Handbook of Preparative Inorganic Chemistry V1
- 2nd Edition - January 1, 1963
- Imprint: Academic Press
- Editor: Georg Brauer
- Language: English
- eBook ISBN:9 7 8 - 0 - 3 2 3 - 1 6 1 2 7 - 5
Handbook of Preparative Inorganic Chemistry, Volume 1, Second Edition focuses on the methods and mechanisms involved in conducting experiments on inorganic chemistry. Composed of… Read more
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Request a sales quoteHandbook of Preparative Inorganic Chemistry, Volume 1, Second Edition focuses on the methods and mechanisms involved in conducting experiments on inorganic chemistry. Composed of contributions of various authors, the first part of the handbook focuses on special methods and devices for inorganic preparations. The materials mentioned include metals, plastics, pure solvents, and mercury. The text also looks at the importance of temperature and electrical discharges at the laboratory. The second part focuses on elements and compounds, hydrogen peroxide, and fluorine. Schematic diagrams and numerical representations are presented. The chemical reactions of these compounds when exposed to different laboratory conditions are analyzed through numerical representations and schematic diagrams. The handbook also presents lengthy discussions on the properties, compositions, and chemical responses of elements, compound, alkali metals, and earth metals. The formulas, reactions, and methodologies used in the experiments are presented. Considering the value of experiments contained, this manual is a valuable reference for readers interested in studying inorganic chemistry.
From the Preface to the First Edition
Preface to the Second Edition
Translation Editor's Preface
Conversion of Concentration Units
Part I Preparative Methods
Preparative Methods
Assembly of Apparatus
Glass
Ceramic Materials
Metals
Plastics
Pure Solvents
Mercury
Sealing Materials and Lubricants
High Temperatures
Low Temperatures
Constant Temperature
Temperature Measurement
High Vacuum and Exclusion of Air
Special Vacuum Systems
Gases
Liquefied Gases as Solvent Media
Electrical Discharges
Purification of Substances
Analysis of Purity
Powder Reactions
Part II Elements and Compounds
Section 1. Hydrogen, Deuterium, Water
Hydrogen H2
Pure Water
Deuterium and Deuterium Compounds
Deuterium D2
Hydrogen Deuteride HD
Deuterium Fluoride DF
Deuterium Chloride DCl
Deuterium Bromide DBr
Deuterium Iodide DI
Deuterium Sulfide D2S
Deuterosulfuric Acid D2SO4
Deuteroammonia ND3
Deuterophosphoric Acid D3PO4
Section 2. Hydrogen Peroxide
Hydrogen Peroxide H2O2
Section 3. Fluorine, Hydrogen Fluoride
Fluorine F2
Hydrogen Fluoride HF
Section 4. Fluorine Compounds
General Remarks
Chlorine Monofluoride ClF
Chlorine Trifluoride ClF3
Bromine Trifluorid BrF3
Bromine Pentafluoride BrF5
Iodine Pentafluoride IF5
Iodine Heptafluoride IF7
Dioxygen Difluoride O2F2
Oxygen Difluoride OF2
Chlorine Dioxide Fluoride ClO2F
Chlorine Trioxide Fluoride ClO3F
Chlorine Tetroxide Fluoride ClO4F
Sulfur Tetrafluoride SF4
Sulfur Hexafluoride SF6
Thionyl Fluoride SOF2
