Annual Reports in Inorganic and General Syntheses-1973

Preface

Main Group Hydrides, Alkali and Alkaline Earth Elements

Simple Hydrides

Complex Hydrides

Alkali and Alkaline Earth Elements

General

Oxides

Alkoxides

Oxygen-Bonded Chelates

Other Salts and Complexes of Oxy Compounds

Sulfur-Containing Compounds

Compounds with Group V Elements

Organometallic Compounds

References

Boron

General

Novel Procedures

Inorganic Boron Derivatives

Metal-Boron Compounds

Organoboranes

Hydroboration

Carboranes

Boranes

Ring Systems

Four-Coordinate Boron

BX3 Complexes

BX4 Complexes

References

Aluminum, Gallium, Indium and Thallium

Introduction

Synthetic Methods

Hydride Complexes

Hydrogen-Bridged Transition Metal Compounds

Reactions of Organometallic Compounds

Insertion Reactions

Exchange Reagents

Cyclization Reactions

Alkane Elimination Reactions

Organohalides and Pseudo Halides

Cyclopentadienyls and Related Complexes

Complexes with O, N, S and P Ligands

Donor-Acceptor Interactions with Metal Carbonyl and Metal Dinitrogen Complexes

Metal-Metal Bonded Compounds

Homonuclear Group III

Group Ill-Main Group

Group Ill-Transition Metal

Complexes in Catalytic Systems

Miscellaneous

Halide and Addition Compounds

Lower Oxidation States

References

Silicon

General

Silicon-Hydrogen

Silicon-Halogen

Silicon-Nonmetal

Silicon-Oxygen

Silicon-Nitrogen

Silicon-Sulfur

Silicon-Carbon

Silicon-Metal

Silicon-Silicon

Silicon Containing Complexes

References

Germanium, Tin and Lead

General

MR4 Compounds

Metal-Carbon Bonded Compounds

Metal-Nitrogen Bonded Compounds

Metal-Oxygen Bonded Compounds

Metal-Halogen Bonded Compounds

Compounds with More Than One Group IVa Metal Atom

Reactions of MR4 Compounds

Metal-Metal Bonded Compounds

Organometallic Compounds

Coordination Compounds

Coordination Compounds of Ge, Sn, Pb

Miscellaneous Compounds and Reactions

References

Nitrogen

Compounds with no N-N Bonds

Compounds with one N-N Bond

Hydrazine Derivatives

Azo and Diazo Compounds

Nitrosamine and Nitramide Derivatives

Compounds with Three or More Linked Nitrogens

References

Phosphorus

Introduction

Phosphides

Phosphorus-Boron Compounds

Phosphorus-Carbon Compounds

Phosphorus-Si, Ge, Sn compounds

Phosphorus-Nitrogen Compounds

Cyclic Phosphazenes

Heterocyclic Phosphazenes

Linear Phosphazenes

Cyclic Phosphazanes and Rings with P-N Bonds

Amides and Amines of Phosphorus

Imides and Imines

Hydrazine Derivatives

Compounds with P-P Bonds

Compounds of Phosphorus with Elements of Group VIA

Phosphorus Oxides, Sulfides and Selenides

Derivatives of Hypophosphoric Acid

Derivatives of Hypodiphosphorous Acid

Derivatives of Phosphorous Acid

Hypodiphosphoric Acid

Orthophosphates

Derivatives of Orthophosphoric Acid

Diphosphoric Acid

Metaphosphates

Halogenophosphoric Acids-Polyphosphates

Spirocompounds

Complexes with Phosphorus Ligands

Phosphorus-Halogen Compounds

Pure Phosphorus-Halogen Compounds

Phosphorus-Chalcogen Halogenides

Phosphorus-Halogen Compounds with Amino and Ester Groups

Cage Compounds

Radicals

References

Arsenic, Antimony and Bismuth

Reviews

Arsenic

Tertiary Arsines

Heteroatom-Arsenic Species

Cyclic Compounds

Acids, Esters, and Alcohols

Arsenic (V) Compounds

Antimony

Antimony (III) as an Acceptor

Antimony (III) as a Donor

General (Tertiary Antimony)

Antimony(V), General

Antimony(V) as an Acceptor

Bismuth

Bismuth(III)

Bismuth(V)

