Introduction to Fluoropolymers
Materials, Technology, and Applications
- 2nd Edition - December 8, 2020
- Imprint: William Andrew
- Author: Sina Ebnesajjad
- Language: English
- Hardback ISBN:9 7 8 - 0 - 1 2 - 8 1 9 1 2 3 - 1
- eBook ISBN:9 7 8 - 0 - 1 2 - 8 1 9 2 9 9 - 3
Introduction to Fluoropolymers, Second Edition, provides a comprehensive overview of the history, principles, properties, processing and applications of fluoropolymers, supportin… Read more
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Request a sales quoteIntroduction to Fluoropolymers, Second Edition, provides a comprehensive overview of the history, principles, properties, processing and applications of fluoropolymers, supporting their development and utilization in high-performance applications, components, and products. This second edition has been updated and expanded to include new in-depth chapters on manufacturing and applications of PTFE and melt processible fluoropolymers.
The book begins by demonstrating the role of fluoropolymers in everyday life, before introducing the history and basic principles of fluoropolymers. This is followed by detailed coverage of the main fluoropolymer types. Properties and applications are illustrated by real-world examples as diverse as waterproof clothing, vascular grafts and coatings for aircraft interiors. The different applications of fluoropolymers show the benefits of a group of materials that are highly water-repellant and flame-retardant, with unrivalled lubrication properties and a high level of biocompatibility. Health and safety and environmental aspects are also covered throughout the book, with a final chapter examining safety, disposal, and recycling in detail.
This book is an essential resource for anyone looking to understand or use fluoropolymer materials in their products. This includes engineers, product designers, manufacturers, scientists, researchers, and other professionals, across industries such as automotive, aerospace, medical devices, food and beverages, high performance apparel, oil and gas, renewable energy, solar photovoltaics, electronics and semiconductors, pharmaceuticals, and chemical processing. This is also a valuable introductory guide for academic researchers and advanced students in plastics engineering, polymer science, and materials science.
- Introduces and demystifies fluoropolymers for a wide audience of engineers, designers, professionals, and researchers, across industries and disciplines
- Covers a broad range of materials, including polytetrafluoroethylene (PTFE), polyvinyl fluoride (PVF), vinylidene fluoride polymers, fluoroelastomers, and more
- Focuses on properties, processing methods and advanced industrial applications of fluoropolymers
Industry: Engineers, product designers, manufacturers, scientists, researchers, and other professionals, across industries (plastics engineering, automotive, aerospace, medical devices, food & beverages, high performance apparel, oil & gas, renewable energy, solar photovoltaics, electronics & semiconductors, pharmaceuticals, chemical processing, etc.);Academia: Researchers and advanced students conducting interdisciplinary research in plastics engineering, polymer science, or materials science
- Cover image
- Title page
- Table of Contents
- Copyright
- Dedication
- List of Contributors
- Introduction
- 1. Fluorine, Fluorocarbons, and Fluoropolymers in Human Life—A Day With the Smiths
- Abstract
- Outline
- References
- 2. From Fundamentals to Applications
- Abstract
- Outline
- 2.1 Introduction
- 2.2 What Makes Fluorine Unique?
- 2.3 Fluorine Characteristics
- 2.4 What Are Fluoropolymers?
- 2.5 Fundamental Properties of Fluoropolymers
- 2.6 Developmental History of Fluoropolymers
- 2.7 Examples of Uses of Fluoropolymers
- References
- 3. Fluoropolymers—Discovery, History, Evolution, and Consumption
- Abstract
- Outline
- 3.1 Roy Plunkett’s Story
- 3.2 Commercialization of Polytetrafluoroethylene
- 3.3 Developmental History of Fluoropolymers
- 3.4 State of Fluoropolymers
- 3.5 Summary
- References
- Further Reading
- 4. History of Expanded Polytetrafluoroethylene and W.L. Gore & Associates
- Abstract
- Outline
- 4.1 Early History of W.L. Gore & Associates
- 4.2 Discovery of Expanded Polytetrafluoroethylene
- 4.3 Who Invented Expanded Polytetrafluoroethylene?