Thionyl Tetrafluoride SOF4
Sulfuryl Fluoride SO2F2
Trisulfuryl Fluoride S3O8F2
Thionyl Chloride Fluoride SOClF
Sulfuryl Chloride Fluoride SO2ClF
Sulfuryl Bromide Fluoride SO2BrF
Fluorosulfonic Acid HSO3F
Potassium Fluorosulfinate KSO2F
Selenium Hexafluoride SeF6
Selenium Tetrafluoride SeF4
Tellurium Hexafluoride TeF6
Nitrogen Trifluoride NF3
Ammonium Fluoride NH4F
Ammonium Hydrogen Fluoride NH4F • HF
Nitrosyl Fluoride NOF
Nitrososulfuryl Fluoride FSO2NO
Nitryl Fluoride NO2F
Fluorine Nitrate NO3F
Phosphorus (ΙII) Fluoride PF3
Phosphorus (V) Fluoride PF5
Phosphorus Dichloride Fluoride PCl2F
Phosphorus Dichloride Trifluoride PCl2F3
Phosphorus Oxide Trifluoride POF3
Tetrachlorophosphonium Hexafluorophosphate (V) PCl4 • PF6
Phosphonitrilic Fluorides (PNF2)3,(PNF2)4
Ammonium Hexafluorophosphate (V) NH4PF6
Ammonium Difluorophosphate (V) NH4PO2F2
Potassium Hexafluorophosphate (V) KPF6
Arsenic (III) Fluoride AsF3
Arsenic (V) Fluoride AsF5
Antimony (III) Fluoride SbF3
Antimony (V) Fluoride SbF5
Antimony Dichloride Trifluoride SbCl2F3
Bismuth (IIΙ) Fluoride BiF3
Bismuth (V) Fluoride BiF4
Carbon Tetrafluoride CF4
Trifluoromethane CHF3
Trifluoroiodomethane CIF3
Carbonyl Fluoride COF2
Carbonyl Chlorofluoride COClF
Carbonyl Bromofluoride COBrF
Carbonyl Iodofluoride COIF
Silicon Tetrafluoride SiF4
Trifluorosilane SiHF3
Hexafluorosilicic Acid H2SiF6
Germanium Tetrafluoride GeF4
Potassium Hexafluorogermanate K2GeF6
Tin (II) Fluoride SnF2
Tin (IV) Fluoride SnF4
Lead (II) Fluoride PbF2
Lead (IV) Fluoride PbF4
Boron Trifluoride BF3
Fluoroboric Acid HBF4
Sodium Fluoroborate NaBF4
Potassium Fluoroborate KBF4
Potassium Hydroxyfluoroborate KBF3OH
Nitrosyl Fluoroborate NOBF4
Aluminum Fluoride
Ammonium Hexafluoroaluminate (NH4)3AlF6
Ammonium Tetrafluoroaluminate NH4AlF4
Gallium (III) Fluoride GaF3
Ammonium Hexafluorogallate (NH4)3(GaF6) 228
Indium (III) Fluoride InF3
Ammonium Hexafluoroindate (NH4)3(InF6)
Thallium (I) Fluoride TlF
Thallium (III) Fluoride TlF3
Beryllium Fluoride BeF2
Ammonium Tetrafluoroberyllate (NH4)2BeF4
Magnesium Fluoride MgF2
Calcium Fluoride CaF2
Strontium Fluoride SrF2
Barium Fluoride BaF2
Lithium Fluoride LiF
Sodium Fluoride NaF
Potassium Fluoride KF
Potassium Hydrogen Fluoride KF • HF
Potassium Tetrafluorobromate(III) KBrF4
Potassium Hexafluoroiodate (V) KIF6
Copper (II) Fluoride CuF2
Silver Subfluoride Ag2F
Silver Fluoride AgF
Silver (II) Fluoride AgF2
Zinc Fluoride ZnF2
Cadmium Fluoride CdF2
Mercury (I) Fluoride Hg2F2
Mercury (II) Fluoride HgF2
Scandium Fluoride ScF3
Yttrium Fluoride YF3
Lanthanum Fluoride LaF3
Cerium (III) Fluoride CeF3
Cerium (IV) Fluoride CeF4
Europium (II) Fluoride EuF2
Titanium (III) Fluoride TiF3
Titanium (IV) Fluoride TiF4
Zirconium (IV) Fluoride ZrF4
Vanadium (III) Fluoride VF3
Vanadium (IV) Fluoride VF4
Vanadium (V) Fluoride VF5
Niobium (V) Fluoride NbF5
Potassium Heptafluoroniobate (V) K2NbF7
Tantalum (V) Fluoride T2F5
Potassium Heptafluorotantalate (V) K2TaF
Chromium (II) Fluoride CrF2
Chromium (III) Fluoride CrF3
Chromium (IV) Fluoride CrF4
Chromyl Fluoride CrO2F2
