Perovskite Ceramics

Recent Advances and Emerging Applications

1st Edition - November 11, 2022
Editors: Jose Luis Clabel Huaman, Victor Anthony Garcia Rivera
Language: English
Paperback ISBN:
9 7 8 - 0 - 3 2 3 - 9 0 5 8 6 - 2
eBook ISBN:
9 7 8 - 0 - 3 2 3 - 9 0 7 1 0 - 1

Perovskite-based ceramics are a significant class of innovative materials with fascinating physical properties, which are now receiving intensive research attention in condensed ma… Read more

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Perovskite-based ceramics are a significant class of innovative materials with fascinating physical properties, which are now receiving intensive research attention in condensed matter physics and in the area of practical device applications. Perovskite Ceramics provides a state-of-the-art review on the latest advances in perovskite-based ceramic materials, as well as the development of devices from these materials for different applications.

Perovskite Ceramics: Recent Advances and Emerging Applications is divided into two main parts. The first part focuses on the basics of perovskite-based ceramic materials and includes chapters on the fundamentals, synthesis and processing, characterization, and properties of these materials. Chapters are also included on bulk and thin materials, phase transitions, polaronic effects and the compensation and screening of ferroelectricity. This section will allow the reader to familiarize themselves with the standard traditional approach, but it will also introduce new concepts that are fast evolving in this field. The second part presents an extensive review of up-to-date research on new and innovative advances in perovskite-based ceramic materials. Chapters cover multiferroic applications, lead-free perovskites, energy storage applications, perovskite-based memories, light manipulation and spectral modifications, and solar cells and fuel cells. All these fields of research are rapidly evolving, so the book acts a platform to showcase latest results on optical strategies and materials for light manipulation, and spectral up- and down-conversion too (mainly rare earth doped oxides and complexes).

The book will be an essential reference resource for academic and industrial researchers working in materials research and development particularly in functional and oxide ceramics and perovskites.

Cover image
Title page
Table of Contents
Copyright
Dedication
Contributors
Preface
Part One: Advanced research
1: Introduction to perovskites
Abstract
1: What is a perovskite?
2: Symmetry matters: From the bumped journey that started with the pursuit of the appropriate symmetry of the mineral perovskite to the search for modern lasers
3: An incredible structural versatility that can lead us to the next generation of solid-state refrigerators: Hybrid perovskites
4: Chemical flexibility: Toward the next generation of electrocatalyzers proposed by modern machine learning tools
5: Never abandon your perovskite; others might find it useful
6: Conclusions
References
2: Methods for the synthesis of ceramic materials with perovskite structure
Abstract
1: Introduction
2: Synthesis and processing of perovskite ceramics
3: Conclusions
References
3: Antiferrodistortive phase transition in doped strontium titanate ceramics: The role of the perovskite lattice vacancies
Abstract
1: Introduction
2: Phase transition of undoped ST ceramics
3: Effect of isovalent doping on the phase transition
4: Acceptor doping/oxygen vacancy effect
5: Donor doping/strontium vacancy effect
6: Conclusions
References
4: Polaronic effects in perovskite oxides
Abstract
Acknowledgments
1: Introduction
2: Response of Frohlich and Holstein polarons to external fields
3: Electron-phonon interaction (EPI) in transition metal oxides
4: Outlook and perspectives
References
Further reading
5: Compensation and screening of ferroelectricity in perovskite oxides
Abstract
Acknowledgments
1: Introduction
2: Proper ferroelectrics
3: Improper ferroelectrics
4: Rashba ferroelectrics
5: Conclusions and outlook
References
6: Crystal structures of copper oxide-based perovskite compounds
Abstract
Acknowledgment
1: Introduction
2: Atomic observation by HREM
3: Crystal structures of Tl-based copper oxides
4: Modulated superstructures of Tl-based copper oxides
5: Crystal structures of Pb-based copper oxides
6: Crystal structures of Hg-based copper oxide
7: Crystal structures of Bi-based copper oxide
8: Structures of lanthanoid-based copper oxides
9: Oxygen ordering in YBa2Cu3O7− x
10: Y-based copper oxides with high JC
11: CO3- and BO3-based copper oxides
12: Defects, interfaces, and surface structures
13: Summary
References
Part Two: Oxide and halide perovskites: Functional and advanced applications
7: Perovskite-structured ceramics in solid oxide fuel cell application
Abstract
1: Introduction
2: Perovskite-structured electrolyte for SOFCs
3: Perovskite-structured electrodes for SOFCs
4: Perovskite-structured coating for the SOFC interconnect
5: Summary
References
8: Perovskite membranes for oxygen separation
Abstract
1: Introduction
2: Perovskite structure and separation phenomena
3: Membrane synthesis and preparation methods
4: Performance and applications
5: Future perspectives
6: Final remarks
References
9: Perovskite lead-free dielectric ceramics: Highly promising materials for energy storage applications
Abstract
Acknowledgment
1: Introduction
2: Energy storage measurement principle
3: Energy storage performance of lead-free dielectrics
4: Breakdown mechanism in dielectric materials
5: Conclusion and future prospectus
References
10: Perovskite-like structure ceramic materials and their design for electrical applications
Abstract
Acknowledgments
1: Introduction
2: The structural link to electrical properties
3: Properties of electroceramics
4: Lead-free piezoceramic materials
5: Processing techniques of polar electroceramics
6: Electrical properties evaluation: Piezoelectric applications
7: Summary
References
11: Multiferroic perovskite ceramics: Properties and applications
Abstract
1: Introduction to multiferroic perovskite ceramics
2: Theory of magnetoelectric properties in ceramics
3: Applications of magnetoelectric composite ceramics
References
12: Functional double perovskites from bulk to thin film heterostructures: The example of La2NiMnO6
Abstract
Acknowledgment
1: Introduction
2: Functional properties of double perovskites
3: Summary
References
13: Perovskite-based emerging memories
Abstract
Acknowledgments
Authors’ contributions
1: Introduction
2: FeRAM technologies
3: MRAM technologies
4: ReRAM technologies
5: Summary, challenges, and outlook
References
14: Perovskite-based light-emitting diodes
Abstract
Acknowledgment
1: Introduction to LED devices
2: State-of-the-art LED structures and technologies
3: Dielectric-optical properties and applications of perovskite-based LEDs
4: Challenges and performances
5: Roadmap of perovskite-based LEDs
6: Conclusions
References
15: Light storage perovskites: Synthesis, mechanisms, and applications
Abstract
1: Light storage materials
2: Synthesis and designing of persistent luminescent perovskites
3: Persistent luminescent mechanism
4: Applications of persistent luminescent perovskites
5: Conclusions
References
16: Halide-based perovskites in photonics: From photocatalysts to highly efficient optoelectronic devices
Abstract
Acknowledgments
1: Introduction
2: Synthesis methods of MHPs
3: Luminescent perovskites: Photoexcitation and emission processes of halide-based nano/QD perovskites
4: Perovskite solar cells (PSCs)
5: Photocatalysis by MHP
6: Conclusions
References
Index

