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Structure and Dynamics of Solutions
- 1st Edition, Volume 79 - October 22, 2013
- Editors: H. Ohtaki, H. Yamatera
- Language: English
- eBook ISBN:9 7 8 - 1 - 4 8 3 2 - 9 1 4 2 - 0
Recent advances in the study of structural and dynamic properties of solutions have provided a molecular picture of solute-solvent interactions. Although the study of thermodynamic… Read more
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Request a sales quoteIt is possible to develop a sound microscopic picture for reaction dynamics in solution without molecular-level knowledge of how reacting ionic or neutral species are solvated and how rapidly the molecular environment is changing with time. A variety of actual examples is given as to how and when modern molecular approaches can be used to solve specific solution problems. The following tools are discussed: x-ray and neutron diffraction, EXAFS, and XANES, molecular dynamics and Monte Carlo computer simulations, Raman, infrared, NMR, fluorescence, and photoelectron emission spectroscopic methods, conductance and viscosity measurements, high pressure techniques, and statistical mechanics methods. Static and dynamic properties of ionic solvation, molecular solvation, ion-pair formation, ligand exchange reactions, and typical organic solvents are useful for bridging the gap between classical thermodynamic studies and modern single-molecule studies in the gas phase.
The book will be of interest to solution, physical, inorganic, analytical and structural chemists as well as to chemical kineticists.
- Language: English
- Edition: 1
- Volume: 79
- Published: October 22, 2013
- Imprint: Elsevier Science
- eBook ISBN: 9781483291420
HO
H. Ohtaki
HY