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# Introduction to Quantum Mechanics

## in Chemistry, Materials Science, and Biology

- 1st Edition - June 7, 2004
- Author: Sy M. Blinder
- Language: English
- Paperback ISBN:9 7 8 - 0 - 1 2 - 1 0 6 0 5 1 - 0
- eBook ISBN:9 7 8 - 0 - 0 8 - 0 4 8 9 2 8 - 5

Introduction to Quantum Mechanics provides a lucid, up-to-date introduction to the principles of quantum mechanics at the level of undergraduates and first-year graduate students… Read more

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Request a sales quote*Introduction to Quantum Mechanics* provides a lucid, up-to-date introduction to the principles of quantum mechanics at the level of undergraduates and first-year graduate students in chemistry, materials science, biology and related fields. It shows how the fundamental concepts of quantum theory arose from classic experiments in physics and chemistry, and presents the quantum-mechanical foundations of modern techniques including molecular spectroscopy, lasers and NMR.

Blinder also discusses recent conceptual developments in quantum theory, including Schrödinger's Cat, the Einstein-Podolsky-Rosen experiment, Bell's theorem and quantum computing.

- Clearly presents the basics of quantum mechanics and modern developments in the field
- Explains applications to molecular spectroscopy, lasers, NMR, and MRI
- Introduces new concepts such as Schrödinger's Cat, Bell's Theorem, and quantum computing
- Includes full-color illustrations, proven pedagogical features, and links to online materials

1. ATOMS AND PHOTONS

1.1 Atomic and Subatomic Particles

1.2 Electromagnetic Waves

1.3 Three Failures of Classical Physics

1.4 Blackbody Radiation

1.5 The Photoelectric Effect

1.6 Line Spectra

1A. Maxwell's Equations

1B. Planck Radiation Law

2. WAVES AND PARTICLES

2.1 Double-Slit Experiment

2.2 Wave-Particle Duality

2.3 The Schrƒodinger Equation

2.4 Operators and Eigenvalues

2.5 The Wavefunction Exercises

3 SIMPLE SYSTEMS

3.1 Free Particle

3.2 Particle in a Box

3.3 Free-Electron Model

3.4 Three-Dimensional Box

Exercises

4. PRINCIPLES OF QUANTUM MECHANICS

4.1 Hermitian Operators

4.2 Eigenvalues and Eigenfunctions

4.3 Expectation Values

4.4 More on Operators

4.5 Postulates of Quantum Mechanics

4.6 Dirac Notation

4.7 Variational Principle

4.8 Spectroscopic Transitions

4A. Radiative Transitions Exercises

5. HARMONIC OSCILLATOR

5.1 Classical Oscillator

5.2 Quantum Harmonic Oscillator

5.3 Eigenfunctions and Eigenvalues

5.4 Operator Formulation

5.5 Quantum Theory of Radiation

5A. Gaussian Integrals

5B. Hermite Polynomials

Exercises

6. ANGULAR MOMENTUM

6.1 Particle in a Ring

6.2 Free Electron Model

6.3 Spherical Polar Coordinates

6.4 Rotation in Three Dimensions

6.5 Theory of Angular Momentum

6.6 Electron Spin

6.7 Addition of Angular Momenta

6A. Curvilinear Coordinates

6B. Spherical Harmonics

6C. Pauli Spin Algebra

7. HYDROGEN ATOM

7.1 Atomic Spectra

7.2 The Bohr Atom

7.3 Hydrogenlike Atoms

7.4 Ground State

7.5 Atomic Orbitals

7.6 p- and d-Orbitals

7.7 Summary on Atomic Orbitals

7.8 Reduced Mass

7A. Laguerre Polynomials

Exercises

8. HELIUM ATOM

8.1 Experimental Energies

8.2 Variational Calculations

8.3 Spinorbitals and the Exclusion Principle

8.4 Excited States of Helium

Exercises

9. ATOMIC STRUCTURE

9.1 Slater Determinants

9.2 Aufbau Principles

9.3 Atomic Configurations and Term Symbols

9.4 Periodicity of Atomic Properties

9.5 Relativistic Effects

9.6 Spiral Periodic Table

9.7 Self-Consistent Field

Exercises

10. THE CHEMICAL BOND

10.1 The Hydrogen Molecule

10.2 Valence Bond Theory

10.3 Molecular Geometry

10.4 Hypervalent Compounds

10.5 Valence-Shell Model

10.6 Transition Metal Complexes

10.7 The Hydrogen Bond

10.8 Critique of Valence-Bond Theory

Exercises

11. DIATOMIC MOLECULE ORBITALS

11.1 Hydrogen Molecule-Ion

11.2 LCAO Approximation

11.3 Homonuclear Diatomics

11.4 Variational Computations

11.5 Heteronuclear Molecules

11.6 Electronegativity Exercises

12. POLYATOMIC MOLECULES

12.1 Hƒuckel MO's

12.2 Woodward-HoÆmann

12.3 Metals and Semiconductors

12.4 Computational Chemistry

12.5 Density Functional Theory

Exercises

13. MOLECULAR SYMMETRY

13.1 The Ammonia Molecule

13.2 Group Theory

13.3 Quantum Mechanics

13.4 Molecular Orbitals for Ammonia

13.5 Selection Rules

13.6 The Water Molecule

13.7 Walsh Diagrams

13.8 Molecular Symmetry Groups

13.9 Dipole Moments and Optical Activity

13.10 Character tables Exercises

14. MOLECULAR SPECTROSCOPY

14.1 Vibration of Diatomic Molecules

14.2 Vibration of Polyatomic Molecules

14.3 Rotation of Diatomic Molecules

14.4 Rotation-Vibration Spectra

14.5 Molecular Parameters from Spectroscopy

14.6 Rotation of Polyatomic Molecules

14.7 Electronic Excitations

14.8 Lasers

14.9 Raman Spectroscopy

Exercises

15. NUCLEAR MAGNETIC RESONANCE

15.1 Magnetic Properties of Nuclei

15.2 Nuclear Magnetic Resonance

15.3 The Chemical Shift

15.4 Spin-Spin Coupling

15.5 Mechanism for Spin-Spin Interactions

15.6 Magnetization and Relaxation Processes

15.7 Pulse Techniques and Fourier Transforms

15.8 Two-Dimensional NMR

15.9 Magnetic Resonance Imaging

Exercises

16. WONDERS OF THE QUANTUM WORLD

16.1 The Copenhagen Interpretation

16.2 Superposition

16.3 Schrƒodinger's Cat

16.4 Einstein-Podolsky-Rosen Experiment

16.5 Bell's Theorem

16.6 Aspect's Experiment

16.7 Multiple Photon Entanglement

16.8 Quantum Computers

Exercises

Suggested References

Answers to Exercises

- No. of pages: 319
- Language: English
- Edition: 1
- Published: June 7, 2004
- Imprint: Academic Press
- Paperback ISBN: 9780121060510
- eBook ISBN: 9780080489285

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### Sy M. Blinder

*Introduction to Quantum Mechanics*on ScienceDirect