1. What is Henry's Law
1.1. The Conventional Concept
1.2. Bunsen1s Heidelberg Group of 1855
1.3. Ostwald's Absorption Coefficient
1.4. Horiuti's Statements on the Ostwald Coefficient9
1.5. The Effect of the Vapor of Liquid S, the "Solvent"
1.6. Other Examples of Confusion
2. Effect of Temperature on Gas Solubility
2.1. The Concept of "Ideal Solubility"
2.2. Deviations from "Ideal Solubility"
2.3. The Reference Line (R-line) Procedure
2.4. n-Butane
2.5. Propane
2.6. Ethane
2.7. Methane
2.8. Data on Hydrogen, Ethane, Ethene, and Propane, Reported by Waters, Mortimer, and Clements (1970)
2.9· Data on Hydrogen and Deuterium, by Cook, Hansen, and Alder (1957)
2.10. Solubility of Hydrogen in Organic Liquids - Data by Maxted and Moon (1936)
2.11. Lannung's Data on Helium, Neon, and Argon (1930)
2.12. The Work of Siddkind and Kasarnowsky on the Solubility of Argon (1931,1933)
2.13. The Concept of Gas Solubility According to Phillips and Williams (1965)
2.14. The Solubility of Krypton - The Work of Korosy (1937), and van Liempt and van Wijk (1937)
2.15. Further Comments on the Making and Filling of Holes
2.16. R-line and "Ideal" Solubilities at 1 Atm and Different Temperatures
2.17. Data on the Noble Gases (He to Xe) by Clever, Battino, Saylor, and Gross
2.18. Solubility of Argon in Alcohols, Carbon Disulphide, and Perfluoroheptane: Lata by Gjaldbaek and Niemann (1958)
2.19. Hildebrand and Colleagues on Solubility and Entropy of Solution
2.20. The Theoretical Approach Based on Statistical Mechanics
2.21. Solubility of Helium, Neon, Hydrogen, and Deuterium in Liquid Argon
3. The Gases Used by Horiuti
3.1. Two Aspects: Solubility and Dilation
3.2. Solubility Data: Gases of "Great Solubility"
3.3. Solubility of Gases at "Medium Solubility"
3.4. Gases of "Small Solubility"
3.5. Data for N2O by Kunerth
3.6. Data on N2O by Yen and McKetta
3.7. Data by G. Jaldbaek for CO in Alcohols
4. Evaluation of Data on Sulfur Dioxide
4.1. The Two Dominating Conventional Concepts
4.2. The Muddle Over Henry's Law
4.3. The Solubility of Sulfur Dioxide in Diethylaniline
4.4. Solubility of SO2 in Benzene
4.5. Data by Albright, Shannon, Yu, and Chueh (1963)
4.6. Data by Pfeifer (1963)
4.7. Solubility in Di-n-butyl Ether
4.8. Solubility in Ethylene Glycol at 0°C
4.9. Solubility in Water
5. Evaluation of Chlorine Data
5.1. Principles and Methods of Measurements
5.2. The Technique of Taylor and Hildebrand (1923)
5.3. Solubility in Hydrocarbons
5.4. Solubility in Halogenated Hydrocarbons
5.5. Solubility in Carbon Disulfide and its Chlorination Products
5.6. Solubility in Organic Compounds Containing Oxygen
5.7. Solubility in Inorganic Chlorides
5.8. Solubility in Water
6. Evaluation of Solubility Data for Hydrogen Sulfide
6.1. Rejection of Henry's Law
6.2. Solubility in Nonaqueous Liquids
6.3. Solubility in n-Decane
6.4. Data by Gerrard
6.5. Solubility in Water
7. The Solubility of Radon 226/86Rn, Thoron 220/86Rn, and Actinon 219/86Rn in Liquids
7.1. The Measurement of Solubility by Radioactivity
7.2. Expression of Solubility of Radon as the Ostwald Coefficient
7.3. The Work of Eva Ramstedt
7.4. The Work of Kofier
7.5. The Work of Nussbaum and Hursh