Molybdenum (VI) Fluoride MoF6
Tungsten (VI) Fluoride WF6
Uranium (IV) Fluoride UF4
Uranium (VI) Fluoride UF6
Manganese (II) Fluoride MnF2
Manganese (ΙII) Fluoride MnF3
Potassium Hexafluoromanganate (IV) KaMnF6
Rhenium (VI) Fluoride ReF6
Iron (II) Fluoride FeF2
Iron (III) Fluoride FeF3
Cobalt (II) Fluoride CoF2
Cobalt (III) Fluoride CoF3
Nickel (II) Fluoride NiF2
Potassium Hexafluoronickelate (IV) K2NiF6
Iridium (VI) Fluoride IrF6
Section 5. Chlorine, Bromine, Iodine
Chlorine Cl2
Chlorine Hydrate Cl2 • 6H2O
Bromine Br2
Bromine Hydrate Br2 • 8H2O
Iodine I2
Hydrogen Chloride HCl
Hydrogen Bromide HBr
Hydrogen Iodide HI
Ammonium Iodide NH4I
Potassium Iodide KI
Iodine Monochloride ICl
Iodine Monobromide IBr
Iodine Trichloride ICl3
Polyhalides
Potassium Triiodide KI3 • H2O
Cesium Dichlorobromide CsBrCl2
Potassium Dichloroiodide KICl2
Cesium Dichloroiodide CsICl2
Potassium Dibromoiodide KIBr2
Cesium Dibromoiodide CsIBr2
Potassium Tetrachloroiodide KICl4
Tetrachloroiodic Acid HICl4 • 4H2O
Dichlorine Oxide Cl2O
Chlorine Dioxide ClO3
Dichlorine Hexoxide Cl2O6
Dichlorine Heptoxide Cl2O7
Bromine Oxides
Diiodine Pentoxide I2O5
Hypochlorous Acid HClO
Sodium Hypochlorite NaClO • 5H2O
Sodium Hypobromite NaBrO • 5H2O
Potassium Hypobromite KBrO • 3H2O
Sodium Chlorite NaClO2 • 3H2O
Chloric Acid HClO3
Ammonium Chlorate NH4ClO3
Barium Chlorate Ba(ClO3)2 • H2O
Bromic Acid HBrO3
Barium Bromate Ba(BrO2)2 • H2O
Iodic Acid HIO3
Perchloric Acid HClO4
Alkaline Earth Perchlorates
Nitrosyl Perchlorate NOClO4
Nitryl Perchlorate NOSClO4
Periodic Acid H5IO6
Sodium Periodates Na3H2IO6, NaIO4
Potassium Periodate KIO4
Barium Periodate Ba3H4(IO6)2
Chlorine Nitrate ClNO3 326
Dipyridineiodine (I) Perchlorate [l(C5H5N)2]ClO4
Bromine (III) Nitrate Br(NO3)3
Iodine (III) Nitrate I(NO3)3
Iodine (ΙII) Sulfate I2(SO4)3
Iodine (ΙΠ) Perchlorate I(ClO4)3
Iodine (III) Iodate I(IO3)3 or I4O9
Oxoiodine (III) Sulfate (IO)2SO4 • H2O
Diiodine Tetroxide IO • IO3 or I2O4
Section 6. OXygen, Ozone
Oxygen O2
Ozone O3
Section 7. Sulfur, Selenium, Tellurium
Sulfur S
Hydrogen Sulfide H2S
Crude Sulfane H2Sx
Pure Sulfanes
Ammonium Hydrogen Sulfide NH4HS
Sodium Hydrogen Sulfide NaHS
Sodium Sulfide Na2S
Potassium Sulfide K2SO
Sodium Disulfide Na2S2
Potassium Disulfide K2S2
Potassium Trisulfide K2S3
Sodium Tetrasulfide Na2S4
Potassium Tetrasulfide K2S4
Sodium Pentasulfide Na2S5
Potassium Pentasulfide K2S5
Potassium Hexasulfide K2S6
Ammonium Pentasulfide (NH4)2S5
Dichloromonosulfane SCl2
Dichlorodisulfane S2Cl2
Dichlorotri-, -tetra-, -penta-, -hexa-, -hepta- and -octa- sulfane S3Cl2, S4Cl2, S5Cl2, S6Cl2, S7Cl2, S8Cl2
Dichlorotrisulfane S3Cl2
Dichlorotetrasulfane S4Cl2
Sulfur Tetrachloride SCl4
Dibromodisulfane S2Br2
Dibromotri-, -tetra-, -penta-, -hexa-, -hepta- and -octa- sulfane S3Br2, S4Br2 , S5Br2, S6Br2, S7Br2, S8Br2
Lower Sulfur Oxides S2O,SO
Disulfur Trioxide S2O3
Polysulfur Peroxide (SO3-4)x
Thionyl Chloride SOCl2
Sulfuryl Chloride SO2Cl2
Chlorosulfonic Acid HSO3Cl
Pyrosulfuryl Chloride S2OBCl2
Thionyl Bromide SOBr2
Peroxymonosulfuric Acid H2SO5
Peroxydisulfuric Acid H2S2O8
