Metal-Organic Framework-Based Nanomaterials for Energy Conversion and Storage

1st Edition - May 10, 2022
Editors: Ram K. Gupta, Tuan Anh Nguyen, Ghulam Yasin
Language: English
Paperback ISBN:
9 7 8 - 0 - 3 2 3 - 9 1 1 7 9 - 5
eBook ISBN:
9 7 8 - 0 - 3 2 3 - 9 9 8 2 9 - 1

Metal-Organic Framework-Based Nanomaterials for Energy Conversion and Storage addresses current challenges and covers design and fabrication approaches for nanomaterials based on… Read more

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Metal-Organic Framework-Based Nanomaterials for Energy Conversion and Storage addresses current challenges and covers design and fabrication approaches for nanomaterials based on metal organic frameworks for energy generation and storage technologies. The effect of synthetic diversity, functionalization, ways of improving conductivity and electronic transportation, tuning-in porosity to accommodate various types of electrolyte, and the criteria to achieve the appropriate pore size, shape and surface group of different metal sites and ligands are explored. The effect of integration of other elements, such as second metals or hetero-atomic doping in the system, to improve catalytic activity and durability, are also covered.

This is an important reference source for materials scientists, engineers and energy scientists looking to further their understanding on how metal organic framework-based nanomaterials are being used to create more efficient energy conversion and storage systems.

