Hydrophilic-Lipophilic Deviation in Formulation Science and Technology
Principles, Methods, and Applications of HLD
- 1st Edition - March 1, 2027
- Latest edition
- Editors: Jean-Louis Salager, Ronald Márquez, Jesús F. Ontiveros
- Language: English
Hydrophilic-Lipophilic Deviation in Formulation Science and Technology: Principles, Methods, and Applications of HLD offers an in-depth examination of the Hydrop… Read more
Description
Description
Hydrophilic-Lipophilic Deviation in Formulation Science and Technology: Principles, Methods, and Applications of HLD offers an in-depth examination of the Hydrophilic-Lipophilic Deviation (HLD) concept as a foundational, quantifiable optimization tool in the formulation science of surfactant, oil, and water systems. It brings together contributions from leading experts to cover the historical development of formulation concepts in the past hundred years, from the Bancroft rule, Winsor R, Beerbover CER, Israelachvili intermolecular packing, Griffin HLB and Shinoda PIT through to the advanced HLD multivariable framework, as a way to select an appropriate multi surrogate expression. It provides a deep dive into critical topics such as surfactant and oil characterization, macro-/micro-/nano-emulsion formulation and properties, particularly interfacial rheology. It also deals with practical applications such as detergency, enhanced oil recovery (EOR), demulsification, asphaltic emulsions, food processing and distribution, cosmetics and medical preparations, and other consumer or industrial products. Each chapter combines theoretical foundations with practical insights, including mistakes and confusions, supported by case studies and recent research findings. The structured approach facilitates a comprehensive understanding the meaning of HLD and its impact on formulation science in various sectors including academia and industry.
This book will address the challenges faced by practitioners in designing and optimizing formulations, ultimately enhancing product performance in interfacial tension, solubilization, time stability and fluid properties. Hydrophilic-Lipophilic Deviation in Formulation Science and Technology: Principles, Methods, and Applications of HLD is written primarily for advanced researchers, scientists, and engineers specializing in formulation science, colloid and interface science, surfactant chemistry, and chemical engineering.
This book will address the challenges faced by practitioners in designing and optimizing formulations, ultimately enhancing product performance in interfacial tension, solubilization, time stability and fluid properties. Hydrophilic-Lipophilic Deviation in Formulation Science and Technology: Principles, Methods, and Applications of HLD is written primarily for advanced researchers, scientists, and engineers specializing in formulation science, colloid and interface science, surfactant chemistry, and chemical engineering.
Key features
Key features
- Introduces the HLD multivariable concept to solve complex formulation problems, enabling accurate prediction of phase behavior and emulsion properties
- Provides in-depth explanation of HLD equations and their practical application in various systems
- Gives the reader guidance on characterizing surfactants and oils using PACN and EACN concepts
- Offers insight into formulation maps for designing stable or unstable emulsion types across different industries
- Outlines strategies to optimize the solubilization of oils in monophasic WIV systems
- Co-Edited by Jean-Louis Salager, a pioneer in surfactant-oil-water systems and formulation science research for more than half a century
Readership
Readership
Researchers, scientists, and engineers specializing in formulation science, colloid and interface science, surfactant chemistry, and chemical engineering
Table of contents
Table of contents
Section 1 Historical Foundations and Fundamental Concepts of HLD as a Surrogate Expression
1. Formulation of Surfactant/Oil/Water Systems: A Historical Approach
2. From SAD to HLD
3. SOW Microstructure particularly at Optimum Formulation
4. Confusions and limitations in different surrogates approach particularly with many different curvature concepts
5. Oils Characterization: EACN Concept
Section 2 Characterization of Oils and Surfactants using HLD
6. Surfactant Characterization: PACN and other parameters including the current trend towards double terms to describe head and tail
Section 3 Emulsion Formulation and Stability using HLD and Formulation Composition Maps
7. Emulsion Formulation
8. HLD and Interfacial Rheology
Section 4 Applications of HLD as an Optimization Tool in Industry and Research
9. HLD in Enhanced Oil Recovery (EOR)
10. HLD and Detergency Applications
11. HLD and Demulsification
12. HLD and Asphaltic Emulsions
13. HLD Equations of State and modelling
14. Closing Perspectives
1. Formulation of Surfactant/Oil/Water Systems: A Historical Approach
2. From SAD to HLD
3. SOW Microstructure particularly at Optimum Formulation
4. Confusions and limitations in different surrogates approach particularly with many different curvature concepts
5. Oils Characterization: EACN Concept
Section 2 Characterization of Oils and Surfactants using HLD
6. Surfactant Characterization: PACN and other parameters including the current trend towards double terms to describe head and tail
Section 3 Emulsion Formulation and Stability using HLD and Formulation Composition Maps
7. Emulsion Formulation
8. HLD and Interfacial Rheology
Section 4 Applications of HLD as an Optimization Tool in Industry and Research
9. HLD in Enhanced Oil Recovery (EOR)
10. HLD and Detergency Applications
11. HLD and Demulsification
12. HLD and Asphaltic Emulsions
13. HLD Equations of State and modelling
14. Closing Perspectives
Product details
Product details
- Edition: 1
- Latest edition
- Published: March 1, 2027
- Language: English
About the editors
About the editors
JS
Jean-Louis Salager
Jean-Louis Salager is Professor Emeritus of Chemical Engineering at the Universidad de Los Andes in Merida, Venezuela. He is internationally recognized for his pioneering work in surfactant-oil-water systems and formulation science. With over five decades of research and teaching experience, he has significantly contributed to the creation and development of the Hydrophilic-Lipophilic Difference (HLD) concept.
Affiliations and expertise
Professor Emeritus, FIRP Laboratory, Department of Chemical Engineering, Universidad de Los Andes, Mérida, VenezuelaRM
Ronald Márquez
Ronald Márquez earned his Ph.D. in Applied Sciences from the Universidad de Los Andes, Venezuela, under the mentorship of Dr. Jean-Louis Salager. His doctoral research centered on the interfacial rheological properties of surfactant-oil-water systems. He completed postdoctoral fellowships at North Carolina State University, working on transforming textile waste into biobased building blocks, and at ESPCI Paris in collaboration with TotalEnergies, focusing on bio-oil/heavy oil interfaces for marine transportation fuels. Dr. Márquez's research interests include interfaces and emulsions, biofuels, interfacial and bulk rheology, surfactants, and sustainable materials. He has authored numerous scientific papers and serves as an Associate Editor of the Journal of Surfactants and Detergents. His professional affiliations include the American Oil Chemists' Society (AOCS) and the American Chemical Society (ACS), where he contributes to the Industry & Communication Committees. Dr. Márquez has been recognized with several awards, including the ENFL American Chemical Society Young Investigator Spotlight Award (2023) and the AOCS Surfactants and Detergents Division's American Cleaning Institute Distinguished Paper Award twice (2019, 2023).
Affiliations and expertise
Assistant Professor, Department of Chemical Engineering, Agrifood, and Biotechnology University of Girona, SpainJO
Jesús F. Ontiveros
Jesús F. Ontiveros is a Maître de Conférences (Associate Professor) at the National Chemistry School of Lille, France (ENSCL-Centrale Lille Institute), within the UMR 8181–UCCS (Unité de Catalyse et Chimie du Solide). He has a robust background in formulation science, specializing in surfactant and oil characterization. His research focuses on surfactant characterization, and studies in phase inversion, foams and microemulsions, particularly for Enhanced Oil Recovery (EOR) and emulsions in cosmetics, energy and other fields.
Affiliations and expertise
Associate Professor, National Chemistry School of Lille (ENSCL-Centrale Lille Institute), France