Heterogeneous Catalysis
Fundamentals, Engineering and Characterizations (with accompanying presentation slides and instructor's manual)
- 1st Edition - January 19, 2022
- Latest edition
- Authors: Giovanni Palmisano, Samar Al Jitan, Corrado Garlisi
- Language: English
- Paperback ISBN:9 7 8 - 0 - 3 2 3 - 8 9 8 4 5 - 4
- eBook ISBN:9 7 8 - 0 - 3 2 3 - 8 8 5 8 9 - 8
Heterogeneous Catalysis: Fundamentals, Engineering and Characterizations provides a comprehensive introduction to the theory of heterogenous catalysis, including thermodyn… Read more
Heterogeneous Catalysis: Fundamentals, Engineering and Characterizations provides a comprehensive introduction to the theory of heterogenous catalysis, including thermodynamic and kinetic aspects, adsorption mechanisms, catalytic reactors and catalyst characterization, with an introduction to sustainable catalysis. Representing a reference source for students and researchers working in this rapidly advancing field, the text reflects the many facets of the discipline, linking fundamental concepts with their applications. Beginning with a step-by-step look at the thermodynamics and energetics of catalysis, from basic concepts to the more complex aspects, the book goes on to cover reaction engineering and modeling, ending with sustainable catalysis and characterization techniques typically used for solid catalysts.
Including presentation slides to support research and learning as well as aid quick understanding of the key concepts, this book will be of interest to postgraduate students and researchers working in chemical engineering, chemistry and materials science as well as industrial researchers.
- Includes an accompanying presentation slides aid for easy understanding of key concepts
- Covers the modeling of catalytic reactors and sustainable catalysis
- Includes adsorption/desorption thermodynamics and kinetics
- Details characterization techniques for the assessment of textural, structural, morphological, optical and chemical properties of the catalysts
Researchers and postgraduate students in chemical engineering, chemistry and materials science. Industrial R&D departments and scholars affiliated to governmental or private research centers
Chapter 1. Introduction
1.1 Historical background
1.2 Fundamental concepts and quantities in catalysis
1.2.1 Fractional coverage
1.2.2 Catalytic activity
1.2.3 Conversion, yield and selectivity
1.3 Importance of heterogeneous catalysis in today’s industry
1.3.1 Ammonia synthesis
1.3.2 Sulfuric acid production
1.3.3 Catalytic cracking
1.3.4 Polymerization of alpha-olefins
Questions and Problems
Chapter 2. Fundamentals of the adsorption process
2.1 Physical and chemical adsorption
2.2 Thermodynamics and energetics of adsorption
2.2.1 Heat of adsorption
2.2.2 Binding energy of adsorbates
2.3 Kinetics of adsorption
2.3.1 Adsorption time
2.3.2 Adsorption rate
2.3.3 Potential energy diagrams
2.3.4 The Elovich equation in chemisorption kinetics
2.3.5 Desorption rate
Questions and Problems
Chapter 3. Adsorption models, surface reaction and catalyst architectures
3.1 Adsorption isotherms and their classification
3.1.1 Langmuir isotherm
3.1.2 Henry isotherm
3.1.3 Freundlich isotherm
3.1.4 Temkin isotherm
3.1.5 BET isotherm
3.1.6 Potential theory of Polanyi
3.1.7 Recent approaches to model adsorption isotherms
3.2 Adsorption isobars and isosteres
3.3 Models for surface reactions
3.4 Catalysts, cocatalysts and supports
3.4.1 Catalyst supports
3.4.2 Co-catalysts
Questions and Problems
Chapter 4. Surface area and porosity
4.1 Estimation of the surface area
4.1.1 Gravimetric and dynamic methods
4.1.2 Volumetric methods
4.2 Estimation of porosity and pore size
4.2.1 Dubinin-Radushkevich and the Dubinin-Astakhov methods
4.2.2 Horvath-Kawazoe method
4.2.3 Saito-Foley method
4.2.4 Barrett-Joyner-Halenda method
4.2.5 Dollimore-Heal method
4.2.6 Density functional theory
4.2.7 Mercury porosimetry
4.3 Hysteresis and capillary condensation
4.4 Pore models ‒ morphology
4.5 Mechanisms of diffusion within catalyst pores
Questions and Problems
Chapter 5. Catalytic reaction engineering
5.1 Catalytic reaction steps
5.1.1 External diffusion
5.1.2 Internal diffusion
5.1.3 Adsorption
5.1.4 Surface reaction
5.1.5 Desorption
5.2 Reaction mechanism and the rate-limiting step
5.3 Catalytic reactor design
5.4 Diffusion and reaction in heterogeneous catalysis
5.4.1 Mass transfer-limited and reaction rate-limited reactions
5.4.2 Diffusion with reaction in a catalyst pellet
5.4.3 Thiele modulus
5.4.4 internal and the overall effectiveness factors
5.4.5 Weisz-Prater and the Mears criteria
5.5 Multiple steady states and thermal hysteresis
5.6 Catalyst deactivation and regeneration
Questions and Problems
Chapter 6. Green heterogeneous catalysis
6.1 Conversion of biomass to biofuels
6.1.1 Biomass feedstock