References

Chalcogens

Oxygen

Sulfur

Polysulfur Compounds

Sulfur(II) Compounds

Cyclic Sulfur-Nitrogen Compounds

Sulfur(IV) Compounds

Sulfur(VI) Compounds

Selenium

Tellurium

References

Halogens and Pseudohalogens

Halogens

Interhalogen Ions

Oxides and Oxo Cations

Halogen Derivatives of Pentafluoroorthoselenic and Telluric Acids

Fluorine

Bromine

Iodine

Pseudohalogen Compounds of Main Group Elements

Complexes of Gallium and Indium

Compounds with Elements of Group V

Compounds with Elements of Group VI

Pseudohalo Complexes of Transition Metals

Hafnium and Zirconium

Chronium, Molybdenum, and Tungsten

Manganese, Technetium, and Thenium

Iron and Osmium

Cobalt, Rhodium, and Iridium

Nickel, Palladium, and Platinum

Copper, Silver, and Gold

Zinc, Cadmium, and Mercury

Pseudohalo Complexes of Inner Transition Metals

References

Noble Gases

Krypton

Xenon

Radon

References

Yttrium, Scandium, Lanthanides and Actinides

The Elements

New Method of Purification

Lanthanide Ions as Reducing Agents

Phase Relationships

High Pressure synthesis

Borides

Fluorides

Lanthanide Nitrates

Double Oxides

Carbides

Mixed Carbides

Isocyanate and Isothiocyanates

Carboxylates

Thiophosphates

Alkoxides

Fluorinated Acetonylpyrazolides

Carbonyls

References

Titanium, Zirconium and Hafnium

Bromides

Alkoxides

Cyclooctatetraenes

Alkoxy Halo Complexes

Oxotitanium Complexes

Silylmethyl and Related Complexes

Complexes Containing Methylbenzene

Direct Synthesis

Synthesis by Ligand Exchange

β-DiKetonate Complexes

Cyclopentadienyl Compounds

Zirconium Hydrocarbyls

Ferrocenyl Titanium

References

Vanadium, Niobium, Tantalum

Vanadium

Halides, Oxohalides, and Adducts

Bronzes and Vanadites

Oxides and Vanadates

Other Simple Compounds

Coordination Compounds

Niobium and Tantalum

General

Halides, Oxohalides, and Adducts

Oxides, Niobates, Tantalates, and Other Oxide Phases

Other Simple Compounds

Coordination Compounds

References

Chromium, Molybdenum, and Tungsten

General

Chromium

Oxides and Hydroxides

Chromâtes and Chromites

Halogen-Containing Compounds of Chromium

Refractory and Related Compounds

Miscellaneous

Molybdenum

Oxides and Their Hydrates

Simple Molybdates

Isopoly Compounds

Heteropoly Compounds

Thiomolybdates and Chalcogenides

Halogen-Containing Compounds

Miscellaneous

Tungsten

Oxides

Tungsten Bronzes and Simple Tungstates

Isopoly and Heteropoly Tungstates

Halogen-Containing Compounds

Miscellaneous Compounds

References

Manganese, Technetium and Rhenium

General

Manganese

Lower Oxidation States

Manganese(II)

Higher Oxidation States

Technetium

Rhenium

Rhenium(I)

Rhenium(II)

Rhenium(III)

Rhenium(IV)

Rhenium(V)

Rhenium(VI)

Rhenium(VII)

References

Iron

General

Compounds with Carbon Donors

Compounds with Nitrogen Donors

Compounds with Oxygen Donors

Compounds with Sulfur Donors

Compounds with Halogen Donors

Miscellaneous

References

Cobalt and Nickel

General

Low Oxidation States - Cobalt(-I), Cobalt(O), and Cobalt(I)

Carbonyls

Phosphine Complexes

Nitrosyls

Other Low-Valent Cobalt Complexes

Low-Valent Nickel Complexes

Carbonyls

Phosphine Complexes

Nitrosyls

Other Low-Valent Nickel Complexes

Cobalt(II) and Nickel(II) Complexes

Complexes with Heavy Donor Atoms

Dimeric and Oligomeric Complexes

Complexes of Macrocyclic Ligands

Oxidative and Reductive Syntheses

Cobalt(III) Complexes

Synthesis by Displacement of Labile Ligands

Binuclear and Oligonuclear Complexes

Unusual Monomeric Cobalt(lll) Complexes

Separation of Cobalt(III) Complexes

Higher Oxidation States

Nickel(III)

Cobalt(V)

References

The Platinum Metals. Part I: Ruthenium, Osmium, Rhodium and Iridium

Introduction

The Chemistry of Ruthenium and Osmium

Group VII Donors

Group VI Donors

Group V Donors

Group IV Donors

Metallation Reactions

The Chemistry of Rhodium and Iridium

Group VII Donors

Group VI Donors

Group V Donors

Group IV Donors

Metallation Reactions and Complexes Containing Metal-Carbon σ-Bonds

References

The Platinum Metals. Part II: Palladium and Platinum

Introduction

Group VII Donors

Group VI Donors

Group V Donors

Group IV Donors

Metallation Reactions and Complexes Containing Metal-Carbon σ-Bonds

References

Copper

General

Copper(I) Compounds

Copper(II)

Copper(II) - Dimers and Polymers

Miscellaneous

References

Silver and GOld

General

Compounds Containing (Ag,Au)-C Bonds

Alkyl, Aryl, and Related Groups

Isocyanide and Carbene Complexes

Other Compounds

Simple Salts and Other Complexes

Simple Salts

Nitrogen Donors

Chalcogen Donors

Miscellaneous Compounds

References

Zinc, Cadmium and Mercury

General Inorganic Compounds

Complex and Coordination Compounds

Organometallic Compounds

Organoadmium

Organomercury

Organozinc

Compounds with Metal-Metal Bonds

References

Metalloporphyrin Synthesis

Some Common Metalloporphyrins

Methods of Metalloporphyrin Synthesis

Group I A

Group II A

Group III A

Group IV A

Group V A

Groups IIIB, IV B, V B

Group VI B

Group VII B

Iron

Cobalt

Ruthenium, Rhodium, Iridium, Osmium

Nickel, Palladium, Platinum

Group I B

Group II B

References