Metal Organic Frameworks
Fundamentals to Advanced
- 1st Edition - April 26, 2024
- Imprint: Elsevier
- Editors: Bhawana Jain, Dakeshwar Kumar Verma, Ajaya Kumar Singh, Jai Singh
- Language: English
- Paperback ISBN:9 7 8 - 0 - 4 4 3 - 1 5 2 5 9 - 7
- eBook ISBN:9 7 8 - 0 - 4 4 3 - 1 5 2 5 8 - 0
Metal Organic Frameworks: Fundamentals to Advanced offers a substantial and complete treatment of published results. The book includes a summary of current research, along with a… Read more
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Request a sales quoteMetal Organic Frameworks: Fundamentals to Advanced offers a substantial and complete treatment of published results. The book includes a summary of current research, along with an in- depth explanation of Metal organic frameworks (MOFs) and applications in this versatile area. Metal organic frameworks (MOFs) are structured frameworks made up of metal ions and organic molecules. These materials are similar to sponges and can absorb, retain and remove molecules from their pores. As a result, metal-organic frameworks (MOFs) are the most rapidly evolving substances in chemistry with the highest surface areas due to their well-ordered pore structure.The exciting and vast surface area allows for more chemical reactions and molecule adsorption, hence this new resource provides the newest updates on the topics covered.
- Covers the synthetic advantages and versatile applications of metal-organic frameworks (MOFs) due to their organic-inorganic hybrid nature and unique porous structure
- Includes energy applications such as batteries, fuel storage, fuel cells, hydrogen evaluation reactions and super capacitors
- Features information on using MOFs as a replacement to conventional engineering materials as they are lightweight, less costly, environmentally-friendly and sustainable
Researchers, advanced students working with MOFs and inorganic chemistry, general chemists, Chemical engineers and material scientists
- Cover image
- Title page
- Table of Contents
- Copyright
- List of contributors
- About the editors
- Part 1: General inception, synthesis and modification
- Chapter 1. Metal-organic frameworks: current trends, challenges, and future prospects
- Abstract
- 1.1 Introduction
- 1.2 History of metal-organic frameworks
- 1.3 Principal investigators and team based on metal-organic frameworks
- 1.4 Functionalized approaches to metal-organic frameworks
- 1.5 Trends in the application of metal-organic frameworks
- 1.6 Challenges
- 1.7 Prospects
- References
- Chapter 2. Metal-organic frameworks constructed from biomolecular building blocks
- Abstract
- 2.1 Introduction
- 2.2 Structural classification and synthesis of metal-organic frameworks
- 2.3 Micro- and macromolecules based on metal-organic framework
- 2.4 Applications of metal-organic framework constructed from biomolecules building blocks
- 2.5 Conclusions
- References
- Chapter 3. Metal organic frameworks: its synthesis, properties and applications
- Abstract
- 3.1 Introduction
- 3.2 Metal-organic framework composites and method of synthesis
- 3.3 Applications of metal-organic frameworks composites
- 3.4 Conclusions
- 3.5 Future outlook
- References
- Chapter 4. Paramagnetic metal-organic frameworks and their nanocomposites
- Abstract
- 4.1 Introduction
- 4.2 Synthesis and characterization of paramagnetic metal-organic frameworks
- 4.3 Synthesis of metal-organic frameworks with paramagnetic metal centers
- 4.4 Methods for synthesizing metal-organic frameworks with paramagnetic metal centers
- 4.5 Coordinative self-assembly
- 4.6 Ligand replacement
- 4.7 Postsynthesis modification
- 4.8 Microwave synthesis
- 4.9 Techniques for characterizing paramagnetic metal-organic frameworks
- 4.10 Magnetic measurements
- 4.11 Electron paramagnetic resonance spectroscopy
- 4.12 Applications of paramagnetic metal-organic frameworks
- 4.13 Nanocomposites of paramagnetic metal-organic frameworks
- 4.14 Future directions and challenges
- 4.15 Conclusion
- References
- Chapter 5. Synthesis and shaping of metal–organic frameworks