Ammonium Peroxydisulfate (NH4)2S2O8
Potassium Peroxydisulfate K2S2O8
Cobalt Sulfoxylate CoSO2 • 3 H2O
Sodium Dithionite Na2S2O4 • 2H2O
Zinc Dithionite ZnS2O4
Sodium Dithionate Na2S2O6 • 2H2O
Barium Dithionate BaS2O6 • 2H2O
Potassium Trithionate K2S3O6
Potassium TetrathionateK2S4O6
Potassium Pentathionate K2S5O6 • 1.5H2O
Potassium Hexathionate K2S6O6
Wackenroder Liquid
Polythionic Acids H2SxO2, H2SxO6
Nitrosyl Hydrogen Sulfate (NO)HSO4
Tetrasulfur Tetranitride S4N4
Tetrasulfur Dinitride S4N2
Disulfur Dinitride S2N2
Sulfur Nitride Tetrahydride S4(NH)
Heptasulfur Imide S7NH
α-Sulfanuric Chloride [OS(N)Cl]3
Trisulfur Dinitrogen Dioxide S3N2O2
Trisulfur Dinitrogen Pentoxide S3N2O5
Selenium Se
Hydrogen Selenide H2Se
Sodium Hydrogen Selenide NaHSe
Sodium Selenide, Potassium Selenide Na2Se, K2Se
Sodium Diselenide Na3Se3
Diselenium Dichloride Se3Cl3
Selenium Tetrachloride SeCl4
Hexachloroselenium Salts
Diselenium Dibromide Se3Br3
Selenium Tetrabromide SeBr4
Selenium Dioxide SeO3
Selenium Oxychloride SeOCl3
Selenous Acid (Anhydrous) H3SeO3
Sodium Selenite Na3SeO2 • 5H2O
Selenic Acid H3SeO4
Sodium Selenate Na3SeO4
Sodium Selenopentathionate Na3SeS4O6 • 3H2O
Selenium Sulfur Trioxide SeSO3
Selenium Nitride Se4N4
Tellurium Te
Colloidal Tellurium Solution
Hydrogen Telluride H2Te
Sodium Telluride, Potassium Telluride Na2Te, K2Te
Sodium Ditelluride Na2Te2
Tellurium Tetrachloride TeCl4
Hexachlorotellurium Salts
Tellurium Tetrabromide TeBr4
Tellurium Tetraiodide TeI4
Tellurium Dioxide TeO2
Tellurous Acid H3TeO3
Sodium Tellurite Na3TeO3
Tellurium Trioxide TeO3
Telluric Acid H6TeO6
Sodium Tetrahydrogentellurate (VI) Na2H4TeO6
Sodium Orthotellurate Na6TeO6
Sodium Telluropentathionate Na3TeS4O6 • 2H2O
Tellurium Sulfur Trioxide TeSO3
Section 8. Nitrogen
Nitrogen N2
Ammonia NH3
Lithium Amide LiNH2
Lithium Imide Li2NH
Sodium Amide NaNH2
Hydrazinium Sulfate N3H6SO4
Hydrazine Hydrate N2H4 • H2O
Hydrazine N2H4
Hydrazoic Acid HN3
Azides
Chlorine Azide ClN3
Monochloramine ClNH2
Nitrogen Trichloride NCl3
Nitrogen Triiodide and Tribromide, Monobromamine
Thionyl Imide SONH
Sulfamide SO2NH2)2
Trisulfimide and Its Silver Salt (SO2NH)3(SO3N)3Ag3 • 3H2O
Nitrous Oxide N3O
Nitric Oxide NO
Nitrogen Trioxide N3O2
Nitrogen Dioxide NO3, N2O48
Nitrogen Pentoxide N3O5
Nitric Acid HNO3
Hyponitrous Acid H2N2O2
Silver Hyponitrite Ag2N2O2
Sodium Hyponitrite Na2N2O2 • 9H2O
Nitramide NH3NO3
Hydroxylammonium Chloride (NH3OH)Cl
Hydroxylammonium Salts
Hydroxylamine NH2OH
Potassium Hydroxylamine Disulfonate HON(SO3K)2
Potassium Dinitrososulfite K2SO3 • (NO)2
Potassium Nitrosodisulfonate ON(SO3K)2
Potassium Nitrilosulfonate N(SO3K)3 • 2H2O
Potassium Imidosulfonate HN(SO3K)2
Potassium Amidosulfonate H2NSO3K
Potassium Chloroimidosulfonate ClN(SO3K)28
Amidosulfonic Acid H2NSO3H
Potassium Hydrazinedisulfonate H2N2(SO3K)2
Potassium Azodisulfonate N2(SO3K)2
Hydroxylamineisomonosulfonic Acid NH3SO4
Nitrosyl Chloride NOCl
Nitrosyl Bromide NOBr
Nitryl Chloride NO2Cl
Sodium Nitrosyl NaNO
Sodium Nitroxylate Na2NO2
Sodium Hyponitrate Na2N2O3
Section 9. Phosphorus
White Phosphorus P4
