Catalysis by Nonmetals
Rules for Catalyst Selection
- 1st Edition - October 30, 2013
- Latest edition
- Author: Oleg V. Krylov
- Editor: Ernest M. Loebl
- Language: English
- Paperback ISBN:9 7 8 - 1 - 4 8 3 1 - 7 5 9 4 - 2
- eBook ISBN:9 7 8 - 1 - 4 8 3 1 - 9 1 7 5 - 1
Catalysis by Non-metals: Rules of Catalyst Selection presents the development of scientific principles for the collection of catalysts. It discusses the investigation of the… Read more
Catalysis by Non-metals: Rules of Catalyst Selection presents the development of scientific principles for the collection of catalysts. It discusses the investigation of the mechanism of chemosorption and catalysis. It addresses a series of properties of solid with catalytic activity. Some of the topics covered in the book are the properties of a solid and catalytic activity in oxidation-reduction reactions; the difference of electronegativities and the effective charges of atoms; the role of d-electrons in the catalytic properties of a solid; the color of solids; and proton-acid and proton-base properties of a surface. The catalytic activity and structure of solids are covered. The type of crystal lattice and crystalline lattice parameters are discussed. The text describes the decomposition of alcohols. A study of the dehydrogenation and hydrogenation reactions is presented. A chapter is devoted to the decomposition of inorganic hydrides. Another section focuses on the hydrogen-deuterium exchange and other simple reactions. The book can provide useful information to scientists, physicists, students, and researchers.
Preface Part I General Methods of Catalyst Selection Introduction1. Properties of a Solid and Catalytic Activity in Oxidation Reduction Reactions 1.1. Electroconductivity 1.2. Work Function 1.3. Width of the Forbidden Zone 1.4. Doped Levels 1.5. The DifiFerence of Electronegativities and the Effective Charges of Atoms 1.6. The Role of J-Electrons in the Catalytic Properties of a Solid 1.7. The Color of Solids2. Solid Properties and Catalytic Activity in Acid-Base Reactions 2.1. Proton-Acid and -Base Properties of a Surface 2.2. Coordination Capacity of Metals 2.3. Dielectric Constant3. Catalytic Activity and Structure of Solids 3.1. Crystalline Lattice Parameter 3.2. Type of Crystal Lattice Part II Principles of Selection of Catalysts for Various Reactions Introduction 4. Decomposition of Alcohols and Acids 4.1. Decomposition of Alcohols 4.2. Decomposition of Acids 5. Dehydrogenation and Hydrogenation Reactions 5.1. Dehydrogenation of Hydrocarbons 5.2. Hydrogenation 5.3. Decomposition of Inorganic Hydrides 6. Hydrogen-Deuterium Exchange and other Simple Reactions7. Reactions of Oxidation and Decomposition of Oxygen-Containing Compounds 7.1. Simple Oxidation Reactions 7.2. Oxidation of Organic Compounds 7.3. The Decomposition of Oxygen-Containing Substances 8. Acid-Base Reactions 8.1. Addition and Removal of Water and Hydrogen Halides 8.2. The Reactions of Condensation and Polycondensation 8.3. Isomerization Reactions 8.4. Cracking and Alkylation of Hydrocarbons9. Polymerization ReactionsConclusions Appendix Physical Properties of Some Nonmetalic Compounds Used as CatalystsReferencesSubject Index
- Edition: 1
- Latest edition
- Published: October 30, 2013
- Language: English
Read Catalysis by Nonmetals on ScienceDirect