Jose Luis Clabel Huaman

Dr. Jose Luis Clabel Huaman is presently, working as a researcher and professor at the Institute of Physics of São Carlos – University of São Paulo, Brazil. He received his Ph.D. in Physics from the Federal University of São Carlos, in 2015. He has remained a post-doctoral fellow at the Brazilian Agricultural Research Corporation, Institute of Physics of São Carlos – University of São Paulo and the Department of Physics – Viçosa Federal University. His main research experience is in Condensed-Matter Physics and Materials Science. His interdisciplinary research interests include investigating multiferroic composites, and ferro-/piezoelectric and luminescent materials for structural and functional applications. He has monitored various aspects and features of ceramics and thin films with perovskite structures, mainly to understand their structural and opto-electronic behavior and their applications. His research works involve the use of a broad-spectrum of material characterization techniques such as X-ray diffraction (XRD), atomic force microscopy (AFM), Raman and Infrared Spectroscopies, thermal analysis, dielectric/magnetic measurement, luminescence spectroscopy, scanning and Transmission Electron Microscopy. He has published more than 15 research articles in high impact international journals.

Affiliations and expertise

Researcher and Professor, Institute of Physics of Sao Carlos – University of Sao Paulo, Brazil

Victor Anthony Garcia Rivera

Dr. Victor Anthony Garcia Rivera achieved his bachelor’s degree in physics from the Universidad Nacional Federico Villarreal, Peru, in 2002. He then went on to obtain his master’s degree in physics from the Universidade Estadual de Campinas, Brazil in 2005 and PhD degree in physics from the Universidade Federal de São Carlos, Brazil, in 2009. He previously worked at the Institute of Physics of Sao Carlos (USP), Brazil for almost six years and then for one year as a researcher at the Center for Optics, Photonics and Lasers at Laval University, in Quebec, Canada. He has also been a program manager of Basic Science Research at CONCYTEC - Peru (Consejo Nacional de Ciencia, Tecnología e Innovación Tecnologica, in Spanish). Currently, he is a principal professor at the Universidad Nacional Mayor de San Marcos, Lima – Peru. He is also the General Editor of the Campus Journal at the University of San Martín de Porres. He is an experimentalist whose research interests include: (i) photonics (fiber and integrated optics, glass materials); (ii) plasmonics (nanowaveguide and plasmon-photon interaction) and (iii) perovskite ceramics (rare-earth substitution and optical properties). He has published over 60 research papers has been a guest editor and author of several book chapters.

Affiliations and expertise

Principal professor, Universidad Nacional Mayor de San Marcos, Lima – Peru General Editor, Campus Journal, University of San Martín de Porres.

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