- 4.4 Other Expanded Polytetrafluoroethylene Players
- References
- 5. Introduction to Thermoplastic Fluoropolymers
- Abstract
- Outline
- 5.1 Introduction
- 5.2 Fluoropolymer Classifications
- 5.3 Fluoropolymer Products
- 5.4 Monomer Synthesis
- 5.5 Monomer Properties
- 5.6 Polymerization and Finishing
- 5.7 Structure Property Relationship
- 5.8 Properties of Polytetrafluoroethylene
- 5.9 Fabrication Techniques
- 5.10 Applications
- 5.11 Safety
- 5.12 Polymerization Surfactant
- 5.13 Economy
- 5.14 Summary
- References
- 6. Manufacturing and Properties of Polytetrafluoroethylene
- Abstract
- Outline
- 6.1 Introduction
- 6.2 Tetrafluoroethylene Polymers
- 6.3 Tetrafluoroethylene Polymerization Regimes
- 6.4 Tetrafluoroethylene Polymerization Mechanism
- 6.5 Suspension Polymerization Regimes
- 6.6 Polymerizing Tetrafluoroethylene by Suspension Method
- 6.7 Comminution of Suspension Reactor Bead
- 6.8 Pelletized (Free Flow) Granular PTFE
- 6.9 Presintered Granular PTFE
- 6.10 PTFE Filled Compounds
- 6.11 Preparation of Polytetrafluoroethylene by Dispersion Polymerization
- 6.12 Dispersion Polymerization of TFE with APFO Replacements
- 6.13 Dispersion Polymerization Reactor
- 6.14 Preparation of Dispersion Grade PTFE
- 6.15 Preparation of Fine Powder PTFE
- 6.16 Characterization of Polytetrafluoroethylene by Properties
- 6.17 Commercial PTFE Resins
- References
- Further Reading
- 7. Processing and Fabrication of Granular Polytetrafluoroethylene
- Abstract
- Outline
- 7.1 Introduction
- 7.2 Resin Selection
- 7.3 Compression Molding
- 7.4 Automatic Molding
- 7.5 Introduction to Isostatic Molding
- 7.6 Ram Extrusion
- 7.7 Summary
- References
- Further Reading
- 8. Fabrication and Processing of Fine Powder Polytetrafluoroethylene
- Abstract
- Outline
- 8.1 Introduction
- 8.2 Resin Handling and Storage
- 8.3 Paste Extrusion Fundamentals
- 8.4 Extrusion Aid or Lubricant
- 8.5 Wire Coating
- 8.6 Extrusion of Tubing
- 8.7 Liner Extrusion
- 8.8 Fine Powder Resin Selection
- References
- 9. Fabrication and Processing of Polytetrafluoroethylene Dispersions
- Abstract
- Outline
- 9.1 Introduction
- 9.2 Applications
- 9.3 Storage and Handling
- 9.4 Surfactants
- 9.5 Principles of Coating Technology
- 9.6 Dispersion Formulation and Characteristics
- 9.7 Glass Cloth Coating
- 9.8 Impregnation of Flax and Polyaramide
- 9.9 Coating Metal and Hard Surfaces
- 9.10 Polytetrafluoroethylene Yarn Manufacturing
- 9.11 Film Casting
- 9.12 Antidrip Applications
- 9.13 Filled Bearings
- 9.14 Dedusting Powders
- 9.15 Other Applications
- References
- 10. Manufacturing Melt-Processible Copolymers of Tetrafluoroethylene
- Abstract
- Outline
- 10.1 Introduction
- 10.2 Molecular and Crystalline Structure
- 10.3 Preparation of Perfluoroalkoxy Polymers
- 10.4 Preparation of Perfluorinated Ethylene Propylene Polymers
- 10.5 Preparation of Ethylene Tetrafluoroethylene Polymers
- References
- 11. Introduction to Vinylidene Fluoride Polymers
- Abstract
- Outline
- 11.1 Synthesis of Vinylidene Fluoride
- 11.2 Properties of Vinylidene Fluoride
- 11.3 Preparation of Vinylidene Fluoride Polymers
- 11.4 Characterization of Polyvinylidene Fluoride
- 11.5 Properties of Polyvinylidene Fluoride
- 11.6 Processing Polyvinylidene Fluoride
- 11.7 Applications
- References
- Further Reading
- 12. Processing and Fabrication of Parts from Melt-Processible Fluoropolymers
- Abstract
- Outline
- 12.1 Introduction
- 12.2 General Considerations
- 12.3 Materials of Construction
- 12.4 Rheology of Fluoropolymers
- 12.5 Processing of Fluoropolymers
- 12.6 Injection Molding
- 12.7 Extrusion
- 12.8 Fluoropolymer Tube Extrusion
- References
- 13. Manufacturing and Properties of Polychlorotrifluoroethylene
- Abstract
- Outline
- 13.1 Introduction
- 13.2 Chlorotrifluoroethylene Polymers
- 13.3 Polymerization of Chlorotrifluoroethylene
- 13.4 Copolymerization of Chlorotrifluoroethylene
- 13.5 Properties of Polychlorotrifluoroethylene
- 13.6 Characterization of Polychlorotrifluoroethylene
- 13.7 Commercial Polychlorotrifluoroethylene Resins
- References
- 14. Processing and Fabrication of Polychlorotrifluoroethylene
- Abstract
- Outline
- 14.1 Introduction
