Advances in Organometallic Chemistry
- 1st Edition, Volume 75 - March 26, 2021
- Imprint: Academic Press
- Editor: Pedro J. Perez
- Language: English
- Hardback ISBN:9 7 8 - 0 - 1 2 - 8 2 4 5 8 1 - 1
- eBook ISBN:9 7 8 - 0 - 3 2 3 - 8 5 0 6 8 - 1
Advances in Organometallic Chemistry, Volume 75, the latest release in this longstanding serial that is known for its comprehensive coverage of topics in organometallic synthe… Read more
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Request a sales quoteAdvances in Organometallic Chemistry, Volume 75, the latest release in this longstanding serial that is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more provides a wide range of information, with this updated release including chapters on Two- and three-coordinate complexes featuring M-C bonds, Polymerization of terpene and terpenoids using well defined organometallic compounds, Bimetallic Frustrated Lewis Pairs, Organometallic based magnetic switches under confinement, Chemical Bonding and Dynamic Magnetism in f-Element Organometallic Sandwich Compounds, Tris-pyridyl Main Group Ligands: Design and Applications, Reactivities of N-heterocyclic carbenes at metal centers, and more.
- Contains contributions from leading authorities in the field of organometallic chemistry
- Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more
- Informs and updates readers on the latest developments in the field
- Carefully edited to provide easy-to-read material
Researchers involved in Organometallic Chemistry from a wide perspective, including synthetic protocols, mechanistic studies and practical applications and to those involved in the use of organometallic complexes in homogeneous catalysis
- Cover image
- Title page
- Table of Contents
- Copyright
- Contributors
- Preface
- Chapter One: Hydrofunctionalization reactions of heterocumulenes: Formation of C–X (X = B, N, O, P, S and Si) bonds by homogeneous metal catalysts
- Abstract
- 1: Introduction
- 2: Hydroboration
- 3: Hydroamination
- 4: Hydroalkoxylation
- 5: Hydrosilylation
- 6: P—H bond reactions
- 7: Hydrothiolation
- 8: Multi E–H hydrofunctionalization
- 9: Concluding remarks
- Acknowledgments
- Chapter Two: Polymerization of terpenes and terpenoids using metal catalysts
- Abstract
- 1: Introduction: Terpenes and terpenoids, origin and classification
- 2: Polymerization of terpenes
- 3: Polymerization of terpenoids
- 4: Copolymerization of terpenoids
- 5: Concluding remarks
- Acknowledgments
- Chapter Three: Bimetallic frustrated Lewis pairs
- Abstract
- 1: Introduction
- 2: Frustrated Lewis pairs
- 3: Bimetallic complexes for bond activation
- 4: Genuine metal-only FLP activation
- 5: Miscellanea
- 6: Conclusions
- Acknowledgments
- Chapter Four: Metallic-based magnetic switches under confinement
- Abstract
- 1: Introduction
- 2: Endohedral fullerenes: Zero-dimensional host cages
- 3: Carbon nanotubes: One-dimensional host nanocontainers
- 4: Metal-organic frameworks: As three-dimensional platforms
- 5: Conclusions
- Acknowledgments
- Chapter Five: Recent advances in the synthesis and application of tris(pyridyl) ligands containing metallic and semimetallic p-block bridgeheads
- Abstract
- 1: Introduction
- 2: Group 13 tris(pyridyl) ligands
- 3: Group 14 tris(pyridyl) ligands
- 4: Group 15 tris(pyridyl) ligands
- 5: Outlook
- Acknowledgments
- Chapter Six: Reactivities of N-heterocyclic carbenes at metal centers
- Abstract
- 1: C—H, C—C, and C—N bond activation
- 2: Reductive elimination
- 3: C—C reductive elimination
- 4: C-X reductive elimination
- 5: C—H reductive elimination
- 6: Insertion into a metal-CNHC bond
- 7: Hydrolytic ring opening
- 8: Ring expansion reactions
- 9: Miscellaneous ring openings
- 10: Miscellaneous NHC reactivity
- 11: Dissociation reactions
- 12: Summary
- Acknowledgment
- Edition: 1
- Volume: 75
- Published: March 26, 2021
- No. of pages (Hardback): 342
- No. of pages (eBook): 342
- Imprint: Academic Press
- Language: English
- Hardback ISBN: 9780128245811
- eBook ISBN: 9780323850681
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Pedro J. Perez
Pedro J. Pérez (FRSC) graduated in 1991 under the supervision of Prof. Ernesto Carmona (Univ. Sevilla, Spain). As a Fulbright Scholar, he then joined Prof. Brookhart's group at UNC-Chapel Hill (USA). He started an appointment as Assistant Professor at the Universidad de Huelva (Spain) in 1993, where he has been promoted several times until the current position of Professor in Inorganic Chemistry (since 2005). His work is devoted to the development of organometallic complexes of late transition-metal as well as their use as catalysts for transformations involving hydrocarbons, including olefin modification, carbon-hydrogen bond functionalization, and click chemistry. He has been recognized by the RSC with the 2015 Homogeneous Catalysis Award, and by the RSEQ (Spain) with the 2007 Inorganic Chemistry Award and the 2016 Gold Medal Award. In 2014 he joined the National Academy of Sciences of Spain as Corresponding Member.
Affiliations and expertise
Professor in Inorganic Chemistry, Homogeneous Catalysis Laboratory, Center for Research in Sustainable Chemistry, Universidad de Huelva, Huelva, SpainRead Advances in Organometallic Chemistry on ScienceDirect