly, lucid and well-written with a combination of depth of coverage and clarity which helps students to work through on their own.

  • Applications of Kinetic Modelling

    • 1st Edition
    • Volume 37
    • G. Hancock + 1 more
    • English
    Volume 37 is concerned with the use and role of modelling in chemical kinetics and seeks to show the interplay of theory or simulation with experiment in a diversity of physico-chemical areas in which kinetics measurements provide significant physical insight. Areas of application covered within the volume include electro- and interfacial chemistry, physiology, biochemistry, solid state chemistry and chemical engineering.A leading contributor to this general area has been Professor W. John Albery, FRS, to whom the contributors and editors dedicate this book.

  • Reaction Kinetics and the Development of Catalytic Processes

    Proceedings of the International Symposium, Brugge, Belgium, April 19-21, 1999
    • 1st Edition
    • Volume 122
    • G.F. Froment + 1 more
    • English
    The symposium "Reaction Kinetics and the Development of Catalytic Processes" is the continuation of the very successful International Symposium "Dynamics of Surfaces and Reaction Kinetics in Heterogeneous Catalysis", held in September 1997 in Antwerp, Belgium. These proceedings contain a unique series of top level plenary lectures mainly focused on• the dynamics of catalytic surfaces• the interaction of the reacting molecules with the solid catalyst• the elementary steps of reaction pathways and molecular kinetics.Surface science techniques, molecular modeling, transient kinetic studies, sophisticated and specific reactors are included to a growing extent in the kinetic modeling and the development of catalytic processes. How this is practiced today and how it will evolve in the coming years, and what benefit can be expected for a more fundamentally based approach is the aim of the symposium.

  • Photokinetics

    Theoretical Fundamentals and Applications
    • 1st Edition
    • Volume 36
    • H. Mauser + 1 more
    • English
    Many books cover the determination of rate constants under different experimental conditions and different chemical composition of the reaction mixture in their formal treatment of thermal kinetics. However, most textbooks are limited to simple mechanisms. In contrast, analogous treatment of photochemical reactions is limited to the publication of special reactions and investigations. Therefore, this book is aimed at providing an overall description of formal photokinetics covering a wider scope than the usual books on kinetics.This volume attempts to provide a concise treatment of both thermo- and photochemical reactions by means of generalised differential equations, their set-up in matrix notation, and their solution by a formalism using numerical integration. At a first glance this approach might be surprising. However, apart from the argument that the didactics of thermal reactions are easier to handle than those of kinetics, the book provides additional reasons in support of this approach. Therefore, the formalism derived allows the evaluation of photochemical reactions, which are superimposed thermal reactions taking into account that the amount of light absorbed varies during the reaction. Because of this, any approximation, either by using total absorbance or negligible absorbance, will cause considerable errors even for simple reactions. The approach chosen to transform the axis of the radiation time into a new variable that includes the photokinetic factor proves that formal kinetics can be applied to thermal and photochemical reactions as well, and even allows the handling of solutions that cannot be homogenised or solid samples in which the concentration varies locally. By using this approach to introduce partial photochemical quantum yields even complex mechanisms can be determined quantitatively.A large number of examples for different mechanisms and an introduction to many spectroscopic and chromatographic methods suitable for photokinetic analyses are provided to enable the reader to carry out a step-by-step evaluation of his own measurements. To reduce the number of formula in some chapters an appendix has been included which contains a detailed description of the calculus of some essential examples. For the convenience of the reader the following has been included:• A large number of examples describing the use of formula• A detailed description of the procedure for applying photokinetics to complex consecutive photoreactions• An Internet address where the reader can find a tutorial for this procedure:http://www... A simple macro to help in programming his own evaluation procedure.

  • Low-temperature Combustion and Autoignition

    • 1st Edition
    • Volume 35
    • M.J. Pilling
    • English
    Combustion has played a central role in the development of our civilization which it maintains today as its predominant source of energy. The aim of this book is to provide an understanding of both fundamental and applied aspects of low-temperature combustion chemistry and autoignition. The topic is rooted in classical observational science and has grown, through an increasing understanding of the linkage of the phenomenology to coupled chemical reactions, to quite profound advances in the chemical kinetics of both complex and elementary reactions. The driving force has been both the intrinsic interest of an old and intriguing phenomenon and the centrality of its applications to our economic prosperity. The volume provides a coherent view of the subject while, at the same time, each chapter is self-contained.