- Abstract
- 5.1 Introduction
- 5.2 Definition of MOFs
- 5.3 Composition of MOFs
- 5.4 Stability of MOFs
- 5.5 Synthesis of MOFs
- 5.6 Solvo(Hydro) thermal
- 5.7 Mechanochemical synthesis
- 5.8 Sonochemical synthesis
- 5.9 Microwave-assisted
- 5.10 Electrochemical synthesis
- 5.11 Layer-by-layer synthesis
- 5.12 Diffusion method
- 5.13 Some other MOF prepared by different method
- 5.14 Shaping of MOF
- 5.15 Granules
- 5.16 Pellets
- 5.17 Thin films
- 5.18 Foam
- 5.19 Gels
- 5.20 Hollow
- 5.21 Others
- 5.22 Conclusion
- References
- Chapter 6. Platinum group-based metal-organic frameworks (MOFs) nanocomposites
- Abstract
- 6.1 Introduction
- 6.2 Synthetic approaches of metal-organic framework materials
- 6.3 Synthesis of Pt-based metal-organic framework nanocomposites
- 6.4 Applications of metal-organic frameworks
- 6.5 Conclusions, issues, and future directions
- References
- Chapter 7. Stability of metal organic frameworks
- Abstract
- 7.1 Introduction
- 7.2 Stability of metal-organic frameworks
- 7.3 Applications
- 7.4 Conclusion
- References
- Part 2: Experimental and theoretical insights
- Chapter 8. Computational screening of metal–organic frameworks for environmental protection
- Abstract
- 8.1 Introduction
- 8.2 Different computational methods
- 8.3 Computation screening of metal–organic frameworks for environmental applications
- 8.4 Conclusion
- References
- Chapter 9. Metal-organic frameworks: computational modeling in ionic compounds
- Abstract
- 9.1 Introduction
- 9.2 Background: ionic metal-organic frameworks
- 9.3 Classification of ionic metal-organic frameworks
- 9.4 Functioning of ion exchange in metal-organic frameworks
- 9.5 The use of computational models in ionic compounds
- 9.6 Conclusion
- References
- Chapter 10. Density functional theory–based molecular modeling for metal-organic frameworks
- Abstract
- 10.1 Introduction
- 10.2 Role of density functional theory in the development of metal-organic frameworks for water adsorption and separation applications
- 10.3 Role of density functional theory in the development of metal-organic frameworks for gas storage, adsorption, and separation
- 10.4 Density functional theory studies at catalytic activity of metal-organic frameworks and derivatives
- 10.5 Role of density functional theory in the structure exploration of metal-organic frameworks and derivatives
- 10.6 Conclusion
- Conflict of interest
- References
- Part 3: Significance and importance
- Chapter 11. Metal-organic frameworks based elecrode materials for supercapacitor application
- Abstract
- 11.1 Introduction
- 11.2 Metal-organic frameworks
- 11.3 Pristine metal-organic framework as electrode material for supercapacitors
- 11.4 Metal-organic framework-derived electrode materials for supercapacitors
- 11.5 Metal-organic framework composites as electrode material for supercapacitors
- 11.6 Future prospect
- References
- Chapter 12. Metal-organic frameworks for reasonable carbon dioxide fixation and electrocatalytic carbon dioxide reduction
- Abstract
- 12.1 Introduction
- 12.2 CO2 and metal-organic frameworks
- 12.3 CO2 fixation
- 12.4 Electrocatalytic CO2 reduction
- 12.5 Summary and future perspectives
- References
- Chapter 13. Metal-organic frameworks for drug delivery: part B
- Abstract
- 13.1 Introduction
- 13.2 Strategies of metal-organic framework for drug delivery
- 13.3 Metal-organic framework synthesis: pathways to various metal-organic framework topologies, morphologies, and composites
- 13.4 Various aspects of metal-organic framework synthesis
- 13.5 MOFs crystals, film/membrane, and composites
- 13.6 Prospects for the future in synthesis of metal-organic frameworks
- 13.7 Metal-organic frameworks in drug delivery
- 13.8 Application of metal-organic frameworks
- Acknowledgments
- Conflict of interest
- References
- Chapter 14. Metal-organic frameworks (MOFs) for drug delivery: part B
- Abstract
- 14.1 Introduction
- 14.2 Synthesis and characterization of metal-organic framework
- 14.3 Structure of metal-organic frameworks
