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Some Electrical and Optical Aspects of Molecular Behaviour
The Commonwealth and International Library: Chemistry Division
- 1st Edition - January 1, 1965
- Author: Mansel Davies
- Editors: Robert Robinson, H. M. N. H. Irving, L. A. K. Staveley
- Language: English
- Paperback ISBN:9 7 8 - 1 - 4 8 3 1 - 8 0 3 3 - 5
- eBook ISBN:9 7 8 - 1 - 4 8 3 1 - 9 6 1 4 - 5
Some Electrical and Optical Aspects of Molecular Behaviour deals with dipole moments, molecular science, and molecular polarizability. The author explains the refractive index and… Read more
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Inside Front Cover One
Inside Front Cover Two
Some Numerical Constants
Preface
Chapter 1: An Introduction
Publisher Summary
Examples
Chapter 2: The Refractive Index and the Electric Permittivity
Publisher Summary
Polarization and Polarizability
The Mossotti-Clausius Equation
The Molar Polarization
The Molar Refraction
Polar Compounds
The Measurement of the Permittivity, ε′
The Debye Equation
Approximate Dipole Moments Evaluated from Solution Data
Other Methods of Dipole Moment Determination
Examples
Chapter 3: Molecular Dipole Moments
Ionic Character of Diatomic Molecules
Other Ionic Molecules
Vector Character of Dipole Moments
Group Moments and Molecular Structure
Intramolecular Rotation
Examples
Chapter 4: The Limitations and Extensions of the Simple (Debye) Treatment of the Molar Polarization
Publisher Summary
The Dipole Concentration
The Onsager Equation
Water and Hydrogen-bonded Liquids
Examples
Chapter 5: Dielectric Dispersion and Molecular Behaviour
Publisher Summary
Phase Angle and Dielectric Loss
The Pellat-Debye Equations
Experimental Study of Dielectric Absorption
Water
Polar Solutes in Non-polar Solvents
Organic Solids
Ionic and Polar Solids
Examples
Chapter 6: Aspects of Molecular Polarizability
Light Scattering
Light Scattering and the Molecular Weight of Solutes
Measurement of Light Scattering by Solutions
Dissymmetric Light Scattering and Molecular Shape
Depolarization of Scattered Light
Anisotropy of the Polarizability
The Kerr Effect
The Data and Interpretation of Molecular Anisotropy
Polarizability and Optical Activity
The Helical Model
The Raman Effect
Summary
Examples
Chapter 7: Electric Forces Between Molecules
Publisher Summary
Ion-Ion
Ion-Dipole
Two Rigid Dipoles
Induced Dipole
Ion-Induced Dipole
Dipole-Induced Dipole
Dispersion (or London) Energy
Quadrupole Moments
Repulsion Energy
Intermolecular Interaction Energies
Dipole Interactions
Ionic Interaction Energies
Examples
Numerical Answers to Examples
Index
- No. of pages: 200
- Language: English
- Edition: 1
- Published: January 1, 1965
- Imprint: Pergamon
- Paperback ISBN: 9781483180335
- eBook ISBN: 9781483196145
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