  • Modern Aspects of Diffusion-Controlled Reactions

    Cooperative Phenomena in Bimolecular Processes
    • 1st Edition
    • Volume 34
    • E. Kotomin + 1 more
    • English
    This monograph deals with the effects of reactant spatial correlations arising in the course of basic bimolecular reactions describing defect recombination, energy transfer and exciton annihilation in condensed matter. These effects lead to the kinetics considered abnormal from the standard chemical kinetics point of view. Numerous bimolecular reaction regimes and conditions are analysed in detail. Special attention is paid to the development and numerous applications of a novel, many-point density (MPD) formalism, which is based on Kirkwood's superposition approximation used for decoupling three-particle correlation functions.The book demonstrates that incorporation of the reaction-induced spatial correlations of similar reactants (e.g., vacancy-vacancy) leads to the development of an essentially non-Poisson spectrum of reactant density fluctuations. This can completely change the kinetics at longer times since it no longer obeys the law of mass action. The language of the correlation lengths and critical exponents similar to physics of critical phenomena is used instead. A relation between MPD theory and synergistics is discussed. The validity of the theorem giving a critical complexity for the two-step reactions exhibiting self-organization phenomena is questioned. Theoretical results are illustrated by numerous experimental data.

  • Advances in Detailed Reaction Mechanisms

    Synthetically Useful Reactions
    • 1st Edition
    • James M. Coxon
    • English
    Advances in Detailed Reaction Mechanisms, Volume 4: Synthetically Useful Reactions focuses on synthetically useful reactions, including transition-metal-med... cycloadditions, the use of organoselenium, organozinc, and metal-arene complexes. This book discusses flavonoid synthesis by cyclization of hydrochalcone. Organized into six chapters, this volume begins with an overview of the mechanistic issues related to a number of metal-mediated cycloaddition reactions that are significant in the context of organic synthesis. This text then examines the basic reaction types that generate carbon–carbon bonds. Other chapters consider enzyme and metal-ion-catalyzed isomerization of sugars. This book discusses as well the reaction patterns inherent in polyfunctional organic molecules that are associated with functional groups. The final chapter deals with the nonenzymatic and enzyme-catalyzed-sca... industrial production triggered by commercial applications. This book is a valuable resource for organic synthesis chemists. Scientists and research workers who are interested in synthetically useful reactions will also find this book extremely useful.

  • Kinetic Models of Catalytic Reactions

    • 1st Edition
    • Volume 32
    • G.S. Yablonskii + 3 more
    • English
    This book has been written by a group of mathematicians and chemists whose common interest is in the complex dynamics of catalytic reactions. Based on developments in mathematical chemistry, a general theory is described that allows the investigation of the relationships between the kinetic characteristics of complex reactions and their detailed reaction mechanism. Furthermore, a comprehensive analysis is made of some typical mechanism of catalytic reactions, in particular for the oxidation of carbon monoxide on platinum metals. In fact, the book presents three kinetics: (a) detailed, oriented to the elucidation of a detailed reaction mechanism according to its kinetic laws; (b) applied, with the aim of obtaining kinetic relationships for the further design of chemical reactors; and (c) mathematical kinetics whose purpose is the analysis of mathematical models for heterogeneous catalytic reactions taking place under steady- or unsteady-state conditions.

  • Electron Tunneling in Chemistry

    • 1st Edition
    • Volume 30
    • R.F. Khairutdinov + 2 more
    • English
    In Volume 30, an attempt is made to consider comprehensively both theoretical and experimental data that have been obtained to date on electron tunneling reactions involving chemical compounds of various classes, and to discuss the role played by these reactions in different areas of chemistry. The discussion of the above problem is preceded by a review of data on tunneling phenomena in nuclear physics, atomic physics, solid-state physics, as well as on the tunneling effects in chemistry that go beyond the framework of the main subject of this monograph. This review is included to acquaint the reader with the role of tunneling phenomena in physics and chemistry as a whole, to show how diversified the kingdom of tunneling phenomena is, and to see more distinctly the similarities and the differences between electron tunneling in chemical reactions and other tunnel phenomena.

  • Reactions at the Liquid-Solid Interface

    • 1st Edition
    • Volume 28
    • R.G. Compton
    • English
    Volume 28 of Comprehensive Chemical Kinetics is concerned with reactions occurring at the solid-liquid interface. Volumes 26 and 27 have dealt with electrochemical reactions. The present volume therefore covers those interfacial processes which involve no net passage of current. The first chapter covers the structure of the interfacial region and its experimental investigation. The second chapter reviews the mechanisms by which heterogeneous catalysis of solution reactions can take place. The third is concerned with the mechanism and kinetics of crystal growth from solution. The final chapter deals with corrosion processes at the metal-solution interface.