Cover image
Title page
Table of Contents
Copyright
Contributors
Editor biography
Part I. Fundamentals
Chapter 1. MOF-based nanostructures and nanomaterials for next-generation energy storage: an introduction
1. Introduction
2. Conclusion
Chapter 2. Recent advances in MOFs for electrochemical energy storage and conversion devices
1. Introduction
2. Common routes used for MOFs synthesis
3. MOFs for electrochemical devices
4. Conclusion
Chapter 3. Design and construction of MOF nanomaterials
1. Introduction
2. Design of metal-organic frameworks
3. Diversification of metal-organic frameworks
4. Conclusion
Chapter 4. Strategies to enhance the electrochemical properties of MOFs
1. Introduction
2. Basics for electrochemical properties of MOFs
3. Strategies to enhance electrochemical properties of MOFs
4. Improvement of conductivity
5. Introducing nanoparticles in MOFs
Chapter 5. Biological MOFs (bio-MOFs) for energy applications
1. Introduction
2. Classification of ligands in bio-MOFs
Part II. Metal–organic frameworks for fuel cells
Chapter 6. MOF-based electrocatalysts for oxygen evolution reactions
1. Introduction
2. Insight into ligand-based modification
3. Insight into structural engineering aspects of MOFs
4. Insight into composition engineering aspects of MOFs
5. Evaluation and characterization techniques for MOF electrocatalysts for efficient OER
6. MOFs-based electrocatalyst materials for oxygen evolution reactions
7. Concluding remarks
Declaration
Chapter 7. Recent development in MOFs for oxygen evolution reactions
1. Introduction
2. MOF-based OER electrocatalysts
3. MOF-derived OER electrocatalysts
4. Future prospective and summary
Chapter 8. Effect of structural modifications on the oxygen reduction reaction properties of metal-organic framework-based catalysts
1. Introduction
2. Kinetics and mechanism of the ORR
3. Catalysts for the ORR
4. Pristine MOFs for the ORR
5. Composites of MOF for the ORR
6. Derivatives of MOF for the ORR
7. Conclusion
Chapter 9. Metal organic framework-based nanomaterials as suitable electrocatalysts for evolution of hydrogen
1. Introduction
2. Performance parameters
3. Reaction mechanism for HER
4. Catalyst requirements
5. Basic overview of MOF
6. MOF in pristine condition
7. MOF-derived materials
8. Conclusions
Part III. Metal–organic frameworks for batteries
Chapter 10. MOF nanomaterials for battery cathodes
1. Introduction
2. Pristine MOFs
3. MOF derivatives
Chapter 11. MOFs and their derivatives for anode of high-performance rechargeable batteries
1. Introduction
2. Anode materials of LIBs
3. Anode materials of SIBs
4. Electrochemical performance evaluation of MOFs and their derivatives
5. Conclusion
Chapter 12. Polyoxometalate-based metal organic frameworks (POMOFs) for lithium-ion batteries
1. Introduction to POMs
2. POMs for LIBs electrodes
3. POMOFs for LIBs electrodes
4. Conclusions
Chapter 13. MOFs-based nanomaterials for metal-sulfur batteries
1. Introduction
2. MOFs-based lithium–sulfur batteries
3. Nonlithium metal–sulfur batteries
4. Conclusion
Chapter 14. MOFs-based nanomaterials for metal-ion batteries
1. Introduction
2. Synthesis of MOFs and MOFs-based electrode materials
3. MOFs based electrode materials for Li-ion battery
4. MOFs-based electrode materials for Na-ion battery
5. MOFs-based electrode materials for Zn-ion battery
6. MOFs-based electrode materials for K-ion battery
7. Conclusion
Chapter 15. MOF-based nanomaterials for zinc-based battery cathodes
1. Introduction
2. Working principles of aqueous Zn-based EES devices
3. MOF-related cathode materials for ZABs
4. Other MOF-related cathode materials for AZIBs
5. Conclusion and perspectives
Chapter 16. MOF-based electrolytes for battery applications
1. Introduction
2. Properties of MOF-based electrolytes
3. MOF-based solid-state electrolytes
4. MOFs in liquid electrolytes
Part IV. Metal–organic frameworks for supercapacitors
Chapter 17. Recent development in MOFs for supercapacitor applications
1. Introduction
2. Overview of supercapacitors
3. Recent developments of MOFs as supercapacitor-pristine, composites, and derivatives
4. Conclusions and outlook
Chapter 18. MOFs–metal oxides/sulfides/phosphides nanocomposites for supercapacitors
1. Introduction
2. MOF composites
3. MOF-derived composites
4. Conclusions–outlook
Chapter 19. MOFs-carbon nanocomposites for supercapacitors
1. Introduction
2. MOFs for supercapacitors
3. MOF-derived nanomaterials for supercapacitors
4. Conclusions and perspectives
Chapter 20. Flexible supercapacitors based on nanocomposites of MOFs
List of abbreviations
1. Introduction
2. Flexible supercapacitors
3. Fabrication methods of MOF nanocomposites
4. Applications of MOF nanocomposites for flexible supercapacitors
5. Conclusions and perspectives
Chapter 21. Other nanocomposites of MOFs for supercapacitors
1. Introduction
2. Metal-based materials/MOF composites
3. MXene/MOF composites
4. Polymer/metal organic framework composites
5. Electrically conducting polymer/metal organic framework composites
6. Concluding remarks
Part V. Metal–organic frameworks for photovoltaics
Chapter 22. MOFs-based dye-sensitized photovoltaics
1. Introduction
2. MOF-based DSSCs
3. Conclusion
Chapter 23. Recent development in MOFs for perovskite-based solar cells
1. Introduction
2. Perovskite solar cells
3. MOF in perovskite solar cells
4. Conclusions and outlook
Chapter 24. Integrating MOFs into dye-sensitized solar cells
1. Introduction
2. Dye-sensitized solar cells
3. Metal organic frameworks for DSSCs
4. Conclusion and future scope
Part VI. Metal–organic frameworks for fuel/gas storage
Chapter 25. Adsorption and storage of hydrogen into porous metal-organic framework solids
1. Brief background
2. Metal-organic framework
3. Postsynthesis modification of MOF
4. Adsorption and storage of hydrogen in MOF
Chapter 26. MOFs for hydrogen storage
1. Introduction
2. Definition and terminologies
3. Synthesis of representative MOF for hydrogen storage
4. Characterization of hydrogen storage in MOF
5. Strategies to improve the adsorption capacity
6. Prospects
Chapter 27. Multicriteria decision making in organic-metal frameworks for fuel storage
1. Introduction
2. The fuel storage in organic-metal frameworks
3. Analytic hierarchy process methodology
4. Conclusion
Chapter 28. Current development in MOFs for hydrogen storage: a mechanistic investigation
1. Introduction
2. Hydrogen storage in MOFs
3. Conclusion
4. Note
Part VII. Metal–organic frameworks for other applications
Chapter 29. MOFs for solar photochemistry applications
1. Introduction
2. TMPI encapsulated in MOFs containing Zn(II), Cd(II), and Zr(IV) MBBS
3. Noncovalent metalloporphyrin encapsulation in MOFs
4. Summary and future prospects
Chapter 30. Metal-organic frameworks for nanogenerators
1. Introduction
2. Recent advances in MOFs for nanogenerators
3. Conclusions
Chapter 31. MOF-based photocatalysts for hydrogen generation by water splitting
1. Introduction
2. Hydrogen gas as fuel
3. Metal organic frameworks for photocatalytic application
4. Structural categories of MOF-based photocatalysts
5. Classification of MOFs as H2 production photocatalyst
6. MOFs for photocatalytic water splitting
7. Roles of MOF materials in photocatalytic water splitting
8. Conclusion and future outlook
Chapter 32. Metal-organic framework for photocatalytic reduction of carbon dioxide
1. Introduction
2. Photocatalytic reduction of CO2—principles, mechanism, and products
3. Metal organic framework
4. Features of MOF-based photocatalyst
5. Strategies to enhance MOF and its derivatives for photocatalysis
6. Photocatalytic reduction of CO2 by different classes of MOFs
7. Outlook and prospect
Chapter 33. MOF-based advanced nanomaterials for electrocatalysis applications
1. Introduction
2. Synthesis strategies
3. Energy conversion applications
4. Conclusion
Index

