
Raney Nickel-Assisted Synthesis of Heterocycles
- 1st Edition - April 14, 2022
- Imprint: Elsevier Science
- Author: Navjeet Kaur
- Language: English
- Paperback ISBN:9 7 8 - 0 - 3 2 3 - 9 9 4 9 2 - 7
- eBook ISBN:9 7 8 - 0 - 3 2 3 - 9 9 4 9 3 - 4
Raney Nickel-Assisted Synthesis of Heterocycles covers the synthesis of heterocycles using Raney nickel. The book focuses on the use of Raney-Ni, a common catalyst in hydrogena… Read more
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Raney Nickel-Assisted Synthesis of Heterocycles covers the synthesis of heterocycles using Raney nickel. The book focuses on the use of Raney-Ni, a common catalyst in hydrogenation reaction and its uses in the synthesis and preparation of heterocycles. Furthermore, it explains how the development of new approaches and strategic deployments in known approaches for the formation of complex heterocyclic compounds continue to drive the field of synthetic organic chemistry, along with updates on efforts to prepare heterocycles through the development of new and efficient synthetic transformations.
Heterocyclic chemistry is an inexhaustible source of novel compounds, providing the most diverse chemical, physical and biological properties through the design of a wide range of combinations of carbon, hydrogen and heteroatoms. Significant focus has been paid to novel approaches to the formation of heterocyclic compounds, which are of practical use acting as modifiers and additives in a wide range of industries such as reprography, plastics, cosmetics, vulcanization accelerators, solvents, antioxidants and information storage.
- Presents complete coverage of Raney Nickel assisted reactions
- Includes the discovery, reactivities, advantages, disadvantages and other characteristics of Raney nickel
- Presents new methodologies for the synthesis of heterocycles
1. Raney nickel-assisted nitro group reduction for the synthesis of five-membered N-heterocycles
1.1 Introduction
1.2 Nitro group reduction involved in the synthesis of pyrroles
1.3 Nitro group reduction involved in the synthesis of fused pyrroles
1.4 Nitro group reduction involved in the synthesis of indoles
1.5 Nitro group reduction involved in the synthesis of fused indoles
1.6 Nitro group reduction involved in the synthesis of pyrazoles
1.7 Nitro group reduction involved in the synthesis of imidazoles and benzimidazoles
1.8 Nitro group reduction involved in the synthesis of triazoles
References
2. Reduction of NO2 group with Raney nickel for the synthesis of heterocycles
2.1 Introduction
2.2 Reduction of NO2 group for the synthesis of five-membered O- and S-heterocycles
2.3 Reduction of NO2 group for the synthesis of six-membered N-heterocycles
2.4 Reduction of NO2 group for the synthesis of six-membered N,N-heterocycles
2.5 Reduction of NO2 group for the synthesis of six-membered N,N,N-heterocycles
2.6 Reduction of NO2 group for the synthesis of six-membered O-heterocycles
2.7 Reduction of NO2 group for the synthesis of seven-membered heterocycles
References
3. Synthesis of heterocycles from cyanide, oxime, and azo substrates using Raney nickel
3.1 Introduction
3.2 Synthesis of heterocycles from cyanide substrates
3.3 Synthesis of five-membered heterocycles from cyanide substrates
3.4 Synthesis of six-membered heterocycles from cyanide substrates
3.5 Synthesis of seven-membered heterocycles from cyanide substrates
3.6 Synthesis of heterocycles from oxime substrates
3.7 Synthesis of five-membered heterocycles from oxime substrates
3.8 Synthesis of six-membered heterocycles from oxime substrates
3.9 Synthesis of heterocycles from azo substrates
References
4. Synthesis of heterocycles from oxazoles and oxazines using Raney nickel
4.1 Introduction
4.2 Synthesis of heterocycles from oxazoles and oxazines
4.3 Synthesis of five-membered N-heterocycles from oxazoles
4.4 Synthesis of five-membered N-heterocycles from oxazines
4.5 Synthesis of five-membered fused N-heterocycles from oxazoles and oxazines
4.6 Synthesis of five-membered O-heterocycles from oxazoles and oxazines
4.7 Synthesis of six-membered heterocycles from oxazoles and oxazines
4.8 Synthesis of higher-membered heterocycles from oxazoles and oxazines
References
5. Raney nickel for the synthesis of heterocycles
5.1 Introduction
5.2 Synthesis of five-membered N-heterocycles
5.3 Synthesis of five-membered N-polyheterocycles
5.4 Synthesis of five-membered fused N-heterocycles
5.5 Synthesis of five-membered N,N-heterocycles
5.6 Synthesis of five-membered N,N,N-heterocycles
5.7 Synthesis of five-membered O-heterocycles
5.8 Synthesis of five-membered O,N- and S-heterocycles
5.9 Synthesis of six-membered N-heterocycles
5.10 Synthesis of six-membered N,N-heterocycles
5.11 Synthesis of six-membered O-heterocycles
5.12 Synthesis of seven-membered heterocycles
References
- Edition: 1
- Published: April 14, 2022
- Imprint: Elsevier Science
- Language: English
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