Critical Evaluation of Some Equilibrium Constants Involving Organophosphorus Extractants
- 1st Edition - January 1, 1974
- Latest edition
- Author: Y. Marcus
- Language: English
Critical Evaluation of Some Equilibrium Constants Involving Organophosphorus Extractants is a supplementary text to the compilation "Equilibrium Constants of Liquid-Liquid… Read more
Critical Evaluation of Some Equilibrium Constants Involving Organophosphorus Extractants is a supplementary text to the compilation "Equilibrium Constants of Liquid-Liquid Distribution Reactions (Introduction, and Part I: Organophosphorus Extractants). The book contains a number of well documented chemical reactions that are critically evaluated. The reactions evaluated comprise those from List 1 for which data are available. There are, however, a great variety of reactions that cannot be critically evaluated due to lack of experimental data and unverifiable results. Chemists will find this compendium very useful.
IntroductionI H+ + DBP- = HDBPII HDBP = HDBPIII 2 HDBP = (HDBP)2IV 1/2 (HDBP)2 + TBP = HDBP · TBP and (HDBP)2 + TBP = (HDBP)2 · TBPV TBP=TBPVI H2O + TBP = H2O · TBPVII H+ + NO-3 + TBP = HNO3 · TBPVIII H+ + Cl- + TBP = HC1 · TBPIX H+ + DE-HP- = HDE-HP; HDE-HP = HDE-HP; 2 HDE-HP = (HDE-HP)2X 1/2(HDE-HP)2 + TBP (or TOPO) = HDE-HP · TBP (or TOPO); (HDE-HP)2 + TBP (or TOPO) = (HDE-HP)2 · TBP (or TOPO)XI UO2+ 2 + 2NO-3 + 2 TBP = UO2(NO3)2(TBP)2XII Pu4+ + 4NO-3 + 2 TBP = Pu(NO3)4(TBP)2XIII H+ + NO-3 + TOPO = HNO3 · TOPOXIV UO2+ 2 + 2NO-3 + 2TBPO = UO2(NO3)2(TB'PO)2XV H+ + NO-3 + DBB'P = HNO3 · DBB'PXVI UO2+ 2 + 2NO-3 + 2 DBB'P = UO2(NO3)2(DBB'P)2
- Edition: 1
- Latest edition
- Published: January 1, 1974
- Language: English
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