Handbook on the Physics and Chemistry of Rare Earths

Including Actinides

1st Edition, Volume 64 - November 21, 2023
Editors: Jean-Claude G. Bunzli, Susan M. Kauzlarich
Language: English
Hardback ISBN:
9 7 8 - 0 - 4 4 3 - 1 9 3 7 4 - 3
eBook ISBN:
9 7 8 - 0 - 4 4 3 - 1 9 3 7 5 - 0

Handbook on the Physics and Chemistry of Rare Earths: Including Actinides, Volume 64, the latest release in this continuous series that covers all aspects of rare earth scienc… Read more

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Handbook on the Physics and Chemistry of Rare Earths: Including Actinides, Volume 64, the latest release in this continuous series that covers all aspects of rare earth science, including chemistry, life sciences, materials science and physics, presents interesting chapters on a variety of topics, with this release including sections on Structure and properties of Ln2M3Ge5 compounds, Giant magnetocaloric effect materials, Lanthanide-based single-molecule magnets, and Magnetic Refrigeration with Lanthanide-Based Materials.

Cover image
Title page
Table of Contents
Series Page
Copyright
Contributors
Preface
Chapter 330: Structural and physical properties of R2M3X5 compounds
Chapter 331: Luminescent lanthanide-based single-molecule magnets
Chapter 332: Modern rare-earth-containing magnetocaloric materials: standing on the shoulders of giant Gd5Si2Ge2
Chapter 333: Rare earth kagome lattice materials
Chapter 334: The Gd3Cu4Ge4 type—structure–property relations
Chapter 335: From binary and complex rare-earth halides via cluster-complex halides to binary and complex polar intermetallics
Chapter 336: Exploring hidden order through Co and Ir substitution in URu2Si2
Dedication to Vitalij K. Pecharsky
Vitalij K. Pecharsky, October 19, 1954 to December 20, 2022
APPENDIX
Chapter 330: Structural and physical properties of R2M3X5 compounds
Abbreviations
1 Introduction
2 R2M3Si5
3 R2M3Ge5
4 R2M3Sn5
5 R2M3(Ga,In)5
6 Other R2M3X5 Variants
7 Conclusion
References
Chapter 331: Luminescent lanthanide-based single-molecule magnets
Abstract
Abbreviations
1 Introduction
2 Two aspects of Ln3+ ions-based complexes: Magnetic properties and photoluminescence
3 Luminescent Ln3+ SMMs
4 Thermometry in luminescent SMMs
5 Conclusions and perspectives
References
Chapter 332: Modern rare-earth-containing magnetocaloric materials: Standing on the shoulders of giant Gd5Si2Ge2
Abstract
List of symbols and acronyms
1 Introduction
2 Modern relevant materials standing on “giant Gd5Si2Ge2” – the shift to gas liquefaction
3 Performance and criticality
4 Epilogue and future outlook
Acknowledgments
References
Chapter 333: Rare-earth kagomé lattice materials
Abstract
1 Introduction
2 The kagomé lattice and representative structure types
3 Electronic and magnetic properties of lanthanide-containing kagomé materials
4 Concluding remarks
Acknowledgments
References
Chapter 334: The Gd3Cu4Ge4 type – Structure–property relations
Abstract
List of symbols and acronyms
1 Introduction
2 Synthesis and crystal chemistry
3 Magnetic and transport properties
4 Mössbauer spectroscopy
5 Summary and outlook
Acknowledgments
References
Chapter 335: From binary and complex rare-earth halides via cluster-complex halides to binary and complex polar intermetallics
Abstract
1 Introduction
2 Rare-earth halides and derivatives
3 Reduced rare-earth halides
4 Complex rare-earth halides
5 Rare-earth metal cluster complexes
6 The competition between cluster complexes and polar intermetallics
7 Conclusions
Acknowledgments
References
Chapter 336: Exploring hidden order through Co and Ir substitution in URu2Si2
Abstract
1 Introduction
2 Experimental details
3 Results
4 Discussion
5 Concluding remarks
Acknowledgments
References

Jean-Claude G. Bunzli

Jean-Claude Bünzli (he/him) is an Honorary Professor emeritus at the EPFL where he founded the Laboratory of Lanthanide Supramolecular Chemistry He earned a degree in chemical engineering in 1968 and a PhD in 1971 from the Swiss Federal Institute of Technology, Lausanne (EPFL). After two years at the University of British Columbia as a teaching postdoctoral fellow (photoelectron spectroscopy) and one year at the Swiss Federal Institute of Technology in Zürich (physical organic chemistry) he was appointed in 1974 as assistant-professor at the University of Lausanne. He launched a research program on the coordination and spectroscopic properties of f-elements and was promoted to full professor of inorganic and analytical chemistry in 1980. During 2009-2013 he was also a World Class University professor at Korea University (South Korea) at the WCU Center for Next Generation Photovoltaic Devices. In 2016, he has been appointed as adjunct professor at the Haimen Institute of Science and Technology (Haimen, Jiangsu, P.R. China) which is a satellite campus of Hong Kong Baptist University. His research interests deal with various aspects of luminescent lanthanide coordination and supramolecular compounds, developing luminescent bioprobes and bioconjugates for the detection of cancerous cells with time-resolved microscopy as well as luminescent materials for various photonic applications, including solar energy conversion. In 1989, he founded the European Rare Earths and Actinide Society which coordinates international conferences in the field and for which he is presently acting as president.

Affiliations and expertise

Swiss Federal Institute of Technology Lausanne (EPFL), Switzerland

Susan M. Kauzlarich

Susan Kauzlarich (she/her) is a Distinguished Professor of Chemistry at the University of California Davis. She received her BS degree in Chemistry from the College of William and Mary and her PhD from Michigan State University. After a postdoctoral research position with John Corbett at Iowa State University, she joined the University of California Davis faculty. She is a world-renowned expert on Zintl phases and the synthesis and characterization of nano-materials, with interests ranging from solar photovoltaics to thermoelectrics and quantum materials. She pioneered the inclusion of rare earth and transition metal analogs of Zintl phases. Prof. Kauzlarich is a Fellow of the American Association for the Advancement of Science and the American Chemical Society. She received the Mayer Distinguished Scholar Award from Argonne National Laboratory, the Francis P. Gavan – John M. Olin Medal, and the American Chemical Society 2022 Inorganic Chemistry Award. She received a NASA Tech Brief Award for her work on thermoelectric power generation. She has been very active in service to the profession: she currently serves as a Deputy Editor for Science Advances after 15 years as an Associate Editor for Chemistry of Materials. She has been recognized for her outstanding mentoring of STEM students, including a U.S. Presidential Award for Excellence in Science, Math, and Engineering Mentoring (2008).

Affiliations and expertise

University of California, Davis

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