- 14.2 Processing Considerations
- 14.3 Compression Molding
- 14.4 Injection Molding
- 14.5 Extrusion
- 14.6 Machining and Joining
- References
- 15. Applications of Fluoropolymers
- Abstract
- Outline
- 15.1 Chemical Processing
- 15.2 Piping
- 15.3 Vessels
- 15.4 Chemical Process Industry Components
- 15.5 Self-Supporting Components
- 15.6 Trends in Using Fluoropolymers in Chemical Service
- 15.7 Semiconductor Processing
- 15.8 Trends for the Use of Fluoropolymers in the Semiconductor Industry
- 15.9 Electrical Applications
- 15.10 Mechanical Applications
- 15.11 Automotive and Aerospace
- 15.12 Medical Devices
- 15.13 Summary
- References
- 16. Fluoroelastomers
- Abstract
- Outline
- 16.1 Introduction
- 16.2 Fluorocarbon Elastomers
- 16.3 Fluorosilicone Elastomers
- 16.4 Fluorinated Thermoplastic Elastomers
- 16.5 Phosphazenes
- 16.6 Safety, Hygiene, and Disposal
- 16.7 New Developments and Current Trends
- References
- Further Reading
- Acronyms and Abbreviations
- Glossary of Terms
- 17. Fluoropolymer and Fluorinated Additives
- Abstract
- Outline
- 17.1 Polymeric Fluorinated Additives
- 17.2 Perfluoropolyether Additives
- 17.3 Polytetrafluoroethylene Modified Waxes
- 17.4 Fluorinated Graphite
- 17.5 Fluorination
- 17.6 Market Size
- References
- Further Reading
- 18. Polyvinyl Fluoride: The First Durable Replacement for Paint
- Abstract
- Outline
- 18.1 Introduction
- 18.2 Basic Properties
- 18.3 Attribute–Application Relationships
- 18.4 Development and Applications of Polyvinyl Fluoride—A Chronological Treatise
- References
- 19. Fluorinated Coatings; Technology, History, and Applications
- Abstract
- Outline
- 19.1 Introduction
- 19.2 Fluoropolymers Used in Coatings
- 19.3 Fluorocoating Compositions
- 19.4 Liquid and Powder Coatings
- 19.5 Application of Fluorocoatings
- 19.6 Commercial Fluorocoating Producers
- 19.7 A Historical Chronology of Fluoropolymer Finish Technology
- 19.8 Food Contact
- 19.9 Commercial Applications of Fluorocoatings
- 19.10 Summary
- References
- 20. Fluorinated Ionomers: History, Properties, and Applications
- Abstract
- Outline
- 20.1 History
- 20.2 Composition
- 20.3 Properties
- References
- 21. Functional Fluoropolymers
- Abstract
- Outline
- 21.1 Introduction
- 21.2 Functional Groups
- 21.3 Functional Fluoropolymers—Partly Fluorinated
- 21.4 Functional Fluoropolymers—Fully Fluorinated
- 21.5 Processing
- 21.6 Applications
- 21.7 Summary
- References
- Index
- Edition: 2
- Published: December 8, 2020
- No. of pages (Hardback): 418
- No. of pages (eBook): 418
- Imprint: William Andrew
- Language: English
- Hardback ISBN: 9780128191231
- eBook ISBN: 9780128192993
SE
Sina Ebnesajjad
Sina Ebnesajjad is the series editor of Plastics Design Library (PDL) published in the William Andrew imprint of Elsevier. This Series is a unique series, comprising technology and applications handbooks, data books and practical guides tailored to the needs of practitioners. Sina was the editor-in-chief of William Andrew Publishing from 2005 to 2007, which was acquired by Elsevier in 2009.
He retired as a Senior Technology Associate in 2005 from the DuPont fluoropolymers after nearly 24 years of service. Sina founded of FluoroConsultants Group, LLC in 2006 where he continues to work. Sina earned his Bachelor of Science from the School of Engineering of the University of Tehran in 1976, Master of Science and PhD from the University of Michigan, Ann Arbor, all in Chemical Engineering.
He is author, editor and co-author of fifteen technical and data books including five handbooks on fluoropolymers technology and applications. He is author and co-author of three books in surface preparation and adhesion of materials, two of which are in their second editions. Sina has been involved with technical writing and publishing since 1974.
His experiences include fluoropolymer technologies (polytetrafluoroethylene and its copolymers) including polymerization, finishing, fabrication, product development, failure analysis, market development and technical service. Sina holds six patents.
Affiliations and expertise
Fluoroconsultants Group, Chadds Ford, PA, USARead Introduction to Fluoropolymers on ScienceDirect