Organic Functional Group Analysis
International Series of Monographs on Analytical Chemistry, Volume 8
- 1st Edition - January 1, 1963
- Imprint: Pergamon
- Author: F. E. Critchfield
- Editors: R. Belcher, L. Gordon
- Language: English
- Paperback ISBN:9 7 8 - 1 - 4 8 3 1 - 2 2 7 3 - 1
- eBook ISBN:9 7 8 - 1 - 4 8 3 1 - 5 5 1 5 - 9
International Series of Monographs on Analytical Chemistry, Volume 8: Organic Functional Group Analysis focuses on the application of versatile and reliable chemical methods for… Read more
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Request a sales quoteInternational Series of Monographs on Analytical Chemistry, Volume 8: Organic Functional Group Analysis focuses on the application of versatile and reliable chemical methods for determining most of the more common organic functional groups. The publication first offers information acids and bases and nitrogen compounds, including differentiations, indicators, methods, amines, and amides. The text then examines carbonyl compounds and derivatives and hydroxyl compounds. Discussions focus on hydroxylamine hydrochloride-triethanolamine methods, hydroxylammonium formate, mercurimetric determination of aldehydes, acylation methods, and bromination method for aromatic hydroxyl compounds. The text takes a look at unsaturated compounds, esters, and carboxylic acid anhydrides. The manuscript also ponders on peroxides and sulfur compounds. Topics include ceric ammonium sulfate method, titration of mercaptans with mercuric perchlorate, and potassium bromate method for sulfides and disulfides. The book is a dependable reference for readers interested in the study of functional groups.
Preface
1. Introduction
Techniques
2. Acids and Bases
Selection of Acid-Base Method
Differentiations
Indicators
Methods
References
3. Nitrogen Compounds
Amines
Amides
Miscellaneous
References
4. Carbonyl Compounds and Derivatives
Hydroxylamine Hydrochloride-Triethanolamine Methods
Hydroxylamine Hydrochloride-Dimethylethanolamine Method
Hydroxylammonium Formate
Mercurimetric Determination of Aldehydes
2,4,-Dinitrophenylhydrazine Colorimetric Method
Summary
References
5. Hydroxyl Compounds
Acylation Methods
Cleavage of 1,2-Glycols
Hydrogen Bromide Method for Tertiary Alcohols (and Diols)
Bromination Method for Aromatic Hydroxyl Compounds
Colorimetric Methods
Summary
References
6. Unsaturated Compounds
Halogenation Methods
Morpholine Method
Mercuric Acetate Method
Silver Perchlorate Method
Summary
References
7. 1,2-Epoxy Compounds
Indirect Hydrogen Bromide Method
Direct Hydrogen Bromide Method
Pyridine Hydrochloride Method
Morpholine Method
Colorimetric Method
Summary
References
8. Esters
Saponification with Aqueous Potassium Hydroxide
Saponification in the Presence of Phenylhydrazine
Saponification with Potassium Hydroxide in Diethylene Glycol
Hydroxamic Acid Colorimetric Method
Summary
References
9. Carboxylic Acid Anhydrides
Aniline-Sodium Hydroxide Method
Morpholine Method
Morpholine-Carbon Disulfide Method
Hydroxamic Acid Colorimetric Method
Summary
References
10. Peroxides
Sodium Iodide-Acetic Anhydride Method
Hydrogen Iodide-Acetic Acid Method
Ceric Ammonium Sulfate Method
Colorimetric Sodium Iodide-Acetic Anhydride Method
Summary
References
11. Sulfur Compounds
Titration of Mercaptans with Mercuric Perchlorate
Iodometric Method for Mercaptans
Potassium Bromate Method for Sulfides and Disulfides
Acid Hydrolysis of Alkyl Sulfates
Titration of Surface Active Sulfates and Sulfonates with Cetyl Pyridinium Bromide
Colorimetric Method for Surface Active Sulfates and Sulfonates
References
Index
- Edition: 1
- Published: January 1, 1963
- Imprint: Pergamon
- Language: English
- Paperback ISBN: 9781483122731
- eBook ISBN: 9781483155159
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