Ionic Liquids in Analytical Chemistry

New Insights and Recent Developments

1st Edition - November 29, 2021
Imprint: Elsevier
Editors: Samuel Carda-Broch, Maria Jose Ruiz-Angel
Language: English
Paperback ISBN:
9 7 8 - 0 - 1 2 - 8 2 3 3 3 4 - 4
eBook ISBN:
9 7 8 - 0 - 1 2 - 8 2 3 3 3 5 - 1

Ionic liquids in Analytical Chemistry: New Insights and Recent Developments focuses on the use of these materials in the field of chemical analysis, paying attention to different… Read more

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Ionic liquids in Analytical Chemistry: New Insights and Recent Developments focuses on the use of these materials in the field of chemical analysis, paying attention to different areas such as sample preparation, separation techniques, spectroscopy and electrochemical methods. Chapters describe the structure and properties of new ionic liquids and eutectic solvents that are widely used in analytical chemistry, review ionic liquids in sample preparation, liquid, micellar liquid and gas chromatography, and capillary electrophoresis. Final chapters are devoted to spectroscopic and electrochemical techniques. The whole volume provides a broad overview of recent applications of ionic liquids.

The book will serve as a valuable resource to researchers and laboratory technicians working in the field, as well as instructors and students of analytical chemistry.

Cover Image
Title Page
Copyright
Table of Contents
Contributors
Foreword
Acknowledgments
Abbreviations
Chapter One Structure and properties of Ionic liquids: Green aspects
Abstract
1.1 Introduction: a brief history of the ionic liquids
1.2 Structural features and their effect on the physical properties of ionic liquids
1.3 Synthesis and properties of different classes of ionic liquids
1.4 Concluding remarks and future directions
References
Chapter Two Achievements and perspectives of using deep eutectic solvents in the analytical chemistry field
Abstract
2.1 Introduction
2.2 Deep eutectic solvents: definition, preparation, and properties
2.3 Advances in analytical chemistry using deep eutectic solvents
2.4 Concluding remarks and future directions
Acknowledgements
References
Chapter Three Ionic liquid-based liquid-phase microextraction techniques
Abstract
3.1 Introduction
3.2 Ionic liquid-based single-drop microextraction
3.3 Ionic liquid-based hollow-fiber liquid-phase microextraction
3.4 Ionic liquid-based dispersive liquid-liquid microextraction
3.5 Nature of ILs used in LPME
3.6 Concluding remarks and future directions
Acknowledgements
References
Chapter Four Ionic liquids and polymeric ionic liquids as sorbents in micro-solid-phase extraction and solid-phase microextraction
Abstract
4.1 Ionic liquids and polymeric ionic liquids: useful properties for analytical sample preparation
4.2 Overview on solid-phase extraction and its current limitations
4.3 µ-SPE: principles and configurations
4.4 Application of ILs and PILs in µ-SPE
4.5 SPME: principles and configurations
4.6 Application of ILs and PILs in SPME
4.7 Concluding remarks and future directions
Acknowledgements
References
Chapter Five Magnetic ionic liquids in analytical sample separation techniques
Abstract
5.1 Introduction
5.2 Magnetic ionic liquids in analytical sample preparation: principles and configurations
5.3 Analytical applications using magnetic ionic liquids
5.4 Concluding remarks and future directions
Acknowledgements
References
Chapter Six Ionic liquids as gas chromatography stationary phases
Abstract
6.1 Introduction
6.2 Ionic liquids structures
6.3 Polarity of different GC stationary phases
6.4 Characterization of ionic liquids using multiple solvation interactions
6.5 Applications of ionic liquids in gas chromatography
6.6 Concluding remarks and future directions
References
Chapter Seven Ionic liquids as mobile phase additives and immobilized on stationary phases in liquid chromatography
Abstract
7.1 Introduction
7.2 Ionic liquids as mobile phase additives
7.3 Ionic liquids immobilized on the stationary phase
7.4 Concluding remarks and future directions
References
Chapter Eight Ionic liquids in capillary electrophoresis
Abstract
8.1 Introduction
8.2 Background and purpose of CE
8.3 CE: CZE and NACE
8.4 EKC
8.5 Concluding remarks and future directions
References
Chapter Nine Ionic liquids in chiral separations
Abstract
9.1 Introduction
9.2 Chiral recognition using NMR spectroscopy
9.3 Chiral recognition using fluorescence spectroscopy
9.4 Chiral recognition using gas and liquid chromatography
9.5 Chiral recognition using capillary electrophoresis
9.6 Concluding remarks and future directions
References
Chapter Ten Spectroscopic techniques using ionic liquids
Abstract
10.1 Introduction
10.2 Insights of ionic liquid using spectroscopy as a tool
10.3 Concluding remarks and future directions
Acknowledgements
References
Chapter Eleven Ionic liquids as electrolytes for electrochemistry
Abstract
11.1 Introduction
11.2 Principles
11.3 Methods
11.4 Concluding remarks and future directions
References
Chapter Twelve Use of ionic liquids in electrochemical sensors
Abstract
12.1 Introduction
12.2 Difference between ionic liquids and ionic liquid crystals
12.3 Types of ionic liquid crystals (mesophases, mesogenic and polymer liquid crystals)
12.4 Structure properties relationship in ionic liquids
12.5 Ionic liquids/solid electrified interface
12.6 Surface modification with ionic liquids and ionic liquid crystals
12.7 Electrochemical sensors with ionic liquids and ionic liquid crystals
12.8 Concluding remarks and future directions
References
Chapter Thirteen Future perspectives for ionic liquids
Abstract
13.1 Introduction
13.2 Pure ionic liquids
13.3 Applications envolving ionic liquids
13.4 Greeness and designer solvents
13.5 Conclusions
References
Index