  • New Techniques for the Study of Electrodes and Their Reactions

    • 1st Edition
    • Volume 29
    • R.G. Compton
    • English
    Volume 29 gives an account of new techniques for the study of electrodes and their reactions. It extends and complements Volumes 26 and 27 of the series which provide an introductory treatment of modern electrochemical methodology and reactions. This volume covers the various branches of spectroelectrochemis... and also some recent purely electrochemical advances. In-situ spectroelectrochemic... techniques are covered by chapters on infrared, Raman, EPR, ellipsometry, electroreflectance, and photocurrent spectroscopy. Ex-situ UHV experiments are treated in a separate chapter. New electrochemical directions are described in chapters on hydrodynamic methods, channel electrodes, and microelectrodes. A final chapter covers computing strategies for the on-line accumulation and processing of electrochemical data.

  • Electrode Kinetics: Reactions

    • 1st Edition
    • Volume 27
    • R.G. Compton
    • English
    Volumes 26 and 27 are both concerned with reactions occurring at electrodes arising through the passage of current. They provide an introduction to the study of electrode kinetics. The basic ideas and experimental methodology are presented in Volume 26, whilst Volume 27 deals with reactions at particular types of electrodes.Chapter 1 of the present volume deals with redox reactions at metal electrodes, Chapter 2 with semiconducting electrodes and Chapter 3 with reactions at metal oxide electrodes. Both theoretical aspects and experimental results are covered.

  • Electrode Kinetics: Principles and Methodology

    • 1st Edition
    • Volume 26
    • C.H. Bamford + 2 more
    • English
    Volumes 26 and 27 are both concerned with reactions occurring at electrodes arising through the passage of current. They provide a comprehensive review of the study of electrode kinetics. The basic ideas and experimental methodology are presented in Volume 26 whilst Volume 27 deals with reactions at particular types of electrodes.Chapter 1 serves as an introduction to both volumes and is a survey of the fundamental principles of electrode kinetics. Chapter 2 deals with mass transport - how material gets to and from an electrode. Chapter 3 provides a review of linear sweep and cyclic voltammetry which constitutes an extensively used experimental technique in the field. Chapter 4 discusses a.c. and pulse methods which are a rich source of electrochemical information. Finally, chapter 5 discusses the use of electrodes in which there is forced convection, the so-called ``hydrodynamic electrodes''.

  • Reactions of Solids with Gases

    • 1st Edition
    • Volume 21
    • C.H. Bamford + 2 more
    • English

  • Simple Processes at the Gas-Solid Interface

    • 1st Edition
    • Volume 19
    • R.G. Compton + 2 more
    • English

  • Liquid Phase Oxidation

    • 1st Edition
    • Volume 16
    • C.H. Bamford + 2 more
    • English

  • Reactions in the Solid State

    • 1st Edition
    • Volume 22
    • Michael E. Brown + 2 more
    • English
    The whole of Volume 22 is devoted to the kinetics and mechanisms of the decomposition and interaction of inorganic solids, extended to include metal carboxylates. After an introductory chapter on the characteristic features of reactions in the solid phase, experimental methods of investigation of solid reactions and the measurement of reaction rates are reviewed in Chapter 2 and the theory of solid state kinetics in Chapter 3. The reactions of single substances, loosely grouped on the basis of a common anion since it is this constituent which most frequently undergoes breakdown, are discussed in Chapter 4, the sequence being effectively that of increasing anion complexity. Chapter 5 covers reactions between solids, and includes catalytic processes where one solid component remains unchanged, double compound formation and rate processes involving the interactions of more than three crystalline phases. The final chapter summarises the general conclusions drawn in the text of Chapter 2-5.

  • The Practice of Kinetics

    • 1st Edition
    • Volume 1
    • R.G. Compton + 2 more
    • English

  • Complex Catalytic Processes

    • 1st Edition
    • Volume 20
    • C.H. Bamford + 2 more
    • English

  • Proton Transfer

    • 1st Edition
    • Volume 8
    • C.H. Bamford + 2 more
    • English

  • Reactions of Non-Metallic Inorganic Compounds

    • 1st Edition
    • Volume 6
    • R.G. Compton + 2 more
    • English

  • Decomposition of Inorganic and Organometallic Compounds

    • 1st Edition
    • Volume 4
    • C.H. Bamford + 2 more
    • English

  • Reactions of Metallic Salts and Complexes, and Organometallic Compounds

    • 1st Edition
    • Volume 7
    • C.H. Bamford + 2 more
    • English

  • Electrophilic Substitution at a Saturated Carbon Atom

    • 1st Edition
    • Volume 12
    • C.H. Bamford + 2 more
    • English

  • Ester Formation and Hydrolysis and Related Reactions

    • 1st Edition
    • Volume 10
    • R.G. Compton + 2 more
    • English