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Organic reactive intermediates
- 1st Edition - November 12, 2012
- Editor: Samuel McManus
- Language: English
- Paperback ISBN:9 7 8 - 0 - 1 2 - 4 1 4 3 1 1 - 1
- eBook ISBN:9 7 8 - 0 - 3 2 3 - 1 4 6 2 7 - 2
Organic Chemistry: A Series of Monographs, Volume 26: Organic Reactive Intermediates focuses on the study of reactive intermediates. This book discusses the methods of formation… Read more
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Request a sales quoteOrganic Chemistry: A Series of Monographs, Volume 26: Organic Reactive Intermediates focuses on the study of reactive intermediates. This book discusses the methods of formation and investigation, factors affecting the stability, and reactions of the intermediate. Other topics include the formation and reaction of free radicals; kinetic aspects of free-radical chain reactions; electronic states and structures of carbenes; and formation of transient carbenes and carbenoids in solution. The intermediacy of nitrenes in reactions; electronic structure and spectra; methods of investigating carbonium ions; and reactions of carbonium ions are also elaborated. This publication likewise covers the preparation of carbanions; factors affecting the stability of carbanions; reactions involving radical ions; and methods of investigating arynes. This volume serves as a textbook for the first graduate-level course, as well as a reference for industrial chemists interested in organic reaction mechanisms.
List of Contributors
Preface
1. Free Radicals
I. Introduction
II. Formation of Free Radicals
III. Reactions of Free Radicals
IV. Reactivities of Free Radicals
V. Kinetic Aspects of Free-Radical Chain Reactions
References
2. Carbenes and Related Species
I. Introduction
II. Electronic States and Structures of Carbenes
III. The Formation of Transient Carbenes and Carbenoids in Solution
IV. Mechanism and Reactivity in Carbene and Carbenoid Reactions
V. Related Species
VI. Conclusion
References
3. Nitrenes
I. Introduction: Nomenclature and Historical Background
II. Intermediacy of Nitrenes in Reactions
III. Electronic Structure and Spectra
IV. Methods of Generation of Nitrenes
V. Reactions
VI. Nitrenium Ions
VII. Applications
References
4. Carbonium Ions
I. General Aspects and Historical Background
II. Methods of Investigating Carbonium Ions
III. Methods of Formation
IV. Factors Affecting the Stability of Carbonium Ions
V. Reactions of Carbonium Ions
VI. Bridged Carbonium Ions
VII. Related Species
References
5. Carbanions
I. General Aspects
II. Methods of Investigation of Carbanions
III. Preparation of Carbanions
IV. Factors Affecting the Stability of Carbanions
V. Reactions of Carbanions
References
6. Radical Ions
I. Introduction
II. Formation of Radical Ions
III. Methods of Investigation of Radical Ions
IV. Reactions Involving Radical Ions
References
7. Arynes
I. General Aspects and Historical Background
II. Methods of Investigating Arynes
III. Methods of Formation of Arynes
IV. Factors Affecting the Formation and Stability of Cyclic Acetylenes and Arynes
V. Reactions of Arynes
VI. Hetarynes
VII. Conclusion
References
Author Index
Subject Index
- No. of pages: 552
- Language: English
- Edition: 1
- Published: November 12, 2012
- Imprint: Academic Press
- Paperback ISBN: 9780124143111
- eBook ISBN: 9780323146272
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