Samuel Carda-Broch

Samuel Carda-Broch was born in Villarreal (Castelló, Spain). He obtained his PhD from the University of Valencia in 1999 under the direction of Prof. García-Álvarez-Coque. After working in the pharmaceutical industry (Italfármaco, Madrid, Spain), in 2001 he moved to the Laboratoire des Sciences Analytiques at the University Claude Bernard in Lyon (France) for a post-doctorate stay under the supervision of Dr. Alain Berthod, granted by a Marie Curie fellowship. In 2002, he moved to the Department of Chemistry and Biochemistry at the Iowa State University (USA), together with Prof. Alain Berthod to work with Prof. Daniel Armstrong. He has worked in the University Jaume I in Castellón (Spain) since 2003, where he is Professor. He has written more than 100 research articles, most focusing on the field of applied analysis, with a main focus on micellar liquid chromatography. He has also made outstanding contributions in countercurrent chromatography and the use of ionic liquids in chemical analysis.

Affiliations and expertise

Professor, University Jaume I in Castellon, Spain

Maria Jose Ruiz-Angel

María José Ruiz-Ángel was born in Valencia (Spain). She obtained her PhD from the University of Valencia (Spain) in 2003 under the direction of Prof. García-Álvarez-Coque. Between 2004 and 2006, she was granted with a post-doctorate fellowship in the Laboratoire des Sciences Analytiques at the University Claude Bernard in Lyon (France) under the supervision of Prof. Alain Berthod. Between 2007 and 2008, she was awarded with a Ramón y Cajal research position in the Department of Analytical Chemistry at the University of Valencia, where she has been Professor since March 2012. She has written over 70 research articles, most focusing on secondary equilibria using surfactants and ionic liquids, fundamental studies in HPLC, modelling and optimisation in HPLC, countercurrent chromatography and development of analytical methods for pharmaceutical and clinical samples.

Affiliations and expertise

Department of Analytical Chemistry, University of Valencia, Spain

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