Cyclophanes
- 1st Edition - January 28, 1983
- Imprint: Academic Press
- Editor: Philip Keehn
- Language: English
- Paperback ISBN:9 7 8 - 0 - 1 2 - 4 3 1 4 5 4 - 2
- eBook ISBN:9 7 8 - 0 - 3 2 3 - 1 5 2 5 6 - 3
Cyclophanes, Volume I is a collection of papers that reviews cyclophane chemistry. One paper describes the genesis of the cyclophane concept, covering its past, present, and future… Read more
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Request a sales quoteCyclophanes, Volume I is a collection of papers that reviews cyclophane chemistry. One paper describes the genesis of the cyclophane concept, covering its past, present, and future possible applications. The results of experimental and theoretical studies show the interrelationships between the structure and energetics in the class of compounds known as cyclophanes. Another paper relates the X-ray crystal structure determinations of cyclophanes to set the crystallographic and structural data of these systems in such a form that will enable comparisons, lead to an understanding of the geometries and deviations, and open the application of data to other areas of cyclophane chemistry. One paper reviews the methods by which nuclear magnetic resonance is applied to assign stereochemistry in the fixed phanes to show the conformational effects that have been observed in the mobile phanes. Another paper explains the synthesis, chemical, and physical properties of [n]cyclophanes, including systems with benzene, naphthalene, anthracene rings, heteroaromatics pyridine, furan, pyrrole, and thiophene. This collection can greatly profit researchers and academicians in the fields of organic chemistry, physical chemistry, and other scientists whose works revolve around aromatic compounds and cyclophanes.
Contributors to Volumes I and II
Preface
Contents of Volume II
1. Cyclophanes: A Personal Account
I. Introduction
II. Genesis of the Cyclophane Concept
III. The Past
IV. The Present
V. The Future
References
2. The Conceptual Chemistry of Cyclophanes
I. Introduction
II. Energetics Considerations Related to Cyclophanes
III. Interrelationships and Insights Regarding Other Classes of Compounds
References
3. Crystal Structure of Cyclophanes
I. Introduction
II. General Structural Features and Geometric Relationships in Cyclophanes
III. Table of Cyclophane Crystal Structure Determinations with Important Crystallographic Data and Structural Features
References
4. Nuclear Magnetic Resonance Properties and Conformational Behavior of Cyclophanes
I. Introduction
II. Simple Fixed Phanes
III. Mobile Phanes
IV. Nuclear Magnetic Resonance Studies on Nuclei Other that 1H
V. Epilogue
References
5. [n]Cyclophanes
I. Introduction
II. Synthesis of [n]Paracyclophanes
III. Synthesis of [n]Metacyclophanes and Other 1,3-Bridged Aromatics
IV. Spectroscopy
V. Chemistry of the Bridged Nucleus
VI. Chemistry of the Bridge
VII. Naturally Occurring [n]Cyclophanes
References
Index
- Edition: 1
- Published: January 28, 1983
- Imprint: Academic Press
- No. of pages: 390
- Language: English
- Paperback ISBN: 9780124314542
- eBook ISBN: 9780323152563
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