Ram K. Gupta

Ram K. Gupta is a Professor in the Department of Chemistry at Pittsburg State University, USA. His research interests include green energy production and storage using conducting polymers, 2D materials, nanostructured materials and composites, polymers from renewable resources for industrial applications, polymer recycling for sustainable future, bio-compatible nanofibers and thin films for tissue regeneration, scaffolds, bio-degradable metallic implants, and antibacterial applications.

Affiliations and expertise

Professor, Department of Chemistry, Kansas Polymer Research Center, Pittsburg State University, Pittsburg, KS, USA

Tuan Anh Nguyen

Tuan Anh Nguyen is Senior Principal Research Scientist at the Institute for Tropical Technology, Vietnam Academy of Science and Technology, Vietnam. He received B.S. in Physics from Hanoi University in 1992, and Ph.D. in Chemistry from the Paris Diderot University (France) in 2003. He was Visiting Scientist at Seoul National University (South Korea, 2004) and University of Wollongong (Australia, 2005). He then worked as Postdoctoral Research Associate and Research Scientist in the Montana State University (USA), 2006-2009. In 2012, he was appointed as the Head of the Microanalysis Department at Institute for Tropical Technology. His research activities include smart sensors, smart networks, smart hospitals, smart cities and digital twins. He edited over 70 Elsevier, 12 CRC Press, 1 Springer, 1 RSC and 2 IGI Global books. He is Editor-In-Chief of "Kenkyu Journal of Nanotechnology & Nanoscience".

Affiliations and expertise

Senior Principal Research Scientist, Institute for Tropical Technology, Vietnam Academy of Science and Technology, Hanoi, Vietnam

Ghulam Yasin

Ghulam Yasin is a researcher in the School of Environment and Civil Engineering at Dongguan University of Technology, Guangdong, China. His expertise covers the design and development of hybrid devices and technologies of carbon nanostructures and advanced nanomaterials for for real-world impact in energy-related and other functional applications.

Affiliations and expertise

Researcher, School of Environment and Civil Engineering, Dongguan University of Technology, Guangdong, China

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Metal-Organic Framework-Based Nanomaterials for Energy Conversion and Storage

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Ram K. Gupta

Tuan Anh Nguyen

Ghulam Yasin