- 14.4 Preparations of metal-organic frameworks
- 14.5 Tuning metal-organic framework characteristics for drug delivery
- 14.6 Metal-organic frameworks used as drug delivery
- 14.7 Application of metal-organic frameworks in drug delivery
- 14.8 Factors affecting drug delivery using metal-organic frameworks
- 14.9 Conclusion
- References
- Chapter 15. Metal-organic frameworks for wastewater treatment
- Abstract
- 15.1 Introduction
- 15.2 Metal-organic frameworks adsorbent in wastewater treatment
- 15.3 Mixed-metal metal-organic frameworks as adsorbent
- 15.4 Metal-organic frameworks fabricated with other materials as adsorbent
- 15.5 Metal-organic frameworks as adsorbent for heavy metal ions from effluents
- 15.6 Metal-organic frameworks as adsorbent for harmful pesticides from agriculture runoff
- 15.7 Metal-organic frameworks as adsorbent for radioactive waste
- 15.8 Conclusion
- References
- Chapter 16. Metal-organic framework as an efficient photocatalyst
- Abstract
- 16.1 Introduction
- 16.2 Photocatalytic degradation of dyes by metal-organic frameworks
- 16.3 Photocatalytic degradation of antibiotics by metal-organic frameworks
- 16.4 Photocatalytic degradation of pesticides by metal-organic frameworks
- 16.5 Photocatalytic reduction of CO2 by metal-organic frameworks
- 16.6 Photocatalytic H2 production by metal-organic frameworks
- 16.7 Future perspectives
- 16.8 Conclusion
- References
- Chapter 17. Emerging role of metal-organic frameworks in renewable energy and fuel storage
- Abstract
- 17.1 Introduction
- 17.2 Third-generation solar cells
- 17.3 Hydrogen storage
- 17.4 Conclusion
- Acknowledgments
- References
- Chapter 18. Thermo-mechanical and anti-corrosion characteristics of metal-organic frameworks (MOFSs)
- Abstract
- Abbreviations
- 18.1 Introduction
- 18.2 Metal-organic frameworks’ thermomechanical properties
- 18.3 Metal-organic frameworks’ anticorrosion properties
- 18.4 Organic inhibitors
- 18.5 How inhibitors work
- 18.6 Mode of action of an inhibitor
- 18.7 Type of adsorption
- 18.8 Physical adsorption
- 18.9 Chemical adsorption
- 18.10 Mechanism of formation of a three-dimensional layer
- 18.11 Mode of action of organic inhibitors
- 18.12 Oxygenated organic compounds
- 18.13 Behavior of inhibitors in acidic medium
- 18.14 Electrostatic bonding
- 18.15 Chemical bonding
- 18.16 Bond
- 18.17 Surface complexes
- 18.18 Hydrogen bonding
- 18.19 Anticorrosive properties of metal-organic frameworks
- 18.20 Conclusion
- References
- Chapter 19. Metal–organic frameworks biomacromolecules for biomedical applications
- Abstracts
- 19.1 Introduction
- 19.2 MOFs—modern technology
- 19.3 Designing of metal–organic frameworks
- 19.4 Functionality of metal–organic frameworks
- 19.5 Applications of metal–organic frameworks
- 19.6 Conclusion and future perspectives
- Acknowledgement
- References
- Chapter 20. Metal-organic frameworks for biosensing application
- Abstract
- 20.1 Introduction
- 20.2 Fabrication of metal-organic frameworks
- 20.3 Biosensor
- 20.4 Point of care
- 20.5 Metal-organic framework-based dopamine biosensors
- 20.6 Metal nanoparticle/metalorganic framework composites
- 20.7 Conclusions and future perspectives
- Compliance with ethical standards
- Acknowledgments
- References
- Chapter 21. Role of metal-organic frameworks in organic reactions
- Abstract
- 21.1 The scope
- 21.2 Metal-organic framework identification
- 21.3 The fundamental preparation processes of metal-organic frameworks
- 21.4 Catalysis identifications
- 21.5 Best practices in metal-organic framework catalysis
- 21.6 Application of metal-organic frameworks as catalysts
- 21.7 Conclusions and future prospects
- References
- Chapter 22. Toxicity of Metal-Organic Frameworks (MOFs) in living system
- Abstract
- 22.1 Introduction
- 22.2 Key factors affecting the toxicity of metal-organic frameworks in living systems
- 22.3 The toxicity of nanoscale or bulk metal-organic frameworks
- 22.4 Which type of toxicity assessment is necessary for the metal-organic framework bulk or its nanoparticles’ planned application?
