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Electronic Charges of Bonds in Organic Compounds
- 1st Edition - October 2, 2013
- Author: G. V. Bykov
- Editor: R. W. Clarke
- Language: English
- Paperback ISBN:9 7 8 - 1 - 4 8 3 1 - 1 7 0 9 - 6
- eBook ISBN:9 7 8 - 1 - 4 8 3 1 - 4 9 5 1 - 6
Electronic Charges of Bonds in Organic Compounds discusses trends in the electronic theory of structure and reactivity of organic compounds. This book focuses on simple and diverse… Read more
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Request a sales quoteElectronic Charges of Bonds in Organic Compounds discusses trends in the electronic theory of structure and reactivity of organic compounds. This book focuses on simple and diverse methods that calculate the electronic charges of bonds from the results of physical methods of investigation. This text is divided into 10 chapters. In Chapter I, brief information is provided about the work of other research workers on the electronic charges of bonds and organic compounds. Chapters II to VI elaborate on the relationship of the electronic charges of bonds to the physical and physicochemical characteristics of molecules and their structural elements. The relationship between the electronic charges of bonds and chemical properties are explained in Chapters VII to X. This publication provides a good reference for students and researchers conducting work on electronic charges of bonds and reactivity of organic compounds.
Preface
Chapter I. Historical Outline and Introduction
1. History of the Classical and Electronic Theory of the Structure of Organic Compounds
2. Conception of Electronic Charges of Bonds
3. Introduction to the Subsequent Chapters
References
Chapter II. Electronegativities (Electronophilic Nature) of Atoms
1. Relationship between Electronegativities of Atoms and Electronic Bond Charges
2. Mechanism of the Mutual Effect of Atoms
References
Chapter III. Dipole Moments
1. Dipole Moments of Halomethanes and Electronegativities of Halogens
2. Dipole Moment of Isobutane and Electronegativity of Carbon
References
Chapter IV. Frequencies of Valency Vibrations of C—H Bonds in Hydrocarbons
1. Relationship of Force Constants and Frequencies of Valency Vibrations to Electronic Bond Charges
2 Electronic Bond Charges in Cyclopropane
References
Chapter V. Interatomic Distances
1. The Linear Relationship between π-Electron Bond Charges and Interatomic Distances
2. Calculating Linear Equations
3. π-Electron Bond Charges in Organic Compounds
4. Relationship between σ-Electron Charges and Bond Lengths
References
Chapter VI. Heats of Formation
1. Two Relationships between the "Heats of Elementization" of Hydrocarbon and Electronic Bond Charges
2. Saturated Hydrocarbons
3. Unsaturated Hydrocarbons
4. Chlorine and Bromine Derivatives of Paraffins
5. Organic Compounds Containing Oxygen
References
Chapter VII. Heat Effects of Organic Reactions
1. Hydrogenation and Bromination of Ethylene and Its Homologues
2. Isomerization of Mono-olefins
References
Chapter VIII. Organic Radicals and Ions
1. Radicals and Dissociation Energies of Bonds
2. Energy Stability of Carbanions and Carbonium Ions
References
Chapter IX. Chemical Properties of σ-Bonds
2. Cleavage Reactions
References
Chapter X. Chemical Properties of σπ-Bonds
1. Addition Reactions
2. Substitution Reactions in Benzene Derivatives
References
Conclusion
Subject Index
- No. of pages: 200
- Language: English
- Edition: 1
- Published: October 2, 2013
- Imprint: Pergamon
- Paperback ISBN: 9781483117096
- eBook ISBN: 9781483149516