Red Phosphorus
Black Phosphorus
Colloidal Phosphorus
Phosphine and Diphosphine PH3P2H4
Sodium Dihydrogenphosphide NaPH2
Phosphonium Iodide PH4I
Thiophosphoryl Chloride PSCl3
Phosphoryl (V) Bromide POBr3
Thiophosphoryl (V) Bromide PSBr3
Diphosphoric Acid Tetrachloride P2O3Cl4
Diphosphorus Tetraiodide P2I4
Phosphorus (III) Iodide PI3
Phosphorus (V) Oxide P2O5(P4O1O)
Orthophosphoric Acid H3PO4
Sodium Dihydrogen Phosphate NaH2PO4 • 2H2O
Potassium Phosphate K3PO4 • 8H2O
Hydroxyapatite Ca1O(PO4)6(ΟΗ)2
Condensed Orthophosphates
Polyphosphates
Metaphosphates
Orthophosphorous Acid H3PO3
Hypophosphorous Acid H3PO2
Barium Hypophosphite Ba(H3PO2)3 • H2O
Hypophosphoric Acid H4P2O6
Disodium Dihydrogen Hypophosphate Na2H3P3O6.6H2O
Tetrasodium Hypophosphate Na4P3O6 • 1OH2O
Barium Dihydrogen Hypophosphite BaH3P2O6 • 2H2O
Potassium Peroxydiphosphate Κ4P3O8
Phosphorus Trisulfide P4S3
Phosphorus Pentasulfide P4S5
Phosphorus Heptasulfide P4S7
Diphosphorus Pentasulfide P2S5
Monothiophosphoric Acid H3PO3S
Sodium Monothiophosphate Na3PO3S • 12H2O
Sodium Dithiophosphate Na3PO2S2 • 11H2O
Barium Dithiophosphate Ba3(PO2S2)2 • 8H2O
Sodium Trithiophosphate Na3POS3 • 11H2O
Sodium Tetrathiophosphate Na3PS4 • 8H2O
Tetraphosphorus Triselenide P4Se3
Triphosphorus Pentanitride P3N5
Phosphonitrilic Chlorides (PNCl2)n
Phosphonitrilic Bromides (PNBr2)n
Monoamidophosphoric Acid H2PO3NH2
Disodium Monoamidophosphate Na2PO3NH2 • 6H2O
Diamidophosphoric Acid HPO2(NH2)2
Phosphoryl Triamide PO(NH2)3
Thiophosphoryl Triamide PS(NH2)3
Pyrophosphoryl Tetramide P2O3(NH2)4
Tetrasodium Imidodiphosphate Na4P2O6NH • 1OH2O
Section 10. Arsenic, Antimony, Bismuth
Arsenic As
Arsine AsH3
Sodium Dihydrogen Arsenide NaAsH2
Arsenic Trichloride AsCl3
Arsenic Tribromide AsBr3
Arsenic Triiodide Asl3
Arsenic Diiodide Asl3
Diarsenic Trioxide Ass2O3(As4O6)
Orthoarsenic Acid H3AsO4
Sodium Dihydrogen Orthoarsenate NaH2AsO4 • H2O
Ammonium Orthoarsenate (NH4)3AsO4 • 3H2O
Tetraarsenic Tetrasulfide As4S4
Diarsenic Pentasulfide As2S5
Ammonium Thioarsenate (NH4)3AsS4
Sodium Thioarsenate Na3AsS4 • 8H2O
Sodium Monothioorthoarsenate Na3AsO3S • 12H2O
Sodium Dithioorthoarsenate Na3AsOaS2 • 11H2O
Antimony Sb
Stibine (Antimony Hydride) SbH3
Antimony (IIΙ) Chloride SbCl3
Antimony (V) Chloride SbCl5
Antimony (III) Oxide Chloride SbOCl
Hexachloroantimonic (V) Acid HSbCl6 • 4.5H2O
Nitrosyl Chloroantimonate (V) NO(SbCl6)
Antimony (III) Bromide SbBr3
Antimony (III) Iodide Sbl3
Ammonium Hexabromoantimonate (IV) (NH4)2SbBr6
Antimony (HI) Oxide Sb2O3
Antimony (V) Oxide Sb2O5
Hydrated Antimony (V) Oxide Sb2O5 • (H2O)x
Diantimony Tetroxide Sb2O4
Antimony (ΙΠ)Sulfate Sb2(SO4)3
Antimony (III) Oxide Sulfate (SbO)2SO4
Sodium Thioantimonate (V) Na3SbS4 • 9H2O
Bismuth Bi
Bismuth (III) Chloride BiCl3
Bismuth Dichloride BiCl2
Bismuth Oxide Chloride BiOCl
Bismuth (III) Bromide BiBr3
Bismuth Oxide Bromide BiOBr
Bismuth (III) Iodide Bil3
Bismuth Oxide Iodide BiOI
Bismuth Oxide Nitrite BiONO2
Bismuth (III) Phosphate BiPO4
Bismuth (III) Borate BiBO3 • 2H2O
Sodium Bismuthate KBiO3
Potassium Bismuthate KaBiO3
