Analytical Chemistry of the Condensed Phosphates
- 1st Edition - October 22, 2013
- Authors: S. Greenfield, M. Clift
- Editors: R. Belcher, H. Freiser
- Language: English
- eBook ISBN:9 7 8 - 1 - 4 8 3 2 - 8 0 6 5 - 3
Analytical Chemistry of the Condensed Phosphates describes the concept and mode of operation of various analytical methods for analysis of the condensed phosphates. This book is… Read more
Analytical Chemistry of the Condensed Phosphates describes the concept and mode of operation of various analytical methods for analysis of the condensed phosphates. This book is composed of ten chapters, and begins with a presentation of the general properties of the condensed phosphates. Considerable chapters are devoted to various analytical techniques used for condensed phosphate analysis, such as gravimetry, titrimetry, and electrometric, chromatographic, physical, and automated methods. A chapter discusses the procedures for the determination of esters of the condensed phosphates. The concluding chapters survey the preferred method of quantitative analysis of these compounds, as well as the preparation of pure samples. This book will prove useful to analytical, inorganic, and organic chemists and researchers.
Foreword
Preface
Acknowledgments
1. General Properties of the Condensed Phosphates
Classification
Structure
Physical Properties
Chemical Properties
Stability in Solution: Degradation Products on Hydrolysis
Reaction with Metal Salts in Solution—Sequestering Action
References
2. Gravimetric Methods
Heavy-metal Salts
Cobalt Complexes
Chromium Complexes
Other Metal Complexes
Organic Bases as Precipitants
References
3. Titrimetric Methods
Titration of the Free Acids
Chain-length Determinations
Titration of Hydrion produced in Precipitation Reactions
EDTA Complexes
Thermometric Titrations
References
4. Electrometric Methods (other than Potentiometry)
Amperometric Titrations
Conductimetric Titrations
Polarographic Methods
References
5. Chromatographie Methods
Paper Chromatography
Thin-layer Chromatography "Adsorption"
Thin-layer Chromatography (ion exchange)
Electrophoresis
Ion Exchange Column Chromatography
Gel Filtration
References
6. Automated Methods
Automated Ion Exchange
Automated Temperature Rise
Appendix 1: Automated Ion Exchange Computer Program Description
Reference
7. Physical Methods other than Chromatography
Ultracentrifugation
Dialysis
Intrinsic Viscosity in Salt Solutions
Light Scattering in Salt Solutions
Flow Birefringence
Anisotropy in Electrical Conductivity
Solubility Fractionation
Refractive Index
Temperature Rise Test
Infrared
X-ray Diffraction
Nuclear Magnetic Resonance
References
8. Methods for the Determination of Esters of the Condensed Phosphates
Determination of Tetra-alkylpyrophosphates
Determination of Tetra-arylpyrophosphates
Determination of Nucleotides containing Condensed Phosphates
References
9. Modus Operandi
Preparation of Samples for Analysis
Qualitative Tests
Preferred Methods of Quantitative Analysis
References
10. Preparation of Pure Samples
Orthophosphoric Acid
Orthophosphate
Pyrophosphate
Triphosphate
Sodium Trimetaphosphate
Sodium Tetraphosphate
Sodium Tetrametaphosphate
Sodium Hexametaphosphate and Sodium Pentametaphosphate
Sodium Octametaphosphate
Madrell's Salt-insoluble Sodium "Metaphosphate"
Graham's Salt—Sodium Polyphosphate Glass
Potassium Kurrol Salt—Insoluble Potassium "Metaphosphate"
References
Index
- Edition: 1
- Published: October 22, 2013
- Language: English
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