7.6. Solubility Data for Radon
7.7. Confusion in the Data Books
7.8. Rational Evaluation of Data for Radon
7.9. The Effect of Temperature and Pressure
7.10. Solubility in Biological Fluids
7.11. Solubility in Aqueous Solutions of Salts and Organic Compounds
7.12. Recent Contributions
7.13. The Solubility of Thoron and Actinon
8. Solubilities of Diborane, and the Gaseous Hydrides of Groups IV, V, And VI of the Periodic Table
8.1. The Purpose of this Analysis
8.2. The Chromatographic Procedure Followed
8.3. Significance of the Distribution Coefficient, K
8.4. Group VI Systems: H2S, H2Se, H2Se, H2Te
8.5. Hydrides of Group V: PH3, AsH3, SbH3
8.6. Hydrides of Group IV: CH4, SiH4, GeH4, SnH4
8.7. Diborane
8.8. Solubility Spectrum 199
8.9. Lack of Numerical Correlation between Ê and N^ Values 199
8.10. Heats of Solution 199
8.11. Influence of Carrier Gas
8.12. Conclusion
8.13. Data for Arsine by Corriez and Berton
9. Solubility of Gases Containing Fluorine
9.1. SF6, CF4, NF3
9.2. Solubility of Octafluoropropane, C3F8, Octafluorocyclobutane, Cyclo C4F8, Chlorotrifluoromethane, CClF3; and for Contrast, Propane and Cyclopropane
9.3 Data for Hexafluoroethane Compared with those for Ethane
9.4. Solubility of Gaseous Chlorofluorohydrocarbons Containing Hydrogen
9.5. Solubility of Freons in Lubricating Oils of Refrigeration Units
9.6. Solubility of CClF3 and CCl2 and CCl2 in Four Liquid Hydrocarbons, and in Tetrachloromethane
9.7. Solubility of Gases in Hexafluorobenzene and in Benzene
9.8. Solubility of Boron Trifluoroacetonitrile, CF3CN
9.9. Solubility of Boron Trifluoride
9.10. Solubility of "Inert Gases" in Human Lung Tissue
9.11. Reference Diagrams for Other Gases Containing Fluorine
10. Hildebrand's Theory in the Light of all Gas Solubility Data
10.1. The Significance of Heat of Vaporization and Boiling Point/1 Atm
10.2. Hildebrand1s Regular Solutions
10.3. Hildebrand's Solubility Parameter
10.4. Examples of Invalid Classifications and Terminology
10.5. Extrapolations of the Mole Fraction, NA, vs Temperature Plots to the Critical Temperature, TC, of the Liquid, S
10.6. Solubility of Vinyl Chloride
10.7. Environmental Significance of the Solubility of Hydrocarbons in Water and Aqueous Solutions of Salts
10.8. Significance of the Solubility of Mercury in Water
10.9. Solubility of Tetraethyllead in Water
10.10. Ideality vs Reality
11. The Hydrogen Halide System
11.1. Previous Analysis by Gerrard
11.2. Vapor Pressure Measurements
11.3. Hydrogen Chloride as a Strong Electrolyte
11.4. Textbook Statements About the Solubility of Hydrogen Halides
11.5. Significance of the Reported Change in Electric Dipole Moment,UHX (Debye throughout) on Dissolution in Liquids
11.6. Hydrogen Fluoride as a "Solvent"
11.7. The Unnecessary Invocation of Fugacity
11.8. Graphical Illustration of the Effect of a Change in Temperature on the Mole Fraction Solubility of the Hydrogen Halides (HCl, HBr, HI)
12. Solubility of Gases in Water and Aqueous Solutions of Salts, Inorganic Acids and Bases, and Organic Compounds
12.1. Solubility in Water
12.2. Himmelblau's Review
12.3. Review by Wilhelm, Battino, and Wilcock
12.4. The Two Papers by Antropoff