Dibismuth Tetroxide Bi2O4
Section 11. Carbon
A) Elemental Carbon
B) Graphite Compounds
C) Volatile Carbon Compounds
Section 12. Silicon and Germanium
Silicon Si
Silanes SiH4(Si3H6, Si3H6)
Polysilanes (SiH)x, (SiH2)x
Silicon Tetrachloride SiCl4
Higher Silicon Chlorides
Silicon Tetrabromide SiBr4
Silicon (II) Bromide SiBr2
Silicon Tetraiodide SiI4
Chlorosilanes SiHCl3, SiH2Cl2, SiH3Cl
Tribromosilane SiHBr3
Dimethyldichlorosilane (CH3)2SiCl2
Chlorosiloxanes Si4O4C18, SinOn-1Cl2n+2
Silicon Monoxide SiO
Silicic Acids
Silicon Oxyhydride H2Si2O3
Silicon Disulfide SiS2
Silicon Tetraacetate Si(CH3COO)4
Silicon Cyanate and Silicon Isocyanate Si(OCN)4, Si(NCO)4
Tetraethoxysilane, Tetramethoxysilane Si(OCaH5)4, Si(OCH3)4
Silicates
Germanium
Germanium (IV) Oxide GeO2
Germanium (II) Oxide GeO
Metallic Germanium Ge
Germanium Hydrides GeH4(Ge2H6, G63H6)
Germanium (IV) Chloride GeCl4
Germanium Dichloride GeCl2
Germanium (IV) Bromide GeBr4
Germanium (IV) Iodide GeI4
Germanium Diiodide GeI2
Trichlorogermane
Methylgermanium Triiodide CH3GeI3
Germanium Nitride Ge3N4
Germanium Disulfide GeS2
Germanium Monosulfide GeS
Tetraethoxygermane Ge(OC2H5)4
Germanium Tetraacetate Ge(CH3COO)4
Section 13. Tin and Lead
Tin Sn
Tin (II) Chloride SnCl2
Tin (IV) Chloride SnCl4
Hexachlorostannic Acid H2SnCl6.6H2O
Ammonium Hexachlorostannate, Potassium Hexachlorostannate (NH4)2SnCl6, K2SnCl6
Tin (II) Bromide SnBr2
Tin (IV) Bromide SnBr4
Tin (II) Iodide SnI2
Tin (IV) Iodide SnI4
Tin (II) Oxide SnO
Stannic Acids SnO2 • nH2O
Sodium Orthostannate Na4SnO4
Tin (II) Sulfide SnS
Tin (IV) Sulfide SnS2
Sodium Metathiostannate Na2SnS3 • 8H2O
Sodium Tetrathiostannate (IV) Na4SnS4 • 18H2O
Tin (IV) Sulfate Sn(SO4)2 • 2H2O
Tetramethyltin Sn(CH3)4
Tetraethyltin Sn(C2H5)4
Tin (IV) Acetate Sn(CH3COO)4
Lead Pb
Lead (IV) Chloride PbCl4
Ammonium Hexachloroplumbate (NH4)2PbCl6
Potassium Hexachloroplumbate K2PbCl6
Potassium Iodoplumbite KPbI3 • 2H2O
Lead (II, IV) Oxide Pb3O4
Lead (IV) Oxide PbO2
Sodium Metaplumbate Na2PbO3
Sodium Orthoplumbate Na4PbO4
Calcium Orthoplumbate Ca2PbO4
Lead Sulfide PbS
Lead (IV) Sulfate PB(SO4)2
Lead Azide Pb(N3)2
Tetramethyllead Pb(CH3)
Tetraethyllead Pb(C2H5)4
Neutral and Basic Lead Carbonate PbCO3, 2PbCO2 • Pb(OH)2
Lead (IV) Acetate Pb(CH3COO)4
Lead Thiocyanate Pb(SCN)2
Section 14. Boron
Boron
Aluminum Boride A1B2, AlB12
Diborane B2H6
Lithium Borohydride LiBH4
Sodium Borohydride NaBH4
Sodium Trimethoxyborohydride NaHB(OCH3)3
Borine Trimethylaminate BH3 • N(CH3)3
Borazole (HBNH)3
s-Trichloroborazole (C1BNH)3
Boron Trichloride BCl3
Boron Tribromide BBr3
Boron Triiodide BI3
Boron Trifluoride Dihydrate BF3 • 2H2O
Dihydroxyfluoroboric Acid H[BF2(OH)2]
Boron Trifluoride Ammoniate BF3.NH3
Boron Trifluoride Etherate BF3 • O(C2H5)2
Boron (III) Oxide B2O3
Boron (III) Sulfide B2S3
Boron Nitride BN
Sodium Orthoborate Na3BO3
Metaboric Acid HBO2
Sodium Metaborate NaBO2
Sodium Tetraborate Na3B4O7
Sodium Pentaborate NaB5O6 • 5H2O
Sodium Perborate NaBO3.4H2O
Lindemann Glass (Lithium Beryllium Borate)
Boron Phosphate BPO4
Boron Arsenate BAsO4
Boron Methoxide B(OCH3)3
