Reactions of Importance in Synthesis
- 1st Edition - January 1, 1994
- Latest edition
- Editor: James M. Coxon
- Language: English
Advances in Detailed Reaction Mechanisms, Volume 3: Reactions of Importance in Synthesis presents the development, discoveries, and understanding of reactions of importance in… Read more
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Advances in Detailed Reaction Mechanisms, Volume 3: Reactions of Importance in Synthesis presents the development, discoveries, and understanding of reactions of importance in synthesis. This book discusses the significance of the reaction to organic synthesis. Organized into seven chapters, this volume begins with an overview of the effects of Lewis acids, aldehyde structure, and addition order upon the diastereoselectivity. This text then discusses the origin of the differences in reactivity and energy between the substrate and transition state conformations. Other chapters consider the influence of organometallic chemistry on the development of methodology in organic synthesis. This book discusses as well the diversity of possible facially dissymmetric dienes and dienophiles, which can be persuaded to undergo a Diels–Alder reaction. The final chapter deals with the variety of methods for the construction of carbocyclic rings. This book is a valuable resource for industrial chemists, graduate students, postdoctoral fellows, and those teaching specialized topics to graduate students.
Contents
List of Contributors
Introduction to The Series: An Editor's Foreword
Preface
Stereochemistry and Mechanism of Allylic Tin-Aldehyde Condensation Reactions
Stereoeletronic Rules in Addition Reactions: "Cram's Rule" in Olefinic Systems
1,4-Addition Reactions of Organocuprates with α,β-Unsaturated Ketones
Diastereofacial Selectivity in the Diels-Alder Reaction
Template Effects of Distannoxanes
N-Alkylation of Nitrogen Azoles
Generation and Cyclization of Unsaturated Organolithiums
Index
- Edition: 1
- Latest edition
- Published: January 1, 1994
- Language: English