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Advances in Organometallic Chemistry
1st Edition - June 17, 2022
Editor: Pedro J. Perez
Hardback ISBN:
9 7 8 - 0 - 3 2 3 - 9 9 0 9 0 - 5
eBook ISBN:
9 7 8 - 0 - 3 2 3 - 9 9 0 9 1 - 2
Advances in Organometallic Chemistry, Volume 78, the latest release in this longstanding serial known for its comprehensive coverage of topics in organometallic synthesis,… Read more
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Advances in Organometallic Chemistry, Volume 78, the latest release in this longstanding serial known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more includes a variety of new chapters in this updated release. Users will find amazing coverage on Multiple bonds stabilized by Terphenyl Ligands, Selectivity in the Activation of C-H Bonds by Rhodium and Iridium Complexes, Transition Metal-Catalyzed C–C and C-B Bond Formation Reactions: Lessons from Computational Studies, Effect of C-Donor Ligands onto Metal-Catalyzed Carbene and/or Nitrene Transfer Reactions, Chemical Bonding and Dynamic Magnetism in f-Element Organometallic Sandwich Compounds, and much more.
- Contains contributions from leading authorities in the field of organometallic chemistry
- Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more
- Informs and updates readers on the latest developments in the field
Researchers involved in Organometallic Chemistry from a wide perspective, including synthetic protocols, mechanistic studies and practical applications and to those involved in the use of organometallic complexes in homogeneous catalysis
- Cover image
- Title page
- Table of Contents
- Copyright
- Contributors
- Preface
- Chapter One: Selectivity in the activation of CH bonds by rhodium and iridium complexes
- Abstract
- 1: Introduction
- 2: Reactions of trispyrazolylborate rhodium complexes
- 3: Reactions of trispyrazolylborate iridium complexes
- 4: Conclusion
- Acknowledgments
- References
- Chapter Two: Transition metal catalyzed cross-coupling and nitrogen reduction reactions: Lessons from computational studies
- Abstract
- 1: Introduction
- 2: Commonly used methods in computational catalysis
- 3: New directions
- 4: Computational methods employed in our research
- 5: Carbon-carbon and carbon-boron bond formation reactions
- 6: Three-membered ring opening
- 7: Four-membered ring opening
- 8: Fe-catalyzed carbon-carbon bond formation
- 9: The future
- 10: Nitrogen reduction
- 11: Electronic structure of transition metal clusters relevant to the enzyme active site
- 12: Metal-metal bonding
- 13: Mechanistic analysis of the silylation of N2 catalyzed by a MoFe complex
- 14: The future
- 15: Summary
- Acknowledgments
- References
- Chapter Three: Cyclic (alkyl)(amino)carbene (CAAC) ligands: Electronic structure and application as chemically- and redox-non-innocent ligands and chromophores
- Abstract
- 1: Introduction and overview
- 2: Electronic structure and reactivity of free CAACs
- 3: Classes of CAACs
- 4: Synthesis of CAACs and their complexes
- 5: Low-valent transition metal CAAC complexes
- 6: Low-valent main group CAAC compounds
- 7: Chemically non-innocent CAAC complexes
- 8: Application of CAACs in photochemistry
- 9: Concluding remarks
- References
- Chapter Four: Recent applications of fluorinated arylborane derivatives
- Abstract
- 1: Introduction
- 2: Perfluoroaryl boranes and their synthesis
- 3: Lewis acidity properties
- 4: Selected applications
- 5: Conclusions and future outlook
- References
- Chapter Five: New insights in luminescent fluorinated transition metal compounds
- Abstract
- 1: Introduction
- 2: Organometallic fluorinated complexes
- 3: Conclusions
- References
- No. of pages: 242
- Language: English
- Published: June 17, 2022
- Imprint: Academic Press
- Hardback ISBN: 9780323990905
- eBook ISBN: 9780323990912
PP
Pedro J. Perez
Pedro J. Pérez (FRSC) graduated in 1991 under the supervision of Prof. Ernesto Carmona (Univ. Sevilla, Spain). As a Fulbright Scholar, he then joined Prof. Brookhart's group at UNC-Chapel Hill (USA). He started an appointment as Assistant Professor at the Universidad de Huelva (Spain) in 1993, where he has been promoted several times until the current position of Professor in Inorganic Chemistry (since 2005). His work is devoted to the development of organometallic complexes of late transition-metal as well as their use as catalysts for transformations involving hydrocarbons, including olefin modification, carbon-hydrogen bond functionalization, and click chemistry. He has been recognized by the RSC with the 2015 Homogeneous Catalysis Award, and by the RSEQ (Spain) with the 2007 Inorganic Chemistry Award and the 2016 Gold Medal Award. In 2014 he joined the National Academy of Sciences of Spain as Corresponding Member.
Affiliations and expertise
Professor in Inorganic Chemistry, Homogeneous Catalysis Laboratory, Center for Research in Sustainable Chemistry, Universidad de Huelva, Huelva, Spain