Trimethylboron B(CH3)3
Triethylboron B(C2H5)3
Trimethylborazine (CH3BO)3
Tri-n-Butylboroxine(n-C4H9BO)3
n-Butylboronic Acid n-C4H9B(OH)2
n-Butylboron Difluoride n-C4H9BF2
Sodium Tetraphenylborate Na[B(C6H5)4]
Section 15. Aluminum
Lithium Aluminum Hydride LiAlH4
Calcium Aluminum Hydride Ca(AlH4)2
Polymeric Aluminum Hydride (Α1Η3)n • xO(C2H5)2
Aluminum Chlorohydride Al2Cl3H3
Aluminum Hydride Trimethylaminate AlH3 • 2N(CH3)3, A1H3 • N(CH3)3
Diethylaluminum Bromide Al(C2H5)2Br
Triethylaluminu Al(C2H5)3
Triethylaluminum Etherate Al(C2H5)3 • O(C3H5)2
Diethylaluminum Hydride Al(C2H5)2H
Aluminum Chloride AlCl3
Aluminum Bromide AlBr3
Aluminum Iodide AlI3
Aluminum Chloride Hydrate AlCl3 • 6H2O
Sodium Tetrachloroaluminate NaAlCl46
Tetrachloroaluminic Acid Dietherate HAlCl4 • 2O(C2H5)2
Aluminum Chloride Ammoniate AlCl3.NH3
Aluminum Chloride-Sulfur Dioxide Adduct AlCl3 • SO2
Aluminum Chloride-Thionyl Chloride Adduct Al2Cl6 • SOCl2
Aluminum Chloride-Phosphorus Pentachloride Adduct AlCl3 • PCl5
Aluminum Bromide-Hydrogen Sulfide Adduct AlBr3 • H2S
Aluminum Iodide Hexaammoniate AlI3 • 6NH3
Aluminum Hydroxide
Aluminum Oxide
Aluminum Sulfide Al2S3
Aluminum Sulfite
Aluminum Selenide Al3Se3
Aluminum Telluride Al2Te3
Aluminum Nitride AlN
Lithium Aluminum Nitride Li3AlN2
Aluminum Azide A1(N3)3
Aluminum Phosphide AlP
Lithium Aluminum Phosphide Li3AlP2
Aluminum Orthophosphate AlPO4
Aluminum Arsenide AlAs
Aluminum Carbide Al4C3
Lithium Aluminum Cyanide LiAl(CN)4
Aluminum Methoxide Al(OCH3)3
Aluminum Ethoxide Al(OC2H5)3
Aluminum Triethanolaminate Al(OC2H4)3N
Aluminum Acetate Al(O2CCH3)3
Aluminum Acetylacetonate Al(C5H7O2)3
Section 16. Gallium. Indium, Thallium
Gallium Ga
Trimethylgallium, Tetramethyldigallane, Digallane GaCH3)3, Ga2H2(CH3)4, Ga2H6
Lithium Tetrahydrogallate LiG2H4
Gallium (III) Chloride GaCl3
Gallium (III) Bromide GaBr3
Gallium (III) Iodide GaI3
Gallium (II) Chloride and Gallium (II) Bromide GaCl2, GaBr2
Gallium Hydroxide Ga(OH)3, GaO(OH)
Gallium (III) Oxide α-Ga2O3, ß-Ga2O3
Gallium (I) Oxide Ga2O
Gallium (III) Sulfide Ga2S3
Gallium (II) Sulfide GaS
Gallium (I) Sulfide Ga2S
Ammonium Gallium (III) Sulfate NH4Ga(SO4)2.12H2O
Gallium Selenide Ga2Se3, GaSe, Ga2Se
Gallium Telluride Ga2Te3, GaTe
Gallium Nitride GaN
Gallium Nitrate Ga(NO3)3
Gallium Phosphide, Arsenide and Antimonide GaP, GaAs, GaSb
Indium In
Indium (IΙ) Chloride InCl3
Indium (III) Bromide InBr3
Indium (III) Iodide InI3
Indium (II) Chloride, Bromide and Iodide InCl2, InBr2, InI2
Indium (I) Chloride, Bromide and Iodide InCl, InBr, InI
Indium Hydroxide In(OH)3
Indium (III) Oxide In2O3
Indium (I) Oxide In2O
Indium Sulfides In2S3, InS, In3S
Indium Selenides and Tellurides In2Se3, InSe, In2Se and In2Te3, InTe, In2Te 865
Indium Nitride InN
Indium Phosphide, Arsenide and Antimonide InP, InAs, InSb
Thallium Tl
Thallium (I) Chloride, Bromide and Iodide TlCl, TlBr ,TlI
Thallium (III) Chloride TlCl3, TlCl3.4H2O
Tetrachlorothallium (III) Acid H(TlCl4).3H2O
Thallium (I) Tetrachlorothallate (ΙΙI) Tl(TlCl4)
Thallium (I) Hexachlorothallate (ΙΙI) Tl3(TlCl6)
Potassium Hexachlorothallate (III) K3(TlCl6) • 2H2O
