Phosphorus
An Outline of Its Chemistry, Biochemistry and Technology
- 2nd Edition, Volume 2 - January 1, 1980
- Latest edition
- Author: D.E.C. Corbridge
- Language: English
Studies in Inorganic Chemistry 2, Phosphorus: An Outline of Its Chemistry, Biochemistry and Technology, Second Edition deals with the organic, inorganic, biochemical, physical,… Read more
Studies in Inorganic Chemistry 2, Phosphorus: An Outline of Its Chemistry, Biochemistry and Technology, Second Edition deals with the organic, inorganic, biochemical, physical, environmental, and technical aspects of phosphorus chemistry. This book is composed of 11 chapters and starts with a brief background of phosphorus with the recognition of three major allotropic modifications of elemental phosphorus. The chemical composition of phosphorus is analyzed as containing either three, four, five, or six oxygen atoms linked to a central phosphorus atom. Simple phosphorus nitrides and other related compounds are also dealt with, including compounds with P-NH2 linkages, P-NF2 linkages, and amides with P-N and P-C linkages. One kind of orthophosphate esters is analyzed, because it is numerous, involved in many life processes, and has various applications in industry and the sciences. Phosphorus sulfur compounds, polyphosphines, ring compounds, and high polymers are also described. This book further discusses the production through the combination of phosphine with borane that gives rise to more varieties of possible phosphorus-boron hydrides, and then explains the simplest but a hypothetical compound known as H2b-Ph2. Attention is also given to the preparation and study of metal-coordination compounds, of which the P atom retains at least an approximate tetrahedral bond configuration. Finally, the chemical methods for the detection and estimation of phosphorus in a compound are explained, where a prior oxidation and/or hydrolysis should first be considered. This text is intended for university undergraduate levels in the discipline of general chemistry. This book can also be a useful reference for research workers and technologists dealing with phosphorus chemistry.
Chapter 1 Introduction and Background 1.1 Historical 1.2 Distribution and Environment 1.3 Atomic Properties and Bonding 1.4 Equilibria and Stereochemistry 1.5 Types of Reaction 1.6 Bond Strengths and Bond LengthsChapter 2 Phosphides and Simple Compounds 2.1 The Element 2.2 Metallic Phosphides 2.3 Oxides 2.4 Sulphides and Selenides 2.5 Hydrides 2.6 Nitrides 2.7 HalidesChapter 3 Phosphates 3.1 Phosphoric and Polyphosphoric Acids 3.2 Orthophosphates 3.3 Condensed Phosphates 3.4 Substituted PhosphatesChapter 4 Phosphorus - Carbon Compounds 4.1 Introduction and Nomenclature 4.2 Phosphines 4.3 Phosphine Oxides 4.4 Phosphonous and Phosphinous Halides 4.5 Phosphonyl and Phosphinyl Halides 4.6 Phosphonium Salts 4.7 Phosphonium Ylids 4.8 Phosphoranes 4.9 Six-coordinated Compounds 4.1 Phosphonous and Phosphinous Acids 4.11 Phosphonic and Phosphinic Acids 4.12 PhosphitesChapter 5 Phosphorus - Nitrogen Compounds 5.1 General Survey 5.2 Compounds with P-NH2 Linkages 5.3 Compounds with P-NR2 Linkages 5.4 Amides with P-N and P-C Linkages 5.5 Hydrazides and Azides 5.6 Cyclic Phosphazenes 5.7 Linear Phosphazenes 5.8 Highly Polymeric Phosphazenes 5.9 Monophosphazenes 5.1 Polymeric PhosphazanesChapter 6 Esters and Biochemistry 6.1 Esters 6.2 Enzymes 6.3 Metabolic Processes 6.4 Nucleic Acids 6.5 Toxic Esters and Medicinal CompoundsChapter 7 Phosphorus – Sulphur Compounds 7.1 Thiophosphoryl Halides 7.2 Phosphorothioic Acids 7.3 Phosphine Sulphides 7.4 Thioated Oxyacids 7.5 Thiophosphonium Salts 7.6 Condensed Phosphorothioates 7.7 Compounds with P-S and P-N Linkages 7.8 Compounds with P-S and P-C LinkagesChapter 8 Polyphosphines, Rings and Polymers 8.1 Polyphosphines 8.2 Rings of Phosphorus & Saturated Carbon 8.3 Rings of Phosphorus & Unsaturated Carbon 8.4 Rings of Phosphorus, Carbon & Oxygen 8.5 Miscellaneous Rings with Phosphorus & Carbon 8.6 High Polymers with P-C Linkages Chapter 9 Phosphorus with Groups III & IV 9.1 Phosphorus and Boron 9.2 Phosphorus and Aluminium 9.3 Phosphorus and Silicon 9.4 Phosphorus and Germanium 9.5 Phosphorus and TinChapter 10 Metal - Phosphorus Coordination Compounds 10.1 Phosphine PH3 Complexes 10.2 Halogen PX3 Complexes 10.3 Organophosphine PR3 Complexes 10.4 Phosphite Complexes 10.5 Phosphonite and Phosphinite Complexes 10.6 Phosphito and Phosphinito Complexes 10.7 Miscellaneous Complexes 10.8 Bonding Effects in Metal Complexes 10.9 Catalytic PropertiesChapter 11 Special Topics 11.1 Hydrogen Bonding 11.2 Stereochemistry and Isomerism 11.3 Pseudorotation & the Trigonal Bipyramid 11.4 Free Radicals 11.5 Radioactivity & Radiochemistry 11.6 Analysis by Chemical & Physical Methods Appendix I Note on LiteratureAppendix II Note on NomenclatureAppendix III Hazards of Common Phosphorus CompoundsAppendix IV Composition of Phosphate Buffer SolutionsAppendix V Properties of White PhosphorusAppendix VI Atomic Data for the ElementsIndex
- Edition: 2
- Latest edition
- Volume: 2
- Published: January 1, 1980
- Language: English
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