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Heterogeneous Catalytic Materials
Solid State Chemistry, Surface Chemistry and Catalytic Behaviour
1st Edition - May 23, 2014
Author: Guido Busca
Hardback ISBN:9780444595249
9 7 8 - 0 - 4 4 4 - 5 9 5 2 4 - 9
eBook ISBN:9780444595218
9 7 8 - 0 - 4 4 4 - 5 9 5 2 1 - 8
Heterogeneous Catalytic Materials discusses experimental methods and the latest developments in three areas of research: heterogeneous catalysis; surface chemistry; and the… Read more
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Heterogeneous Catalytic Materials discusses experimental methods and the latest developments in three areas of research: heterogeneous catalysis; surface chemistry; and the chemistry of catalysts. Catalytic materials are those solids that allow the chemical reaction to occur efficiently and cost-effectively.
This book provides you with all necessary information to synthesize, characterize, and relate the properties of a catalyst to its behavior, enabling you to select the appropriate catalyst for the process and reactor system. Oxides (used both as catalysts and as supports for catalysts), mixed and complex oxides and salts, halides, sulfides, carbides, and unsupported and supported metals are all considered. The book encompasses applications in industrial chemistry, refinery, petrochemistry, biomass conversion, energy production, and environmental protection technologies.
Provides a systematic and clear approach of the synthesis, solid state chemistry and surface chemistry of all solid state catalysts
Covers widely used instrumental techniques for catalyst characterization, such as x-ray photoelectron spectroscopy, scanning electron microscopy, and more
Includes characterization methods and lists all catalytic behavior of the solid state catalysts
Discusses new developments in nanocatalysts and their advantages over conventional catalysts
Chemists, Physical Chemists, Chemical Engineers. Graduate and Post graduate students in Catalysis and Reaction Engineering
Chapter 1. Heterogeneous Catalysts
1.1. Introduction
Chapter 2. Preparation of Solid Catalysts: A Short Summary
2.1. Preparation of catalyst precursors
Chapter 3. Characterization of Real Catalytic Materials: An Overview
3.1. Elemental composition of heterogeneous catalysts
3.2. Structural properties of inorganic materials and its characterization
3.3. Morphology characterization
3.4. Analysis of the surface structure and composition
Chapter 4. Practical Application and Testing of Catalytic Materials: A Synthesis
4.1. Shaping of catalysts for industrial catalytic reactions
4.2. Industrial heterogeneous catalytic reactors
4.3. Deactivation of solid catalysts
4.4. Regeneration of reversibly deactivated catalysts
4.5. Laboratory evaluation of the catalytic activity
4.6. Operando methodologies
Chapter 5. Acid and Basic Catalysts: Fundamentals
5.1. Acido-basicity in liquid phases. Fundamentals and historical perspective
5.2. Reactant activation and acid–base catalysis in liquid phases
5.3. The surface acidity and basicity of solids
5.4. Heterogeneous versus homogeneous acid–base catalysis
Chapter 6. Metal Oxides as Acid-Base Catalytic Materials
6.1. Chemistry of metal oxides
6.2. Composition effect on the surface acido-basicity of metal oxides: an overview
6.3. Acido-basicity of supports for catalysts
6.4. Metal oxides as acid and basic catalytic materials
6.5. Mixed metal oxides and their acido-basicity
Chapter 7. Zeolites and Other Structurally Microporous Solids as Acid–Base Materials
7.1. Zeolites
7.2. Aluminophosphates (AlPOs)
7.3. Silicoaluminophosphates (SAPOs)
7.4. Metal heteroatom containing aluminophosphates (MAPOs)
7.5. Very large-pore zeolitic inorganic materials
7.6. Zeolite-like titanosilicates
7.7. Metal Organic Frameworks (MOFs) and similar materials
Chapter 8. Other Solid Acid and Basic Catalytic Materials
8.1. Acid–base catalytic materials from minerals
8.2. Halide salts and halided oxides
8.3. Sulfides, (oxy)nitrides, carbides, phosphides as acid–base materials
8.4. Heteropolyacids and polyoxometallates
8.5. Solid carbonates, phosphates, sulfates and other salts
8.6. Supported inorganic acids
8.7. Supported alkali and alkali-earth metals or organometallics as “basic catalysts”
8.8. Organo-inorganic hybrid materials
8.9. Carbon-based materials
8.10. Polymeric solid acids and bases (ion exchange resins)
Chapter 9. Metal Catalysts for Hydrogenations and Dehydrogenations
9.1. Bulk metal catalysts
9.2. Supported metal catalysts
9.3. Fundamentals of hydrogenation/dehydrogenation
9.4. Metal catalysts for hydrogenation and dehydrogenation reactions
Chapter 10. Catalysts for Hydrogenations, Dehydrogenations and Metathesis: Sulfides and Oxides
10.1. Metal oxides in hydrogenation and dehydrogenation reactions
10.2. Sulfide catalysts
10.3. Olefin metathesis catalysts
Chapter 11. Oxidation Catalysts
11.1. Fundamentals of oxidation catalysis
11.2. Transition-metal mixed oxides for selective and total oxidation reactions
11.3. Metal catalysts for oxidation reactions
11.4. Catalysts for oxidation reactions in the presence of chlorine
11.5. Catalysts for the production and use of hydrogen peroxide
Chapter 12. Polymerization Catalysts and Heterogenized Homogeneous Catalysts
12.1. Solid polymerization catalysts
12.2. Supported or heterogenized homogeneous catalysts
Chapter 13. Heterogeneous Catalysts and Biomass Conversion
13.1. Heterogeneous catalysts and the future of industrial chemistry
13.2. Biomasses as raw materials for industrial chemistry
13.3. Heterogeneous catalysts and conversion of vegetable oils and animal fats
13.4. Heterogeneous catalysts and the conversion of lignocellulosics
13.5. Heterogeneous catalysts and industrial chemistry from renewables
Index
No. of pages: 478
Language: English
Published: May 23, 2014
Imprint: Elsevier
Hardback ISBN: 9780444595249
eBook ISBN: 9780444595218
GB
Guido Busca
Universita di Genova, Fiera del Mare, Pad. D, 1-16129 Genova Italy
Affiliations and expertise
Universita di Genova, Fiera del Mare, Pad. D, 1-16129 Genova Italy