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Boron Fluoride and Its Compounds as Catalysts in Organic Chemistry
International Series of Monographs on Organic Chemistry
- 1st Edition - January 1, 1958
- Authors: A. V. Topchiev, S. V. Zavgorodnii, Ya. M. Paushkin
- Editors: W. Doering, D. H. Barton
- Language: English
- Hardback ISBN:9 7 8 - 0 - 0 8 - 0 0 9 1 2 8 - 0
- Paperback ISBN:9 7 8 - 1 - 4 8 3 1 - 6 8 5 5 - 5
- eBook ISBN:9 7 8 - 1 - 4 8 3 1 - 8 4 3 6 - 4
Boron Fluoride and Its Compounds as Catalysts in Organic Chemistry deals with the concerns associated with the utilization of boron fluoride as a catalyst. The title provides a… Read more
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Request a sales quoteBoron Fluoride and Its Compounds as Catalysts in Organic Chemistry deals with the concerns associated with the utilization of boron fluoride as a catalyst. The title provides a comprehensive account of boron fluoride, such as its properties, compounds, and related methodologies. The coverage of the text includes the preparation and recovery of boron fluoride, along with the physical and chemical properties. The selection also covers various boron fluoride compounds and their respective reaction to various processes, such as alkylation, polymerization, and nitration. The book will be of great interest to students, researchers, and practitioners of organic chemistry.
Introduction
I. Methods for the Preparation and Recovery of Boron Fluoride
1. Methods for the Preparation of Boron Fluoride
2. A Brief Evaluation of the Methods for the Preparation of Boron Fluoride
3. Methods of Recovery of Boron Fluoride
II. Physical and Chemical Properties of Boron Fluoride and Its Derivatives
1. Physical Properties
2. Chemical Properties
3. Derivatives of Boron Fluoride and Their Reactions
III. Coordination Compounds of Boron Fluoride
1. Coordination Compounds of Boron Fluoride with Inorganic Substances
2. Coordination Compounds of Boron Fluoride with Organic Substances
IV. Compounds of Boron with Hydrogen and Their Physico-Chemical Properties
1. Physical Properties of Boranes
2. Chemical Properties of Boranes
3. Methods of Preparation of Boranes
4. Methods of Preparation of Derivatives of Boranes
V. Compounds of Boron Fluoride in Alkylation Reactions
1. Alkylation of Isoparaffins with Olefines
2. Alkylation of Naphthene Hydrocarbons with Olefines
3. Alkylation of Aromatic Hydrocarbons with Olefines and Their Derivatives
4. Alkylation of Aromatic Hydrocarbons with Substituted Olefines
5. Alkylation of Aromatic Hydrocarbons with Acetylene and Diene Compounds
6. Destructive Alkylation of Aromatic Hydrocarbons with Paraffins
7. Alkylation of Benzene and Its Homologues with Alkyl Halides
8. Alkylation of Benzene and Its Homologues with Alcohols
9. Alkylation of Benzene and Its Homologues with Ethers and Esters
10. Alkylation of Naphthalene and Other Poly Cyclic Aromatic Hydrocarbons
11. Alkylation of Phenols and Their Derivatives
12. Alkylation of Heterocyclic Compounds
13. Alkylation of Acetoacetic Ester
14. Alkylation of Amines
VI. Boron Fluoride Compounds in Polymerization Reactions
1. Polymerization of Olefines
2. Polymerization of Vinyl- and Allyl-Derivatives of Carbo- and Heterocyclic Compounds
3. Polymerization of Acetylenic and Dienic Compounds
4. Polymerization of Terpenes and Other Compounds
5. Copolymerization of Unsaturated Compounds
VII. the Addition of Organic Substances Containing Oxygen or Sulphur to Ethylenic Compounds
1. Addition of Water and Alcohols to Olefines
2. Reactions of Ethylenic Compounds with Acetals, Alkyl Halides, Anhydrides and Aldehydes
3. Addition of Carboxylic Acids to Olefines and Their Substituted Derivatives
4. Reactions of Ketene
5. Reactions of Ethylenic Compounds with Organic Substances Containing Sulphur
VIII. The Addition of Organic Compounds Containing Oxygen to Acetylenic and Dienic Hydrocarbons
1. Addition of Water and Alcohols to Acetylenic Compounds
2. Addition of Alcohols to Dienic Hydrocarbons
3. Addition of Carboxylic Acids and Chloroanhydrides to Acetylenic and Dienic Compounds
4. Additions of Arylamines to Acetylenic Hydrocarbons
IX. Isomerization and Cyclization Reactions
1. Isomerization of Hydrocarbons
2. Isomerization of Vinylethinylcarbinols
3. Isomerization of Alkylphenyl Ethers
4. Rearrangements Connected with the Migration of the Halogen Atom in the Benzene Ring
5. Rearrangements of Compounds Containing Nitrogen
6. Cis-Trans-Isomerization and Cyclization
X. Nitration and Sulphonation Reactions
1. Nitration
2. Sulphonation
XI. Condensation Reactions in the Presence of Boron Fluoride
1. Condensation of Carbon Monoxide with Olefines, Alcohols and Ethers
2. Reactions of A-Oxides
3. Various Reactions for Preparing Ethers and Esters
4. Condensation of Aldehydes
5. Acylation Reactions
XII. Various Reactions Which Are Carried Out in the Presence of Boron Fluoride
1. The Cracking Reaction
2. Dealkylation and Disproportionation
3. Separation and Purification of Hydrocarbons By Means of Boron Fluoride Compounds
Supplementary References on Boron Fluoride
(Subject Index)
- No. of pages: 326
- Language: English
- Edition: 1
- Published: January 1, 1958
- Imprint: Pergamon
- Hardback ISBN: 9780080091280
- Paperback ISBN: 9781483168555
- eBook ISBN: 9781483184364
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