12.5. Comparison of the Solubilities of the Noble Gases in Water and in Olive Oil
12.6. Thermodynamical Aspects
12.7. Solubility of Gases in Aqueous Solutions of Inorganic Salts
12.8. Solubility of Gases in Aqueous Solutions of Other Compounds
12.9. The Work of Sada and Colleagues
13. Gases in Sea Water
13.1. Resources of the Sea
13.2. The Oceans; their Physical Chemistry and General Biology
13.3. Marine Chemistry
13.4. Dissolved Gases other than CO2
13.5. Solubility of Carbon Dioxide in Pure Water, Synthetic Sea Water and Synthetic Sea Water Concentrates at 10 to45 atm and at - 5° to 25°C
13.6. SO2 in Sea Water
13.7. Recent Discussions on the Chemistry of Sea Water
14. Aerosol Propellants
14.1. The Aerosol Handbook
14.2. The Fluorocarbon Propellants
14.3. The Chlorocarbon Propellants
14.4. Hydrocarbon Propellants
14.5. The Compressed Gas Propellants
14.6. The Ether Propellants
14.7. Hsu and Campbell's Work on the Solubility of N2O and CO2
14.8. Carbon Dioxide as an Aerosol Propellant
15. The Solubility op Nitric Oxide
15.1 Initial Approach
15.2. Registration of the Mole Fraction Solubilities of Nitric Oxide on the Reference Line Diagram for Krypton
15.3. Comments on the Individual Papers
15.4. Solubility in Water
15.5. Solubility in Solutions of Metallic Salts
15.6. Solubility of Nitric Oxide in Aqueous Solutions of Sulphuric Acid
15.7. Solubility of Nitric Oxide in Nitrosyl Chloride
15.8. Solubility of Nitric Oxide in Nitrose
15.9. Further Comment on the Work of Manchot
16. Biotechnological Aspects
16.1. Scope of Interest
16.2. Data by Meyer and Gottlieb-Billroth
16.3. Data on CO2 by Van Slyke and Colleagues
16.4. Data by Vibrans
16.5. Data by Schaffer and Haller
16.6. Data by Cull en and Gross
16.7. The Paper of Davidson, Eggleston, and Foggie
16.8. The Solubility of C02 in Body Fat 370
16.9. Connection of the Solubilities of Gases in Olive Oil and the Theories of Transport through Cell Membranes
16.10. Cyclopropane as an Anesthetic Gas
16.11. Halothane, CF3CHClBr, as an Anesthetic Gas
16.12. Solubility of "Inert" Gases in Human Lung Tissue
16.13. The Work of Yeh and Peterson
16.14. Pauling's Molecular Theory of General Anesthesia
16.15. The Diffusion of Gases in Protein Solutions
17. More on Making Holes
17.1. "Nonpolar" Gases in Water
17.2. A Test of Pierotti's Theory
17.3. Other Data by De Ligny and Colleagues
17.4. Solubility of Gases in Polyethylene
17.5. Solubility of Nitric Oxide and "Henry's Law Constants"
17.6. The Solubility of Mercury in Liquids
17.7. Solubility of Water in Hydrocarbons
17.8. Solubility of Gases in Water Containing Colloids
17.9· Lewis and Randall's Calculation of Activity
17.10. The Aspects of Surface Tension and Viscosity
17.11. Comments on Certain Measurements of the Solubility of Hydrocarbon Gases, Including Acetylene (Ethyne)
17.12. Determination of Gas Solubilities by Gas-Liquid Chromatography
17.13. Predictions of Gas Solubilities
18. Evaluation of Data on Phosphine
18.1. Solubility of Phosphine in Organic Liquids
18.2. Significance of Acid-Base Function
18.3. Thermodynamic Data
18.4. Comparison with Arsine and Stibine
18.5. Acknowledgment
References
Index