6.1.2 Traditional thermochemical processes for catalytic conversion of biomass
6.1.3 Aqueous phase reforming for hydrogen and alkanes production
6.2. Electrocatalysis
6.2.1 Fundamentals of electrocatalytic processes
6.2.1.1 Types of electrochemical cells
6.2.1.2 Electrochemical kinetics
6.2.2 Water electrolysis
6.2.2.1 Hydrogen evolution reaction
6.2.2.2 Oxygen evolution reaction
6.2.3 Electrochemical CO2 reduction
6.3 Photocatalysis
6.3.1 Fundamentals of photocatalytic processes
6.3.2 Water and wastewater purification
6.3.3 Organic synthesis
Questions and Problems
Chapter 7. Characterization techniques
7.1 X-ray diffraction
7.2 X-ray photoelectron spectroscopy
7.3 X-ray absorption spectroscopy
7.4 Electron microscopy
7.5 Infrared and Raman spectroscopy
7.6 Temperature programmed methods
7.7 Electrochemical techniques
7.7.1 Voltammetry
7.7.2 Electrochemical impedance spectroscopy
7.8 UV-visible and photoluminescence spectroscopy
7.8.1 UV-visible spectroscopy
7.8.2 Photoluminescence spectroscopy
7.9 Solid-state nuclear magnetic resonance (NMR) and electron paramagnetic resonance (EPR) spectroscopies
7.9.1 NMR
7.9.2 EPR
7.10 Computational tools: density functional theory and molecular dynamic simulations
Questions and Problems
- Edition: 1
- Latest edition
- Published: January 19, 2022
- Language: English
GP
Giovanni Palmisano
Giovanni Palmisano is a Professor of Chemical and Petroleum Engineering at the Khalifa University, United Arab Emirates, where he leads research activities mostly focussed on photocatalysis. In Khalifa University he has developed and taught PhD level courses on heterogeneous catalysis and heterogeneous photocatalysis for the past 10 years. He has been main advisor of 9 PhD and MSc students and, overall, he has 15 years of experience in photo‐ and electro‐catalytic processes. His current research activities are mainly focused on photocatalysis applied to water, environment, materials functionalization, energy and organic chemistry. He is co‐author of ca. 110 highly cited journal papers, seven patents, six books and six book chapters. He is associate editor of the Journal of Environmental Chemical Engineering and reviewing editor of Frontiers in Chemistry among others.
Affiliations and expertise
Affiliations and expertise
Professor of Chemical and Petroleum Engineering, Khalifa University, Abu Dhabi, United Arab EmiratesSJ
Samar Al Jitan
Samar Al Jitan is a Postdoctoral Researcher at the University of Antwerp, Belgium. She obtained her PhD in Chemical Engineering from Khalifa University, United Arab Emirates, in 2021. Her current research focuses on developing efficient photocatalytic systems for the conversion of CO2 into fuels. Samar received her B.Sc. degree in Chemical Engineering from the American University of Sharjah (UAE) in 2015 and her M.Sc. degree in Chemical Engineering from Khalifa University of Science and Technology in 2017. Currently, she is pursuing a Ph.D. degree in Engineering from Khalifa University of Science and Technology under the supervision of Dr. Giovanni Palmisano. Samar’s research interests and expertise include photocatalytic reduction processes, advanced oxidation processes, photocatalytic conversion of CO2, photocatalytic degradation of VOCs, photocatalytic wastewater treatment, synthesis and surface modification of photocatalysts, advanced material characterization and analytical chemistry techniques. She is the co‐author of 3 book chapters, 2 of which are on photocatalysis.
Affiliations and expertise
Postdoctoral Researcher, University of Antwerp, BelgiumCG
Corrado Garlisi
Corrado Garlisi is a R&D project manager at AGC Glass Europe, Belgium. He obtained his PhD in Interdisciplinary Engineering from Khalifa University, United Arab Emirates. His main research fields are: heterogeneous catalysis, photocatalysis and thin-film coatings for glass functionalization. Corrado received his bachelor’s and master’s degrees in Chemical Engineering from University of Palermo (Italy). Before pursuing his PhD, he did a two‐year fellowship at ENEA ‐ Italian National Agency for New Technologies, Energy and Sustainable Development ‐ in Brindisi (Italy). Afterwards, he joined Khalifa University of Science and Technology, where he received his PhD in Interdisciplinary Engineering. His research interests include smart glass, heterogeneous catalysis, advanced oxidation technologies, photocatalytic water treatment and nanotechnology. His expertise is mainly focused on thin film deposition by PVD and CVD techniques, optical, morphological, structural characterization of materials and catalyst testing. He is the co‐author of 28 articles in peer‐reviewed journals, 2 book chapters on photocatalysis and 1 US patent.
Affiliations and expertise
R&D project manager, AGC Glass Europe, Belgium.Read Heterogeneous Catalysis on ScienceDirect