Electronic Charges of Bonds in Organic Compounds

PrefaceChapter I. Historical Outline and Introduction 1. History of the Classical and Electronic Theory of the Structure of Organic Compounds 2. Conception of Electronic Charges of Bonds 3. Introduction to the Subsequent Chapters ReferencesChapter II. Electronegativities (Electronophilic Nature) of Atoms 1. Relationship between Electronegativities of Atoms and Electronic Bond Charges 2. Mechanism of the Mutual Effect of Atoms ReferencesChapter III. Dipole Moments 1. Dipole Moments of Halomethanes and Electronegativities of Halogens 2. Dipole Moment of Isobutane and Electronegativity of Carbon ReferencesChapter IV. Frequencies of Valency Vibrations of C—H Bonds in Hydrocarbons 1. Relationship of Force Constants and Frequencies of Valency Vibrations to Electronic Bond Charges 2 Electronic Bond Charges in Cyclopropane ReferencesChapter V. Interatomic Distances 1. The Linear Relationship between π-Electron Bond Charges and Interatomic Distances 2. Calculating Linear Equations 3. π-Electron Bond Charges in Organic Compounds 4. Relationship between σ-Electron Charges and Bond Lengths ReferencesChapter VI. Heats of Formation 1. Two Relationships between the "Heats of Elementization" of Hydrocarbons and Electronic Bond Charges 2. Saturated Hydrocarbons 3. Unsaturated Hydrocarbons 4. Chlorine and Bromine Derivatives of Paraffins 5. Organic Compounds Containing Oxygen ReferencesChapter VII. Heat Effects of Organic Reactions 1. Hydrogenation and Bromination of Ethylene and Its Homologues 2. Isomerization of Mono-Olefins ReferencesChapter VIII. Organic Radicals and Ions 1. Radicals and Dissociation Energies of Bonds 2. Energy Stability of Carbanions and Carbonium Ions ReferencesChapter IX. Chemical Properties of σ-Bonds 1. Substitution Reactions at a Saturated Carbon Atom 2. Cleavage Reactions ReferencesChapter X. Chemical Properties of σ-Bonds 1. Addition Reactions 2. Substitution Reactions in Benzene Derivatives ReferencesConclusionSubject Index