- 22.5 Moving metal-organic framework nanoparticle design toward safety and sustainability
- 22.6 Conclusion
- References
- Index
- Edition: 1
- Published: April 26, 2024
- No. of pages (Paperback): 558
- No. of pages (eBook): 500
- Imprint: Elsevier
- Language: English
- Paperback ISBN: 9780443152597
- eBook ISBN: 9780443152580
BJ
Bhawana Jain
Dr Bhawana Jain received her doctorate degree in year 2011 from Govt. V. Y. T. PG. Autonomous College, Durg (C.G.), India. She had fellowships from UGC (Postdoctoral Fellowship for Women) and worked as a postdoctoral fellow at Govt. V.Y.T. PG. Autonomous College, Durg (C.G) India. She has 15 years of Research experience. She is actively engaged in the development of nanomaterials (CeO2, graphene oxide, ZnO, CuO, NiO, etc.), based nanobiocomposite for wastewater treatment containing different pollutants, dyes, drug, organic matter etc. She has publihed 32 international research and review articles including book chapters, in an internationally reputed press for publications, namely Elsevier, Springer Nature, Wiley, ACS. With total Citations as <500, h-index being 13, i-index 15. She received Certificate of Merit from American Chemical Society, USA in 2016. Currently, she is actively engaged in the research and development of Organic-inorganic metal halide perovskite for solar cell device.
Affiliations and expertise
Siddhachalam Laboratory, Raipur, IndiaDV
Dakeshwar Kumar Verma
Dakeshwar Kumar Verma is Assistant Professor of Chemistry at Government Digvijay Autonomous Postgraduate College, Rajnandgaon, India. His research is mainly focused on the preparation and design of organic compounds for various applications.
Affiliations and expertise
Department of Chemistry, Government Digvijay Autonomous Postgraduate College, Rajnandgaon, Chhattisgarh, IndiaAS
Ajaya Kumar Singh
Dr Ajaya Kumar received his Ph.D. degree on Kinetics and oxidation from University of Allahabad Uttar Pradesh, India. His research focuses on multiple areas such as developing strategies, based on synthesis, characterization, properties modification, design, fabrication, characterization of nanostructures, quantum dots, perovskite materials and photocatalyst for waste water treatment, and advanced oxidation processes. He has received various awards a Certificate of Merit in 2016 from American Chemical Society (USA) and is also the member of various societies.
Affiliations and expertise
Department of Chemistry, (DST-FIST Sponsored), Govt. V. Y. T. PG. Autonomous College, (College with Potential for Excellence), Chhattisgarh, IndiaJS
Jai Singh
Dr. Jai Singh is an Associate Professor at Guru Ghasidas Vishwavidyalaya's Department of Pure and Applied Science (Central University). He received his doctorate in the subject of II-VI oxide nanomaterials from Banaras Hindu University in Varanasi, India. Soon after completing his Ph.D., he joined Cologne University in Cologne, Germany, to do post-doctoral research in the areas of 2D materials, Transparent Conducting Oxide (TCO) materials, and Energy materials, and then moved to Pusan National University in Busan, South Korea, and Sejong University in Seoul, South Korea, to do the same. He has received several prestigious national and international awards, including the GATE Fellowship from the Ministry of Human Resource Development, the CSIR-Junior Research Fellowship and Senior Research Fellowship from the Council of Scientific and Industrial Research, the Postdoctoral Fellowship from Busan National University, the NSC Postdoctoral Fellowship from Taiwan, and the Visiting Fellowship from Cologne University in Germany.
Affiliations and expertise
Associate Professor, Guru Ghasidas Vishwavidyalaya's, Department of Pure and Applied Science (Central University), Chhattisgarh, IndiaRead Metal Organic Frameworks on ScienceDirect