Potassium Pentachloroaquothallate (ΙΙI) K2(TlCl5H2O) • H2O
Cesium Nonachlorodithallate (III) Cs3(Tl2Cl9)
Thallium (III) Bromide TlBr3 • 4H2O
Thallium (I) Tetrabromothallate (III) Tl(TlBr4)
Thallium (I) Hexabromothallate (ΙΙI) Tl3(TlBr6)
Rubidium Hexabromothallate (III) Rb3(TlBr6) • 8/7H2O
Thallium Triiodide TlI • I2, TlI3
Thallium (I) Oxide Tl2O
Thallium (I) Hydroxide TlOH
Thallium (II) Oxide Tl2O3, Tl2O3 • xH2O
Thallium SulfidesT
Thallium (I, ΙΙI) Selenide Tl2Se.Tl2Se3, TlSe
Thallium (I) Sulfate Tl2SO4
Disulfatothallic (III) Acid HTl(SO4)2 • 4H2O
Thallium (III) Hydroxide Sulfate Tl(OH)SO4 • 2H2O
Thallium (I) Nitride Tl3N
Thallium (I) Nitrate TlNO3
Thallium (I) Carbonate Tl2CO3
Thallium (II) Formate, Thallium (I) Malonate, Clerici's Solution
Section 17. Alkaline Earth Metals
Beryllium Be
Beryllium Chloride BeCl2
Beryllium Bromide BeBr2
Beryllium Iodide Bel2 892
Beryllium Oxide and Beryllium Carbonate BeO, BeCO3
Beryllium Hydroxide Be(OH)3
Sodium BeryHates
Beryllium Sulfide BeS
Beryllium Selenide and Beryllium Telluride BeSe, BeTe
Beryllium Nitride Be3N2
Beryllium Azide Be(N3)2
Beryllium Carbides Be2C, BeC2
Beryllium Acetate Be(CH3COO)2
Basic Beryllium Acetate Be4O(CH3COO)6
Magnesium Mg
Magnesium Hydride MgH2
Magnesium Chloride MgCl2
Magnesium Bromide MgBr2
Magnesium Iodide MgI2
Magnesium Oxide MgO
Magnesium Hydroxide Mg(OH)2
Magnesium Sulfide MgS
Magnesium Selenide MgSe
Magnesium Telluride MgTe
Magnesium Nitride Mg3N2
Magnesium Azide Mg(N3)2
Magnesium Phosphide and Magnesium Arsenide Mg3P2, Mg3As2
Magnesium Carbides MgC2, Mg2C3
Magnesium Silicide Mg2Si
Magnesium Germanide Mg2Ge
Calcium, Strontium, Barium Metals
Calcium Strontium and Barium Hydrides CaH2, SrH2, BaH2
Calcium, Strontium, Barium Halides
Calcium Oxide CaO
Strontium Oxide SrO
Barium Oxide BaO
Calcium Hydroxide Ca(OH)2
Strontium Hydroxide Sr(OH)2 • 8H2O, SrO • 9 H2O
Calcium, Strontium, Barium Peroxides CaO2, SrO2, BaO2
Calcium, Strontium, Barium Sulfides CaS, SrS, BaS
Calcium, Strontium, Barium Selenides CaSe, SrSe, BaSe
Calcium, Strontium, Barium Nitrides Ca3N2, Sr3N2, Ba3N2
Barium Azide Ba(N3)2
Calcium Phosphide Ca3P2
Calcium Carbide CaC2
Calcium Cyanamide CaCN2
Calcium Silicides CaSi, CaSi2
Calcium Germanide CaGe
Section 18. Alkali Metals
Alkali Metal Compounds from Minerals
Free Alkali Metals
Alkali Hydrides NaH, KH, RbH, CsH and LiH
Alkali Metal Oxides LisO, Na2O , K2O , Rb2O , Cs2O
Lithium and Sodium Peroxides Li2O2 and Na2O2
Alkali Dioxides
Lithium Hydroxide LiOH • H2O, LiOH
Rubidium and Cesium Hydroxides RbOH, CsOH
Lithium Nitride Li3N
Phosphides, Arsenides, Antimonides and Bismuthides of Alkali Metals from the Elements
Sodium and Lithium Carbides Na2C2, Li2C2
Alkali Metal Carbonates of Highest Purity
Silicides and Germanides of Alkali Metals from the Elements NaSi, KSi, RbSi, CsSi, NaGe, KGe, RbGe, CsGe
Formula Index
- Edition: 2
- Published: January 1, 1963
- Imprint: Academic Press
- No. of pages: 1030
- Language: English
- eBook ISBN: 9780323161275
Read Handbook of Preparative Inorganic Chemistry V1 on ScienceDirect