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Advances in Organometallic Chemistry
- 1st Edition, Volume 81 - May 22, 2024
- Editor: Pedro J. Perez
- Language: English
- Hardback ISBN:9 7 8 - 0 - 4 4 3 - 2 9 4 2 0 - 4
- eBook ISBN:9 7 8 - 0 - 4 4 3 - 2 9 4 2 1 - 1
Advances in Organometallic Chemistry, Volume 81 in this ongoing series, highlights new advances in the field, with this new volume presenting interesting chapters written by an int… Read more
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Request a sales quoteAdvances in Organometallic Chemistry, Volume 81 in this ongoing series, highlights new advances in the field, with this new volume presenting interesting chapters written by an international board of authors. Specific chapters cover Recent Advances in the Catalytic Applications of NHC-Early Abundant Metals (Fe, Mn, Co) Complexes, A Guide to Non-Carbonyl, Non-Isocyano Organometallic Chemistry of Technetium-99 from Discovery to 2023, and Cyclopentadienyl, Amidinate (CPAM) Complexes of Groups 4 - 6 Transition Metals.
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- Cover image
- Title page
- Table of Contents
- Copyright
- Contributors
- Preface
- Chapter One: A tale of two metals: The Mizoroki-Heck reaction as a guide to compare the chemical characters of nickel and palladium in catalysis
- Abstract
- 1 Introduction
- 2 Economic, environmental, and health issues associated with the use of nickel and palladium
- 3 A comparison of the chemical characters of nickel and palladium
- 4 The palladium-catalyzed Mizoroki-Heck reaction
- 5 Nickel catalysts for the Mizoroki-Heck reaction
- 6 Nickel vs. palladium: a survey of fundamental processes associated to the mechanism of the Mizoroki-Heck reaction
- 7 A global comparison of the M(0)/M(II) M-H cycle for palladium and nickel: the computational perspective
- 8 The role of open-shell, intermediate oxidation states in the M-H reaction
- 9 Conclusion and outlook
- Acknowledgments
- References
- Chapter Two: Recent advances in the catalytic applications of NHC-early abundant metals (Mn, Co, Fe) complexes
- Abstract
- Graphical abstract
- 1 Introduction
- 2 NHC-Mn catalyzed reactions
- 3 NHC-Co catalyzed reactions
- 4 NHC-Fe catalyzed reactions
- 5 Conclusions
- Acknowledgements
- References
- Chapter Three: Structural organometallic chemistry of technetium-99
- Graphical abstract
- Abstract
- 1 Introduction
- 2 Organotechnetium chemistry
- 3 Practical considerations and general methods
- 4 Challenges in organotechnetium chemistry
- Acknowledgment
- References
- Chapter Four: Challenges in the computational modelling of bimetallic C–H activation processes
- Abstract
- 1 Introduction
- 2 Donor effects
- 3 Ion-pairs
- 4 Solvent effects
- 5 Summary and future outlook
- 6 Computational methods
- Acknowledgements
- References
- Chapter Five: Asymmetric hydrogenation using Rh- and Ir-complexes with P-stereogenic phosphine/aminophosphine containing ligands
- Abstract
- 1 Introduction
- 2 The early days of P-stereogenic ligands in asymmetric hydrogenation
- 3 Latest developments in the application of P-stereogenic ligands for asymmetric hydrogenation
- 4 Conclusions
- Acknowledgments
- References
- No. of pages: 398
- Language: English
- Edition: 1
- Volume: 81
- Published: May 22, 2024
- Imprint: Academic Press
- Hardback ISBN: 9780443294204
- eBook ISBN: 9780443294211
PP
Pedro J. Perez
Pedro J. Pérez (FRSC) graduated in 1991 under the supervision of Prof. Ernesto Carmona (Univ. Sevilla, Spain). As a Fulbright Scholar, he then joined Prof. Brookhart's group at UNC-Chapel Hill (USA). He started an appointment as Assistant Professor at the Universidad de Huelva (Spain) in 1993, where he has been promoted several times until the current position of Professor in Inorganic Chemistry (since 2005). His work is devoted to the development of organometallic complexes of late transition-metal as well as their use as catalysts for transformations involving hydrocarbons, including olefin modification, carbon-hydrogen bond functionalization, and click chemistry. He has been recognized by the RSC with the 2015 Homogeneous Catalysis Award, and by the RSEQ (Spain) with the 2007 Inorganic Chemistry Award and the 2016 Gold Medal Award. In 2014 he joined the National Academy of Sciences of Spain as Corresponding Member.
Affiliations and expertise
Professor in Inorganic Chemistry, Homogeneous Catalysis Laboratory, Center for Research in Sustainable Chemistry, Universidad de Huelva, Huelva, Spain